• Title/Summary/Keyword: Organic additive

Search Result 269, Processing Time 0.023 seconds

Study on the Cycling Performances of Lithium-Ion Polymer Cells Containing Polymerizable Additives

  • Kim, Dong-Won
    • Bulletin of the Korean Chemical Society
    • /
    • v.30 no.2
    • /
    • pp.319-322
    • /
    • 2009
  • Gel polymer electrolytes were prepared by immersing a porous poly(vinylidene fluoride-co-hexafluoropropylene) membrane in an electrolyte solution containing small amounts of polymerizable additive (3,4-ethylenedioxythiophene, thiophene, biphenyl). The organic additives were electrochemically oxidized to form conductive polymer films on the electrode at high potential. With the gel polymer electrolytes containing different organic additive, lithium-ion polymer cells composed of carbon anode and LiCo$O_2$ cathode were assembled and their cycling performances were evaluated. Adding small amounts of thiophene or 3,4-ethylenedioxythiophene to the gel polymer electrolyte was found to reduce the charge transfer resistance in the cell and it thus exhibited less capacity fading and better high rate performance.

Property Change by Organic Additives in Electroplated Nickel-copper Thin Films (유기첨가제에 의한 전기도금 니켈-구리 박막의 물성변화)

  • Lee, Jung-Ju;Hong, Ki-Min
    • Journal of the Korean Magnetics Society
    • /
    • v.15 no.3
    • /
    • pp.198-201
    • /
    • 2005
  • We investigated the effects of organic additives on the properties of nickel-copper thin films prepared by electroplating. Compared with thin films fabricated by pure electrolyte only, the films utilizing organic additives show different crystalline orientations. With no alteration of plating conditions simply adding the organic materials changed the composition of copper and nickel. The concentration of nickel could be varied to $65-95\%$ depending on the species and concentration of the additives. The change of material property has contributed to the increase or decrease of the magnetoresistance.

Organic Electrolyte of the Additive the Gamma-Butyroloctone (GBL) for Additive Material Application to High Voltage Electrochemical Capacitor (Gamma-butyroloctone(GBL)을 첨가한 유기계 전해액의 고전압용 전기화학 커패시터로의 응용)

  • You, Sun-Kyung;Park, Soo-Gil
    • Journal of the Korean Electrochemical Society
    • /
    • v.20 no.1
    • /
    • pp.13-17
    • /
    • 2017
  • In this study, we studied the organic electrolyte application to electrochemical capacitor for high operation voltage. For high operating voltage, 5 wt % of gamma butyroloctone (GBL) was added in the bare electrolyte. During the cycle performance, stable SEI layers were formed by reductive decomposition of additive GBL. As a result, columbic efficient of 1M $SBPBF_4$ in EC:DMC(1:1) with GBL composite was enhanced to 70% after the 2000th cycle at voltage range 0-3.5 V. Additionally, SEI layer protected the surface of electrode and prevent the side-reaction between electrolyte to electrode.

Conducting and interface characterization of carbonate-type organic electrolytes containing EMImBF4 as an additive against activated carbon electrode

  • Kim, Mingyeong;Kim, Kyungmin;Kim, Seok
    • Carbon letters
    • /
    • v.16 no.1
    • /
    • pp.51-56
    • /
    • 2015
  • Carbonate-type organic electrolytes were prepared using propylene carbonate (PC) and dimethyl carbonate (DMC) as a solvent, quaternary ammonium salts, and by adding different contents of 1-ethyl-3-methyl imidazolium tetrafluoroborate ($EMImBF_4$). Cyclic voltammetry and linear sweep voltammetry were performed to analyze conducting behaviors. The surface characterizations were analyzed by scanning electron microscopy method and X-ray photoelectron spectroscopy. From the experimental results, increasing the $EMImBF_4$ content increased the ionic conductivity and reduced bulk resistance and interfacial resistance. In particular, after adding 15 vol% $EMImBF_4$ in 0.2 M $SBPBF_4$ PC/DMC electrolyte, the organic electrolyte showed superior capacitance and interfacial resistance. However, when $EMImBF_4$ content exceeded 15 vol%, the capacitance was saturated and the voltage range decreased.

