• Title/Summary/Keyword: Organic IC

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A Study of Interference Factor of Analysis Method of Hexavalent Chromium in Soil using UV/VIS Spectrometry and Application of Ion Chromatography (자외선/가시선 분광법을 이용한 토양 중 6가 크롬 분석방법의 방해요인 분석 및 이온크로마토그래피 적용에 관한 연구)

  • Noh, Hoe-Jung;Lee, Myung-Gyu;Lee, Hyeon Seok;Kim, Mira;Kim, Dongho;Kim, Tae Seung
    • Journal of Soil and Groundwater Environment
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    • v.17 no.6
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    • pp.33-42
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    • 2012
  • This study was performed to find the problems according to interference factors (organic matter, pH, Cr, Mn, Fe, clay, and etc.) when we analyzed the hexavalent chromium [Cr(VI)] in soils using UV/VIS spectrometer (US EPA 7196A), attempted to evaluate the domestic applicability of analytical method (US EPA 7199) using IC-UV/VIS spectrometer as alternative method. The recovery rate of certified reference materials was 75.0% (US EPA 7196A) and 101.4% (US EPA 7199) by the analytical methods. As the results of performing QA/QC about US EPA 7199, method detection limit (MDL) and limit of quantification (LOQ) were 0.062 mg/kg, 0.196 mg/kg, respectively. The LOQ of US EPA 7199 was lower than that of the current soil official testing method in Korea (0.5 mg/kg). Cr(VI) contents in 23 soil samples were compared by the analytical methods of EPA 7196A and 7199. Cr(VI) was detected in 13 of 23 soil samples by EPA 7196A, while EPA 7199 was not detected in any soil samples. The Cr(VI) content in 23 soil samples by EPA 7196A was not clearly correlated with Cr, Fe, Mn and clay content in the soil samples. However, the contents of Cr(VI) and organic matter of the soil samples had the highest coefficient of determination ($R^2$) of 0.80. In order to evaluate the correlation between the recovery rates of Cr(VI) and organic matter contents in the soil samples, the recovery rates of 5 soil samples added Cr(VI) standard solution were analyzed by the analytical methods. According to the results, the higher the organic matter contents in soil samples, the lower the recovery rates of Cr(VI) by US EPA 7196, while in case of US EPA 7199, the recovery rates were stable regardless of the organic matter contents.

Effects of Soil Organic Matter Content on Activity Change, Vertical Migration, and Persistence of Two Nematicides, Carbofuran and Ethoprophos, to Root-Knot Nematode, Meloidogyne incognita (토양중 유기물함량 차이에 따른 고구마뿌리혹선충(Meloidigyne incognita)에 대한 Carbofuran과 Ethoprophos의 효력변동, 수직이동성 및 잔효성조사)

  • Song, Cheol;Hwang, In-Taek;Jang, Kyoung-Soo;Cho, Kwang-Yun
    • Korean journal of applied entomology
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    • v.38 no.1
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    • pp.47-52
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    • 1999
  • Effects of organic matter content in soil on activity. vertical migration. and persistence of two nernaticides. carbofuran and ethoprophos. to root-knot nematode, Mrloitlog!~iei ~lcognita.w ere investigated. As the organic matter content increased. activity of the nernaticides tended to be reduced. Both nematicides exhibited control values of more than 80'k' to M. iix.o,yilit~iln 0-2 cm depth soil layer from the surface. regi~rdless of organic matter content in soil. In 2-4 cm depth soil layer. however. the control value of the neniaticides varied with the organic niatter content in soil. The control value of carbofuran in the soil layer was ranged from I0 to 30'2,. depending on the soil organic niatter content. In contrast. ethoprophos had no control value against M. i/ic.o,ytlitcr in the \oil layer, except that the nematicide had a control value of 30% when the organic matter content was 0.4%. Furthermore. ethoprophos had no effect on controlling M. i/ic.o,gtiitrr in soil layer of below 4cm. whereas control values of carbofuran were approximately from 5 to 20% in all test soils having different organic matter contents. These results indicate that carbofuran has more vertical migration effect than ethoprophos. Persistence of the two neniaticides was also decreased with increasing soil organic matter content. Half life of carbofuran was 2-3 weeks in soil containing 0.4% organic matter, whereas it was found to be I week in soils containning 0.8 ant1 1.6% of organic matter. On the other hand. activity of ethoprophos was reduced to half in 3-3 weeks and in 2-3 weeks in soil containing 0.4 and 0.8%, and 1.6%) of organic matter, respectively. However, no activity of the both nernaticides was found in soil containing 3.2% of organic matter.

