• Title/Summary/Keyword: Organic base

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The antiwear performance of several organic phosphates from the aspect of interaction between polyolester base oil and additive (Polyolester base oils과의 상호작용에 의한 Organic Phosphates계 내하중첨가제의 마모방지 성능)

  • ;Masabumi Masuko
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1999.06a
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    • pp.189-194
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    • 1999
  • The antiwear performance of several organic phosphates ,such as tricrecylphosphate(TCP), tributylphosphate(TBP), diphenylhydrogenphosphate(DPHP) ,dissolved in polyol ester based oils is studied. These organic phosphates are well known for antiwear additive for lubricating oil that produce reacted surface protective film. These antiwear additives can drastically reduce wear with their concentration increasing, because the amount of additive adsorbed on metal sur(ace increases. But in the higher concentration region, the wear is increased by excessive and corrosive reaction of the metal surface with these additives. That is to say, there is an optimum concentration for minimum wear. The optimum concentration was different with the kinds of base oils and additives. Different polyolesters showed different optimum concentrations of the additive. The order of optimum concentration among the polyolesters was different with different phosphates. The order of the optimum concentration is shown that the effect of the concentration of additives on the antiwear performance. It can be explained by the interaction between additives and base oils using the solubility parameter.

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Effect of coagulation conditions on ultrafiltration for wastewater effluent

  • Maeng, Sung Kyu;Timmes, Thomas C.;Kim, Hyun-Chul
    • Membrane and Water Treatment
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    • v.8 no.2
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    • pp.185-199
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    • 2017
  • Low-pressure membrane filtration is increasingly used for tertiary treatment of wastewater effluent organic matter (EfOM), mainly comprising organic base/neutral compounds. In-line coagulation with underdosing, charge neutralization, and sweep floc conditions prior to ultrafiltration (UF) was studied to determine removals of the EfOM components and consequent reduction of fouling using polyethersulfone membranes. Coagulation and UF substantially reduced fouling for all coagulation conditions while removing from 7 to 38% of EfOM organic acids. From 7 to 16% of EfOM organic base/neutrals were removed at neutral pH but there was no significant removal for slightly acid coagulation conditions even though fouling was substantially reduced. Sweep floc produced the lowest resistance to filtration but may be inappropriate for in-line use due to the large added volume of solids. Charge-neutralization resulted in poor recovery of the initial flux with hydraulic cleaning. Under-dosing paralleled sweep floc in reducing hydraulic resistance to filtration (for sub-critical flux) and the initial flux was also easily recovered with hydraulic cleaning. Hydrophobic and hydrophilic base/neutrals were identified on the fouled membranes but as previously reported the extent of fouling was not correlated with accumulation of organic base/neutrals.

Effect of Application of Organic Fertilizer on the Growth of Korea Lawngrass(Zoysia matrella L. Merr.) by base-dressing and top-dressing application (기비 및 추비에 의한 유기질비료의 사용이 금잔디(Zoysia matrella L. Merr.)의 생육에 미치는 영향(影響))

  • Ham, Suon-Gyu;Lee, Jyung-Jae;Kim, In-Seob
    • Journal of the Korea Organic Resources Recycling Association
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    • v.2 no.1
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    • pp.41-49
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    • 1994
  • This experiment was carried out in order to study the effect of organic fertilizer on the growth of Korean lawngrass (Zoysia matrella L. Merr.) and the change of soil chemical characteristics. The results obtained are summarized as follows : 1. Organic fertilizer was appropriate for base-dressing in the sod establishment of Korean lawngrass(Z. matrella L. Merr.) 2. Chlorophyll contents in mixed application plot of complex fertilizer(21-17-17) and organic fertilizer were more abundant than that in single application plot of organic fertilizer. 3. Application of organic fertilizer promotes the contents of available phosphorous in soil. 4. Dry weights of base-dressing and top-dressing plot had more weight about 40%, 12% than that of control plot, respectively. So base-dressing was more effective than top-dressing in the application of organic fertilizer.

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Acid-Base Bifunctional Metal-Organic Frameworks: Green Synthesis and Application in One-Pot Glucose to 5-HMF Conversion

  • Zhang, Yunlei;Jin, Pei;Meng, Minjia;Gao, Lin;Liu, Meng;Yan, Yongsheng
    • Nano
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    • v.13 no.11
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    • pp.1850132.1-1850132.14
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    • 2018
  • The direct synthesis of metal-organic frameworks (MOFs) with acidic and basic active sites is challenging due to the introduction of functional groups by post-functionalization method often jeopardize the framework integrity. Herein, we report the direct synthesis of acid-base bifunctional MOFs with tuning acid-base strength. Employing modulated hydrothermal (MHT) approach, microporous MOFs named $UiO-66-NH_2$ was prepared. Through the ring-opening reaction of 1,3-propanesultone with amino group, $UiO-66-NH_2-SO_3H-type$ catalysts can be obtained. The synthesized catalysts were well characterized and their catalytic performances were evaluated in one-pot glucose to 5-HMF conversion. Results revealed the acid-base bi-functional catalyst possessed high activity and excellent stability. This work provides a general and economically viable approach for the large-scale synthesis of acid-base bi-functional MOFs for their potential use in catalysis field.

