• Title/Summary/Keyword: Organic Compound

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The Development of Functional $TiO_2$-Biodegradable Plastic Composite Material by Thermal Spraying (용사를 이용한 고기능 $TiO_2$-생분해성 플라스틱 복합재료의 개발)

  • ;;Akira Ohmori;Takahiro Nakatsuji
    • Proceedings of the KWS Conference
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    • 2004.05a
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    • pp.316-318
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    • 2004
  • In recent years, plastic waste has been recognized as a worldwide environmental issue. To solve the disposal problem of the plastic waste, alternative treatment such as the use of biodegradable plastic(polybutylene succinate: PBS) is indeed highly in demand due to its merit of PBS buried in soil decomposed into carbon dioxide and water. In the present study, for the production of further functional PBS with TiO$_2$ as photocatalyst, which shows the decomposition of detrimental organic compound and pollutant under ultraviolet irradiation, we attempted to prepare photocatalytic TiO$_2$ coatings on PBS substrate by HVOF and plasma spraying techniques under various conditions using three kinds of agglomerated powders (P200: 200nm, P30: 30nm, P7: 7nm). The microstructures of coatings were characterized with SEM and XRD analysis, and the photocatalytic efficiency of coatings was evaluated through the photo degradation of gaseous acetaldehyde. Therefore, such functional TiO$_2$-Plastic composite material is expected to considerably contribute to the reduction of aggravated environmental problem.

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Studies on the Oxidative Structural Change of Azo Dye Acid Red 27 by Ozone (O3에 의한 아조염료 Acid Red 27의 산화분해시 구조 변화에 관한 연구)

  • Baek, Mi-Hwa;Kim, Dong-Su
    • Journal of Korean Society on Water Environment
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    • v.21 no.6
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    • pp.564-568
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    • 2005
  • The structural change of azo dye (Acid Red 27) by oxidation with ozone has been investigated using FT-IR and $^1H$ NMR. The solution pH was observed to decrease during oxidation reaction, which was considered to be due to the generation of several organic and inorganic acids as the result of the decomposition of azo compound. The FT-IR analysis showed that changes of specific absorption bands of Acid Red 27 were observed after ozonation. When azo dye was oxidized by ozone, several new peaks were shown to appear by $^1H$ NMR analysis and the peaks were generally shifted to the direction of up field. This was presumably due to the breakage of benzene ring contained in the molecular structure of Acid Red 27 by the oxidation and the shape of peaks was shown to change according to the reaction time.

Studies on the Substrances Contained in Glucomannan Lowering Liver and Serum Cholesterol Levels (구약고구마(Glucomannan)의 섬유질이 간 및 혈청지질에 미치는 영향)

  • 이숙경
    • Journal of Food Hygiene and Safety
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    • v.6 no.2
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    • pp.73-78
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    • 1991
  • As reported previously, it was found that glucomannan, contains a potent cholesterol-lowering material. This study was designed to characterize this material further. Both the water sluble and the alcohol soluble extracts of glucomannan were prepared, and each of these extracts were capable of reducing serum and liver cholestrol levels of rats: This finding indicates that a potent cholesterol-lowering material contained in glucomannan is an organic compound with hydrophilic groups.

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Application of nanofiltration membrane in the recovery of aluminum from alkaline sludge solutions

  • Cheng, Wen Po;Chi, Fung Hwa;Yu, Ruey Fang;Tian, Dun Ren
    • Advances in environmental research
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    • v.5 no.2
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    • pp.141-151
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    • 2016
  • Large amounts of aluminum hydroxide ($Al(OH)_3$) exist in water purification sludge (WPS) because of the added aluminum coagulant in water treatment process. Notably, $Al(OH)_3$ is an amphoteric compound, can be dissolved in its basic condition using sodium hydroxide to form aluminate ions ($Al(OH)_4{^-}$). However, in a process in which pH is increasing, the humid acid can be dissolved easily from WPS and will inhibit the recovery and reuse of the dissolved aluminate ions. This study attempts to fix this problem by a novel approach to separate $Al(OH)_4{^-}$ ions using nanofiltration (NF) technology. Sludge impurity in a alkaline solution is retained by the NF membrane, such that the process recovers $Al(OH)_4{^-}$ ions, and significantly decreases the organic matter or heavy metal impurities in the permeate solution. The $Al(OH)_4{^-}$ ion is an alkaline substance. Experimental results confirm that a recovered coagulant of $Al(OH)_4{^-}$ ion can effectively remove kaolin particles from slightly acidic synthetic raw water.

Application of the Eco-friendly Materials for the Interior Design (친환경 실내 디자인 소재 개발 활용 방안)

  • Sung, Nak-Bong
    • The Journal of the Korea Contents Association
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    • v.11 no.10
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    • pp.209-216
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    • 2011
  • This paper, the shielding material is suggested using by the korean paper, lacquer, and charcoal those can be used more eco-friendly materials for the interior design. Also, it is designed the image-wall for improving of the electromagnetic shielding and the beauty. Suggested shielding material is manufactured with the thickness of 2 mm by the printing method of the lacquer and charcoal on the korean paper. This material has the shielding effectiveness over 95% until 2 GHz. The application for the interior design using more eco-friendly material can be reduced the effect of electromagnetic wave and the chemical substances like as the formaldehyde and the volatile organic compound (VOC).

