• Title/Summary/Keyword: Organic media

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Mobility of silver nanoparticles (AgNPs) and oxidative degradation of endocrine disrupting chemicals by saturated column experiments (포화컬럼실험에서 산화공정을 적용한 내분비계 장애물질의 제거 및 은나노물질의 거동 연구)

  • Kim, Yejin;Heo, Jiyong
    • Journal of Korean Society of Water and Wastewater
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    • v.32 no.6
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    • pp.499-505
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    • 2018
  • We applied column experiments to investigate the environmental fate and transport of silver nanoparticles(AgNPs) in fully saturated conditions of porous media. These column experiments were performed to emphasize oxidation method with $H_2O_2$ concentration and acidic conditions. The mobility of AgNPs was decreased with the increasing ionic strength that the surface charge of AgNPs(zeta potential) was neutralized with the presence of positive ions of $Na^+$. Additionally, it was also affected due to that not only more increased aggregated size of AgNPs and surface charge of quartz sand. The decreased breakthrough curves(BTCs) of bisphenol-A(BPA) and $17{\alpha}$-ethynylestradiol(EE2) were removed approximately 35.3 and 40%. This is due to that endocrine disrupting chemicals(EDCs) were removed with the release of $OH{\cdot}$ radicals by the fenton-like mechanisms from acidic and fenton-like reagent presenting. This results considered that higher input AgNPs with acidic conditions is proved to realistic in-situ oxidation method. Overall, it should be emphasized that a set of column experiments employed with adjusting pH and $H_2O_2$ concentration in proved to be effective method having potential ability of in-situ degradation for removing organic contaminants such as BPA and EE2.

Anemarrhena asphodeloides Extract Inhibits the Mycelial Growth of Magnaporthe oryzae and Controls the Rice Blast Disease

  • Joo, Myoung Ho;Yeo, Yu Mi;Choi, Pil Son;Lee, Jae Hyeok;Yang, Kwang-Yeol;Lee, Young Jin
    • Korean Journal of Plant Resources
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    • v.31 no.6
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    • pp.695-703
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    • 2018
  • Previously, we have reported a plant extract isolated from Lysimachia foenum gracum Herba as a new environment friendly biopesticide that has the mycelial growth inhibition effect on Magnaporthe oryzae, the pathogenic fungus of the rice blast disease. For the finding of additional biopesticide candidate, we tested the mycelial growth inhibitory effects about 700 species of plant extracts on PDA media. Among them, the extract of Anemarrhena asphodeloides showed prominent inhibitory effect of which $IC_{50}$ was $139.7{\mu}g/ml$. Mycelial radii of M. oryzae were measured on PDA medium containing the four organic solvent fractions isolated from total extract from A. asphodeloides. Ethyl acetate fraction showed the impressive inhibitory effect of $IC_{50}$, $54.12{\mu}g/ml$. In the subsequent rice field test for the total extract of A. asphodeloides, we obtained encouraging 62.0% control rate of rice blast disease without any phytotoxicity. It is almost equivalent to that of chemical pesticides implying the applicability of the extract as a new biopesticide. In further study, the analysis of active ingredients of the extract would be necessary for the development of a new biopesticide and for the verification of cellular mechanism by which the mycelial growth of M. oryzae inhibited.

Preparation of Simultaneous Analysis Method of PAHs (Polycyclic Aromatic Hydrocarbons) and Monitoring PAHs in Groundwater (지하수 중 다환방향족탄화수소류(PAHs, Polycyclic Aromatic Hydrocarbons)의 동시분석법 마련 및 수질실태조사)

