• Title/Summary/Keyword: Organic Compound

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Characteristics of Chlorination Byproducts Formation of Amino Acid Compounds (아미노산 성분에서의 염소 소독부산물 생성 특성)

  • Son, Hee-Jong;Choi, Young-Ik;Bae, Sang-Dae;Jung, Chul-Woo
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.5
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    • pp.332-340
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    • 2009
  • This study was conducted to analyze and determine formation potentials for chlorination disinfection by-products (DBPs) from twenty amino acid compounds with or without $Br^-$. Two of twenty amino acid compound were tryptophan and tyrosine that were relatively shown high for formation of trihalomethanes (THMs)/dissolved organic carbon (DOC) whether or not $Br^-$ presented. Other 18 compounds were shown low for formation of THMs/DOC whether or not $Br^-$ presented. Five amino acid compounds that were tryptophan, tyrosine, asparagine, aspartic acid and histidine were shown high for formation of haloacetic acids (HAAs)/DOC whether or not $Br^-$ presented. Although formation of dichloroacetic acid (DCAA) was dominated in asparagine, aspartic acid and histidine, trichloroacetic acid (TCAA) was dominated in tryptophan and tryptophan. The formation of haloacetnitriles (HANs)/DOC whether or not $Br^-$ presented was high in Aspartic acid, histidine, asparagine, tyrosine and tryptophan. Specially, aspartic acid was detected 660.2 ${\mu}$g/mg (HAN/DOC). Although the formation of chloralhydrate (CH)/DOC was shown high in asparagine, aspartic acid, histidine, methionine, tryptophan and tyrosine, the formation of Chloropicrin (CP)/DOC was low (1 ${\mu}$g/mg) in twenty amino acid compounds. The formations of THM, HAA and HAN were also investigated in functional groups of amino acids. The highest formation of THM was shown in amino acids compounds (tryptophan and tyrosine) with an aromatic functional group. Highest, second-highest, third-highest and fourth-highest functional groups for formation of HAA were aromatic, neutral, acidic and basic respectively. In order of increasing functional groups for formation of HAN were acidic, basic, neutral and aromatic.

Antibacterial Activity of Herbal Medicine Extracts against Edwardsiella tarda (어병세균 Edwardsiella tarda에 대한 한약재 추출물의 항균활성)

  • Kim, Ah-Ra;Kim, Do-Kyun;Byun, Tea-Hwan;Jo, Eun-Jee;Lee, Eun-Woo;Kwon, Hyun-Ju;Kim, Byung-Woo;Kim, Tae-Hoon;Lee, Kyung-Bon;Kim, Young-Man
    • Food Science and Preservation
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    • v.18 no.1
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    • pp.87-90
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    • 2011
  • The methanol extracts of 19 commercial herb medicines was analyzed to antibacterial activities against Edwardsiella tarda, causing several fish diseases. Rhus javanica showed most strong antibacterial activity against E. tarda and Escherichia coli. Methanol extract of R. javanica was further extracted using several organic solvents having different polarity. Extract from ethyl acetate fraction showed strong activity against E. tarda as well as E. coli. Minimal inhibitory concentration, MIC of R. javanica extract was measured and resulted showing $64\;{\mu}g/m{\ell}$ for E. tarda and $256\;{\mu}g/m{\ell}$ for E. coli. It is needed that, from these results, further purification and isolation of reposible compound of these activities and further study on the synergy effect using combination with antibiotics against pathogenic bacteria.

Effects of Salinity and Moisture Content on Aerobic Composting of Food Wastes (염분도와 수분함량이 음식폐기물의 호기성 퇴비화에 미치는 영향)

  • 박석환
    • Journal of Environmental Health Sciences
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    • v.24 no.1
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    • pp.120-131
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    • 1998
  • This study was performed to define the physicochemical characteristics of food waste and food wastewater, and to find the effect of moisture content variation and salinity variation on aerobic composting for food wastes. In moisture content variation experiment, the samples of 2-1, 2-2, 2-3 and 24 were prepared by the moisture content of 83.8%, 70.9%, 64.8% and 45.1%, respectively. In salinity variation experiment, the samples of 3-1, 3-2, 3-3 and 3-4 were prepared by the salinity of 0.99%, 1. 69%, 1.75% and 2.34%, respectively. In both experiments, aerobic composting reactors were operated by the mode which was composed of half an hour's stirring and 2 hour's aeration per day, for 45 days. The followings are the conclusions that were derived from this study. 1. In the study of physicochemical characteristics of food waste and food wastewater, the values of pH were 4.19 and 3.96, the values of salinity were 0.91% and 1.17%, and the values of conductivity were 7.6 mS/cm and 18.2 mS/cm, respectively. 2. In food waste, the moisture content was 60.3%, organic compound content was 96.1%, total carbon was 48.0%, total nitrogen was 1.5%(therefore, C/N ratio was 32), and the concentration of total phosphorus was 1.34 mg/kg. 3. The time of temperature ascending was delayed, the highest temperature was lowered, the duration period of high temperature was shortened by the increasing of moisture content. In the higher moisture content, anaerobic condition was formed, bad smell was released, insects were gathered and multiplicated, and the reaction rate of composting was reduced. 4. In moisture content experiment, C/N ratios were changed from the range of 31.2-34.8 at the beginning phase to that of 20.4-28.4 at the last phase. 5. In salinity experiment, the reduction rate of volume was increased(40.3%) when the salinity was decreased(0.99%). Also, the reduction rate of mass was increased(51.8%) when the salinity was decreased(0.99%). This fact denotes that salinity hinders the process of composting. 6. the concentrations of total nitrogen and total phosphorus were increased from 0.74% to 1.10%, and from 0.82 mg/kg to 3.44 mg/kg, respectively when the salinity was decreased from 2.34% to 0.99%.