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Organic Integrated Circuits based on Pentacene TFTs

  • Xu, Yong-Xian;Kong, Sang-Bok;Song, Chung-Kun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1680-1682
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    • 2007
  • The integrated circuits such as inverters, ring oscillators, NAND and NOR gates, and rectifiers were fabricated on PEN substrate by using pentacene TFTs. The OTFTs used bottom contact structure and produced the average mobility of $0.26\;cm^2/V.sec$ and on/off current ratio of $10^5$. All circuits worked successfully like the simulation results. Especially, the rectifier was able to operate up to 1 MHz input signals, and ring oscillator exhibited oscillation frequency of 1MHz at-40V.

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Melixyloidin, A New Acridone Alkaloid from Melicope xanthoxyloides Leaves

  • Saputri, Ratih Dewi;Tanjung, Mulyadi;Tjahjandarie, Tjitjik Srie
    • Natural Product Sciences
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    • v.27 no.3
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    • pp.183-186
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    • 2021
  • A new acridone alkaloid, melixyloidin (1), and two known alkaloids (2-3) were isolated from Melicope xanthoxyloides (F. Muell) T.G. Hartley leaves. The structure of melixyloidin were elucidated using NMR spectra and high-resolution ESIMS data. Acridone alkaloids 1-3 were evaluated against MCF-7 and HeLa cells. 1,3,4-Trimethoxy-10-methylacridin-9-one (2) showed potent cytotoxic activity against MCF-7 cells with an IC50 value of 5.31 μM.

Organic-inorganic Hybrid Dielectric with UV Patterning and UV Curing for Global Interconnect Applications (글로벌 배선 적용을 위한 UV 패턴성과 UV 경화성을 가진 폴리실록산)

  • Song, Changmin;Park, Haesung;Seo, Hankyeol;Kim, Sarah Eunkyung
    • Journal of the Microelectronics and Packaging Society
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    • v.25 no.4
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    • pp.1-7
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    • 2018
  • As the performance and density of IC (integrated circuit) devices increase, power and signal integrities in the global interconnects of advanced packaging technologies are becoming more difficult. Thus, the global interconnect technologies should be designed to accommodate increased input/output (I/O) counts, improved power grid network integrity, reduced RC delay, and improved electrical crosstalk stability. This requirement resulted in the fine-pitch interconnects with a low-k dielectric in 3D packaging or wafer level packaging structure. This paper reviews an organic-inorganic hybrid material as a potential dielectric candidate for the global interconnects. An organic-inorganic hybrid material called polysiloxane can provide spin process without high temperature curing, an excellent dielectric constant, and good mechanical properties.

Change of Vegetation and Soil Characteristics of Green Roofs in Dongguk University (동국대학교 옥상녹화 지역의 식생 및 토양특성 변화)

