• Title/Summary/Keyword: Organic electroluminescent

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A New Door for Molecular-Based Organic Electroluminescent Devices

  • Jou, Jwo-Huei;Wang, Wei-Ben;Hsu, Mao-Feng;Lai, Wen-Hsuan;Chen, Chin-Ti;Chin, Chih-Lung
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.350-353
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    • 2009
  • While the comparatively high MW would make the employed molecules extremely difficult to vacuum-evaporate, and result in poor device performance, the wet-process has been proven to be quite effective and convenient as usual to the fabrication of high-efficiency OLEDs composing high MW components.

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Phosphorescent Iridium(III) Complexes based on the ppy Ligands Containing Electron-withdrawing Carbonyl Groups

  • Lee, Kum-Hee;Park, Jeong-Keun;You, Jae-Nam;Seo, Ji-Hyun;Kim, Young-Kwan;Yoon, Seung-Soo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.762-766
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    • 2009
  • We have synthesized and demonstrated a red emission in Organic Light Emitting Diodes (OLEDs) using phosphorescent iridium(III) complexes based on the 2-phenylpyridine ligands with electron-withdrawing carbonyl groups. Among those, a device exhibited highly efficient red-orange emission with the luminance of 20460 cd/$m^2$ at 12 V, the luminous efficiency of 22.0 cd/A at 20 mA/$cm^2$, and the $CIE_{x,y}$ coordinates of (x=0.560, y=0.439 ) at 10 V.

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The Viscosity Dependency of the Organic Electroluminescent Diode On Ink-Jetting Characteristics (유기EL 잉크 점성에 따른 잉크젯 분사 특성)

  • Kang K.T;Kim M.K;Kim H.J;Hwang J.Y;Kang H.S;Park M.S
    • Journal of the Semiconductor & Display Technology
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    • v.4 no.2 s.11
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    • pp.21-24
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    • 2005
  • Ink-jetting characteristics of pulse width and pulse amplitude for a piezoelectric ink jet printer driver have been mapped with various polymer EL ink. In this study, the jetting characteristics have been classified into 4 regime; no Jetting, unstable jetting, stable jetting, and spraying, and the importance of fluid viscosity on the scope of the stable jetting regime has been emphasized. The relation between jetting speed and the width and amplitude of driving signal has also been investigated and the effect of the speed on the jetting characteristics has been discussed.

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A Study on the properties of ELD of Mu1tistructure Using by Alq$_3$ (Alq$_3$를 이용한 다층 구조의 ELD 특성 연군)

  • 채수길;김태완;강도열
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.116-119
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    • 1997
  • In this paper A double-layer organic electroluminescent(EL) device was fabricated using a TPD(N,N'-dipheny] -N,N'-bis(3-methylphenyl)-[1,1'-biphenyl]-4.4'-diamine: aromatic diamine), as a hole-transport material and tris (8-hydroxy quinolinate) aluminum(Alq$_3$) as a an emiting material and its performance characteristics were investigated. structure of devices is ITO/TPD/Alq$_3$/Al. we have fabricated hole transport layer of two types. Doping material of Hole Transport material is Poly(methyl methacrylate)(PMMA) and PEI(Poly-Ether-Imide). Carrier injection from the electrodes to the doped PMMA and PEI layer through the dopants and concomitant electroluminescence from Alq$_3$were observed. Green emission with luminance of 40cd/m$^2$was achieved at a drive voltage of 30V

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Luminescent and electrical properties of MEH-PPV and 1,1,4,4-Tetraphenyl-1,3-butadiene Double Layer films (MEH-PPV와 TPB 다층박막의 광발광 및 전기적 특성)

  • 이명호;김영관;신동명;최종선;김정수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.163-166
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    • 1997
  • Electroluminescent(EL) dcvice based on organic thin layers have attracted lots of interests because of thier possible application as large-area light-emitting displays. It was known that MEH-PPV and 1, 1, 4, 4, -Tetraphenyl-1, 3-butadiene(TPB) has red and blue emission peak at 580nm and 480nm, respectively. In this study, MEH-PPV films and TPB films were prepared by spin coating and vacuum deposition method, respectively. Films of MEH-PPV and TPB double layer were also prepared by the same method. Photoluminescent(PL) characteristics of these single and doubler layers were investigated, where a cell structure of glass substrate/ITO/MEH-PPV and/or TPB/Al was employed. It was found that the photoluminescent efficiency of TPB film was higher than that of MEH-PPV film with a single layer and also with a double structure. These films have also different I-V characteristics.

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INFLUENCE OF ANTHRECENE DOPING ON ELECTRICAL AND LIGHT-EMITTING BEHAYIOR OF 8-HYDROXYQUINOLINE-ALUMINUM BESED ELECTROLUMINESCENT DEVICES

  • Kinoshita, Osamu;Yamaguchi, Ryuichi;Masui, Masayoshi;Takeuchi, Manabu
    • Journal of the Korean institute of surface engineering
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    • v.29 no.5
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    • pp.449-453
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    • 1996
  • In order to improve EL performance, anthracene was doped into the 8-hydroxyquinoline-aluminum (Alq$^3$) light-emitting layer of organic double layered EL cells. The EL cells were fabricated on ITO glass substrates by vacuum deposition. Doping of anthracene to the light-emitting $Alq^3$layer was performed by means of co-evaporation. The doping concentration was changed in the range of 5 to 30 wt.%. It was confirmed that anthracene doping of appropriate concentration increased the available current density and brightness of the EL cells. Carrier mobility of the $Alq^3$ layer was measured by time of flight method. The influence of anthracene doping on the cell performance was discussed.

