• Title/Summary/Keyword: Organic Se

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Investigation on Posssiblility of Composting by Properties Analysis of Organic Sludge Composts (각종 유기성오니의 성상분석에 의한 퇴비화가능성의 검토)

  • Han, E.J.;Choi, H.G.;Lee, J.A.;Kim, K.Y.;Lee, C.K.;Park, K.H.;Phae, C.G.
    • Journal of the Korea Organic Resources Recycling Association
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    • v.8 no.1
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    • pp.109-120
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    • 2000
  • In the analysis of the common categories, moisture contents and organic concentrations were not much different according to the types of industry or treatment facilities. When heavy metals contribution of the sludge from domestic and industrial wastewater treatment facilities was analyzed, As, Hg and Cr concentrations were relatively high among 42 standards of the fertilizer law. As concentration war higher in 28 of 42 facilities (67%) than limits of the fertilizer law. Hg concentration was not acceptable in the 21 of 42 facilities (50%). Cr concentration was not acceptable in 9 of 42 facilities (21%). From these results, It is found that As is the most frequently detectable component and contaminant than any other heavy metals in sludges. The data from this experiment was also compared with the guidelines of harmful organics and the rest of heavy metals that are regulated by some of the foreign countries. Be, Se and Mo concentrations were lower than the limits. Among the organics, the average concentration of PCB (10 samples) was 26.2 ppb. The highest concentration was 162.6 ppb in the sludge of the municipal wastewater treatment facilities and the lowest concentration was 2.14 ppb from the skin manufacturing industry. From the leaching analysis of re-manufacturing goods from the sludge, most of them was acceptable on the regulation law but Cr concentration was over the limit.

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Influence of dietary organic trace minerals on enteric methane emissions and rumen microbiota of heat-stressed dairy steers

  • A-Rang Son;Mahfuzul Islam;Seon-Ho Kim;Sung-Sill Lee;Sang-Suk Lee
    • Journal of Animal Science and Technology
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    • v.65 no.1
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    • pp.132-148
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    • 2023
  • Ruminants are the main contributors to methane (CH4), a greenhouse gas emitted by livestock, which leads to global warming. In addition, animals experience heat stress (HS) when exposed to high ambient temperatures. Organic trace minerals are commonly used to prevent the adverse effects of HS in ruminants; however, little is known about the role of these minerals in reducing enteric methane emissions. Hence, this study aimed to investigate the influence of dietary organic trace minerals on rumen fermentation characteristics, enteric methane emissions, and the composition of rumen bacteria and methanogens in heat-stressed dairy steers. Holstein (n=3) and Jersey (n=3) steers were kept separately within a 3×3 Latin square design, and the animals were exposed to HS conditions (Temperature-Humidity Index [THI], 82.79 ± 1.10). For each experiment, the treatments included a Control (Con) consisting of only basal total mixed rations (TMR), National Research Council (NRC) recommended mineral supplementation group (NM; TMR + [Se 0.1 ppm + Zn 30 ppm + Cu 10 ppm]/kg dry matter), and higher concentration of mineral supplementation group (HM; basal TMR + [Se 3.5 ppm + Zn 350 ppm + Cu 28 ppm]/kg dry matter). Higher concentrations of trace mineral supplementation had no influence on methane emissions and rumen bacterial and methanogen communities regardless of breed (p > 0.05). Holstein steers had higher ruminal pH and lower total volatile fatty acid (VFA) concentrations than Jersey steers (p < 0.05). Methane production (g/d) and yield (g/kg dry matter intake) were higher in Jersey steers than in Holstein steers (p < 0.05). The relative abundances of Methanosarcina and Methanobrevibacter olleyae were significantly higher in Holstein steers than in Jersey steers (p < 0.05). Overall, dietary organic trace minerals have no influence on enteric methane emissions in heat-stressed dairy steers; however, breed can influence it through selective alteration of the rumen methanogen community.