  • Lee, Sang-Jin;Park, Gwan-Soo;Kim, Dong-Il;Lee, Dong-Kun;Kil, Sung-Ho;Jang, Seong-Wan;Park, Beom-Hwan;Yun, Jun-Young;Jang, Kwan-Woo;Lee, Ho-Young;Kwon, Oh-Jung
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.16 no.1
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    • pp.193-206
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    • 2013
  • This study was to provide the base data on the status of vegetations and soils in green roofs by analyzing the soil and vegetation characteristics of 4 green roofs in Dongguk University in September 2012. Sanglokwon(SW), Dongguk Hall(DH), University Library(UL), and Information and Culture Hall P(IC) were established in 2005, 2008, 2009, and 2010, respectively. The areas of green roofs were $700m^2$, $2,300m^2$, $1,240m^2$, and $640m^2$ in SW, DH, UL, and IC respectively. The investigated floras of vascular plants were 26 families, 55 genera, 65 species in Sanglokwon(SW), 53 families, 99 genera, 112 species in Dongguk Hall(DH), 43 families, 77 genera, 84 species in University Library(UL), and 41 families, 71 genera, 75 species in Information and Culture Hall P(IC), respectively. A positive correlation is shown between the number of plant species and planting area. Total nitrogen, organic matter, and potassium in soil have positive correlation with the number of plant species. The number of plant species was proportional to area and increased more than twice after planting. About a quarter of the invaded plants (including native and naturalized species) were naturalized plants. The total soil depths including vegetation soil and drainage soil at SW, DH, UL, and IC were 20cm, 10cm, 10cm, and 8cm, respectively. The depths of vegetation soil at SW, DH, UL, and IC were <7cm, <3cm, <2cm, and <2cm respectively. The soil pH in vegetation soil ranged from 5.22 to 5.36, and from 6.13 to 6.39 in drainage soil. Available-P concentration ranged from 10.17 to 189.77mg/kg in vegetation soil and from 6.70 to 81.17mg/kg in drainage soil. Carbon concentration in vegetation soil ranged from 2.93 to 9.70%, and 2.93 to 9.70% in drainage soil. Carbon contents in 20cm, 10cm, 10cm, and 8cm soil depths were $2.62kg/m^2$, $1.89kg/m^2$, $0.50kg/m^2$, and $0.53kg/m^2$ at SW, DH, UL, and IC, respectively.

Tyrosinase-inhibitory and Radical Scavenging Activities from the Seeds of Coix lachryma-jobi L. var. ma-yuen [Roman] Stapf (율무의 tyrosinase 저해활성과 radical 소거효과)

  • Kim, Jong-Kil;Lee, Heum-Sook
    • Korean Journal of Food Science and Technology
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    • v.32 no.6
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    • pp.1409-1413
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    • 2000
  • The seeds of Coix lachryma-jobi L. var. ma-yuen(yullmoo) were investigated for the free radical scavenging and mushroom tyrosinase inhibitory activities. Brown yullmoo, which contains bran in the seed, has also been evaluated for comparison. After partitioning of the total methanol extracts of yullmoo and brown yullmoo, each organic layer exhibited mild or potent dose-dependent inhibition(about 20-80%) on 1,1-diphenyl picryl hydrazyl(DPPH) free radical with the concentration of $300\;{\mu}g/ml$ to $800\;{\mu}g/ml$. n-Butanol fraction of yullmoo showed the most potent scavenging effect on DPPH free radical. $IC_{50}$ of n-butanol fraction was $423\;{\mu}g/ml$, about six to seven fold higher concentration than standard BHT at the same inhibition rate. As for the tyrosinase inhibitory activity, all of the fractions including the methanol extract exhibited the similar activities even after partitioning. The chloroform fraction of brown yullmoo was found to show the most potent inhibitory activity with an $IC_{50}$ of $321.5\;{\mu}g/ml$.

