• Title/Summary/Keyword: Organic media

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Organic Solvent Dyeing(III) -The Interpretation of Dyeing Behavior by Thermodynamic Parameters on Dyeing of Polyester Fiber in Alkanes as Dyeing Media- (유기용매염색(III) -Alkane류를 염색매체로 한 PET의 염색에 있어서 열역학적 파라미터에 의한 염착거동 해석-)

  • 김태경;임용진;조광호;조규민
    • Textile Coloration and Finishing
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    • v.12 no.1
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    • pp.52-60
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    • 2000
  • In the prior studies, we reported that the dye uptakes of C. I. Disperse Violet 1 on polyester fiber in hexane and cyclohexane were higher than those in the other solvents, as the number of carbon atoms of alkanes decreased, the dye uptake increased, and the logarithmic plot of the dye uptakes vs. the solubilities of the dye showed that the dye uptakes are inversely proportional to the solubilities. In this study, for Interpretation of dyeing behavior of C. I. Disperse Violet 1 on polyester in alkanes, the thremodynamic parameters of dyeing, such as standard affnity, heat of dyeing(enthalpy change), entropy change, diffusion coefficient, and activation energy of diffusion, were obtained from isotherms and dyeing rates at different temperature. As the number of carbon atoms of alkanes increased, the standard affinity decreased, but the heat of dyeing(enthalpy change) and the entropy change showed larger negative values. These results mean that as the number of carbon atoms of alkanes increases, the dye uptake decreases, but both the fraction of the dye molecules dyed at relatively highly aligned or compact region of polyester fiber and the regularity of dye aggregates in the fiber become increased. As the number of carbon atoms of alkanes increased, the diffusion coefficient decreased, but the activation energy of diffusion increased. In the alkane of larger number of carbon atoms, because the solubility of the dye is higher, the desorption rate of the dye is faster and the diffusion coefficient is smaller than those in the smaller alkanes. But the energy required to separate the dye molecules from the alkane molecules is much higher because the interaction between the alkane molecule and the dye molecule become strong with the number of carbon atoms.

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The Syntheses of Phthalocyanine Hybrid Derivatives and Their Properties (프탈로시아닌계 하이브리드 유도체들의 합성 및 이의 특성에 관한 연구)

  • Kim, Seong Jin;An, Ba Ryong;Lee, Gun-Dae;Park, Seong Soo
    • Applied Chemistry for Engineering
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    • v.24 no.3
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    • pp.266-273
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    • 2013
  • Phthalocyanine (Pc), porphyrin, subphthalocyanine, and perylene compounds can be applicable to the fields of optical storage media, organic solar cell, LCD, PDP, semiconductor, and counterfeit money detection etc. In this study, phthalocyanine hybrid derivatives were synthesized by cross-linking perylene, subphthalocyanine, or porphyrin to the main frame of Pc. Absorbtion band of two different wavelengths appeared simultaneously in the phthalocyanine hybrid derivatives. Compared to phthalocyanine, the solubility was enhanced and the degree of Q-band shift was changed according to the kind of substitute compounds. The chemical and optical properties of samples were analyzed using FT-IR, $^1H-NMR$, and UV-Vis spectroscopic techniques.

The Comparative Study on the Residential Conditions and the Community Consciousness of the National Rental Housing (국민임대아파트단지의 거주실태 및 커뮤니티의식 비교 연구)

