• 제목/요약/키워드: Organic compounds detection

검색결과 152건 처리시간 0.028초

이상적인 음료수 공급을 위한 수질관리에 관한 연구 (Study on the Water Management to get High Quality of Drinking Water)

  • 김형석;신현덕;박경석
    • 환경위생공학
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    • 제6권1호
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    • pp.7-25
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    • 1991
  • Until now, pure drinking water grnerally menas the water without taste, odor, general bacteria, coliform, and other exotic substance. Such a definition has been changing recently due to the finding of numerous other inorganic and organic substances unknown to us. 10 years ago, major causes of death were infectious agents and parasites contained in water, but recently, it has become apparent that some substances contained in drinking water cause cancer and heart diseases. We must drink about 2L of water everyday in order to maintain healthy condition. Waters used for drinking include tap water, well water, spring water, filtered water, etc., but the quality of drinking water has more polluted due to the industrial development and population increase. For example, industrial waste waters from industrial plants pollute the water supply sources ; toxic substances contained in the waste waters pollute the ground water sources by penetrating the geological strata, and municipal, livestock, public building waste waters also pollute the water supply sources. Sometimes, the polluted surface waters were announced to be polluted by various kinds of orgainc substance, and it is reported that the pollution of ground water by orga nic substances has few in number but high in its concectration comparing with those of surface water. As the water quality pollution level increases, so the amount of disinfectant also increase. For example, chlorine solution, one of widely used disinfectants, creates trihalomethane(THM), a carcinogen, and halogen compounds. According to Oliver, through chlorine disinfection process, humine substance and chlorine create bolatile organic halide and nonvolatile organic halide by chemical reaction. There are tens or hundreds filtering devices, but filtering principles and maintenance metjhods are different, so their efficiency tests are needed. According to Smith, the effeciency tests aginst over 30 Ameican filtering devices show that 10 devices can remove 85% of volatile organics and further studies on filtered waters are underway. In consideration of important impacts of polluted drinking water on national health, authors studied the state of water quality pollution against tap water used as drinking water, filtration device passed water, ground water, and conserved drinking water ; tested the efficiency of filtration devices for tap water ; tried to sep up the detection method by using ion chromatography based on negative ion and positive ion by using single column, and attemped the simple filtration method for general households.

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다중가스센서를 이용한 화재의 조기검출에 대한 연구 (A Study on the Early Fire Detection by Using Multi-Gas Sensor)

  • 조시형;장향원;전진욱;최석임;김선규;강종위;최삼진;박찬원
    • 센서학회지
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    • 제23권5호
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    • pp.342-348
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    • 2014
  • This paper introduced a novel multi-gas sensor detector with simple signal processing algorithm. This device was evaluated by investigating the characteristics of combustible materials using fire-generated smell and smoke. Plural sensors including TGS821, TGS2442, and TGS260X were equipped to detect carbon monoxide, hydrogen gas, and gaseous air contaminants which exist in cigarette smoke, respectively. Signal processing algorithm based on the difference of response times in fire-generated gases was implemented with early and accurately fire detection from multiple gas sensing signals. All fire experiments were performed in a virtual fire chamber. The cigarette, cotton fiber, hair, polyester fiber, nylon fiber, paper, and bread were used as a combustible material. This analyzing software and sensor controlling algorithm were embedded into 8-bit micro-controller. Also the detected multiple gas sensor signals were simultaneously transferred to the personnel computer. The results showed that the air pollution detecting sensor could be used as an efficient sensor for a fire detector which showed high sensitivity in volatile organic compounds. The proposed detecting algorithm may give more information to us compared to the conventional method for determining a threshold value. A fire detecting device with a multi-sensor is likely to be a practical and commercial technology, which can be used for domestic and office environment as well as has a comparatively low cost and high efficiency compared to the conventional device.