  • Kim, Deok Hyun;Park, Sunhwa;Yoon, Jong Hyun;Choi, Hyojung;Kim, Moonsu;Jeong, Do Hwan;Kim, Young;Kim, Hyun-Koo
    • Journal of Soil and Groundwater Environment
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    • v.25 no.4
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    • pp.67-76
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    • 2020
  • Polycyclic aromatic hydrocarbons (PAHs) are organic compounds that tend to persist in environmental media for a long period of time. This work presents a 2-year monitoring study of occurrence of three PAHs (benzo(a)pyrene, naphthalene, and fluoranthene) in groundwater. The groundwater samples were collected from 106 sites of nation's groundwater quality monitoring network and analyzed by simultaneous analysis method to quantify the concentrations of the PAHs. Benzo(a)pyrene was not detected in all samples. Naphthalene and fluoranthene concentrations ranged from not detected to 12.8 ng/L and not detected to 10.5 ng/L with their detection frequency being 57.8 and 4.2%, respectively. The concentrations of PAHs in ground- and drinking waters are not currently regulated in Korea, but the concentration levels of naphthalene and fluoranthene found in this work were lower than the regulatory limits of other countries (naphthalene 0.001~0.07 mg/L, fluoranthene 0.001~1.4 mg/L). The monitoring result of this study revealed that PAHs exist as trace amounts in domestic groundwater, however continuos monitoring is necessary to protect groundwater from PAHs contamination with growing industrialization and urbanization.

Separation of Uranium(VI) and Vanadium(V) from Sulfuric Acid Media by Amine Based Extractants through Liquid-liquid Extraction Technique (황산 용액으로부터 아민계 추출제의 액-액 추출법에 의한 우라늄(VI)과 바나듐(V)의 분리)

  • Jeon, Jong-Hyuk;Lee, Jin-Young;Kim, Joon Soo;Yoon, Ho-Sung;Jyothi, Rajesh Kumar
    • Resources Recycling
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    • v.30 no.4
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    • pp.64-74
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    • 2021
  • The importance of uranium metal is growing day by day in light of its increasing global demand for fulfilling societal needs through atomic power programs. Considering the high demand for uranium, it is necessary to find innovative hydrometallurgical techniques to separate uranium from other associated elements, especially vanadium. This study deals with the separation of uranium(VI) and vanadium(V) from sulfuric acid solutions using commercial amine-based extractants diluted in kerosene. The concentrations of the sulfuric acid solutions ranged from 0.005 to 5.0 mol/L. The effect of extractant concentration ranging from 0.005 to 0.2 mol/L was studied. The temperature was maintained at 25℃ and the experiment was performed for 30 min at an aqueous: organic phase ratio of 1 (A:O = 1:1). The calculated separation factors (SFs) are presented and comparisons are made among all the experiments.

COVID-19 Discourse and Social Welfare Intervention through Online News Big Data: Focusing on the Elderly Living Alone (온라인 뉴스 빅데이터를 통한 코로나 19 담론과 사회복지 개입방안: 독거노인을 중심으로)

  • Yeo, Jiyoung
    • 한국노년학
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    • v.41 no.3
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    • pp.353-371
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    • 2021
  • The purpose of this study is to provide clues to social welfare policy making by revealing discourse on social intervention and response based on big data on elderly living alone in the COVID-19 situation. Keyword analysis, network analysis, and topic analysis were utilized to explore the ways in which news media have portrayed challenges facing older individuals and the ways in which the central and local government as well as private organization have responded to them. Results are as follows. First, networks(degree, closeness, betweenness) were formed around region, delivery, society, support, and vulnerability, suggesting an increased demand for economic assistance and social support as well as stronger service delivery systems. Second, key topics derived included "establishing public delivery systems", "establishing local networks", "Managing care gap", "Establishing a private economic support system", and "Establishing service organization system". Based on the research results, discourse on the organic role of government, communities and the private sector has been presented, suggesting policy and practical implications by proposing a discussion on how to intervene for elderly living alone in disaster situations such as COVID-19.

Development of Passive Samplers for Volatile Organic Compounds (휘발성 유기화합물용 수동식 시료채취기 개발)