  • Lee, Won-Young;Kang, Soon-Joo
    • Journal of the Korean housing association
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    • v.19 no.2
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    • pp.19-30
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    • 2008
  • The purpose of the study is to provide basic data to be useful for living environment of National Rental Housing, through comparative analysis of residential conditions, community consciousness of residents, characteristics of 3 complexes, whose residents have lived more than 3 years, different in area and size. Deungchon 11 Complex in Seoul, Eui-wang Naeson Complex, and Incheon Samsan 4 Complex are chosen for the investigation and the survey and 242 copies of the questionnaire are analyzed for the final result. Analyzing the contents of the survey results are as follows those deriving conclusions and suggestions. 1) Housing and construction standards are required to reconsider for enhancing of community consciousness and housing satisfaction of residents of National Rental Housing. 2) Spending on residential move, and minimize the unnecessary expense of low-income housing need to do to promote stability. 3) Facilities and equipments for residents are needed considering barrier-free design which introduces universal design. 4) Welfare facilities such as culture space and after-school classroom for teenagers are needed. 5) By using the broadcast media actively pro-mote, various layers are encouraged moving into National Rental Housing, through the concept of housing opportunities for change. 6) In short-term, community space are need remodeling and various activity programs are developed to induce activation of community facilities. In long-term, users considering a community facility plan, actively promoting activities, methods and operating system support for the government in the continuing policy and management is needed, when the National Rental Housing are planned to build. Therefore, the organic aspects such as the development and operation of the community program as well as the physical aspects such as the community space and facilities for the active community of the National Rental Housing are constantly considered in the follow-up studies.

Antibacterial Effect of Siegesbeckia pubescens Extract against Fish Pathogenic Streptococcus iniae (희렴(Siegesbeckia pubescens) 추출물의 어병세균 Streptococcus iniae에 대한 항균활성)

  • Choi, Bo La;Cho, Eun-Ji;Lee, Myeong Jin;Lee, Seong Hyun;Kim, Chae Eun;Oh, Se Young;Kim, Kyoung-Hoon;Jeong, Chang Hwa;Lim, Eun Seo;Kim, Tae Hoon;Lee, Eun-Woo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.49 no.5
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    • pp.678-682
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    • 2016
  • Antibacterial activity of 80% methanol extract from 13 commercial herb medicines was measured against fish pathogens Streptococcus iniae, causing several diseases in various kind of fish. Siegesbeckia pubescens showed the strongest antibacterial activity against S. iniae. Methanol extract of S. pubescens was further extracted using several organic solvents having different polarity. Extract from n-hexane and ethyl acetate fraction showed strong activity. Minimal inhibitory concentration, MIC of S. pubescens extract was measured and resulted showing 8 μg/mL with n-hexane fraction and 32 μg/mL with ethyl acetate fraction against S. iniae. The growth of S. iniae was fully inhibited by adding 50 μg/mL (final concentration) of n-hexane or ethyl acetate fraction in the liquid media. It is needed that, from these results, purification and isolation of responsible active compound(s) of these activities and further study on the synergy effect using combination with commercial antibiotics against fish pathogenic bacteria.

Stuidies on Production of Nucleic acid Derivatives by Microorganisms (IV) -Effect of Culture Media on 5′-IMP Accumulation by Brevibacterium ammoniagenes- (미생물에 의한 핵산관연물질의 생산에 관한 연구(제사보) -Brevibacterium 속 세균 변리주의 5'-inosinic acid 발효 배지성분에 관하여 -)

  • Bae, Moo;Lee, Gye-Jun
    • Microbiology and Biotechnology Letters
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    • v.1 no.2
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    • pp.75-78
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    • 1973
  • Effects of nitrogen sources, supplement of vitamins and minerals on the accumulation of 5'-inosinic acid by an adenineless mutant of Brevibacterium ammoniagenes were examined. Maximal yield of 5'-inosinic acid was attained by the use of yeast extract. as organic nitrogen source Casamino acid supplemented with $Mn^{++}$, $Zn^{++}$ Ca-D-pantothenate and thiamine HCl could be subsitute for it. Subsequent experiment using the defined medium showed that the concentration of these trace element in the medium affected inosinic acid accumulation markedly. And it was found that the simulataneous addition of $Mn^{++}$ (20$\mu\textrm{g}$1). $Zn^{++}$(10$\mu\textrm{g}$1). thiamine Hcl(10mg/1) and Ca-D-pantothenate (5mg/l) to the defined medium stimulated inosinic acid accumulation, from which 7mg/ml of inosinic acid was obtained.