시료 중 잔류 항생제 분석 방법: III. 기기 분석 방법 (Determination of Veterinary Antibiotic Residues: III. Analytical Methods_A Review)

  • 김찬식;류홍덕;정유진;김용석;류덕희
    • 한국물환경학회지
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    • 제32권6호
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    • pp.649-669
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    • 2016
  • This study explored the analytical conditions for 21 veterinary antibiotics which have been popularly sold in South Korea in 2014 but have not yet been targeted in EPA method 1694. Most of the selected antibiotics were separated by a reverse-phase C18 column with a combination of (buffered) water and organic polar solvent, which was commonly methanol and acetonitrile in the gradient elution mode. Volatile additives such as formic acid, ammonium acetate and ammonium formate were usually added to the mobile phases to minimize asymmetrical and tailing of antibiotics' peaks and to increase their ionization in mass spectrometry. The analytical methods of aminoglycoside antibiotics were distinct from those of the other antibiotics in terms of adoption of ion-pair chromatography (IPC) and hydrophilic interaction liquid chromatography (HILIC) capable of retaining and separating extremely polar compounds due to their hydrophilicity. Trifluoroacetic acid or heptafluorobutyric acid was frequently added to the mobile phase as an ion-pair reagent for the IPC. Tandem mass spectrometry was numerously applied to the detection of antibiotics using positive electrospray ionization (ESI) and the selected reaction monitoring (SRM) mode. All reviewed analytical methods had been/were validated by evaluating recovery, limits of detection and quantification, decision limit or detection capability of the methods.

열탈착-저온농축-GC/FID/FPD에 의한 도시 생활폐기물 매립장에서 방출되는 휘발성 유기화합물의 측정에 관한 연구 (Determination of Volatile Organic Compounds emitted from Municipal Solid Waste Landfill Site by Thermal Desorption-Cryofocusing-GC/FID/FPD)

  • 김만구;정영림;서영민;남성현;권영진
    • 분석과학
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    • 제14권3호
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    • pp.274-285
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    • 2001
  • 본 연구는 ppb와 ppt 정도의 농도 수준으로 존재하고 있는 대기 중 휘발성 유기화합물을 분석하기 위해 열탈착-저온농축-GC/FID/FPD를 개발하였다. 그리고 고체흡착제가 충진된 흡착관과 자체 제작한 휴대용 가스채취기를 사용하여 강원도 춘천지역에 위치한 근화동과 혈동리 생활폐기물 매립장에서 배출되는 VOCs를 채취하였다. 저온농축방법으로는 분석컬럼을 직접 저온 농축하는 on-column 저온 농축장치와 0.8mm loop를 이용한 저온농축장치를 서로 비교 검토해 보았다. On-column 저온농축법은 loop에 비해 분리능은 좋으나 흡착관에 채취한 시료를 저온농축할 때 요구되는 50 psi의 높은 탈착압력으로 인해 흡착관의 SwageLok fitting이 마모되어 가스가 새는 문제점이 발생하였다. 이에 반해 탈착압력을 낮추고 탈착유량을 늘리기 위해 설계한 loop 경우에는 탈착압력이 0.4 psi로 on-column에 비해 매우 낮아 가스가 새는 것을 방지할 수 있었다. 열탈착-저온농축-GC/FID/FPD로 분석한 근화동과 혈동리 생활폐기물 매립장에서 검출된 물질로는 toluene, xylene, ethylbenzene등 탄화수소류와 악취물인 styrene, limonene, dimethyl disulfide 등이 검출되었다. 그리고 매립지에서 방출되는 VOCs는 매립되는 폐기물의 조성과 매립기간에 따라 다르게 나타났다. 검출된 화합물은 저온농축-GC/MS를 이용하여 확인하였다.

