• 제목/요약/키워드: Organic base

검색결과 435건 처리시간 0.027초

放射性 요오드化 反應 (第 II 報) 有機容媒 中에서의 各種 芳香誘導體의 低溫 요오드化 反應 (Radio iodination (II) Radio iodination of various aromatic derivatives in organic solvent at low temperature)

  • 김유선;김종두
    • 대한화학회지
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    • 제12권1호
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    • pp.35-38
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    • 1968
  • Radio iodination of various aromatic derivatives (aniline, toluene, iodobenzene, acetanilide, benzene, benzoic acid) were achieved at low temperature by a chloroamine-T procedures in presence of polar solvent(dioxane). Organic base (piperidine) was used as the catalyst. Iodine replacement reaction had occured on the aromatic or alicyclic ring by this reaction, and the kind and ratio of iodinated products were proved to be different from those of usual iodide reaction in organic solvent at low temperature. The reactivity of various aromatic or alicyclic compounds towards the present iodination system was evaluated and the scope and limitation of the present procedures in the preparation of radio pharmaceuticals were discussed.

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Low temperature curable organic gate insulator for organic field-effect transistors

  • Kim, Joo-Young;Jung, Myung-Sup;Lee, Sang-Yoon;Kim, Jong-Min;Kim, Jang-Joo
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.664-666
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    • 2008
  • Low-temperature curable organic insulator was prepared through blending of polyimide type base resin and cross-linking agent. The newly developed resin can be formed into films using a wet process and cured at $130^{\circ}C$. Using the low temperature cured film as the gate dielectric layer, the field effect mobility of $0.15\;cm^2/V{\cdot}s$ was obtained from a pentacene field effect transistor in the saturation regime and no hysteresis behavior was observed in transfer curves.

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제조 조건에 따른 Polyaniline의 전기적 성질 (Electrical Properties of Polyaniline according to Preparation Conditions)

  • 김언령;김태영;이보현;김종은;서광석;배종현
    • 한국전기전자재료학회논문지
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    • 제14권3호
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    • pp.215-222
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    • 2001
  • Polyaniline-Camphorsulfonic Acid Emeraldine Salt(PANI-CSA ES) was prepared by doping Polyaniline Ermeralidine Base(PANI EB) with DL-10-Camphorsulfonic Acid(CSA). PANI-CSA ES was solved in an organic solvent by ultrasonification for different periods of time and its surface resistivity was measured. Several PANI-CSA ES solutions solved in different organic solvents were prepared and their surface resistivities were measured. Thermal stability of film casted with PANI-CAS ES solution in m-cresol was estimated by measuring its surface conductivity and the content of this moisture and organic solvents. PANI-CSA ES was blended with different polymeric binders to improve its physical properties and the surface resistivities of several kinds of PANI-CSA ES blends were measured as a function of the content of PANI-CSA ES. PANI-CSA ES polymerized by 1-step oxidative polymerization was prepared and its surface resistivity was measured.

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Facile Syntheses of Metal-organic Framework Cu3(BTC)2(H2O)3 under Ultrasound

  • Khan, Nazmul Abedin;Jhung, Sung-Hwa
    • Bulletin of the Korean Chemical Society
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    • 제30권12호
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    • pp.2921-2926
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    • 2009
  • Cu-BTC[$Cu_3(BTC)_2(H_2O)_3$, BTC = 1,3,5-benzenetricarboxylate], one of the most well-known metal-organic framework materials (MOF), has been synthesized under atmospheric pressure and room temperature by using ultrasound. The Cu-BTC can be obtained in 1 min in the presence of DMF (N,N-dimethylformamide), suggesting the possibility of continuous production of Cu-BTC. Moreover, the surface area and pore volume show that the concentration of DMF is important for the synthesis of Cu-BTC having high porosity. The morphology and phase also depend on the concentration of DMF : Cu-BTC cannot be obtained at room temperature in the absence of DMF and aggregated Cu-BTC (with low surface area) is produced in the presence of high concentration of DMF. It seems that the deprotonation of benzenetricarboxylic acid by base (such as DMF) is inevitable for the room temperature syntheses.

