• Title/Summary/Keyword: Organics

Search Result 561, Processing Time 0.032 seconds

Estimation of Dissolved Organics Characteristics and THM Formation from Different Organics Sources Based on Molecular Weight Distribution

  • Jeong, Kyu-Yeon;Ko, Young-Song;Lee, Yoon-Jin
    • Journal of Environmental Health Sciences
    • /
    • v.33 no.2 s.95
    • /
    • pp.158-165
    • /
    • 2007
  • 본 연구는 근원에 따른 용존 유기물의 특성을 평가하기 위해 하천수, 호소수, 하수 2차 처리 유출수의 자연수 및 Aldrich, Wako 사에서 공급된 휴믹산을 대상으로 분자량 분포에 따른 물리 화학적인 수질 특성, 생분해도, 소독, 부산물의 생성 등을 고찰하였다. SUVA를 이용해서 자연수의 생분해 가능성을 평가한 결과 호소수, 하수, 하천수 순으로 예측되었으며 이는, 실제 생분해도 실험 결과와 유사하였다 생분해 반응 중 저분자 영역대의 용존 유기물은 점차 감소하였고 반면에 고분자 영역대의 용존 유기물은 증가하였다. SMP는 전체 용존 유기물의 0.7-5.5%정도 관찰되었으며 고분자 물질을 많이 함유한 시료에서 높게 나타났다. THM 생성은 대체로 고분자 물질이 높을수록 증가하였으며 THMFP도 Wako 휴믹산을 제외한 샘플에서 이와 유사한 경향을 나타냈다.

An Acid Deposition engineering Model (공학적 산침적 모델에 관한 연구)

  • 조석연
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.9 no.E
    • /
    • pp.390-396
    • /
    • 1993
  • An acid deposition Engineering Model was developed by parameterizing the role of organics in the photochemistry and by simplifying liquid phase processes. This Engineering Model concept was implemented onto the Sulfur Transport Eulerian Model II(STEM II). The Engineering Model version of the STEM(STEM-ENG) saves the CPU time over 50 times and produces the upper and lower limit values prodicted by the original STEM II. These limits obtained by the STEM-ENG can be used to estimate the importance of organics in acid and O3 production. The STEM-ENG with 30,000 grid points can be run on any recent PCs to give a quick assessment of air quality.

  • PDF

Electron Transport Layer(ETL) in the New Organics applied to evaluate the characteristics of OLED (유기물의 ETL적용에 따른 OLED의 특성평가)

  • Kim, Tae-Yong;Moon, Dae-Gyu
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2008.04a
    • /
    • pp.37-38
    • /
    • 2008
  • In this paper, we have developed Organic light-emitting devices(OLEDs) using various thicknesses of new electron transport layer. The device structure of ITO/ 2-TNATA(15nm)/ DPVBi(40nm)/ New ETL(20nm,60nm,100nm)/ LiF(0.5nm)/Al(100nm) has been used. The operating voltage of the device was almost independent of the new ETL thickness, due to its high electron conducting property. For example, the operating voltages of the devices with 20nm and 60nm layers are almost 5V at a current density $200mA/cm^2$. The device with the new ETL shows the low turn-on of 2.5V.

  • PDF

Characteristics of Groundwater Quality in Kyungnam Province (경상남도 지역의 지하수질 특성조사)

  • 김승현;이찬원;허종수
    • Journal of Environmental Science International
    • /
    • v.7 no.6
    • /
    • pp.859-865
    • /
    • 1998
  • The analysis of groundwater quality in Kyungnam Province was conducted using monitoring results obtained during 1994. According to the analysis, most heavy metals and pesticides listed in Korean drinking water standards were not detected in Kyungnam Province groundwater, but arsonic and volatile organics such as TCE and PCE were detected. Four inorganic contaminants were detected and frequency of violating the standards was in order of $NO_3-N, F^-, As, NH_3-N$. Of organics, TCE and PCE were the only contaminants detected. TCE more frequently violated the standards than PCE. Correlation was investigated among contaminants detected in Kyungnam Province groundwater. The correlation results showed that high correlation existed among dissolved solids, hardness, and $SO_4^{2-}$.

  • PDF

Molecular Weight Distribution Characterization of Organics for the Dongbok Lake Water by Coagulation and Adsorption of Activated Carbon (동복 호소수의 응집침전 및 활성탄 흡착에 의한 용존유기물 분자량 분포 특성)

  • 정경훈;최형일
    • Journal of Environmental Science International
    • /
    • v.7 no.1
    • /
    • pp.104-111
    • /
    • 1998
  • The Dongbok lake water before and after alum coagulation and activated carbon adsorption were analyzed in terms of organic contents, molecular weight distributuin (MWD), and UV-absorbance. Dissolved organic compounds in the Dongbok lake were fractionated into three molecular size classes by gel permeation chromatography. The fractionation was reasonably successful in isolating compounds with The bulk of the dissolved carbon was present in compounds of molecular weight in the range of 3,000~10,000. Alum coagulation preferentially treated molecules of high molecular weight, which has molecules larger than 10,000. The dissolved organic carbon (DOC) removal after activated carbon adsorption was high in the Fraction B , IR . The $A_{260}$/DOC ratio after alum and activated carbon treatment the Fraction II, III. This results suggest that the organics remaining after each treatment has a trihalomethane formation potential

