• Title/Summary/Keyword: Organic phosphorous

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Nutrients removal enhancement using a modified rotating activated bacillus contactor (RABC) process (수정 RABC 공정을 이용한 영양염류 제거능 제고에 관한 연구)

  • Kim, Sunhee;Kim, Donghwan;Jang, Giung;Kim, Eung-Ho
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.1
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    • pp.99-104
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    • 2016
  • This study was performed to develop a new process technology for advanced wastewater treatment using a modified Rotating Activated Bacillus Contactor (RABC) process that adopts anoxic-oxic suspended biomass tanks to enhance nutrients removal. A modified lab-scale RABC process was applied to examine its applicability and to obtain the design factors for the optimum operation of the system. The modified RABC process showed a little more stable and high nutrients removal efficiency than the prototype RABC process: about 70% of nitrogen and 55% of phosphorous removal when the low organic loading (influent COD 200mg/L). However, the processing efficiency of nutrients removal rates was enhanced to great extent when high organic loading: nitrogen 90% and phosphorous 85% (influent COD 500mg/L). High organic loading stimulated extremely good biomass attachment on the reticular carrier RABC stage and the excellent nutrients removal, nevertheless with almost no offensive odor.

Effect of Application of Organic Fertilizer on the Growth of Korean Lawngrass(Zoysia matrella L. Merr.) (유기질비료의 시용이 한국잔디(Zoysia matrella L. Merr.)의 생육에 미치는 영향)

  • 함선규;이정재;김인섭
    • Asian Journal of Turfgrass Science
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    • v.7 no.2_3
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    • pp.61-66
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    • 1993
  • This experiment was carried out in order to study effect of organic fertilizer on the growth of Korean lawngrass(Zoysia matrella L. Merr.) and the change of soil chemical characteristics. Results obtained are summarized as follows: l. Organic fertilizer was appropriate for base-dressing in the establishment of turfgrass by means of sod. 2. Chlorophyll contents in mixed application plot of complex organic fertilizer were more abundant than that in single application plot of organic fertilizer. 3. The yield of dry weight in single application plot of organic fertilizer was greater about 40% than that in control plot. 4. As a whole, the growth of Korean lawngrass in mixed application plot of complex and organic fertilizer was more greater than that in single application plot of complex fertilizer. 5. Application of organic fertilizer promote effectiveness of available phosphorous in soil.

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A Study on the Enhancement of Soil Fertility in the Reclaimed Land for Growing Tobacco (연초 재배를 위한 개간지 토양의 비옥도 증진에 관한 연구)

  • 정훈채;조성진
    • Journal of the Korean Society of Tobacco Science
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    • v.2 no.1
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    • pp.37-52
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    • 1980
  • Two-year experiment was conducted to investigate the effect of phosphorous, lime, increased compost, and/or boron application on the yield and quality of leaf tobacco growm in the results are summarized as follows; 1) Compared to the conventional treatment, plants grown in the treated plots in the second year showed much better growth and their yield components such as leaf area index and unit leaf weight were much greater. 2) At the end of first year crop, the pH and amount of exchangeable cations in the treated plots reached those in mature soil, but the amount of organic matter and of available phosphorous were still below those of the mature soil. Application of additional compost was more effective in enhancing soil fertility than was additional phosphorous application. 3) The yield of tobacco grown in the second year was 15-20% higher in the treated plots, compared to conventional plot, with high statistical significance. Though the quality of leaf tobacco was not significantly different among treatments, the increase of 3-7% was obtained in the treated plot. The highest total income(yield x price/kg) came from the plot treated with additional compost and phosphorous application (adjusted at 3% level on the basis of phosphorous absorption coefficient), which produced 34% more than the conventional plot.

