• Title/Summary/Keyword: Organic media

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Green synthesis of aluminum-based metal organic framework for the removal of azo dye Acid Black 1 from aqueous media

  • Jung, Kyung-Won;Choi, Brian Hyun;Lee, Seon Yong;Ahn, Kyu-Hong;Lee, Young Jae
    • Journal of Industrial and Engineering Chemistry
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    • v.67
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    • pp.316-325
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    • 2018
  • Aluminum based metal-organic framework using a di-carboxylate linker succinic acid (Al-SA MOF), are synthesized in water with minimal generation of secondary pollutants. The physicochemical properties of Al-SA MOF were examined, followed by its utility for the adsorption of Acid Black 1 (AB1) in aqueous media. Influences of key parameters such as pH, contact time, initial AB1 concentration,temperature, and selectivity on the adsorption process were assessed. A series of adsorption mechanisms are proposed, which involve electrostatic, hydrogen bonding, and hydrophobic interactions. These findings suggest that Al-SA MOF is a potent candidate in removing complex azo dyes molecules from aqueous media.

Fashion Accessory Design Using Media Art (미디어아트를 이용한 패션 액세서리 디자인)

  • JeKal, Mee;Lee, Youn-Hee
    • Journal of the Korean Society of Costume
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    • v.58 no.4
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    • pp.1-12
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    • 2008
  • The expansion of media art has not only developed the digital technology but also given lots of environmental evolution to improve various fields of design as the main topic of the 21st century. The purpose of this study is aimed at proposing the new design that integrates fashion accessaries with media art technology. This will be done by understanding the social environment in digital ages and studying technology of design based on a variety of literature about changes in our society, neo value, vision, culture and art with fundamental notion of media art. First stage for this study, put an idea into just fashion accessary design because it is not sufficient to incoporate fashion and media art technology. The presented OLED(Organic Light Emitting Diodes) in this study is a kind of display to be in a limelight in the next generation and can be applied to various field of design. media art simultaneously moved into the scope of artistic debates. As a result, we can found that the use of audiovisual introduced numerous new aspects to the conceptual and aesthetic engagement with questions of conception. Today, the presented forms of art and inter-action from the closed -circuit work to interactive media art installations to open process-exist as parallel possibilities.

Effects of Growth Regulators and Organic Nitrogen Sources on the Production of Heavy Chain Immunoglobulin G in Suspension Cultures of Transgenic Tobacco Cells

  • Shin, Joong-Han;Kim, Kyoung-Heon;Kim, Tae-Hwan;Lee, James M.;Lee, Hyong-Joo
    • Journal of Microbiology and Biotechnology
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    • v.13 no.2
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    • pp.256-262
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    • 2003
  • To enhance the production of heavy chain immunoglobulin G (HC IgG) in the suspension cultures of transgenic tobacco cells (Nicotiana tabacum), the effects of adding various cytokinins (i.e., growth regulators) and organic nitrogen sources to culture media were investigated. Four different cytokinins including kinetin, isopentenyladenine (IPA), 6-benzylaminepurine (BA), and zeatin were tested with or without dichlorophenoxyacetic acid (2,4-D), which is a typical growth regulator supplemented in the standard Murashige and Skoog (MS) medium. The productivity of intracellular HC IgG was increased by 36 and $42\%$, compared to the control, especially when IPA (2 mg/l) or BA (0.2 mg/l) was added to the media in the presence of 2,4-D, respectively. In the study of organic nitrogen sources, addition of each casein hydrolysate and tryptone to the culture media at a final concentration of 0.01 and 1 g/l, respectively. increased the productivity or he IgG as much as 68 and $67\%$, respectively, in comparison with the control, which was is MS medium without supplementation of any organic nitrogen sources. This study shows that the optimization of media composition could offer significant improvements in the production of foreign proteins in the suspension cultures of transgenic plants.

The Impact of Psychological and Environmental Factors on Consumers' Purchase Intention toward Organic Food: Evidence from Vietnam

  • NGUYEN, Dinh Toan;TRUONG, Dinh Chien
    • The Journal of Asian Finance, Economics and Business
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    • v.8 no.1
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    • pp.915-925
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    • 2021
  • The study investigates some psychological and environmental factors affecting the intention to purchase organic foods of consumers in the inner-city of Hanoi. Impact factors applied for the study include three psychological factors (health concern, environmental concern, consumer awareness of organic foods) and seven environment factors (family's opinion, friends and colleagues' opinion, influence of celebrities, expert's opinion, social status, mass media, state's encouragement). We analyzed research data from 396 consumers to measure the impacting level of these factors. The convenient sampling method was used to collect the research sample. The measurement applied a 5-point Likert scale classifying from 1-completely disagree to 5-completely agree. Based on previous studies, the research model was recommended. We had estimated the reliability of the scales through Cronbach's Alpha and composite reliability. The research data is analyzed by using Structural Equation Model method (SEM). The findings of the study suggest that psychological factors (health concern, environmental concern, consumer awareness of organic foods) had a significantly positive influence on consumer's purchase attention toward organic food. The results also revealed that environmental factors (family's opinion, friends and colleagues' opinion, influence of celebrities, expert's opinion, mass media) were positively linked to consumer's purchase attention toward organic food.