유기질 비료의 시용이 배 과원의 토양과 엽과 눈 특성에 미치는 영향 (Effects of Compost Application on Soil Properties and Leaf and Bud Characteristics of Pear Trees in Orchard Farms)

  • 이재안;김월수;최현석
    • 한국유기농업학회지
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    • 제17권4호
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    • pp.567-575
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    • 2009
  • 본 실험은 미생물이 포함되어있는 환경 친화적인 상업용 유기질비료(compost)를 2년 동안시용함으로서, 토양 내 화학성과 '신고' 배 수체생장을 향상시킬 수 있는 지를 알아보기 위하여 수행하였다. 시판된 유기질 비료 처리는 토양 내 미생물생체량과 토양 pH, 유기물함량, 그리고 양이온 치환용량을 관행재배 구에 비해서 증가시켰다. 유기질 비료 처리에 의해 개선된 토양환경은 엽 내 무기성분 함량에는 크게 영향을 미치지 못했으나, 엽 두께를 증가키시고, 엽과 꽃눈 수를 증가시킴으로서, 배 수체생장에 크게 영향을 미친 것으로 판단된다.

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Study on the characteristics of the organic thin-film transistors according to the gate electrode surface treatments

  • Kim, Hye-Min;Park, Jae-Hoon;Bong, Kang-Wook;Kang, Jong-Mook;Lee, Hyun-Jung;Han, Chang-Wook;Choi, Jong-Sun
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권2호
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    • pp.1292-1294
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    • 2007
  • In this report, the effects of chemical surface treatments of ITO gate electrodes of OTFTs have been studied by using acid and base solutions. As a result, it is observed that the threshold voltage of OTFTs could be influenced and modified by the surface treatments. The device with an ITO gate electrode surface-treated by a base solution shows the lowest threshold voltage of -7.66 V, while the threshold voltages are about -13.51 V and -15.3 V for the devices without a surface treatment and with the acid solution treatment, respectively. It is thought that the work function of ITO electrode surface might be affected by the surface treatments, thereby influencing the threshold voltage.

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자색고구마 첨가 요구르트의 제조 및 특성 (Preparation of Yogurt from Milk Added with Purple Sweet Potato)

  • 전승호;이상욱;신용서;이갑성;류일환
    • 한국식품영양학회지
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    • 제13권1호
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    • pp.71-77
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    • 2000
  • New type yogurt base were prepared from milk added with skim milk powder or purple sweet potato, and fermented by lactic acid bacteria (Streptococcus thermophilus and Bifidobacterium infantis, 1:1, v/v). The yogurt proudcts were evaluated for acid production(pH, titratiable acidity), number of viable cell, viscosity, sensory properties, and color value. The composition of some organic acids was also analyzed by GC. The acid production slightly decrerased by addition with purple sweet potato. There was no significant difference in viable cell counts between control (yogurt added with only skim milk powder) and yogurt added with purple sweet potato, and viable cell counts of all samples were above 9.08 log cfu/ml. Viscosity of yogurt added with purple sweet potato(36,800∼46,000 centipoise) was higher than that of yogurt added with only skim milk powder(32,200 centipoise). The overall sensory score of yogurt added with purple sweet potato(38.6%, dry base) was the best of tested yogurt. The major organic acid of yogurt added with purple sweet potato was lactic acid. its content was 0.997∼1.203%. malic acid, succinic acid, oxalic acid, and fumaric acid were analyzed out a little. Lightness and yellowness decreased by addition with purple sweet potato but redness increased. Total color difference($\Delta$E) with yogurt addition with purple sweet potato and only skim milk powder were very high(above 11.46).

