• Title/Summary/Keyword: Organic Supports

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Sulfate Reduction in the Marine Environments: Its Controlling Factors and Relative Significance in Mineralization of Organic Matter (해양환경의 황산염 환원율 조절요인 및 유기물 분해에 있어 황산염 환원의 중요성)

  • 현정호;이홍금;권개경
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.8 no.2
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    • pp.210-224
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    • 2003
  • Sulfate reduction is a microbiological process which occurs ubiquitously in anaerobic marine environment. Sulfate reducing bacteria play a significant role in anaerobic decomposition of organic matter and regeneration of inorganic nutrients which supports the primary production in the water column (i.e., benthic-pelagic coupling) and, in special case, could be responsible for the harmful algal bloom in the coastal marine environment. Summary of the sulfate reduction rates reported in various marine sedimentary environments revealed that supply of organic substrates and presence of various electron acceptors (i.e., $O_2$, NO$_{3}$$^{[-10]}$ , Fe(III) and Mn(IV), etc.) for other aerobic and anaerobic respiration directly affect the sulfate reduction rate and relative significance of sulfate reduction in organic matter mineralization. Significance of temperature, macrophytes and bioturbation is discussed as factors controlling supply of organic substrates and distribution of electron acceptors. Finally, we suggest studies on the anaerobic microbiological processes associated with biogeochemical element cycles in the coastal environments of Korea where massive operation of organic enriched fish cage farm, frequent occurrence of toxic algal bloom and hypoxia and conservation of tidal flat are of major environmental issues.

Technical Development and Direction of Sustainable Agriculture in Korea (우리나라 친환경 농업의 현황과 발전방향)

  • Park Moo-Eon
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2001.09a
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    • pp.3-33
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    • 2001
  • A review on the technical development and agricultural policy direction for sustainable agriculture has been made to clarify the present conditions of agricultural environment for food production and natural resource conservation and to study prospects and solutions successfully to achieve food safety and environment conservation as the 21st agricultural paradigm. Although great improvement of environmentally sound and resource-conserving techniques, sustainability of Korean agriculture has been damaged by quantitative reduction and quality deterioration of agricultural land resources, insufficient implementation of low-input and organic matter recycling techniques and also improper cropping system. It is concluded that goal of sustainable agriculture can be successfully achieved by further improvement of environmentally friendly techniques, and stronger escalation of national implementation programmes with more financial supports including direct payments for sustainability of agriculture under systematical support and cooperation of AKS (agricultural knowledge system).

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A Study on efficient application of elderly human resource through the aged for start business (고령자창업을 통한 고령인적자원의 효율적 관리방안에 관한 연구)

  • Jung, Lee-Sang
    • Management & Information Systems Review
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    • v.25
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    • pp.143-169
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    • 2008
  • The purpose of this paper is to propose alternatives to help for the aged to implement start business as a method to recreate the aged population for their second life. There are three considerations that supports start business for the elderly. The first is to reinforce educational support system for the aged. Through the lifelong education, the aged require easy start business' information. This is not only goverment's job, a local autonomous entity is to support in the form of organic organization. The second is the maintenance of financial support system. Besides start business education, various financial support system must serve for the aged to challenge their start business enthusiastically. The last consideration is formation of start business network that joins the aged efficiently. Based on these aspects, the application for increasing elderly human resource is to consider both employment program of the aged and also start business program for them.

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Selective Removal of HCN and Aldehydes in Mainstream Smoke by Impregnated Activated Carbon and Functionalized Silica-gel (기능성 실리카겔과 첨착 활성탄에 의한 주류연 중 시안화수소와 알데히드의 선택적 흡착)

  • Lim Heejin;Shin Chang-Ho;Yang Burm-Ho;Hong Jin-Young;Ko Dongkyun;Lee Young-Tack
    • Journal of the Korean Society of Tobacco Science
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    • v.27 no.2
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    • pp.171-177
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    • 2005
  • Coconut based activated carbon and silica-gels were impregnated with 3-aminopropyltri ethoxysilan(APS) and N-(2-aminoethyl)-3-aminopropyl triethoxysilane (AEAPS) in order to investigate the effect of the amine group and the pore size of the supports on the removal of hydrogen cyanide(HCN) and aldehydes in mainstream smoke(MS). The physicochemical properties of the supports were analyzed by using thermal gravity analyzer(TGA), $N_2$ adsorption and desorption isotherms$(BET,\;N_2)$, and SEM-EDS. According to our experimental data, there was no significant difference in the delivery amount of HCN and aldehydes of non-functionalized silica-gels having meso-pores bigger than $20\AA$. In the case of silica-gels functionalized with APS(APS silica-gel), the delivery amounts of hydrogen cyanide(HCN) and aldehydes decreased with the increase of APS concentration. Silica-gel functionalized with AEAPS(AEAPS silica-gel) showed higher removal efficiency than that of APS silica-gels. The delivery amounts of HCN and aldehydes of activated carbon impregnated with APS and AEAPS increased with the increase of the APS and AEAPS concentrations. In accordance with the specific surface area analysis results, APS and AEAPS molecules decreased the specific surface area by blocking the micro-pores of the activated carbon. The volatile organic components removal efficiency by the micro-pores was higher than that of the amine group impregnated into the activated carbon.

