• 제목/요약/키워드: Organic Form

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Symmetric Bis-Azospiropyrans: Synthesis, Characterization and Colorimetric Study

  • Nourmohammadian, Farahnaz;Abdi, Ali Ashtiani
    • Bulletin of the Korean Chemical Society
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    • v.34 no.6
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    • pp.1727-1734
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    • 2013
  • Synthesis and characterization of some novel symmetric bis-azospiropyrans are reported in this study. These bis-azospiropyrans are bifunctional chromophores with two spiropyrans linked by a bis-azo extended aromatic system that produce more color strength (large molar absorption coefficient in mero forms) due to appending two azospiropyran chromophores on one molecule. Comparing to the molar absorption coefficients of the conventional spiropyran chromophores (${\varepsilon}=0.31{\times}10^4\;M^{-1}{\cdot}cm^{-1}$) and mono-azospiropyran chromophores ($1.35{\times}10^4\;M^{-1}{\cdot}cm^{-1}$), the novel synthesized photochromes showed astonishingly increased molar absorption coefficients ($2.3-3.8{\times}10^4\;M^{-1}{\cdot}cm^{-1}$) at the same conditions. Such high molar absorption coefficients confers high sensitivity to light and more color intensity of mero form, that leads to improvement of their light sensitivity and better discrimination of spiro (OFF) form from mero (ON) ones in molecular switches. The structures were deduced from their MS, FT-IR, and $^1H$-NMR spectroscopic data and CHN analysis. All the synthesized photochemically bifunctional compounds revealed fluorescent emission in their colorless form which was faded out after exposing to UV light. Fluorescence quantum yield values of the mero forms were 0.25-0.81 and two high fluorescence quantum yield values (0.60 and 0.81) were found in these series.

Exfoliation of Dion-Jacobson Layered Perovskite into Macromolecular Nanoplatelet

  • Lee, Won-Jae;Yeo, Hyun Jung;Kim, Do-Yun;Paek, Seung-Min;Kim, Young-Il
    • Bulletin of the Korean Chemical Society
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    • v.34 no.7
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    • pp.2041-2043
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    • 2013
  • A layered perovskite of Dion-Jacobson phase, $RbLaTa_2O_7$, was successfully exfoliated into colloidal suspension via successive ion-exchange and intercalation reaction. The pristine perovskite $RbLaTa_2O_7$ was synthesized by conventional solid-state reaction, and then, it was ion-exchanged with hydrochloric acid to obtain a protonic form of perovskite. The resulting proton-exchanged perovskite was reacted with ethylamine to increase interlayer spaces for further intercalation reaction. Finally, the ethylamine-intercalated form was exfoliated into nanosheets via an intercalation of bulky organic cations (tetrabutylammonium). According to X-ray diffraction (XRD) analysis, the TBA-intercalated form showed remarkably increased interlayer spacing (${\Delta}d$ = 1.67 nm) in comparison with that of the pristine material. Transmission electron microscopic image of exfoliated perovskite clearly revealed that the present exfoliated perovskite were composed of very thin layers. This exfoliated perovskite nanosheets could be applicable as building blocks for fabricating functional nanocomposites.

점토로부터 철불순물의 생물학적 제거에 미치는 탄소원의 영향

  • Lee, Eun-Young;Cho, Kyung-Suk;Ryu, Hee-Wook;Bae, Moo
    • Microbiology and Biotechnology Letters
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    • v.25 no.6
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    • pp.552-559
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    • 1997
  • Fe (III) impurities in clay could be microbially removed by inhabitant dissimilatory Fe (III) reducing microorganisms. Insoluble Fe (III) in clay particles was leached out as soluble reductive form, Fe (II). The microorganisms removed from 10 to 45% of the initial Fe (III) when each sugar was supplemented to be in ranges of 1 - 5 % (w/w; sugar/clay). The microorganisms reduced 2.1 - 12.8 mol of Fe (III) per 100 mol of carbon in sugars metabolized when sugars such as glucose, maltose, and sucrose were used as sole carbon source. Bacillus sp. IRB-W and Pseudomonas sp. IRB-Y were isolated from the enrichment culture of the clay. The isolates were considered to participate in metabolizing organic compounds to fermentative intermediates with relatively little Fe (III) reduction at initial Fe (III) reduction process. By the microbial treatment, the whiteness of the clay was increased form 63.20 to 79.64, whereas the redness was obviously decreased form 13.47 to 3.55. This treatment did not cause any unfavorable modifications in mineralogical compositions of the clay.