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식품 중 발기부전치료제 및 유사물질의 분석 (Determining Anti-impotence drug-like compounds in Food)

  • 최동미;임무혁;이경진;권광일;정지윤;박건상;홍무기;이철원
    • 분석과학
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    • 제17권6호
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    • pp.520-526
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    • 2004
  • 식품 중 발기부전치료제 및 유사물질 (anti-impotence drug-like compounds)인 실데나필, 바데나필, 타다라필, 호모실데나필, 홍데나필 및 하이드록시호모실데나필에 대해 고속액체크로마토그라피를 이용하여 동시분석을 시도하였다. 환제나 캅슐제 등 고체 시료의 경우 균질화한 후 일정량을 취하고, 드링크제 등 액체시료의 경우 일정량을 취하여 물에 희석한 후 유기용매로 추출하여 대상물질에 대해 photodiode array 스펙트럼의 최대흡수파장을 확인하였다. 인산을 함유한 아세토니트릴을 이동상으로 하고 $C_{18}$ 컬럼으로 분석한 결과 바데나필, 홍데나필, 하이드록시호모실데나필, 실데나필, 호모실데나필, 타다라필의 순으로 용리되었으며, PDA 스펙트럼의 최대흡수파장은 바데나필의 경우 216 nm, 홍데나필의 경우 233 및 282 nm, 하이드록시호모실데나필, 실데나필 및 호모실데나필의 경우 222 및 293 nm, 그리고 타다라필의 경우 284 nm이었다. 검출한계는 물질마다 차이는 있으나 신호대 잡음비 3이상에서 0.04 mg/kg이었으며 평균 회수율은 95 ~ 109% 이었고 식품시료 중 검출된 대상물질은 1.7 (홍데나필) ~ 63 (타다라필) mg/1회복용량 수준이었다.

서울시 도로변 빗물과 지하수의 VOCs오염 (Volatile Organic Compounds contamination in some urban runoff and groundwater samples in Seoul City)

  • 이평구;박성원;전치완;신성천
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제6권3호
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    • pp.73-91
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    • 2001
  • 미국지질조사소 NAWQA 프로그램에서 선정한 기준에 따라, 도시지역에서 채취한 도로를 흐르는 빗물과 일부 지하수의 휘발성유기화합물의 오염을 평가하기 위해 62개 휘발성유기화합물을 선택하였다. 62개 휘발성유기화합물은 3종류의 aromatic hydrocarbons, 13 종류의 alkyl benzenes, 1개의 ether, 26종류의 halogenated alkanes, 10종류의 halogenated alkenes 및 9종류의 halogenated aromatics를 포함하고 있다. 서울시 지역의 도로를 흐르는 빗물과 지하수의 휘발성유기화합물의 함량은 2000년 3월, 6월 및 11월에 시료를 채취하여 분석하였다. 모두 78개 시료(44개 도로를 흐르는 빗물시료, 27개 지하수 시료, 7개 하수종말처리장의 시료)가 채취되었으며, purge and trap 방법으로 추출하여 GC-MS로 분석하였다. 그 결과, alkyl benzenes과 aromatic hydrocarbons이 서울지역에서 자동차 통행에 의해 가장 영향을 받는 유기화합물이다. 분석된 62개 휘발성 유기화합물 중, 도로에 흐르는 빗물에서 검출되지 않은 휘발성유기화합물 성분은 단지 11개 성분뿐이었으나, 채취된 지하수에서 검출된 휘발성유기화합물은 14개 성분만이 검출되었다. 도로를 흐르는 빗물에서의 톨루엔 함량은 시료 채취 장소에 따라 변화가 매우 심하고, 0.1-29,310ppb이다. 벤젠의 함량은 0.05-33.0ppb, ethylbenzene은 0.05-960ppb, trichloromethane(chloroform)은 0.08-20ppb, trichloroethylene(TCE)는 0.03-4.30ppb, 1,1,2 trichloroethane은 0.1-50.0ppb이다. 채취된 일부 지하수 시료에 대한 예비조사 결과, dichloromethane(methylene chloride), trichloromethane(chloroform)와 toluene 등이 가장 자주 검출되는 성분이었다. 대부분의 aromatic hydrocarbons, alkyl benzenes및 다른 유기용매 성분은 검출농도 이하이다.