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Studies on the Cultural Characteristics of Cellulase Production by Roseofomes subflexibilis (Roseofomes subflexibilis로부터 Cellulase 생산을 위한 배양학적 성질)

  • Chang, Hyung-Soo
    • The Korean Journal of Mycology
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    • v.31 no.2
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    • pp.77-83
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    • 2003
  • For the purpose of utilizing cellulose resources by cellulolytic enzymes of Roseofomes subflexibilis, it's cultural conditions for the production of cellulolytic enzymes in synthetic media were investigated. The results obtained were summarized as follows : The optimum temperature and pH for the enzyme production were $30^{\circ}C$ and pH 4.0, respectively. Among the carbon sources, glucose was good for the production of cellulase. The optimum concentration of saccharose as 1.2%. As a organic nitrogen source, yeast extract was good for the mycelial growth. The optimum concentration of yeast extract as 1.5%. As a inorganic nitrogen source, $NH_{4}H_{2}PO_{4}$ was good for the mycelial growth. The optimum concentration of $NH_{4}H_{2}PO_{4}$ were 1.1%. The mineral salt of $Al_{2}(SO_{4})_{3}$ was effective and the optimum concentration was 0.1 M.

Effect of Transgenic Rhizobacteria Overexpressing Citrobacter braakii appA on Phytate-P Availability to Mung Bean Plants

  • Patel, Kuldeep J.;Vig, Saurabh;Nareshkumar, G.;Archana, G.
    • Journal of Microbiology and Biotechnology
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    • v.20 no.11
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    • pp.1491-1499
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    • 2010
  • Rhizosphere microorganisms possessing phytase activity are considered important for rendering phytate-phosphorus (P) available to plants. In the present study, the Citrobacter braakii phytase gene (appA) was overexpressed in rhizobacteria possessing plant growth promoting (PGP) traits, for increasing their potential as bioinoculants. AppA was cloned under the lac promoter in the broadhost-range expression vector pBBR1MCS-2. Transformation of the recombinant construct pCBappA resulted in high constitutive phytase activity in all of the eight rhizobacterial strains belonging to genera Pantoea, Citrobacter, Enterobacter, Pseudomonas (two strains), Rhizobium (two strains), and Ensifer that were studied. Transgenic rhizobacterial strains were found to display varying levels of phytase activity, ranging from 10-folds to 538-folds higher than the corresponding control strains. The transgenic derivative of Pseudomonas fluorescens CHA0, a well-characterized plant growth promoting rhizobacterium, showed the highest expression of phytase (~8 U/mg) activity in crude extracts. Although all transformants showed high phytase activity, rhizobacteria having the ability to secrete organic acid showed significantly higher release of P from Ca-phytate in buffered minimal media. AppA overexpressing rhizobacteria showed increased P content, and dry weight (shoot) or shoot/ root ratio of mung bean (Vigna radiata) plants, to different extents, when grown in semisolid agar (SSA) medium containing Na-phytate or Ca-phytate as the P sources. This is the first report of the overexpression of phytase in rhizobacterial strains and its exploitation for plant growth enhancement.

Treatment of Acid Mine Drainage Using Immobilized Beads Carrying Sulfate Reducing Bacteria (황산염환원균 고정화 담체를 이용한 산성광산배수 처리)

  • Kim, Gyoung-Man;Hur, Won;Baek, Hwan-Jo
    • Economic and Environmental Geology
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    • v.41 no.1
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    • pp.57-62
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    • 2008
  • The application of constructed subsurface-flow wetlands for treatment of wastewater from abandoned mines is being increased. Crushed limestone, oak chips, and mushroom composites are often employed in a bulk form, as the substrates in the bed media. Efficiency of the subsurface-flow treatment system drops with time as the hydraulic conductivity of the wetland soil decreases significantly, presumably due to chemical reactions with the wastewater. The purpose of this study is to investigate the applicability of immobilized beads carrying sulfate reducing bacteria for acid mine drainage treatment system. The ingredients of immobilized beads are organic materials such as mushroom composite and oak chips, limestone powder for a pH buffer, mixed with a modified Coleville Synthetic Brine. It was found that immobilized beads are more efficient than the bulk form for pH recovery, sulfate and heavy metal removal.