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A Study on the Works of Philip Treacy II (필립트레이시(Philip Treacy) 작품연구II)

  • Kim, Eun-Sil
    • Journal of the Korean Society of Costume
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    • v.59 no.10
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    • pp.151-171
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    • 2009
  • The purpose of this study is to analyze the formative relationship between clothes and hat with the works by Philip Treacy, the designer who raised hats to one of important fashion accessories. The method to analyze the relationship between clothes and hats was the formative analysis by Marian L. Davis and Marilyn R. Delong. The results suggest that clothes and hat had an organic relationship, and a hat style was changed with formative elements of clothes. Clothes and hats by Philip Treacy were analysed in the aspects of Form, Color, Material, and Decoration. As a result, hats by Philip Treacy were mainly designed by the relationship between whole types without a closed line and showed geometric and formative forms, similarly harmonized with clothes. To highlight hats, the achromatic colors such as black and gray were used. Besides clothes and hats were coordinated by the same colors, but contrary colors were used to express a strong image. Felt or straw materials maily used to express a formative and fixed form were well matched with smooth, opaque, and lusterless materials such as wool. Also when transparent materials were used for hats, lace was used for clothes. A hat made of acrylic was matched with clothes made of glossy vinyl coating materials. Decoration was mainly removed but if used, feather decoration was added to clothes.

A Study on the Formative Relationship of between Artistic Eye-Makeup and Clothing - Focus on Fashion Magazine From the 2000's to 2010 - (조형적 측면에서 본 예술로서의 아이메이크업과 의복과의 상관성 연구 - 2000년부터 2010년까지 패션잡지를 중심으로 -)

  • Kim, Eun-Sil
    • Journal of the Korean Society of Costume
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    • v.62 no.3
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    • pp.120-136
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    • 2012
  • The purposes of this study is to analyze the formative relationship between artistic eye-makeup and clothes design by focusing on the period from 2000 to 2010 and to find out the development direction of the next makeup design. This study considered formative theory to analyze the formative relationship between artistic eye-makeup and clothes design of $Marian$ $L.$ $Davis$ and $Marilyn$ $R.$ $Delong's$ theory, and analyzed the formative relationship between artistic eye-makeup and clothes design in an aspect of line and form, color and material, The results are as follows: First, the shapes of the artistic eye-makeup such as tear drops, and rectangular paisleys were similar with the form of clothes such as the hourglass, cylinders and mix-types. Second, monotonic color coordination mainly appeared and sometimes contrast color coordination that induced complex contrast coordination were apparent as well. Third, the objects of the artistic eye-makeup such as glitter papers, spangles and beads had similar features as the material of clothes such as silk and spangle, and contrast was partially used like colors. The results suggest that artistic eye-makeup and clothes have an organic relationship, and artistic eye-makeup is changed with formative elements of clothes.

Study of Furniture Design Utilizing 3D Printers Joris Laarman (요리스 라만(Joris Laarman)의 3D프린터를 활용한 가구디자인에 관한 연구)

  • Lee, Hyun Jung
    • Journal of the Korea Furniture Society
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    • v.27 no.2
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    • pp.128-136
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    • 2016
  • Digital designs that appear in the three-dimensional virtual space by the digital type are designed as there is not an image created with an organic artificially generated (Creation) and representation (Modifying), developed by the specific environment given. The advanced digital design will produce a result with an algorithm according to a mathematical operation and the environment and has the nature of generating the real world, changes, development and affinity (Genetic Process). The digital design process is largely defined by a set of processes that are consistently designed to integrate form of creation, reproduction, proceeds in three steps, while the manufacture and assembly as a form of maintenance as possible the intended form of control data from the concept of building. By Joris Laarman 3D printer design is a simulation created by the digital process by the various algorithms and design achieved through the development of 3D printers, such as new materials and MX3D. From the mold production of a complex whole by using a robot and other digital production tool extracts a variety of forms.