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환경대기 중 저분자 PAHs 측정을 위한 흡착-열탈착-GC/MS 방법의 적용 (Application of Adsorption Sampling and Thermal Desorption with GC/MS Analysis for the Measurement of Low-Molecular Weight PAHs in Ambient Air)

  • 서석준;서영교;황윤정;정동희;백성옥
    • 한국대기환경학회지
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    • 제30권4호
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    • pp.362-377
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    • 2014
  • Polycyclic aromatic hydrocarbons (PAHs) have been of particular concern since they are present both in the vapor and particulate phases in ambient air. In this study, a simple method was applied to determine the vapor phase PAHs, and the performance of the new method was evaluated with a conventional method. The simple method was based on adsorption sampling and thermal desorption with GC/MS analysis, which is generally applied to the determination of volatile organic compounds (VOCs) in the air. A combination of Carbotrap (300 mg) and Carbotrap-C (100 mg) sorbents was used as the adsorbent. Target compounds included two rings PAHs such as naphthalene, acenaphthylene, and acenaphthene. Among them, naphthalene was listed as one of the main HAPs together with a number of VOCs in petroleum refining industries in the USA. For comparison purposes, a method based on adsorption sampling and solvent extraction with GC/MS analysis was adopted, which is in principle same as the NIOSH 5515 method. The performance of the adsorption sampling and thermal desorption method was evaluated with respect to repeatabilities, detection limits, linearities, and storage stabilities for target compounds. The analytical repeatabilities of standard samples are all within 20%. Lower detection limits was estimated to be less than 0.1 ppbv. In the results from comparison studies between two methods for real air samples. Although the correlation coefficients were more than 0.9, a systematic difference between the two groups was revealed by the paired t-test (${\alpha}$=0.05). Concentrations of two-rings PAHs determined by adsorption and thermal desorption method consistently higher than those by solvent extraction method. The difference was caused by not only the poor sampling efficiencies of XAD-2 for target PAHs and but also sample losses during the solvent extraction and concentration procedure. This implies that the levels of lower molecular PAHs tend to be underestimated when determined by a conventional PAH method utilizing XAD-2 (and/or PUF) sampling and solvent extraction method. The adsorption sampling and thermal desorption with GC analysis is very simple, rapid, and reliable for lower-molecular weight PAHs. In addition, the method can be used for the measurement of VOCs in the air simultaneously. Therefore, we recommend that the determination of naphthalene, the most volatile PAH, will be better when it is measured by a VOC method instead of a conventional PAH method from a viewpoint of accuracy.

유기지방산 신규악취물질에 대한 저온농축 열탈착방식 (Thermal desorber)의 검량특성 연구 (A study on the calibration characteristics of organic fatty acids designated as new offensive odorants by cryogenic trapping-thermal desorption technique)

  • 안지원;김기현;임문순;주도원
    • 분석과학
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    • 제22권6호
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    • pp.488-497
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    • 2009
  • 이 연구에서는 2010년 기준의 지정악취물질에 해당하는 유기지방산과 함께 기존 VOC류 지정 악취물질들을 포괄적으로 분석할 수 있는 흡착관-열탈착 분석기법을 연구하였다. 이러한 분석기법의 검량특성을 평가하기 위해, Tenax TA를 충전한 시료흡착관을 준비하였다. 그리고 여기에 유기지방산 4종 (propionic acid (PA), butyric acid (BA), isovaleric acid (IA), valeric acid (VA))을 위시한 13 가지 조사성분을 함유한 작업용 표준시료를 주입하고 저온농축기법으로 분석하였다. 유기지방산의 분석감도를 절대량 (ng) 및 농도기준 (ppb)의 검출한계로 비교해 보았을 때, 다른 일반적인 VOC 악취성분들에 비해 약 1.5-2배 낮게 나타나는 것을 확인하였다(PA: 0.24 ng (0.16 ppb), BA: 0.19 ng (0.11 ppb), IA: 0.15 ng (0.07 ppb), and VA: 0.28 ng (0.13 ppb)). 분석의 재현성을 RSE로 표시할 경우, 대부분의 성분들이 5% 이내로 안정적으로 나타난 반면, BA (8.02%), IA (14.0%), VA (5.08%)는 5%가 넘을 정도로 낮은 재현성을 보였다. 이러한 결과를 내부표준물질을 이용한 검량으로 비교하였을 때, 대다수 성분의 재현성이 향상되는 양상을 보였다(PA: $1.1{\pm}0.4%$, BA: $10{\pm}0.46$, IA; $12{\pm}0.3%$, VA: $4{\pm}0.1%$). 이 연구의 결과, 악취공정시험법에서 유기지방산의 분석방법으로 권장한 알칼리 흡수법에 대비하여 흡착튜브를 이용한 시료의 채취가 보다 유용한 대체방법으로 활용 가능한 것으로 나타났다.