Performance Evaluation of Anaerobic Bioreactors and Effects of Ammonia on Anaerobic Digestion in Treating Swine Wastewaters

  • Lee, Gook-Hee;Seo, Jun-Won;Kim, Jong-Soo
    • Korean Journal of Environmental Agriculture
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    • v.25 no.3
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    • pp.195-201
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    • 2006
  • The operational characteristics of anaerobic bioreactors in treating swine wastewater were evaluated upto hydraulic retention time (HRT) of 1 day and organic loading rate (OLR) of $5.1kg-COD/m^3{\cdot}d$ for 200 days. The bioreactors were effective in treating swine wastewaters with COD removal efficiency of $78.9{\sim}81.5%$ and biogas generation of $0.39{\sim}0.59m^3/kg-COD_r$ at OLR of $1.1{\sim}2.2kg-COD/m^3{\cdot}d$. The two-stage ASBF anaerobic bioreactors was effective in treating different characteristics of swine wastewaters since they showed high and stable COD removal efficiency at high OLR due to effective retention of biomass by media and staging. The effects of ammonia on anaerobic digestion were investigated by operating two-stage ASBF reactors using swine wastewaters as influent without and with ammonia removal at HRT of $1{\sim}2$ days and OLR of $2.2{\sim}9.6kg-COD/m^3{\cdot}d$ for 250 days. The COD removal efficiency and biogas generation of two-stage ASBF reactors was decreased by increasing influent ammonia concentrations to 1,580 mg (T-N)/L with increasing OLR to $6.3kg-COD/m^3{\cdot}d$, while those were increased by maintaining influent ammonia concentrations below 340 mg (T-N)/L by MAP precipitation with increasing OLR to $9.6kg-COD/m^3{\cdot}d$. Initial inhibition of ammonia on anaerobic processes was observed at a concentration of 760 mg (T-N)/L and the COD removal efficiency and biogas generation dropped to 1/2 at ammonia concentration ranges of $1,540{\sim}1,870mg$ (T-N)/L. It is essential to remove ammonia in swine wastewaters to an initial inhibition level before anaerobic processes for the effective removal of COD.

Application of MBBR Process in the Activated Sludge Process (기존 활성슬러지 공정의 MBBR 공정 적용가능성 평가)

  • Park, Woon-Ji;Lee, Hae-Seung;Lee, Chan-Ki;Kim, Sung-Gun
    • Journal of Korean Society on Water Environment
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    • v.20 no.5
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    • pp.457-465
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    • 2004
  • The objective of this study is to evaluate the possibility to apply the Moving Bed Biofilm Reactor(MBBR) in the activated sludge treatment process with existing aerobic HRT. Optimal operation conditions were assumed according to the analysis of organic matter and nutrients removal efficiencies depending on loading variations. The process was operated under different conditions: RUN I(HRT=7.14hr, $I{\cdot}R=100%$), RUN II(HRT=6.22hr, $I{\cdot}R=100%$), RUN III(HRT=6.22 hr, $I{\cdot}R=150%$), RUN IV(HRT=6.22hr, $I{\cdot}R=200%$), the TBOD removal efficien cies are 88%, 88.5%, 94.6%, 97.6%, respectively. Overall TSS removal efficiency is 90%, and it is increasing in RUN IV. In the case of Nitrogen, the highest removal efficiency of 90% was observed in RUN III and RUN IV, Nitrification and Denitrification rates are 0.013-0.016kg $NH_3-N/kg$ Mv-d and 0.009-0.019kg $NO_3/kg$ Mv-d, respectively. Phosphorus removal efficiencies are 89.6% in RUN I, 91.5% in RUN II, 84.3% in RUN III, and 76.4% in RUN IV. The process under shorter SRT yields better performance in terms of phosphorus removal. It was noticed that to achieve the effluent phosphorus concentration ofless than 1mg/L and removal efficiency higher than 80%, SRT should not be longer than 10 days. Experimental result shows that HRT of 6.22 hours is suitable for this treatment process, and, as a result, the aerobic reactor including moving media and DO depletion tank have a sufficient effect to the process performance.