• Title/Summary/Keyword: Organics

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Evaluation on Removal of Organics and Nutrients from Reverse Osmosis Concentrate using Activated Carbon (활성탄을 이용한 역삼투 농축수의 유기물 및 영양염류 제거 평가)

  • Joo, Sung Hee;Park, Jong Min;Lee, Yang Woo
    • Journal of Korean Society on Water Environment
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    • v.28 no.3
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    • pp.479-482
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    • 2012
  • Membrane process has been one of the widely applied wastewater treatment options, especially in field. However, one of the tricky issues in the process is to treat concentrates generated from reverse osmosis (RO) system in a manner of saving cost with maximum efficiency for treating a wide range of contaminants. Stimulated with the challenging issues, we have conducted a series of experimental studies in the evaluation for removing organics and nutrients using activated carbon. Results indicated that while powdered activated carbon (PAC) efficiently removed organics and the extent of removal was proportional to the PAC dosage, little removal of nitrogen and phosphorus was observed despite increasing the PAC dose. Interestingly, applying PAC was superior in removing organics than using granular activated carbon (GAC). These results suggest smaller particle size with higher surface area could provide greater chemical reactivity in removing organics.

Performances of Ceramic-tube and Pall-ring Upflow Anaerobic Filters Treating a Dairy Waste (세라믹튜브 및 패킹형플라스틱 여재충전 상향류식 혐기성여상에 의한 유가공 폐수처리)

  • Hur, Joon-Moo;Chang, Duk;Pae, Hyung-Suk;Kim, Soo-Young
    • Journal of Korean Society of Water and Wastewater
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    • v.14 no.1
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    • pp.37-44
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    • 2000
  • Laboratory experiments were conducted to investigate the performances of anaerobic filters packed with ceramic tube and pall-ring media treating a dairy waste. The media packing volume was 65% of effective volume of anaerobic filter. Organics removals of anaerobic filters were maintained above 80% even at an organics loading rate of $10kgCOD/m^3/d$, and this was comparable to aerobic treatment of organic wastes. Organics removals of the ceramic tube anaerobic filters were always lower than those of the pall-ring anaerobic filters due to intrinsic physical property of ceramic tube, especially lower void space which caused to clogging and entrapment of biogas, substrate transfer limitation, and irregular evolution of biogas leading to loss of solids and biomass. This was clearly observed in higher concentration of TSS in the effluent from the ceramic tube anaerobic filter despite of higher retention capacity of TSS compared with pall-ring media. Vertical distribution of organics and solids in the filters showed above 90% of organics and solids in influent were removed below 20% of reactor height, and 50% of remaining organics and solids were removed though media packing zone. Effluent quality from the anaerobic filter was heavily depended on media itself as well as suspended biomass formed below media. It is therefore concluded that the type of media played an important role in biomass accumulation arid gas-liquid-solid separation efficiency. Type of media did not affect the start-up behaviors of the anaerobic filter, and supernatant from anaerobic digested sludge showed a good performance as a seeding materials.

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Micellar Enhanced Ultrafiltration Using PEO-PPO-PEO Block Copolymer (PEO-PPO-PEO 블록공중합체를 사용한 마이셀 증진 한외여과법 (유해유기물의 가용화 및 분리특성))

  • 최영국;이동진;김정훈;김동권;이수복
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.04a
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    • pp.83-86
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    • 1998
  • 1. Introduction : Low molecular harmful organics such as 1-naphthol and phenol are widely used in industries, and pose serious environmental problems. Wastewater containing low molecular harmful organics may be ejected from various sources including metal-plating industries, circuit-board manufacturing process, photographic and photo-processing industries, refineries and metal-tailing leachate. The pollution of nation harbors, waterways and ground water resources with these organics has reached critical portions, and might also give hazardous influence on human health. Micellar enhanced ultrafiltration(MEUF) is a recently developed process to remove dissolved organics and/or heavy metals present in small or trace quantities from aqueous solution. In this system, the fatal defect is leakage of surfactants especially at low concentration below CMC(critical micelle concentration), which becomes a secondary pollution. Our group proposed to use biosurfactant and polymeric micelle to solve problems mentioned above. In this study we investigated a modified MEUF using PEO-PPO-PEO (polyethyleneoxide-polypropyleneoxide-polyethyleneoxide) block copolymers for the removal of organic solutes such as 1-naphthol and phenol from aqueous wastewater. We proposed PEO-PPO-PEO block copolymers as new surfactants for forming micelles in MEUF, and investigated the solubilization characteristics and efficiency for the removal of 1-naphthol and phenol. PEO-PPO-PEO block copolymers are, environmentally mild and safe as biosurfactants.