  • Miyeon, Jang;Gwangyong, Yi;Hyeonjin, Jeon
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.32 no.4
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    • pp.359-370
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    • 2022
  • Objective: This study is intended to design a commercially available passive sampler and conduct performance test on its use as a media for evaluating a working environment. Methods: This study was conducted to select adsorbents, design models, and evaluate storage stability and sampling rates for the development of new types of passive samplers. Results: The impurity detection, adsorbent capacity and breakthrough volume of five types of activated carbon were tested for selection of an adsorbent. One product was selected in consideration of the efficiency of purchase. A number of passive samplers were designed in a radial style and a badge style using plastic as a material. The final two prototypes were made using molds or 3D printing. For the storage stability evaluation, samples were stored at different temperature for 1~21 days and then analyzed. Most of the chemicals had excellent storage stability when refrigerated. However, some chemicals such as dichloromethane and methyl ethyl ketone need to be analyzed as soon as possible after sampling. Conclusion: In this study, new types of passive samplers for 66 chemical compounds were developed. The evaluation of storage stability and sampling rates showed different results depending on the properties of the chemical substance. For some chemicals such as methyl ethyl ketone and dimethylformamide, activated carbon is inappropriate as an absorbent. In future studies, additional experiments are required on chemicals that are difficult to collect with activated carbon.

Analysis of the Theme Song of Musical Film "Aladdin" Focusing on the Theme Song 'Speechless' (뮤지컬 영화 "알리딘"의 테마곡 분석 - 테마곡 'Speechless'를 중심으로)

  • Si, On-Sung;Min, Kyung-Won
    • Journal of Korea Entertainment Industry Association
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    • v.14 no.7
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    • pp.263-273
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    • 2020
  • In 2019, Disney's musical film "Aladdin" was newly introduced with Princess Jasmine's theme song "Speechless," which was not featured in the animation "Aladdin" in 1992. Written as a theme song, "Speechless" expresses Princess Jasmine as a self-reliant, enterprising and dignified woman. The song made the change in Princess Jasmine's character very articulate. She has developed herself as an active and enthusiastic character from a rather passive and reserved figure. The musical film "Aladdin" has drawn much attention and love from many audiences with its own narrative and original songs, but the addition of a new theme song "Speechless", which was not in the animation in 1992, made the musical film "Aladdin" even more powerful and meaningful. The study examined the organic relationship between the musical features and narratives of the newly included theme song 'Speechless' in the musical film Aladdin. Through the analysis of the six scenes that include the musical features of the theme song "Speechless," the study looked at how the relationship between music and narratives had an influence on cinematic expression.

Characteristics of Doenjang (Soybean Paste) Fermented with Multiple Starters Including Tetragenococcus halophilus

  • Ji Yeon Yoo;Dong Sin Kim;Tae Jin Kim;Yun Ji Kang;Min Jae Kim;Jeong Hwan Kim
    • Microbiology and Biotechnology Letters
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    • v.51 no.2
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    • pp.147-156
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    • 2023
  • Tetragenococcus halophilus CY54, an isolate from jeotgal, grows best in media with 5% NaCl and can grow at 18% and higher salt concentration. Three different doenjang samples were prepared with multiple starters including T. halophilus CY54. TBZA doenjang was prepared with T. halophilus, Bacillus subtilis, Zygosaccharomyces rouxii and Aspergillus oryzae. BZA doenjang was prepared with the same 3 starters except T. halophilus. KACC doenjang was prepared with a single starter, B. subtilis KACC16750. During 16 weeks of fermentation at 25℃, the viable counts were maintained in the range of 7-8 log CFU/g in all 3 samples. As fermentation progressed, pH decreased and titratable acidity (TA) gradually increased. Crude protein contents decreased slightly. TBZA doenjang showed higher amino-type nitrogen (ANN) and volatile basic nitrogen (VBN) contents, and KACC doenjang showed higher ammonia-type nitrogen (AMN) content. TBZA doenjang showed higher fibrinolytic and protease activity than other doenjang samples. Metabolites analyses by GC/MS showed that doenjang samples were separated from each other by partial least squares-discriminant analysis (PLS-DA) analysis. Seventeen major metabolites involved in the differences between samples were identified and they included organic acids, amino acids, sugars, fatty acids and alcohols. TBZA doenjang showed higher contents for most metabolites responsible for flavor and taste of fermented foods including doenjang. These results showed that T. halophilus could be useful as a starter for doenjang and can improve the product quality by accelerating the fermentation processes.