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Change in Opto-electrical Characteristics in Poly[3-octylthiophene-co-3-(4-fluorophenyl)thiophene] according to the Copolymerization Ratio (Poly[3-octylthiophene-co-3-(4-fluorophenyl)thiophene]에서 공중합 비율에 따른 전기 광학적 특성의 변화)

  • 신선호;정애영;김주현;이후성;김동표
    • Polymer(Korea)
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    • v.25 no.3
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    • pp.399-405
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    • 2001
  • Poly[3-octylthiophene-co-3-(4-fluorophenyl)thiophene]s were synthesized in 2:1, 1:1, and 1:2 mole ratios, and organic electroluminescent devices were fabricated using the copolymers. The opto-electrical properties of the copolymers were studied by PL, EL spectra, I-V, and V-L curves of the organic electroluminescent devices in conjunction with the energy band diagrams which were obtained from the cyclic voltammogram and the electronic absorption spectra. The LUMO energy level of P(OT/FPT)(1:1) is the lowest as -3.35 eV. In the copolymers P(OT/FPT)(2:1) and P(OT/FPT)(1:1) the ${\lambada}_{max}$ in the PL and EL spectra red-shifted as the mole ratio of fluorophenyl group increased while in P(OT/FPT)(1:2) it showed a blue-shift. This indicates that the backbone chain is twisted due to the steric hinderance of the fluorophenyl group leading to shorter ${\pi}$-conjugation length. P(OT/FPT)(1:1) showed the highest EL intensity and the highest power efficiency among the three copolymers. In P(OT/FPT)(1:2) the roughness of the film surface causes unusually high local leakage current leading to the low efficiency of electroluminescence.

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Blue Emitting Cationic Iridium Complexes Containing Two Substituted 2-Phenylpyridine and One 2,2'-Biimidazole for Solution-Processed Organic Light-Emitting Diodes (OLEDs)

  • Yun, Seong-Jae;Seo, Hoe-Joo;Song, Myungkwan;Jin, Sung-Ho;Kim, Young Inn
    • Bulletin of the Korean Chemical Society
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    • v.33 no.11
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    • pp.3645-3650
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    • 2012
  • Two new blue emitting cationic iridium(III) complexes with two substituted 2-phenlypyridine ligands as main ligands and one 2,2'-biimidazole as an ancillary ligand, $[(L1)_2Ir(biim)]Cl$ (1) and $[(L2)_2Ir(biim)]Cl$ (2), where L1 = 2-(2',4'-difluorophenyl)-4-methylpyridine, L2 = 2-(2',4'-difluoro-3'-trifluoromethylphenyl)-4-methylpyridine and biim = 2,2'-biimidazole, were synthesized for applications in phosphorescent organic light-emitting diodes (PhOLEDs). Their photophysical, electrochemical and electroluminescent (EL) device performances were examined. The photoluminescent (PL) spectra revealed blue phosphorescence in the 450 to 485 nm range with a quantum yield of more than 10%. The iridium(III) compounds studied showed good solubility in organic solvents with no solvatochromism dependent on the solvent polarity. The solution-processed OLEDs were prepared with the configuration, ITO/PEDOT:PSS (40 nm)/mCP:Ir(III) (70 nm)/OXD-7 (20 nm)/LiF (1 nm)/Al (100 nm), by spin coating the emitting layer containing the mCP host doped with the iridium phosphors. The best performance of the fabricated OLEDs based on compound 1 showed an external quantum efficiency of 4.5%, luminance efficiency of 8.52 cd $A^{-1}$ and blue emission with the CIE coordinates (x,y) of (0.16, 0.33).

Effects of Low Workfunction Metal Acetate Layers on the Electroluminescent Characteristics of Organic Light-Emitting Diodes (저일함수 금속 아세트산 화합물 층을 사용한 유기발광다이오드의 전기발광 특성 향상)

  • Kim, Mansu;Yu, Geun-Chae;Kim, Young Chul
    • Korean Chemical Engineering Research
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    • v.51 no.5
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    • pp.634-639
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    • 2013
  • We investigated the effects of a cathode underlayer on the electroluminescence (EL) characteristics of organic light-emitting diodes (OLEDs) using various metal acetates (M-acetate, M = Li, Na, K, Cs) as a cathode underlayer. When 1 nm thick M-acetate layers were used as a cathode underlayer, the OLEDs with M-acetate showed better EL performance than the device with the conventional LiF electron injection layer except the device with Cs-acetate. More enhanced current density and improved EL characteristics were obtained when lower work function metal acetate was employed. In addition, the optimum M-acetate layer thickness that gives the best device performance proved to be 0.7 and 2.0 nm for Li-acetate and Cs-acetate, respectively, probably depending on the molecular size of M-acetate. The OLEDs with the M-acetate layers of optimized thickness demonstrated more than 60% enhanced current efficiency compared with that of the device using an LiF layer at the same applied voltage.

Emission Properties of Europium Complex Utilizing Multilayer Quantum-well Str by Vacuum Vapor Deposition Method (Europium Complex를 이용하여 저작한 다층구조의 발광 특성)

  • Lee, Sang-Pil;Kim, Ok-Byoung;Lee, Han-Sung;Kim, Young-Kwan;Kim, Jung-Soo
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1747-1749
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    • 1999
  • Organic electroluminescent devices (OLEDs) have received a great deal of attention due to their potential application as full-color displays. Europium complexes are known as excellent red color-emitting materials for OLEDs since they show intense photoluminescence at around 610 nm with a sharp spectral bandwidth. In this study, triple-layer and multiple quantum-well structures consisting of Eu$(TTA)_3$(bpy) complex well layer sandwiched triphenyldiamine derivative (TPD) layers were fabricated and their photoluminescent characteristics were investigated. Sharp emission at the wavelength of 615 nm has been observed from the triple-layer and multiple quantum-well structures containing Eu complex. Details on the electrical properties of these structures will be also discussed.

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