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Removal of Ammonia Nitrogen and Organics from Piggery Wastewater Using BACC Process-II. Effect of COD/N on Removal of NItrogen and Organics (BACC를 이용한 축산폐수의 암모니아성 질소 및 유기물의 제거 II. COD/N비가 질소 및 유기물 제거에 미치는 영향)

  • 성기달;류원률;김인환;조무환
    • KSBB Journal
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    • v.16 no.2
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    • pp.140-145
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    • 2001
  • To treat piggery wastewater containing refractory compounds including nitrogen, physical treatments using zeolite and biological processes were investigated. In biogical treatment, the removal efficiencies of organics and nitrogen in bioreador using BACC (Biological Activated Carbon Cartridge) media filled with granule activated carbon were examined. The best removal efficiencies achieved for TKN and COD(sub)cr were 82% and 53% respectively, when zeolite dosage was 300 g/L. Specific nitrogen removal ability was 3.2 mg/g at a zeolite dosage of 50 g/L, whereas specific nitrogen removal ability was 1.8 mg/g at a zeolite dosage of 300 g/L. The increased of C/N ratio resulting from the removal of nitrogen using zeolite led to an increase in removal efficiency of organics. As C/N ratio was increased to 2.0, 2.44 and 6.58 at a HRT of 48 hours in a BACC bioreactor, removal efficiencies of COD(sub)cr were increased to 53.5%, 57.4% and 80.6%. The removal efficiency of wastewater using a zeolite dosage of 399 g/L was increased by 27.1% compared to that of control treatment.

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Adsorption Behavior of Heavy Metals and Organics in the Mixed Packed Column of Scoria/Activated Carbon (스코리아/활성탄의 혼합 충전탑에서의 중금속 및 유기물의 흡착 거동)

  • Kim, Seung-Geon;Moon, Soo-Hyoung;Lee, Ho-Won
    • Applied Chemistry for Engineering
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    • v.32 no.1
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    • pp.97-101
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    • 2021
  • Adsorption properties of heavy metals and organics in the mixed packed column of scoria and activated carbon, as well as physicochemical properties and functional groups of scoria were investigated. As the mixing ratio of scoria increased, the average removal ratios of cadmium, nickel, chromium, and lead ions increased, but that of benzene and toluene decreased. The mixed packed column of scoria and activated carbon could be effectively used for the simultaneous removal of heavy metals and organics. Scoria has Si-H and Si-O functional groups, and it was confirmed that Si-O functional groups greatly contributed to the adsorption of heavy metals.

Characterization of Dissolved Organics Based on Their Origins (상수 원수에 따른 용존 유기물의 특성 평가)

  • 허준무;박종안;장봉기;이종화
    • Journal of Environmental Science International
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    • v.8 no.3
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    • pp.337-347
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    • 1999
  • This study was carried out to evaluate the characteristics of dissolved organics based on their origins, which were divided into two categories. The first group consisted of river, lake and secondary sewage treatment effluent, which were chosen as representative of their origins. The second group were artificial samples which were made of AHA(Aldrich humic acids) and WHA(Wako humic acids). Physicochemical characteristics, biological degradability and THMEP(trihalomethane formation potential) of the samples were analysed based on the AMWD(apparent molecular weight distribution). Large portion of dissolved organic carbon(DOC) in the river and lake samples was comprised of LMW(low molecular weight), which that of AHA and WHA was HMW(high molecular weight). The DOC of the lake was evenly distributed in the all range of molecular weight. The river, lake and secondary treated effluent have lower ultraviolet(UV) absorbance at 254nm, and have a higher amount of humic acids. Higher absorbance of humic acids means that aliphatic bond and benzenoid type components that absorb UV light were contained in these kind of humic acids. It was expected that lake sample was the most biodegradable in the different samples investigated, and in order of secondary sewage treatment effluent, river, WHA and AHA based on the result of determination of specific ultraviolet absorbance(SUVA). Biodegradability showed similar result except for AHA, while dissolved organics in the range of LMW decreased during the biodegradability test, and on the contrary those of HMW increased. Production of the SMPs(soluble micobial products) was observed during humicfication of dissolved organics and the SMPs were higher production of the SMPs. THM formation was high in the samples containing HMW and similar tendency was shown in the THMEP(trihalomethane formation potential), except for WHA.