Studies on the Organic Base Complexes and their Application to Analytical Chemistry. I. A Study on the Formation of Chlorpromazine Bromothymol Blue Complex and its Application to Analytical Chemistry. (4 유기염기착화합물의 분석화학적연구 I. Chlorpromazine Bromthymol Blue Complex 의 분석화학적연구)

  • 김차덕;심상혁;서정현
    • YAKHAK HOEJI
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    • v.9 no.1_2
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    • pp.14-17
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    • 1965
  • It has been known that the organic base complexes formed with the anionic acid base indicators are highly soluble in non-polar solvents but relatively insoluble in water. In the work reported here the formation of the complex between chloropromazine and bromothymol blue was studied and applied it to the determination of the base. The values to determine the binding ratio of the base with the indicator at pH 3.5 obtained from the application of Job's method of continuous variation and mol ratio method were both 1:1. From the application of this reaction to the determination of the base with carbon tetrachloride as the solvent for the extraction, fairy good results have been obtained.

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Removal of Non-biodegradable Organic Contaminants in Wastewater from crude oil reserve base Using Pulse UV System (Pulse UV 장치를 이용한 원유비축시설 발생폐수의 난분해성 유기오염물질 제거)

  • Sohn, Jin-Sik;Park, Soon-Ho;Jung, Eui-Taek
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.6
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    • pp.861-867
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    • 2011
  • Wastewater from crude oil reserve base usually contains large amount of non-biodegradable contaminants. The conventional wastewater treatment progress can hardly meet the regulation of wastewater effluent quality. This study investigated the removal of non-biodegradable organic contaminants in wastewater from crude oil reserve base using a pulse UV treatment. The modified process incorporating pulse UV process was set up to treat the wastewater from crude oil reserve base. The treatment process is composed with coagulation and flocculation, micro-bubble flotation, sand filter, pulse UV system, and GAC filter. The results show CODMn was effectively removed by the process with pulse UV system and it can meet the wastewater effluent regulation. The single effect of pulse UV process in CODMn removal was not significant(9~15% based on sand filtered effluent), however with the subsequent activated carbon filter the removal ratio CODMn was increased up to 28% compared to the process without pulse UV syetem.

Aspects of a head-mounted eye-tracker based on a bidirectional OLED microdisplay

  • Baumgarten, Judith;Schuchert, Tobias;Voth, Sascha;Wartenberg, Philipp;Richter, Bernd;Vogel, Uwe
    • Journal of Information Display
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    • v.13 no.2
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    • pp.67-71
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    • 2012
  • In today's mobile world, small and lightweight information systems are becoming increasingly important. Microdisplays are the base for several near-to-eye display devices. The addition of an integrated image sensor significantly boosts the range of applications. This paper describes the base-building block for these systems: the bidirectional organic light-emitting diode microdisplay. A small and lightweight optic design, an eye-tracking algorithm, and interaction concepts are also presented.

Thermo- and Acid/base-induced Spectral Switching of a Poly(N-isopropylacrylamide) Copolymer Containing Benzopyran-based D-π-A type Dye Units

  • Lee, Eun-Mi;Gwon, Seon-Yeong;Ji, Byung-Chul;Kim, Sung-Hoon
    • Textile Coloration and Finishing
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    • v.22 no.3
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    • pp.181-186
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    • 2010
  • A thermoresponsive poly(NIPAM-co-dye) labeled with benzopyran-based D-$\pi$-A type dye was prepared by typical radical copolymerization. It can be also constructed a acid/base-induced molecular switch by modulation of intramolecular charge transfer with protonation/deprotonation. The lower critical solution temperature behavior was investigated by means of UV-vis spectroscopy which allows the measurement of the phase transition from $25^{\circ}C$ to $45^{\circ}C$ in aqueous DMSO solution. The morphology of the internal microstructure of the poly(NIPAM-co-dye) hydrogel was observed by scanning electron microscopy. The reversible switch could be obtained by thermal and acid/base stimuli.

Experimental study on axial response of different pile materials in organic soil

  • Canakci, Hanifi;Hamed, Majid
    • Geomechanics and Engineering
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    • v.12 no.6
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    • pp.899-917
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    • 2017
  • Sixty four tests were performed in a steel tank to investigate the axial responses of piles driven into organic soil prepared at two different densities using a drop hammer. Four different pile materials were used: wood, steel, smooth concrete, and rough concrete, with different length to diameter ratios. The results of the load tests showed that the shaft load capacity of rough concrete piles continuously increased with pile settlement. In contrast, the others pile types reached the ultimate shaft resistance at a settlement equal to about 10% of the pile diameter. The ratios of base to shaft capacities of the piles were found to vary with the length to diameter ratio, surface roughness, and the density of the organic soil. The ultimate unit shaft resistance of the rough concrete pile was always greater than that of other piles irrespective of soil condition and pile length. However, the ultimate base resistance of all piles was approximately close to each other.

The First Report on Chemoselective Biguanide-Catalyzed Henry Reaction under Neat Conditions

  • Alizadeh, Abdolhamid;Khodaei, Mohammad M.;Abdi, Gisya;Kordestani, Davood
    • Bulletin of the Korean Chemical Society
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    • v.33 no.11
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    • pp.3640-3644
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    • 2012
  • An efficient synthetic method for direct Henry reaction catalyzed by a biguanide; namely metformin, as an organosuper-base, between a variety of aromatic and aliphatic aldehydes and nitromethane under neat conditions has been developed. Convenient procedure for removal of the catalyst, chemoselective acquiring of ${\beta}$-nitroalcohols as predominant products, as far as possible short reaction time with excellent conversions are advantages of the developed protocol.