  • PDF

A Study on the Treatment of Organic Wastewater by Ozone Electrolysis (유기성 폐수의 오존전해처리에 관한 연구)

  • 정홍기;이태호
    • Journal of environmental and Sanitary engineering
    • /
    • v.11 no.2
    • /
    • pp.59-63
    • /
    • 1996
  • To treat certain wastewater that has alcohol and phenol, we performed the ozone electrolysis by using the titanium electrode. In this experiment, we examined decomposition voltage of organics, time for electrolysis, and removal efficiency of organics. In addition we compared the ozone oxidation electrolysis. The followings are results; 1. When it comes to the alcohol treatment in wastewater, ozone electrolysis showed higher removal efficiency than ozone oxidation or electrolysis. 2. After comparing the decomposition rate of methylalcohol, ethylalcohol, and prophylalcohol in ozone electrolysis, we knew the fact that increasing carbon number made the decomposition rate slow. 3. According to the treatment of alcohol by ozone electrolysis, decomposition voltage was 50V, time for electrolysis was three hours, and treatment acidity was neutral (pH 6.5 - 8.1). 4. Ozone electrolysis was effective to the phenol treatment. When we treated phenol by using ozone electrolysis for three hours, TOC treatment efficiency was 95%. However, ozone oxidation just showed 45% treatment efficiency.

  • PDF

Removal of Organics and Nirtogen in Wastewater Using 2 Stage A/O(RBC) Process (RBC 반응조를 이용한 2단 A/O 공정에서 유기물질 및 질소제거)

  • 최명섭;손인식
    • Journal of Environmental Health Sciences
    • /
    • v.29 no.3
    • /
    • pp.59-64
    • /
    • 2003
  • This study was conducted to investigate anoxic-RBC-anoxic-RBC process and its application to remove biologically organics and nitrogen. BOD and total-nitrogen(T-N) removal efficiencies were decreased as volumetric loading rate increased. But, the removal efficiency changes of T-N were little, as compared to BOD. Increase of internal recycle rate had few affect of BOD and T-N removal rates. Also, influent allocation(to 2nd anoxic reactor) had few affect of BOD removal efficiency rate. However, when the influent allocation rate was 30%, T-N removal efficiency was increased to 84.1 %. BOD/N ratio applied to 2nd anoxic reactor was increased to range of 3.65-4.37 as influent allocation rate increased to range 20∼35%. But, it might also cause adverse effect such as decrease of denitrification rate in excessive influent allocation rate.

Preliminary Study on the Total Dissolved Organics Measurement and Their Contribution to Conductivities at Elevated Temperature

  • Kim, Kwang-Rag;Kang, Hee-Suk;Park, Seung-Woo;Lee, Sung-Ho;Ahn, Do-Hee;Lee, Han-Soo;Hongsuk Chung;Sung, Ki-Woung
    • Proceedings of the Korean Nuclear Society Conference
    • /
    • 1996.11a
    • /
    • pp.127-132
    • /
    • 1996
  • Total organic carbon (TOC) derived from organics is one of tile possible contamination in the reactor water system and causes of pH change and high conductivity levels. Measurements of total dissolved oxidizable carbon were carried out and its contribution to conductivities at elevated temperature was studied by using tile thermodynamic equilibrium analysis in carbonic acid system. The calculated conductivities were in good agreement with tile levels observed for tile formation of carbonic acid from salicylic acid solution.

  • PDF

Effect of Coagulation Condition on Coagulation/Ultrafiltration Membrane Process (응집·한외여과 공정에서 응집조건 결정에 관한 연구)

  • Moon, Seong-Yong;Lee, Sang-Hyup;Kim, Seung-Hyun;Moon, Byung-Hyun
    • Journal of Korean Society on Water Environment
    • /
    • v.21 no.4
    • /
    • pp.379-384
    • /
    • 2005
  • In this research, coagulation was employed as the pretreatment for membrane process. The effective coagulation conditions were decided after the discussion of different coagulant doses and mixing conditions, etc. Raw water was taken from Nakdong River. The best operation occurred when G value was $230s^{-1}$ and the slow mixing lasted around 5 minutes at G value was $23s^{-1}$. To investigate the optimum coagulant dosage, the optimum organics removal was target as organic removal reduces membrane fouling effectively than particle removal. This result indicated that organics are more important causes than turbidity for membrane fouling. However, turbidity becomes an important factor after certain amount of organic matters is removed.

Application of SMBR process in food wastewater advanced treatment (SMBR을 이용한 음식폐수의 고도처리)

  • 윤용수;강광남;정순형
    • Journal of environmental and Sanitary engineering
    • /
    • v.16 no.1
    • /
    • pp.34-39
    • /
    • 2001
  • Submerged Membrane Bio-Reacter(SMBR) process was used to food wastewater treatment. From laboratory pilot-scale experiment data, it was confirmed that this process was very effective process for organics, suspended solid, and N, P treatment. It was found that BOD and COD removal rate were obtained 90% and 92%, respectively, for 150 days operation. Organics loading rate did not affect to the removal efficiency because MLSS concentration in aerobic tank was highly maintained. IN the case of first reactor operated with anoxic and second reactor operated as aerobic, T-N, T-P removal rate were obtained 93% and 95%, respectively. It was shown that removal efficiency could be maintained stable due to the complete removal of SS and sludge production decreased with increasing of sludge retention time.

  • PDF