Relationship among Physical & Chemical Properties of Supports and Performance of Methane Fermentation in Anaerobic Fluidized-Bed Reactor (혐기성 유동층 반응기에서 지지체의 물리.화학적 특성과 메탄 발효 성능 사이의 관계)

  • 조무환;남영섭정재학김정목
    • KSBB Journal
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    • v.8 no.5
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    • pp.431-437
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    • 1993
  • Active carbon which has the smallest bulk and wet density was found as the best support media among 4 different kinds of materials(celite, natural zeolite, Pusuk stone, active carbon) to make a proper fluidized-bed with small energy consumption. Its minimum and optimum fluidization velocity were found as 0.03cm/sec and 0.25cm/sec, respectively. As organic loading rate for methane fermentation was increased, CODcr removal efficiencies of all the media were decreased. But, CODcr, removal efficiencies of active carbon was maintained more than 90% in this experimental range of the organic loading rate. Larger amount of microorganism was adsorbed on the active carbon which has very high specific surface area. At the organic loading rate of 16g CODcr,/l day, its adsorbed cell mass was 157mg/g. Comparing natural zeolite with roast celite, adsorbed cell mass did not increase in proportion to specific surface area of the media. Even though roast celite has the same specific surface area as the Pusuk stone, its organic removal ability was superior to that of the Pusuk stone, which explains that the relatively great surface roughness and the positive surface charge are important for cell adsorption. It was concluded that the support media for anaerobic fluidized reactor should have small wet density and small fuidization velocity, if possible, in order to increase cell adsorption by reducing the fluid shear stress.

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Clinical application of auto-tooth bone graft material

  • Park, Sung-Min;Um, In-Woong;Kim, Young-Kyun;Kim, Kyung-Wook
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.38 no.1
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    • pp.2-8
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    • 2012
  • Introduction: Auto-tooth bone graft material consists of 55% inorganic hydroxyapatite (HA) and 45% organic substances. Inorganic HA possesses properties of bone in terms of the combining and dissociating of calcium and phosphate. The organic substances include bone morphogenetic protein and proteins which have osteoinduction capacity, as well as the type I collagen identical to that found in alveolar bone. Auto-tooth bone graft material is useful as it supports excellent bone regeneration capacity and minimizes the possibility of foreign body reaction,genetic diseases and disease transmission. Materials and Methods: Implant placement combined with osteoinductive regeneration,preservation of extraction socket, maxillary sinus augmentation, and ridge augmentation using block type,powder type, and block+powder type autobone graft materialwere performed for 250 patients with alveolar bone defect and who visited the Department of Oral and Maxillofacial Surgery, College of Dentistry, Dankook University from September 2009 to August 2011. Results: Clinical assessment: Among the 250 patients of auto-tooth bone graft, clinical assessment was performed for 133 cases of implant placement. The average initial stabilization of placed implants was 74 implant stability quotient (ISQ). Radiological assessment: The average loss of crestal bone in the mandible as measured 6 months on the average after the application of prosthesis load was 0.29 mm, ranging from 0 mm to 3.0 mm. Histological assessment: In the histological assessment, formation of new bone, densified lamellated bone, trabecular bones, osteoblast, and planting fixtures were investigated. Conclusion: Based on these results, we concluded that auto-tooth bone graft material should be researched further as a good bone graft material with osteoconduction and osteoinduction capacities to replace autogenous bone, which has many limitations.