Uranium Occurrences in Coaly Meta-Pelites in the Jinsan Area (진산일대(珍山一帶) 탄질변성이암층내(炭質變成泥岩層內)의 우라늄의 부존상태(賦存狀態))

  • Chi, Se-Jung;Kim, Se-Hyun;Lee, Pyeong-Koo
    • Economic and Environmental Geology
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    • v.18 no.1
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    • pp.1-9
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    • 1985
  • To understand the characteristics of uranium distribution, and the correlation of the uranium content and major constituents in uraniferous black slates from the Jinsan area of Ogcheon Fold Terrain, forty representative specimens were analyzed by mineralogical and radiometric techniques. According to statistical analysis, the uranium has a positive correlation with organic carbon and limonite, but a negative relation to muscovite and other opaques. The relationship with the highest and meaningful correlation is between log uranium and organic carbon. The log uranium-organic carbon correlation coefficient is 0.845 and these two constituents have about 71.4% association. It suggests that the abundance of organic carbon controlled the uranium precipitation. The relationship of organic carbon to log uranium can be expressed by following regression equation log ($U_3O_8{\times}10^4+1$)=-1.3447+2.5599 log (organic carbon). The multiple regression equation of different major components to log uranium is log ($U_3O_8{\times}10^4+1$)=0.77396+ 0.04465 (organic carbon)+0.00574 (quartz)-0.00964 (muscovite)+0.37827 (biotite)-0.02286 (clay substance)+0.01268 (other silicates)+0.1032 (barite)-0.00224 (apatite)+0.01606 (calcite)+0.08258 (hematite)-0.02406 (limonite)-0.01715 (other opaques).

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Biosynthesis of Organic Germanium Using Cordyceps militaris (동충하초를 이용한 유기게르마늄의 생산)

  • Kim, Seung;Kim, Jae-Sung;Sapkota, Kumar;Choi, Bong-Suk;Park, Se-Eun;Park, Yeal;Chun, Hong-Sung;Yoo, Jin-Cheol;Choi, Han-Seok;Kim, Myung-Kon;Kim, Sung-Jun
    • The Korean Journal of Mycology
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    • v.34 no.2
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    • pp.84-87
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    • 2006
  • In the present study, an attempt has been made to produce a high quality medicinal mushroom Cordycops militaris supplemented with organic Ge. Cordycops militaris was cultivated in SDAY liquid medium containing yeast extract 10 g, peptone 10 g, glucose 40 g per liter and chrysalis media supplemented with inorganic Ge at 100, 500, 1000, and 5000 ppm concentrations. The greatest organic Ge production of 442.4 ppm/g and 284 ppm/g were observed in SDAY liquid and Chrysalis media cultures supplemented with 100 ppm inorganic Ge respectively. Similarly, 4,509.7 ppm/g and 1,058 ppm/g of organic Ge were obtained from liquid and chrysalis media cultures supplemented with 5,000 ppm and 1,000 ppm inorganic Ge, respectively. In addition, higher concentration of organic Ge was obtained in mycelia than fruiting bodies. These results indicate that the concentration of organic Ge increase with decreasing inorganic Ge concentration in the medium. This is the first report on production of high valuable Cordyceps militaris contained with organic Ge.

One step facile synthesis of Au nanoparticle-cyclized polyacrylonitrile composite films and their use in organic nano-floating gate memory applications

  • Jang, Seok-Jae;Jo, Se-Bin;Jo, Hae-Na;Lee, Sang-A;Bae, Su-Gang;Lee, Sang-Hyeon;Hwang, Jun-Yeon;Jo, Han-Ik;Wang, Geon-Uk;Kim, Tae-Uk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.307.2-307.2
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    • 2016
  • In this study, we synthesized Au nanoparticles (AuNPs) in polyacrylonitrile (PAN) thin films using a simple annealing process in the solid phase. The synthetic conditions were systematically controlled and optimized by varying the concentration of the Au salt solution and the annealing temperature. X-ray photoelectron spectroscopy (XPS) confirmed their chemical state, and transmission electron microscopy (TEM) verified the successful synthesis, size, and density of AuNPs. Au nanoparticles were generated from the thermal decomposition of the Au salt and stabilized during the cyclization of the PAN matrix. For actual device applications, previous synthetic techniques have required the synthesis of AuNPs in a liquid phase and an additional process to form the thin film layer, such as spin-coating, dip-coating, Langmuir-Blodgett, or high vacuum deposition. In contrast, our one-step synthesis could produce gold nanoparticles from the Au salt contained in a solid matrix with an easy heat treatment. The PAN:AuNPs composite was used as the charge trap layer of an organic nano-floating gate memory (ONFGM). The memory devices exhibited a high on/off ratio (over $10^6$), large hysteresis windows (76.7 V), and a stable endurance performance (>3000 cycles), indicating that our stabilized PAN:AuNPs composite film is a potential charge trap medium for next generation organic nano-floating gate memory transistors.