Effect of Biosolids on Heavy Metal Bioavailability and Organic Acid Production in Rhizosphere of Zea mays L. (Biosolid 처리가 옥수수 근권의 유기산 생성과 중금속 유효도에 미치는 영향)

  • Koo, Bon-Jun;Chung, Doug-Young
    • Korean Journal of Soil Science and Fertilizer
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    • v.38 no.4
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    • pp.173-179
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    • 2005
  • A greenhouse experiment was conducted to evaluate the composition of organic acids on the bioavailability of heavy metals in the rhizosphere of corn (Zea mays L.) over 12 weeks after treatment of biosolids. After planting the plants were sampled at 12th week and analyzed for heavy metals in shoot and root and organic acids in the rhizosphere. Results showed that biomass yields of Zea mays L. grown on biosolids-treated media were significantly higher than those grown on standard media. The effect of biosolids on biomass yields of Zea mays L. was in order of Riverside ${\approx}$ Los Angeles ${\approx}$ MWRDGC > Milorganite > Nu-earth > standard media. Metal uptake by Zea mays L. was closely related with the contents contained on biosolids treated. In the plot treated with Nu-earth the uptake of Cd and Zn by shoot was significantly higher than those at the plots treated with other biosolids. The uptake patterns of Cd and Zn by root were similar to those of shoot. The uptake of Cr and Ni was significantly higher with application of Nu-earth over other biosolids. In all cases, the major organic acids in the rhizoshpere were lactic, acetic, propionic, butyric, and oxalic acids. Other organic acids were glutaric and succinic and occasionally, pyruvic and tartaric acids were also found. And the organic acid compositions did not vary significantly with the treatments of biosolids. Butyric and acetic acids were distinctively dominant both in the standard and the biosolids treatments.

Nitrogen Removal in Fluidized Bed and Hybrid Reactor using Porous Media (다공성 담체를 이용한 유동상 및 하이브리드 반응기에서의 질소제거)

  • Jun, Byong-Hee
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.5
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    • pp.542-548
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    • 2005
  • A fluidized bed reactor containing porous media has been known to be effective for nitrogen and organic matters removal in wastewater. The porous media which attached microbes plays important roles in simultaneous nitrification/denitrification (SND) due to coexistence of oxic, anaerobic and anoxic zone. For SND reaction, oxygen and organic substrates should be effectively diffused from wastewater into the intra-carrier zone. However, the overgrowth heterotrophic microbes at the surface of porous media may restrict from substrates diffusion. From these viewpoints, the existence and effect of heterotrophic bacteria at surface of porous media might be the key point for nitrogen removal. A porous media-membrane hybrid process was found to have improved nitrogen removal efficiency, due to stimulated denitrification as well as nitrification. Microelectrode studies revealed that although intra-media denitrification rate in a conventional fluidized bed was limited by organic carbon, this limitation was reduced in the hybrid process, resulting in the increased denitrification rate from 0.5 to $4.2\; mgNO_3-N/L/hr$.

Effect of $BaTiO_3$ Dispersion on the Properties of Cast Tapes in Processing of Multilayer Ceramic Capacitor(MLCC) (적층 세라믹콘덴서 제조공정에서 $BaTiO_3$의 분산이 테이프캐스팅 성형체의 물성에 미치는 영향)

  • 김봉호;김병관;김명호;백운규
    • Journal of the Korean Ceramic Society
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    • v.33 no.2
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    • pp.214-222
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    • 1996
  • The effect of physicochemical properties of organic solvent and dispersant among organic solvent dispersant binder and plasticizer which are used as processing additives in MLCC fabrication process on the dispersion of BaTiO3 was studied. The steric and electrostatic stabilization mechanisms in dispersion of BaTiO3 in organic media were evaluated respectively. The sttability of BaTiO3 achieved bysteric stabilization was dependent on the fraction of surface coverage of dispersant adsorption on BaTiO3. The electrostatic repulsive forces of BaTiO3 particles dispersed in orgainc media was found to be appreciabley great and dependent mainly on the kinds of organic solvent used. The mechanism affecting the stability of BaTiO3 was studied by the method of rheologi-cal behaviors of BaTiO3 suspension.