A Study on the Wear Properties by EP(Extreme Pressure) Additive Composition in a Lubricated Concentrated Contact (윤활시스템에서 극압첨가제 조성에 따른 마모특성 연구)

  • 김용석;류재환
    • Tribology and Lubricants
    • /
    • v.19 no.3
    • /
    • pp.159-166
    • /
    • 2003
  • This research for replacement of chlorine or sulfur based EP(extreme pressure) -additives which is restricted materials by environmental regulation. The subject of this study is as follows, 4-ball test and friction coefficient test were experimented in accordance with temperature and velocity, compounding with several organic or inorganic metallic elements. After 4-ball test, wear area of steel ball was analysed by SEM-EDX. As the analysis, organic and inorganic elements make a effect for extreme pressure lubricity. It is shown that the friction coefficient of lubricant which includes chlorine or sulfur additives, the scoring phenomenon is found accord-ing to temperature and the scuffing phenomenon at 200$^{\circ}C$. Applying to Na, P, S, Zn, Ca based on inorganic and organic elements, the result showed that friction coefficient is decreased more and more, as increasing temperature of lubricant. The additive based on S, Cl, P elements is effect far extreme pressure in the sample#1 and Na, P, S, Zn, Ca in sample #2. These elements are environmental contaminants and S, Cl based on EP additives which are very popular in domestic industry, when they are properly composed with non-chlorine based on additives and Na, P, S, Zn, Ca organic or inorganic elements. It is showed that lubricity and excellent anti-wear properties.

Effects of Dietary formulated feed Additive on Growth Performance and Carcass Traits in Hanwoo Steers (반추위 발효 조절 항생제 대체 물질이 한우 거세우 생산성과 육질특성에 미치는 영향)

  • Ryu, Chaehwa;Park, Hae-Ryoung;Cho, Sangbuem;Choi, Nag-Jin
    • Korean Journal of Organic Agriculture
    • /
    • v.24 no.4
    • /
    • pp.869-879
    • /
    • 2016
  • The present study was conducted to evaluate the effects of dietary formulated feed additive on growth performance and carcass traits of Hanwoo steers. A formulated feed additive reported to reduce heat load in the rumen in our previous research was used (Cho et al., 2014). Total 32 herds of Hanwoo steers were assigned into two groups of control and treatment. Total mixed ration was provided as basal diet for cattle and 100 g of additive was supplemented on diet for treatment. Feeding trial was performed during 120 days before slaughter. For growth performance, 3 periods (0~90 days; 90~120 days; 0~120 days) were allotted and average daily gain, feed requirement and final body weight were determined. Loin meat between $12^{th}$ and $13^{th}$ rib was used for meat quality analysis after slaughtering. Only $1^{st}$ period showed significantly improved growth performance of treatment (P<0.05) and there were no significant difference in other periods. At $3^{rd}$ periods (overall), a trend of increased average daily gain was found at treatment (P=0.075). Carcass performance and quality did not show significant differences between treatment and control (P>0.05). In meat quality, treatment showed significant increment in all measured meat colors (P<0.05) and significantly less sharing force compared to the control (P<0.05). Although no significant difference in growth performance and carcass yield were found, remarkably improved economic status was detected in treatment group. In conclusion, it could be suggested that application of a formulated feed additive specialized in reduction of heat load in the rumen was able to increase economical balance through enhancing heat stress condition of ruminant and growth.

유기용제노출사업장의 역학조사를 위한 기초연구(I)

  • Park Hui-Ryeon;Lee Nae-U;Choe Jae-Uk
    • Proceedings of the Korean Institute of Industrial Safety Conference
    • /
    • 2001.11a
    • /
    • pp.303-308
    • /
    • 2001
  • Various organic solvents are most commonly using material in various factories, for examples, paint producting process and other industries, actually most of them are toxic materials, If many kinds of organic chemicals are concurrently exposed to workplace, toxidities can be influenced as additive effect or synergistic effect.(omitted)

  • PDF

Properties Change of Electroplated Permalloy Thin Films by Organic Additives (유기첨가제에 의한 전기도금 퍼말로이 박막의 물성변화)

  • Bang, Won-Bae;Bae, Jong-Hak;Hong, Ki-Min;Chung, Jin-Seok;Ko, Young-Dong;Lee, Hee-Bok
    • Journal of the Korean Magnetics Society
    • /
    • v.17 no.3
    • /
    • pp.133-136
    • /
    • 2007
  • We investigated the changes of the magnetic properties in electroplated Permalloy thin films by a few organic additives added to the plating electrolytes. Under identical electroplating conditions, the crystalline orientations and the surface roughness of the plated thin films were different from those prepared with a pure electrolyte. These property changes reduced the coercivity and increased the magnetoimpedance ratio (MIR) up to 20%.