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Depositional Environment and Distribution of Heavy Metal off the Shihwa Dam

  • Oh, Jae-Kyung
    • Journal of the korean society of oceanography
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    • 제32권3호
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    • pp.120-127
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    • 1997
  • Depositional environment off the Shihwa Dam has been studied to investigate the change of sedimentation process and the pollution. In order to understand how the sediments are distributed, polluted and modified, depositional factors have been analyzed and compared with the previous data. Study area, located off the Shihwa Dam, was surveyed to collect 25 bottom samples and 2 cores in 1996 and echo-sounding in 1997. These sediments were analyzed for the study of the global characteristics of sediment such as grain size and organic matter. Among these samples, the selected twenty surface sediments were analyzed for the comparison with their contents of metallic elements (Al, Mn, Fe, V, Cr, Co, Ni, Cu, Zn, Cd, Pb, As). According to field and lab analysis of sediments, three sedimentological zones have been generally identified around study area; near the dam (sandy Silt), near the dike (Sand) and offshore (silty Sand) zones. Textural parameters show that the content of silt and clay is dominant near the dam excepting the dike zone of LNG Storage Base and offshore (Palmido). The total concentration of Mn, Ni, Fe, Zn and Cd in bulk sediments was increased after the construction of the dam, while the content of Mn and Cr were higher near tidal channel than in the offshore area. Meanwhile, the annual increasing pattern of some heavy metal has appeared in this area. Based on this primary study, modification of the depositional environment may be caused by the construction of the dam and LNG Storage Base. Additionally, environmental evaluation on organic/inorganic factors has been suggested for interpreting environmental changes caused by coastal development in the nearshore such as the Shihwa coastal area.

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Occurrence and distribution characteristics of weed species in organic paddy fields

  • Hwang, Ki Seon;Jung, Sunghoon;Kim, Sung-Chul;Chung, Doug-Young;Park, Kee Woong
    • 농업과학연구
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    • 제44권3호
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    • pp.325-331
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    • 2017
  • This study was conducted to investigate the dominance and distribution of weed species in organic and conventional paddy fields. The organic paddy fields were maintained for organic farming for more than five years in Anseong, Gyeonggi province of Korea. According to the Braun-Blanquet method, 42 and 36 weed species were found in the organic paddy fields in 2015 and 2016, respectively, while 38 and 36 weed species were found in the conventional paddy fields in 2015 and 2016, respectively. As a result of two years' survey, 53 species from 24 families in the organic paddy fields were identified and classified as 32 annuals, 3 biennials and 18 perennials. In conventional paddy fields, 51 species from 24 families (30 annuals, 6 biennials, and 15 perennials) were identified. According to the classification by family, the most abundant weed species were Compositae (9 species), followed by Poaceae (8 species) and Polygonaceae (6 species) in organic paddy fields. In conventional paddy fields, Compositae (9 species) were the most abundant weed species, followed by Cruciferae (6 species), Poaceae, Polygonaceae, and Cyperaceae. This result indicates that the difference in diversity of weeds in paddy fields was influenced more by the agricultural environment than the type of cultivation. Our results could be used as a base data to control the occurrence of weed species in the paddy fields.

복합 전처리를 통한 하수슬러지의 가용화 및 생물학적 유용성에 관한 연구 (A study for Solubilization and Bioavailability of Sewage Sludge Using the Complex Pre-treatment)

  • 강정현;이희수;이태진
    • 유기물자원화
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    • 제19권3호
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    • pp.35-43
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    • 2011
  • 본 연구에서는 하수슬러지를 전처리 과정을 통해 가용화한 후 혐기성 생물학적 분해를 실시하였다. 산 또는 알칼리 조건과 초음파처리를 복합적으로 적용하여 전처리 후 슬러지의 가용화율을 비교하였으며 알칼리 조건에서 초음파처리를 병행하였을 때 최대 가용화율을 얻을 수 있었다. 가용화된 슬러지의 생물학적 유용성은 복합전처리를 실시한 경우 빠른 생물학적 분해와 더불어 총 가스 발생량은 10배 이상 증가하였으며 가용화된 슬러지에서 바이오가스 생산 가능성을 확인 하였다. 전처리를 실시한 슬러지를 이용하여 생물학적 분해를 실시하였을 때 약 50%정도 높은 수소생성율의 지표가 되는 B/A비를 확인할 수 있었으나 수소생성에 저해가 되는 lactic acid와 propionic acid가 검출되는 것으로 보아 후속연구가 필요할 것으로 판단되었다.