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Biguanide-Functionalized Fe3O4/SiO2 Magnetic Nanoparticles: An Efficient Heterogeneous Organosuperbase Catalyst for Various Organic Transformations in Aqueous Media

  • Alizadeh, Abdolhamid;Khodaei, Mohammad M.;Beygzadeh, Mojtaba;Kordestani, Davood;Feyzi, Mostafa
    • Bulletin of the Korean Chemical Society
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    • v.33 no.8
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    • pp.2546-2552
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    • 2012
  • A novel biguanide-functionalized $Fe_3O_4/SiO_2$ magnetite nanoparticle with a core-shell structure was developed for utilization as a heterogeneous organosuperbase in chemical transformations. The structural, surface, and magnetic characteristics of the nanosized catalyst were investigated by various techniques such as transmission electron microscopy (TEM), powder X-ray diffraction (XRD), vibrating sample magnetometry (VSM), elemental analyzer (EA), thermogravimetric analysis (TGA), $N_2$ adsorption-desorption (BET and BJH) and FT-IR. The biguanide-functionalized $Fe_3O_4/SiO_2$ nanoparticles showed a superpara-magnetic property with a saturation magnetization value of 46.7 emu/g, indicating great potential for application in magnetically separation technologies. In application point of view, the prepared catalyst was found to act as an efficient recoverable nanocatalyst in nitroaldol and domino Knoevenagel condensation/Michael addition/cyclization reactions in aqueous media under mild condition. Additionally, the catalyst was reused six times without significant degradation in catalytic activity and performance.

Enzymatic Synthesis of Lauric Acid Butyl Ester in Organic Media Containing Nonionic Surfactants (비이온 계면활성제를 포함한 유기 용액에서의 효소에 의한 라우르산부틸에스테르의 합성)

  • Cheong, Yong-Il;Lim, Kyung-Hee
    • Applied Chemistry for Engineering
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    • v.16 no.5
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    • pp.705-711
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    • 2005
  • The reaction of lauric acid vinyl ester with n-butanol was established to give lauric acid butyl ester by subtilisin A-catalyzed transesterification in organic media containing nonionic surfactants. Pyridine has been used as an organic solvent since it provides higher yields than other organic solvents. However, because of stench of pyridine, compounds enzymatically synthesized in pyridine may be unsuitable as ingredients for foods and drugs. Hence, in order to select an organic solvent to replace pyridine, sugar esters were synthesized with the protease in various organic media. However, no solvent paralleled pyridine in yields. On the basis of this result, pyridine-based W/O microemulsions containing nonionic surfactants and water were used in enzymatic synthesis of the sugar ester, and when Tween 60, Brij 56, or 1-O-octyl-${\beta}$-D-glucopyranose was used for the W/O microemulsions, the yield was higher.

A Study on a Fixed Bed Biofilm Process Using Porous Glass Media (다공성(多孔性) 유리메디아를 이용한 고정상(固定床) 생물막법(生物膜法)에 관한 연구(硏究))

  • Yoon, Tae Il;Kim, Jae Hoon
    • Journal of Korean Society of Water and Wastewater
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    • v.10 no.1
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    • pp.112-120
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    • 1996
  • In this study, the porous glass media was utilized as biomass carrier, and the optimum characteristics of this new media in fixed bed biofilm process were investigated. The characteristics of media considered here are a void volume fraction, a specific surface area, and surface characteristics of media. The effect of surface roughness and material could be clearly demonstrated by the fact that the porous glass media showed a good potential for biofilm development. This might results from the fact that biofilm is initially formed in the surface cavities of the media is protect from the shear effect. Therefore, the microcolonies are not readily detached by the fluid shear. In the steady state, biofilm formation along the packing bed depth was different from media to media. The specific area was also an important factor for the attachment of microorganism on the media surface. The specific area was also an important factor for the attachment of microorganism on the media surface. In the case of porous glass media, about $100m^2/m^3$ was enough to obtain a good organic removal efficiency The organic removal efficiency could be improved by increasing the void volume fraction in the reactor, at least 80% was required to obtain a high removal efficiency and prevent clogging. From the analysis of kinetics study, the yield coefficient, Y, was 0.42 mgMLSS/mgSBOD, endogenous respiration coefficient, ke, was $0.12day^{-1}$ and substrate removel coefficient of Mckinney. km, was $16.8hr^{-1}$ for the porous glass media G-2

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