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The Application of Non-phosphorous AEC Program in Cooling Water Systems of Petrochemical Industry

  • Li, Dagang;Hong, Mike;He, Gaorong
    • Corrosion Science and Technology
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    • v.7 no.1
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    • pp.16-21
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    • 2008
  • A non-phosphorous program employing an alkyl epoxy carboxylate (AEC) has been successfully applied to petrochemical and other large industrial open recirculating cooling water systems. AEC is a patented non-phosphorous calcium carbonate scale inhibitor that has demonstrated better scale inhibition abilities than traditional organic phosphonates. In addition to its antiscalant properties, AEC inhibits carbon steel corrosion when used at high dosages. AEC can be combined with zinc to form a non-phosphorous program with very low levels of phosphate to provide an environmentally acceptable program. In actual applications, the total phosphate developed in the cooling system from cycling the makeup is below 1 ppm as $PO_4$. This level has complied with the highest standards of wastewater discharge limitations. The performance of two AEC/Zinc applications is reviewed. In both cases excellent corrosion and scale control were achieved with AEC/Zinc programs. One case history details the performance with a low hardness water (100 ppm calcium, as $CaCO_3$) operating at 8-10 cycles of concentration. The corrosive nature of the water and the long retention time of the system stressed both the corrosion and scale control capabilities of the program. The second case history demonstrates the performance of the program with a moderate hardness water (400-600 ppm calcium, as $CaCO_3$), but under harsh conditions of high temperature and low flow. The AEC/zinc combination has been found to be highly effective in controlling the corrosion of ferrous metals. AEC can provide good corrosion inhibition at high concentrations, while zinc is known to be an excellent cathodic inhibitor. The combination of the two inhibitors not only provides a synergistic blend that is effective over a wide range of operating conditions, but also is environmentally friendly.

Physico-chemical properties between organic and conventional kiwifruit orchards in Korea

  • Cho, Y.;Kim, B.;Cho, H.;Jeong, B.
    • Korean Journal of Organic Agriculture
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    • v.19 no.spc
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    • pp.242-246
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    • 2011
  • Organic kiwifruit orchard soils were compared with conventional ones in Korea. Soil structure of organic soil had higher gaseous and liquous phase as well as soil porosity in the surface soil. Although the nutritional level of each orchards were quite different among soils, the analysis of both system revealed that organic kiwifruit orchard soil had similar or even higher nutrient level (N and organic matter content in surface soil) compared to conventional ones. The organic matter content of deep soil also had the high tendency in deep soil of organic soil. Higher level of nitrogen in organic surface soil is presumably due to the excessive application of organic compost and liquid fertilizer rather than the contribution by grasses such as green manure. Available phosphorous level of organic system was quite high but similar in surface soil of both system, compared to the recommended level. Potassium, calcium and magnesium levels were also enough in organic kiwifruit orchard soils.

Radical Addition Reaction of Phosphorous based Flame Retardant with End Groups of PET (1) - Reaction of Bisphenol A bis(diphenyl phosphate) - (PET 말단에 대한 인계난연제의 라디칼계 부가반응 (1) - 비스페놀에이비스다이페닐포스페이트의 반응 -)

  • Kim, Min-Kwan;Ghim, Han-Do
    • Textile Coloration and Finishing
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    • v.24 no.1
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    • pp.33-38
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    • 2012
  • In this study, to increase flame retardation of poly(ethylene terephthalate) (PET) in burning, bisphenol A bis(diphenyl phosphate) (BDP), a well known flame retardant containing phosphorous, was reacted on end groups of PET by radical pathway. End-capping mechanism of PET with BDP was suggested and confirmed by spectroscopic and thermal analysis. From 400 MHz $^{31}P$ solid state FT-NMR spectrum of end-capped PET (PET-BDP), phosphorus spectra peak in BDP was found at ca. -20 ppm. Furthermore, P-C bond stretching vibration peaks were found ca. $600cm^{-1}$ in FT-IR spectrums of PET-BDP. These results showed that BDP can be chemically added on end groups of PET by our method. Thermal characteristics of pure PET (pPET) and PET-BDP were measured and evaluated by TGA analysis. There was not significant changes in thermal characteristics of PET-BDP compared to that of pPET.