Catalytic Deep Oxidation of Volatile Organic Compound Toluene over CuO/γ-Al2O3 Catalysts at Lower Temperatures (CuO/γ-Al2O3 촉매상에서 휘발성 유기화합물 톨루엔의 저온산화)

  • Kim Sang-Hwan;Kim Jae-Sik;Yang Hee-Sung;Y Vu Trinh Nhu;Park Hyung-Sang
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.1
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    • pp.64-73
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    • 2007
  • The catalytic activity of transition metals (Cu, Co, Mn, Fe and Ni) supported on ${\gamma}-Al_2O_3$ for the oxidation of toluene was investigated in the microreactor of fixed-bed type. The catalytic activity of transition metals for the oxidation of toluene turned out to be increasing in the order of Ni$Cu/{\gamma}-Al_2O_3$ catalysts for the oxidation of toluene increased with the increasing loadings of copper, reached the maximum activity at 5% loadings of copper, and decreased with higher loadings of copper in the catalysts. The activity of $Cu/{\gamma}-Al_2O_3$ catalysts for the oxidation of toluene decreased with the increasing calcination temperatures. This might result from the decreasing surface area of catalysts due to the sintering of copper oxide as well as ${\gamma}-Al_2O_3$ supports. The 5wt% $Cu/{\gamma}-Al_2O_3$ catalysts calcined at $400^{\circ}C$ for 4 hrs in the air showed the highest activity for the oxidation of toluene. Mutual inhibition was observed for the binary mixture of toluene and xylene. The activity of the easy-to-oxidize toluene was greatly decreased while the difficult-to-oxidize xylene was slightly decreased in the binary mixture of toluene and xylene. It might suggest that the inhibition of toluene and xylene in the binary mixture resulted from the competitive adsorption for the adsorbed oxygen on the catalytic surface.

Preparation of Composite Membranes for Recovery of Unreacted Olefin Monomers (미반응 올레핀계 모노머 회수를 위한 복합막의 제조)

  • Kim, Hyun-Gi;Kim, Sang-Yong;Kim, Sung-Soo
    • Membrane Journal
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    • v.20 no.4
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    • pp.297-303
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    • 2010
  • Composite membranes were prepared for membrane/cold condensation process for recovery of unreacted olefin monomer from the polyolefin polymerization process by solution coating and plasma polymerization processes. Poly(dimethylsiloxane) (PDMS) solution was coated on polysulfone (PSF) support and increase of prepolymer content in solution made more dense membrane structure to result in the increase of separation factor while absolute flux decreased. Permeation of organic materials through the composite membranes follows the sorption and diffusion mechanism, which brought about the results that separation factor increased with critical temperature of the organic materials, and that flux increased with the increase of the molar volume. Crosslinking period affected the permeation characteristics. Other types of composite membranes were fabricated by plasma polymerization of siloxane materials on polypropylene (PP) and PSF supports. PP was tested as a support for composite membranes, which had not been used so far in solution coating process, and plasma polymerization made the composite membranes equivalent performances to those of membranes prepared by solution coating process.

Advances of Post-combustion Carbon Capture Technology by Dry Sorbent (건식흡수제 이용 연소배가스 이산화탄소 포집기술)

  • Yi, Chang-Keun
    • Korean Chemical Engineering Research
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    • v.48 no.2
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    • pp.140-146
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    • 2010
  • This paper addresses recent status and trends of carbon dioxide capture technologies using dry sorbents in the flue gas. The advantages of dry sorbent $CO_2$ capture technology are broader operating temperature range, less energy loss, less waste water, less corrosion problem, and natural properties of solid wastes. Recently, U.S.A. and Korea have been developing processes capturing $CO_2$ from real coal flue gas as well as sorbents improving sorption capacity to decrease total $CO_2$ capture cost. New class of dry sorbents have been developed such as chemisorbents with alkali metals of which material cost is low, amines physically adsorbed on silica supports, amines covalently tethered to the silica support, carbon-supported amines, polymer-supported amines, amine-containing solid organic resins and metal-organic framework. The breakthrough is needed in the materials on dry sorbents to decrease capture cost.

Removal of Volatile Organic Compounds from Water Using PU/PDMS-PTFE Composite Membranes by Vapor Permeation Separation Process (PU/PDMS-PTFE 복합막을 이용한 증기투과공정에 의한 물로부터 휘발성 유기화합물 제거)

  • Rhim Ji Won;Cheon Se Won;Yun Tae Ihl;Shin Hyun Su;Kim Baek Ahm;Chung Rae Ick
    • Membrane Journal
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    • v.15 no.1
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    • pp.44-51
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    • 2005
  • Polyurethane-polysiloxanes (PU/PDMS) was synthesized using 4,4'-diphenylmethane diisocyanate (MDI) and 1,4-butanediol (BD) to overcome the weakness to the organic chemicals. The composite membranes were prepared onto porous poly(tetrafluoroethylene) (PTFE) supports. In vapor permeation experiments, the flux increased with increasing operating temperatures and feed concentrations while the separation factors showed the opposite trend, so-called 'trade-off'. In this study, the effect of the flux on the operating temperatures was not severe since the content of the soft segments is fairly higher than that of the hard segments. The composite membrane type of PU/PDMS maintained high flux and separation factor as well when comparing with the dense type membranes.