Advanced Retention and Drainage Technology Offers Improved Performance and Operational Cost Savings

  • Freeman William L.
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.239-243
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    • 2006
  • Papermaking has changed remarkably during the past 20 years, creating huge pressures on retention and drainage programs. During this time, technology has advanced from single PAM flocculants to inorganic microparticle-based programs and then to micropolymer-based programs. In today's evolving fine paper market, retention and drainage programs have to meet increased demands in many areas, such as increased speed, GAP formers, dilution headboxes, higher ash levels, reduced furnish quality, lower cost, and increased machine efficiency. Hercules recently introduced a new technology that offers performance and stability improvements and operational cost savings as compared to existing advanced technologies. $PerForm(R)$ SP Advanced Retention and Drainage Technology consists of a family of products based on a structured organic particulate that offers papermakers the ultimate flexibility for management of wet end chemistry. This paper compares $PerForm(R)$ SP Advanced Retention and Drainage Technology to inorganic microparticle and micropolymer technologies and provides multiple case histories on machines that demonstrate the benefits of the technology. In these case histories, the PerForm SP is shown to provide improved retention and drainage that results in improved performance and operational cost savings to the mill.

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BioCC: An Openfree Hypertext Bio Community Cluster for Biology

  • Gong Sung-Sam;Kim Tae-Hyung;Oh Jung-Su;Kwon Je-Keun;Cho Su-An;Bolser Dan;Bhak Jong
    • Genomics & Informatics
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    • v.4 no.3
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    • pp.125-128
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    • 2006
  • We present an openfree hypertext (also known as wiki) web cluster called BioCC. BioCC is a novel wiki farm that lets researchers create hundreds of biological web sites. The web sites form an organic information network. The contents of all the sites on the BioCC wiki farm are modifiable by anonymous as well as registered users. This enables biologists with diverse backgrounds to form their own Internet bio-communities. Each community can have custom-made layouts for information, discussion, and knowledge exchange. BioCC aims to form an ever-expanding network of openfree biological knowledge databases used and maintained by biological experts, students, and general users. The philosophy behind BioCC is that the formation of biological knowledge is best achieved by open-minded individuals freely exchanging information. In the near future, the amount of genomic information will have flooded society. BioGG can be an effective and quickly updated knowledge database system. BioCC uses an opensource wiki system called Mediawiki. However, for easier editing, a modified version of Mediawiki, called Biowiki, has been applied. Unlike Mediawiki, Biowiki uses a WYSIWYG (What You See Is What You Get) text editor. BioCC is under a share-alike license called BioLicense (http://biolicense.org). The BioCC top level site is found at http://bio.cc/

Aluminum Toxicity on Corn Seedlings (옥수수 유묘(幼苗)에 대(對)한 알미늄 독성(毒性))

  • Lee, Yong-Seok
    • Korean Journal of Soil Science and Fertilizer
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    • v.10 no.2
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    • pp.75-78
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    • 1977
  • Corn (Zea may, L.) was grown alternatively in nutrient solution and hydroxy Al or Al-citrate solution to identify the form of Al which induces Al toxicity on Corn seedlings. Corn seedlings exposed to hydroxy Al solution was very toxic but Al-citrate solution did not show any toxic symptoms. At pH 7 with Al-citrate solution, severe Fe, deficiency was induced probably by the decrease of stability constant of Al-and Fe-oganic complexes and subsequent precipitation of Al-and Fe-as a hydroxide form. Addition of humic acid ameliorated the Al toxicity somewhat at pH 4.7 with hydroxy-Al solution but at pH 7 it induced more severe Fe deficiency.

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A Study on the Development of Low Speed Twin-Hull Form for Seabed Organic Sediment Collection (해저 유기퇴적물 수거를 위한 저속 쌍동형 선형개발 연구)

  • Park, Je-woong;Kim, Do-jung;Oh, Woo-jun;Jeong, Uh-cheul
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.22 no.2
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    • pp.246-252
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    • 2016
  • In this study, conceptual design of the fore-body hull form of catamaran type dredging vessel was performed that can effectively remove the contaminated sediments in coastal seabed. The hull form was simpled for the easy hull construction and the resistance performance was investigated to find out the effect of hull form parameters between variation of waterline and angle of entrance, etc. The relation between resistance performance and characteristics of free surface flows according to variation of bow forms was investigated by model testing in the circulating water channel and using Ansys CFX. The improvement of ship resistance performance to the wave resistance decrease due to improved wave pattern has been verified according to move the stem and the volume of the shoulder to the fore part of the vessel.