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Synthesis and Characteristics of Organic Emitting Materials for OLEDs using Color Conversion Method (색변환법 유기전계발광 소자용 유기 발광 재료의 합성 및 특성 분석)

  • Kwak, Seon-Yeop;Ryu, Jung-Yi;Nam, Jang-Hyun;Lee, Tae-Hoon;Kim, Tae-Hoon;Son, Se-Mo
    • Journal of the Korean Graphic Arts Communication Society
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    • v.23 no.1
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    • pp.77-97
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    • 2005
  • Organic light-emitting diodes(OLEDs) have received considerable attention since they were first reported by Tang. Novel organic fluorescent materials have been reported on synthesis and application of new organic light-emitting materials. Despite of much recent progress, fabrication of full-color OLEDs still remained to be done. Many method have been proposed to full-color OLEDs displays such as using separated red, green and blue emitters, stacking separate rad, green and blue emitter, using a white emitter with individually pattered color filters, microcavity structures and using a blue emitter with individually patterned fluorescent materials. The last method has much attention because of easy fabrication of OLEDs and low-priced fabrication. This paper reports the optical and electrical characteristics of OLEDs using novel molecules containing biphenyl structure. Optical properties of biphenyl derivatives doped with poly(9-vinyl carbazole)(PVK) are measured and found Forster energy transfer process in the blends. And devices were fabricated as ITO/PEDOT/PVK doped with biphenyl derivatives/$Alq_3$/Li:Al and I-V-L characteristics and EL efficiency of devices were examined.

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Synthesis of New Blue OLEDs with Biphenyl Structure and Relationship between EL Efficiency and Drift Mobility (Biphenyl 구조를 가진 새로운 청색 유기 발광 재료의 합성 및 EL효율과 이동도의 관계에 대한 연구)

  • Lee, Tae-Hoon;Ryu, Jung-Yi;Kim, Tae-Hoon;Nam, Jang-Hyun;Park, Seong-Soo;Son, Se-Mo
    • Journal of the Korean Graphic Arts Communication Society
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    • v.22 no.2
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    • pp.179-198
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    • 2004
  • Organic electroluminescent devices are light-emitting diodes in which the active materials consist entirely of organic materials. Recently, many fluorescent organic materials have been reported and the study on synthesis and application of new organic light-emitting materials has been demanded. This paper reports the optical and electrical characteristics of OLEDs using novel polymers containing biphenyl structure. First, Optical properties of novel light-emitting biphenyl derivatives doped with poly(9-vinyl carbazole)(PVK) and emitted blue, bluish green color, which is attributed to the overlap area between PL spectrum of host(PVK) and absorption spectra of guests(polymer). This is correspondent with F$\"{o}$rster energy transfer process in the blends. And, OLED devices were fabricated using poly (3,4-ethylenedioxy thiophene) (PEDOT) as a hole injection material and tris-(8-hydroxyquinoline) aluminum ($Alq_3$) as an electron transporting material. EL devices fabricated as ITO/PEDOT/PVK doped with biphenyl derivatives/$Alq_3$/Li:Al and I-V-L chatacteristics and emitting efficiency of EL devices were examined. Finally, the drift mobility of PVK doped with biphenyl derivatives and $Alq_3$ were measured by TOF technique varying applied electric field. EL efficiency was increased as the ratio of hole mobility of PVK doped with biphenyl derivatives and electron mobility of $Alq_3$ was close to one.