Radical Addition Reaction of Phosphorous based Flame Retardant with End Groups of PET (2) - Reaction of Resorcinol bis(diphenyl phosphate) - (PET 말단에 대한 인계난연제의 라디칼계 부가반응 (2) - 리소시놀비스다이페닐포스페이트의 반응 -)

  • Kim, Min-Kwan;Sohn, Kwang-Ho;Ghim, Han-Do
    • Textile Coloration and Finishing
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    • v.24 no.1
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    • pp.39-44
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    • 2012
  • To improve flame retardation of poly(ethylene terephthalate) (PET) against burning, resorcinol bis(diphenyl phosphate) (RDP), phosphorous containing flame retardant, was incorporated into PET backbone by radical reaction pathway. Radical endcapping of PET with RDP was confirmed by spectroscopic and thermal analysis. From 400 MHz $^{31}P$ solid state FT-NMR spectrum of PET with RDP (PET-RDP), phosphorus spectra peak in RDP was found at ca. -10 ppm. Furthermore, P-C bond stretching vibration peaks were found ca. $530cm^{-1}$ in FT-IR spectrums of PET-RDP. These results indicated that RDP can be chemically bound at the ends of PET by radical addition method. Thermal characteristics of pure PET (pPET) and PET-RDP were measured and evaluated by TGA thermal analysis. There was not significant changes in thermal characteristics of PET-RDP compared to that of pPET.

Synthesis of Blue Emitting Materials for Organic Light Emitting Device (유기발광디바이스용 청색발광재료의 합성)

  • Chung, Pyung Jin;Cho, Min Ju
    • Applied Chemistry for Engineering
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    • v.16 no.6
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    • pp.755-759
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    • 2005
  • This study was based on organic electroluminescence display. Especially, DPAVBi, AVBi and DPVBi for the emitting materials were synthesized by Wittig, Wittig-Horner reaction. This reaction was conducted between phosphorous ylide and 4-(diphenylamino)benzaldehyde, 9-anthraldehyde and benzophenone. The structural property of reaction products were analyzed by FT-IR, $^1H-NMR$ spectroscopy and thermal stability, reactivity and PL property were analyzed by melting point, yield and emission spectrum, respectvely. The photoluminescence spectra of a pure DPAVBi, AVBi and DPVBi were observed at approximately 445nm, 484nm and 450nm, respectively. In this study, it was known that DPAVBi, AVBi, DPVBi had a different reaction properties according to stability of ${\alpha}$-position carbonyl group of the aldehyde, ketone.

Comparison of Soil Physico-chemical and Microbial Characteristics in Soil of 'Niitaka' Pear Orchards between Organic and Conventional Cultivations (유기농법과 관행농법에 의해 재배한 '신고'배 과원 토양의 물리화학적 및 미생물학적 특성 비교)

  • Choi, Hyun-Sug;Li, Xiong;Kim, Wol-Soo;Lee, Youn;Jee, Hyeong-Jin
    • Korean Journal of Organic Agriculture
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    • v.19 no.2
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    • pp.229-243
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    • 2011
  • Consumers' interest and government's support for the fruits rapidly increased organic fruit productions. This study was examined to compare the soil physicochemical and microbial properties of orchards soil in conventionally and organically management systems. Organic cultivation had lower soil bulk density, solid phase, and penetration resistance than the conventional cultivation. Soil pH and organic matter contents increased from March to August, and the values were greater in the organic cultivation than the conventional cultivation. Total nitrogen (N) and phosphorous concentrations decreased from March to August, and the organic soils had greater N but lower phosphorous concentrations than the conventional soils. Soil microbial carbon biomass increased 36% and 15% for organic and conventional cultivations, respectively, from March to August. Soil microbial N biomass was greater in June than March or August, and the organic cultivation had a greater biomass N compared to the conventional cultivation. Soil dehydrogenase and chitinase activities were greater in June than in March or August. ${\beta}$-glucosidase activity declined in both cultivations, while the phosphatase activity increased. Organic cultivation had greater enzyme activities in March, June, and August, except for the acid phosphatase activity in June.