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Functional Gene Analysis to Identify Potential Markers Induced by Benzene in Two Different Cell Lines, HepG2 and HL-60

  • Kim, Youn-Jung;Song, Mi-Kyung;Sarma, Sailendra Nath;Choi, Han-Saem;Ryu, Jae-Chun
    • Molecular & Cellular Toxicology
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    • v.4 no.3
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    • pp.183-191
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    • 2008
  • Volatile organic compounds (VOCs) are common constituents of cleaning and degreasing agents, paints, pesticides, personal care products, gasoline and solvents. And VOCs are evaporated at room temperature and most of them exhibit acute and chronic toxicity to human. Benzene is the most widely used prototypical VOC and the toxic mechanisms of them are still unclear. The multi-step process of toxic mechanism can be more fully understood by characterizing gene expression changes induced in cells by toxicants. In this study, DNA microarray was used to monitor the expression levels of genes in HepG2 cells and HL-60 cells exposed to the benzene on IC20 and IC50 dose respectively. In the clustering analysis of gene expression profiles, although clusters of HepG2 and HL-60 cells by benzene were divided differently, expression pattern of many genes observed similarly. We identified 916 up-regulated genes and 1,144 down-regulated genes in HepG2 cells and also 1,002 up-regulated genes and 919 down-regulated genes in HL-60 cells. The gene ontology analysis on genes expressed by benzene in HepG2 and HL-60 cells, respectively, was performed. Thus, we found some principal pathways, such as, focal adhesion, gap junction and signaling pathway in HepG2 cells and toll-like receptor signaling pathway, MAPK signaling pathway, p53 signaling pathway and neuroactive ligand-receptor interaction in HL-60 cells. And we also found 16 up-regulated and 14 down-regulated commonly expressed total 30 genes that belong in the same biological process like inflammatory response, cell cycle arrest, cell migration, transmission of nerve impulse and cell motility in two cell lines. In conclusion, we suggest that this study is meaningful because these genes regarded as strong potential biomarkers of benzene independent of cell type.

Antioxidants and Acetyl-cholinesterase Inhibitory Activity of Solvent Fractions Extracts from Dendropanax morbiferus (황칠나무의 용매 분획별 추출물의 항산화 활성 및 Acetyl-cholinesterase 저해 활성비교)

  • Yu, Ji Min;Moon, Hyung In
    • Korean Journal of Plant Resources
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    • v.31 no.1
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    • pp.10-15
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    • 2018
  • The leaves and stems of Dendropanax morbiferus were separated from organic solvents with methanol. The organic solvent fractions were fractionated with dichloromethane, ethyl acetate and butanol according to the systematic fractionation method. Oxidation in the body induces aging, and antioxidant activity has attracted the attention of many people as a preventive component to suppress negative reactions in the body. To investigate the antioxidant activity of Dendropanax morbiferus were subjected to DPPH free radical assay. In addition, acetyl cholinesterase inhibitions were performed for Alzheimer's disease as an aging neurological disease. As a result, it was confirmed that the antioxidant effect of DPPH was generally good in the antioxidant test. The ethyl acetate fractions of Dendropanax morbiferus stems and leaves were $IC_{50}=30{\mu}g/m{\ell}$. Acetyl cholinesterase inhibition experiments were carried out at a concentration of $250{\mu}g/m{\ell}$. Dendropanax morbiferus stems fractions showed dichloromethane fraction of 57.68%, which significantly inhibited the activity of acetyl cholinesterase.

Cytotoxic Polyene Antibiotics from Myxococcus stipitatus JW111 (Myxococcus stipitatus JW111이 생산하는 Polyene계 항암활성물질)

  • Ahn, Jong-Woong
    • Applied Biological Chemistry
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    • v.45 no.2
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    • pp.114-118
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    • 2002
  • Phenalamides $A_1{\sim}A_3$ were reisolated as cytotoxic substances from culture broth of Myxococcus stipitatus JW111. The producing strain was isolated from the marine sediment collected off the shore of Geomun Island, Korea. The active principles were extracted from cell mass with acetone and successively purified by silica gel column chromatography, Sephadex LH-20 column chromatography, and finally recycling prep. HPLC. These compounds demonstrated significant cytotoxicity against certain human cancer cells, having $IC_50$ values ranging from 0.23 to 0.50 ${\mu}g/ml$. Moreover, they also inhibited the growth of adriamycin-resistant HCT/ADM human cancer cell line as well as its parent sensitive cell line.