Effects of Inorganic Aerosols on the Gas-Phase Reactions of the Hydroxyl Radical with Selected Aliphatic Alkanes

  • Oh, Sewon;Andino, Jean M.
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.E3
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    • pp.129-136
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    • 2003
  • Effects of inorganic aerosols on the kinetics of the hydroxyl radical reactions with selected aliphatic alkanes have been investigated using the relative rate technique. The relative rates in the absence and presence of aerosols were determined for n-butane, n-pentane, n-hexane, n-octane, and n-decane. P-xylene was used as a reference compound. Inorganic aerosols including (NH$_4$)$_2$SO$_4$, NH$_4$NO$_3$, and NaCl aerosols at two different aerosol concentrations that are typical of polluted urban conditions were tested. Total surface areas of aerosols were 1400 (Condition I) and 3400 $\mu$$m^2$ cm$^{-3}$ (Condition II). Significant changes in the relative rates in the presence of the inorganic aerosols were not observed for the n-butanel/$.$OH, n-pentanel/$.$OH, n-hexanel/$.$OH, n-octanel/$.$OH, and n-decanel/$.$OH reactions versus p-xylenel/$.$OH reaction. These results suggest that the promoting effects depend on the semiconducting property of the aerosols and the nature of the organic compounds.

The Composition of Odor Compounds Emitted from Municipal Solid Waste Landfill (도시 생활폐기물 매립지에서 발생되는 악취물질의 조성에 대한 연구)

  • Son, Youn-Suk;Kim, Jo-Chun;Kim, Ki-Hyung;Lim, Bo-A;Park, Kang-Nam;Lee, Woo-Keun
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.6
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    • pp.666-674
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    • 2007
  • In this study, sampling and analysis was carried out for 13 compounds, in order to investigate the odorous compound emissions from landfill stacks and surrounding ambient air. These results revealed that concentration of hydrogen sulfide was $0.13{\sim}0.66\;ppb$ in the ambient air. Also, concentrations of hydrogen sulfide ($151{\sim}358\;ppm$) were the highest value in odorous sulfur compounds from landfill stacks. In case of VOC, toluene was obtained the highest out of volatile organic compounds. It was found that the concentrations of hydrogen sulfide near the landfill was higher than that inside city such as Seoul although it was located in a rural area. The result was due to the effect of hydrogen sulfide emitted from landfill stacks.

Comparison of Biodegradation of pyrene between Rhizosphere Soil and Non-rhizosphere Soil (Rhizosphere 토양과 Non-rhizosphere 토양에서 Pyrene의 분해속도 비교)

  • 김상채;이의상;서성규
    • Journal of Korea Soil Environment Society
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    • v.3 no.2
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    • pp.71-78
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    • 1998
  • Pyrene is a common petroleum contaminant. This compound is recalcitrant to biological degradation and persists long in contaminated environments. A microcosm experiment was conducted to investigate the degradation rate of pyrene in three different of soil : rhizosphere soil ; non-rhizosphere soil ; and sterilized soil. The degradation rate followed the order of rhizosphere soil)non-rhizosphere soil)sterilized soil. And the rate did not change significantly when organic acids commonly found in the rhizosphere were added to each soil but it seemed to be well related to the increase of the number of microorganisms. Overall, it appears that pyrene is degraded faster in the rhizosphere soil which has the higher microorganism density.

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Effects of pH on the growth, total nitrogen, total phosphorus and organic compound removal in heterotrophic culture of Chlorella sorokiniana applied wastewater treatment (pH와 탄소원이 Chlorella sorokiniana의 heterotrophic 배양 및 하폐수고도처리능에 미치는 영향)

  • Park, Jeong-Eun;Cho, Yong-Beom;Zhang, Shan;Hwang, Sun-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.6
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    • pp.703-709
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    • 2013
  • Among many microalgae cultivation types, heterotrophic culture with low cost carbon sources and energy saving culture method is crucial. A result of estimating the effects of pH on wastewater treatment using heterotrophic growing microalgae Chlorella sorokiniana shows that there was no difference in microalgae growth amount and nitrogen, phosphorus removal rate by wide range of pH(5 ~ 9). From pH 5 to 9, total nitrogen, phosphorous and glucose removal rates were 10.5 mg-N/L/d, 2 mg-P/L/d, 800 ~ 1000 mg/L respectively. This study reveals that C. sorokiniana cannot metabolite glycerol heterotrophically, however, glucose and acetate were proper carbon sources for growth and T-N, T-P and TOC removal. This research highlights the potential of heterotrophic microalgal growth with wastewater treatment plant with wide range of pH and carbon sources.

A Study on Formation of Conductive Pattern on Polymer Using LDS (LDS를 이용한 폴리머상의 전도성 패턴 형성 연구)

  • Paik, Byoung-Man;Lee, Jae-Hoon;Shin, Dong-Sig;Lee, Kun-Sang
    • Laser Solutions
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    • v.12 no.4
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    • pp.6-11
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    • 2009
  • The LDS(Laser Direct Structuring) process uses thermoplastic polymers with a additive compound that serves as plating seed after the activation by laser. It can realize industry requirement such as miniaturization of electrical component, design flexibility and reduction of production steps. The purpose of this study is to introduce LDS, and to investigate the fundamental mechanism. Also the characteristics of conductive patterns were investigated with respect to laser fluence and intensity. We have used a pulsed fiber laser (wavelength : 1064nm) and copper electroless plating to fabricate conductive patterns. The result showed that laser induced metal-organic complex was caused metalization by electroless copper plating, the critical laser fluence was $1.41\;J/cm^2$ at a scan speed of 1 m/s.

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