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Synthesis and Characterization of Organo-modified Montmorillonite by Ion-exchange Method (유기물로 수식된 몬트모릴로나이트 제조 및 특성조사)

  • Kim, Jae-Myung;Yoo, Jung-Whan;Choi, Eui-Seok;Lee, Sung-Min;Kim, Hyung-Tae
    • Journal of the Korean Ceramic Society
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    • v.41 no.1
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    • pp.41-44
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    • 2004
  • Hydrophilicity and hydrophobicity of pottery bodies can be controlled via chemical substitution of layered clay with hydrophilic and hydrophobic organics. In this study, organo-clay nanocomposites were prepared by ion-exchange of montmorillonite with dodecylamine and hexadecylamine, respectively. Substitution sites of organics and the interval changes of layered materials are characterized by FT-IR and WAXD and organics amounts loaded and water comtents contained by C/S analysis and TG-DSC. The organics were selectively intercalated so that increase layer interval from 12${\AA}\; to\;16{\AA}$. Organo-modified clay is changed to more hydrophobic comparing to clay itself.

A Study on the Ozonation of Organic Materials in Sewage and Waste Water (오존을 이용한 오 .폐수처리에 관한 연구)

  • 황상용;이규성;김병석
    • Journal of environmental and Sanitary engineering
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    • v.6 no.1
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    • pp.103-108
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    • 1991
  • Visibility studies are conducted in oxidizing organic compounds with ozone to investigate the oxidation in the waste and sewage water. While the ozone has been used as one of the major oxidation of the waste and sewage water, it is not effective to distroy the polluted organic compounds with the practical concentration in waste water treatment. The result are shown follows ; 1. Upon oxidizing organic compound with ozone, the former is much oxidized under three meters and the latter under the ABS waste water. 2. In case of being oxidized organics waste water with ozone codis, much removed under medicine and chemical waste water than anothers of primary treatment process. 3. The final treated waste water of oxidizing organics is higher than that of filtered water or sedimented water. Specially in organics waste water the colority after oxidizing decrease from 95% to 99.9% this suggests that any organic compounds produced during ozonation night be dissdved in the final treated waste water.

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Electron Transport Layer(ETL) in the New Organics applied to Red phosphorescent organic light-emitting devices (새로운 유기물질을 ETL로 사용한 인광 RED 유기발판소자)

  • Kim, Tae-Yong;Moon, Dae-Gyu
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.04a
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    • pp.76-77
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    • 2009
  • In this paper, We have studied Electron Transport Layer(ETL) in the New Organics applied to Red phosphorescent organic light-emitting devices. The structure of ITO/2-TNATA(15nm)/CBP;$Ir(piq)_3$/DPVBi(30nm)/New ETL(60nm)/LiF(0.5nm)/Al(100nm) has been used, measured changing doping concentration of EML. The results of OLED turn-on voltage at 2.2V, and Maximum Luminance at 2.8V was $1000cd/m^2$. This high luminance at low voltage results from a high electron. conduction of the new electron transport layer.

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The Removal Rates of the Constituents of Litters in the Littoral Grassland Ecosystems in the Lake Paldangho I. Organics (팔당호 연안대 초지생태계에서 낙엽 구성성분의 유실률 I.유기물)

  • 심규철;강경미;장남기
    • Asian Journal of Turfgrass Science
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    • v.10 no.2
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    • pp.143-150
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    • 1996
  • The removal rates of gross production and organic matters were investigated in the Lake Paldangho. In 1995 and 1996, soils and litter sarraples were collected and annual mean production and removal rates were calculated. Communities in the Lake Paldangho were Phragrnites communis, Miscanthus sacchariflorus, Typha aegustata and Scirpas tahernaemoutani. Removal constants of aquatic plant communities estimated by the mathematical theoretical models, were 0.826, 0.567, 0.571 and 0.751, respectively. The durations of reaching half of initial organic amounts were 0.839 yeras, 1.221 years, 1.213 years and 0.922 years respectively at the steady state of removal and accumulation for organics For organics, the rapidity of removal were more speedy P. communis, S.tahernaemontani, T. augustata, M sacehariflorus in order. The times needed for 99% removal were 6.051 years, 6.651 years, 8.752 years and 8.811 years, respectively. Key wotds:Gross production, Organic matters, Lake Paldangho, Phragmites communis, Mis-ca ethus sacchariflorus, Typha angustata, Scirpus tahernaemoutani., Removal constants.

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