Effects of the Recirculation Port Location on Treatment Efficiency of an Anaerobic Hybrid Reactor Consisted of a Fluidized Bed and a Packed Bed (유동상과 충전상이 결합된 혐기성 혼성 반응조에서 순환수의 인출지점이 처리효율에 미치는 영향)

  • Kim, Seong-Yong;Park, Soo-Young;Cho, Kwang-Myeung
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.11
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    • pp.1935-1944
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    • 2000
  • This research was performed to investigate the effects of the location of recirculation port on the wastewater treatment efficiency of an anaerobic hybrid reactor consisted of a fluidized bed and a packed bed. The recirculation port was located either at the top of the packed bed (Reactor 2) or above the fluidized bed (Reactor 1). Media for the fluidized bed and the packed bed were granular activated carbon and Pall ring-type plastic media. respectively. At organic loading rates(OLR) up to $6.2kg\;COD/m^3-day$. Reactor 2 showed somewhat better performance than Reactor 1 with COD removal efficiencies of 85.0-95.2%. The COD removal efficiencies of the reactors drastically deteriorated at OLRs above $6.2kg\;COD/m^3-day$, and the tendency was more severe for Reactor 1 than for Reactor 2. Eventhough the two reactors showed similar effluent SS concentrations at OLRs below $3.6kg\;COD/m^3-day$, Reactor 2 showed higher effluent SS concentrations than Reactor 1 at OLRs above $5.3kg\;COD/m^3-day$. Reactor 2 was stabler than Reactor 1 with a methane production rate of $5.5kg\;COD/m^3$-day at the OLR of $13.3kg\;COD/m^3-day$. An abrupt increase in effluent volatile acid concentration was observed at the OLR of $6.2kg\;COD/m^3-day$ for Reactor 1 and $7.1kg\;COD/m^3-day$ for Reactor 2. and the increase was greater in Reactor 1. In conclusion. the range of OLR for adequate treatment in the hybrid reactor was determined according to the location of the internal recirculation port. It is more desirable for higher OLRs to locate the recirculation port at the top of the packed bed in order to utilize the whole volume of the reactor.

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Treatment Characteristics of Soil Clothing Contact Oxidation Process using Bio-media (생물담체를 충진한 토양피복 산화접촉공정의 하수처리특성)

  • Kim, Hong-Jae;Kang, Jae-Hee;Lee, Ki-Seok;Motoki, Kubo;Kang, Chang-Min;Chung, Seon-Yong
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.4
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    • pp.414-419
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    • 2005
  • This study was performed to compare the treatment efficiencies of two media, newly developed Bio-rock and conventional gravel, in soil clothing contact oxidation process. The composition of synthetic wastewater were $COD_{Cr}$ $150{\sim}370\;mg/L$, $BOD_5$ $150{\sim}270\;mg/L$, T-N $20{\sim}60\;mg/L$, T-P $5{\sim}25\;mg/L$, pH 7 and 2 mL/L of trace element solution. The experiment using two reactors was comparatively conducted for the flow rate of 40 L/d for 13 months, respectively. Initially Bio-rock reactor was increased to pH 12 due to $Ca(OH)_2$ with hydration of cement, but gravel reactor was dropped to pH 4 due to the degradation of organic material and nitrification. This significant pH variation deteriorated the growth and activity of microorganism. But the high pH of Bio-rock seems favorite to ammonia stripping and precipitation of phosphate. Such pH variation of Bio-rock and gravel reactors were finally stabilized to pH 8 and pH 6, respectively. The removal efficiencies of organic compounds from Bio-rock reactor were 96% of $COD_{Cr}$, 98% of $BOD_5$, 80% of T-N and 85% of T-P which stably coping against variation of influent concentration. But those of gravel reactor were 96% of $COD_{Cr}$, 96% of $BOD_5$, 42% of T-N and 40% of T-P, respectively. The Bio-rock was 2 times higher than T-N and T-P in treatment efficiency. And electron-microscopic examination showed that Bio-rock was more favorable to microbial adherence than gravel. The microbial populations were $5.2{\times}10^6\;CFU/mL$ of Bio-rock reactor compared to $2.6{\times}10^6\;CFU/mL$ in gravel reactor. In result Bio-rock was favor to microbial adherence and high treatment efficiency in spite of variation of influent concentration which had the advantages in saving running time and reducing site requirement.