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A Study on Optical Properties of Nanocomposite Composed of Au Nanorods and Organic Dyes (금 나노막대와 유기 염료로 구성된 나노복합체의 광학특성 연구)

  • Kim, Ki-Se;Yoo, Seong Il;Sohn, Byeong-Hyeok
    • Clean Technology
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    • v.20 no.2
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    • pp.141-145
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    • 2014
  • In this study, we studied optical properties on the layer-by-layer (LbL) assemblies consisting of Au nanorods and organic dyes. For this purpose, poly (allylamine hydrochloride), PAH and poly (styrene sulfonate), PSS were selected as ionic polymers and rhodamine B isothiocyanate (RB) was utilized as an organic dye based on its spectral overlap with plasmon band of Au nanorods. In the view point of assembling methods, RB was covalently attached to PAH, then, LbL structure of Au [PSS/PAH]2/PSS/PAH-RB was prepared by sequential coating of PAH, PSS, PAH-RB on Au nanorods. Since the prepared LbL assembly exhibits both plasmonic and fluorescent properties, we studied the mutual nanorod-dye properties by dissolving Au nanorods.

Transepithelial Transport of Organic Cation and Its Inhibition by Sulfhydryl and Carboxyl Reagents in Opossum Kidney Cell Monolayer

  • Woo, Jae-Suk;Oh, Se-Ok;Jung, Jin-Sup;Kim, Yong-Keun;Lee, Sang-Ho
    • The Korean Journal of Physiology
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    • v.30 no.1
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    • pp.53-62
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    • 1996
  • Transepithelial transport of tetraethylammonium (TEA) was studied in monolayers of opossum kidney cells cultured on permeable membrane filters. $[^{14}C]-TEA$ was transported across the OK cell monolayer from basolateral to apical side by a saturable process which can be stimulated by acidification of the apical medium. The apparent Michaelis-Menten constant $(K_{m})$ and the maximum velocity$(V_{max})$ for the transport were $41\;{\mu}M$ and 147 pmole/ mg protein/ min, respectively. The transport was significantly inhibited by unlabelled TEA, amiloride, cimetidine, choline, and mepiperphenidol added to the basolateral side at 1 mM and was slightly inhibited by 5 mM $N_{1}-methylnicotinamide\;(NMN).$ Unlabelled TEA added to the apical side stimulated the $basolateral-to-apical\;{^{14}C}-TEA$ transport, suggesting that the TEA self-exchange mechanism was involved at the apical membrane. Sulfhydryl reagents such as ${\rho}-chloromercuribenzoic\;acid\;(PCMB)\;and \;{\rho}-chloro-mercuribenzene\;sulfonate \;(PCMBS)$ and carboxyl reagents such as N,N'-dicyclohexylcarbodiimidem (DCCD) and N-ethoxy-carbonyl-2-ethoxy-1,2-dihydro-quinoline(EEDQ) inhibited the TEA transport at both the basolateral and apical membranes of the OK cell monolayer. These results suggest that OK cell monolayers possess a vectorial transport system for organic cations which is similar to that for organic cation secretion in the renal proximal tubule.

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Characteristics on Thermal Maturity of Organic Matter, Block VI-1 in the Ulleung Basin (울릉분지 6-1광구 유기물의 열적 성숙도 특성)

  • Cheong Tae-Jin;Lee Young-Joo;Ryu Byong-Jae;Oh Jae-Ho;Kim Ji-Hoon;Yi Songsuk;Park Se-Jin
    • The Korean Journal of Petroleum Geology
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    • v.10 no.1_2 s.11
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    • pp.1-9
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    • 2004
  • A total of 17 exploratory wells were drilled from the Block VI-1 and recently commercial gas field was discovered in the Ulleung Basin. Thermal maturity of organic matter in the sediments from the drilling wells were evaluated for the characterization of the petroleum system of the basin. Level of thermal maturation of organic matter is different depending on the area to area. The top of oil window is located at about 800 m in the Dolgorae 5 area, and it is relatively deeper in both western and northern areas. It seems that thermal maturity of organic matter reached present stage before tectonism in the deformed zone 2, whereas thermal maturation continued after tectonism in other zones.

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