오존산화에 의한 수처리공정에서 VOCs의 제거 특성 (VOCs Removal in Drinking Water Treatment Process by Ozonation)

  • 한명호;최준호;임학상
    • 상하수도학회지
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    • 제11권2호
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    • pp.65-75
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    • 1997
  • Removal characteristics of volatile organic carbons(VOCs) by ozone oxidation and other processes in the raw water of the 1st Nakdong water treatment plant were investigated. Dichrolomethane, toluene and other 7 compounds were detected in the raw water. With regard to detected 4 compounds in finally treated water, it was found that VOCs could not be removed effectively by traditional water treatment process. Benzene, 1,2-dichlorobenzne were not detected in the raw water but they were detected in the process of treatment. The compound of highest detection frequency was dichloromethane. When the raw water was controlled at pH 7, temperature $20^{\circ}C$, 5 minutes as contact time, 10 minutes as reaction time, the removal rate of THMFP, $KMnO_4$ demand, TOC, $UV_{254nm}$ and $NH_3-N$ were 46.4%, 22%, 19.6%, 31% and 8%, respectively. From estimating the finally treated water qualities in 7 kinds of treatment processes, P-6 process(raw water-chlorination-coagulation-ozonation) was most effective for organics removal and THMs control. Removal efficiencies for $KMnO_4$ demand and TOC by the process which combined preozonation with coagulation was twice better than only preozonation. $NH_3-N$ removal rate was shown as 10% by P-3 process(raw water-coagulation-ozonation), but 83% of $NH_3-N$ was removed by P-4 process(raw water-coagulation-chlorination). It was found that the chlorination is more effective than the ozonation for the NH3-N removal as commonly known.

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프탈로시아닌계 하이브리드 유도체들의 합성 및 이의 특성에 관한 연구 (The Syntheses of Phthalocyanine Hybrid Derivatives and Their Properties)

  • 김성진;안바룡;이근대;박성수
    • 공업화학
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    • 제24권3호
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    • pp.266-273
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    • 2013
  • 프탈로시아닌, 포르피린, 서브프탈로시아닌 및 퍼릴렌 화합물들은 광저장매체, 유기 태양전지, LCD, PDP, 반도체, 위폐 감별용 재료 등으로 응용된다. 본 연구에서는 퍼릴렌, 서브프탈로시아닌 및 포르피린을 프탈로시아닌 프레임에 가교 결합시켜서 프탈로시아닌계 하이브리드 유도체를 합성하였다. 합성된 하이브리드 시료들은 두 가지 다른 파장영역을 동시에 흡수하였다. 또한, 프탈로시아닌에 비하여 유도체의 도입으로 인하여 시료의 용해도가 향상되었으며, 치환된 유도체의 종류에 따라 Q-band가 장파장 영역으로 이동하는 정도가 상이하였다. 시료들의 화학적 특성 및 광학적 특성은 FT-IR, $^1H-NMR$, UV-Vis를 이용하여 비교 분석하였다.