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Fermentation and Functional Properties of Korean Traditional Liquor, Hahyangju (하향주의 발효 및 기능적 특성)

  • Park, Chi-Duck;Jung, Hee-Kyoung;Kim, Dae-Ik;Lee, In-Seon;Hong, Joo-Heon
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.36 no.4
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    • pp.464-469
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    • 2007
  • This research was worked out to investigate fermentation and functional properties of Hahyangju. Hahyangju was brewed by traditional method and the changes in chemical component and microorganisms in wine mash were evaluated during brewing. In the course of the first mash brewing, the yeast cell number was the highest after 6 days fermentation, and contained 11% alcohol, 0.82% total acidity and 0.53% amino acidity The final product of Hahyangju contained 19.2% alcohol, 0.32% reducing sugar, 0.46% total acidity and 0.24% amino acidity. The major organic acid was lactic acid containing 680.04mg/100mL. The total phenolic compound contents and electron donating ability of Hahyangju were 263.16 ppm and 93.08%, respectively. Nitrate scavenging effect was measured at various PH (1.2, 3.0, 4.2, 6.0); the highest effect was at pH 1.2 as 90.26%. Angiotensin converting enzyme (ACE) inhibition activity and fibrinolytic activity of Hahyangju ware 87.5% and 19.1 unit, respectively.

Biofilter Treatment of Waste Air Containing Malodor and VOC: 2. Transient Behavior of Biofilter with Improved Design to Eliminate Malodor and VOC (악취 및 VOC를 함유한 폐가스의 바이오필터 처리: 2. 개선된 바이오필터설계에 의한 악취 및 VOC 제거거동)

  • Lee, Eun Ju;Lim, Kwang-Hee
    • Korean Chemical Engineering Research
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    • v.51 no.1
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    • pp.136-143
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    • 2013
  • In this study, both transient behaviors of a biofilter system with improved design and a conventional biofilter were observed to perform the treatment of waste air containing malodor and volatile organic compound (VOC). Their behaviors of removal efficiency and treated concentration of malodor and VOC were compared each other. During 1st~7th stages of improved biofilter system operation it was observed that the order of treated ethanol concentration at each sampling port was switched due to the difference of microbe-population-distribution in spite of the difference of biofilter effective height. However, at 8th stage of its operation, the order of treated ethanol concentration at each sampling port was consistent to the order of biofilter effective height at each sampling port. The same was applied to the case of hydrogen sulfide, even though the difference of switched treated-hydrogen sulfide-concentrations was less than that of switched treated-ethanol-concentrations. The ethanol-removal efficiency of the biofilter system with improved design was ca. 96%, which was greater by 2% than that of the conventional biofilter. The transient behavior of treated hydrogen sulfide concentration of both biofilters were similar to each other. However, the concentration of hydrogen sulfide treated by the biofilter system with improved design was observed lower than that by the conventional biofilter. The hydrogen sulfide-removal efficiency of the biofilter system with improved design was higher by ca. 2% than that of the conventional biofilter. Therefore, the hydrogen sulfide-removal efficiency of the biofilter system with improved design was observed to be enhanced by the same as its ethanol-removal efficiency.

Durability Evaluation of Inorganic-Impregnated Concrete Exposed to Long-Term Chloride Exposure Test (무기계 침투제를 적용한 콘크리트의 장기폭로실험을 통한 염해 내구성 평가)

  • Kwon, Seung-Jun;Park, Sang-Soon;Lho, Byeong-Cheol
    • Journal of the Korea Concrete Institute
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    • v.20 no.3
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    • pp.283-290
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    • 2008
  • The repair technique using surface impregnation of reactive compound is so effective for deteriorated concrete structures that many researches are recently focused on these works. Particularly, inorganic impregnant is regarded as ecofriendly material because there is no air-pollution during manufacturing process as well as field coating works. Furthermore, The delamination between old concrete and impregnated surface does not occur, resulting from different material characteristics. In order to evaluate the durability performance of surface-impregnated concrete, durability evaluation through the long-term exposure tests is significant, however, experiments are usually limited to the temporary and qualitative laboratorial scope. In this study, durability characteristics for inorganic and organic/inorganic impregnated concrete specimens are evaluated through longterm chloride exposure test. The specimens with 21MPa and 34MPa strength have been prepared and exposed to chloride attack in the atmospheric, tidal, and submerged conditions. Evaluation for compressive strength, chloride penetration, and electrical potential (half cell potential) for steel corrosion are performed for the specimens exposed for 2 years. From the results, no distinct strength gaining is observed but the resistance to chloride penetration and steel corrosion is evaluated to be improved through surface impregnation. The more improved resistance to chloride attack is measured in the inorganic impregnated concrete and the results from atmospheric condition show more improved resistance to chloride attack than those from submerged and tidal condition.

Effect of the Late Fall Fertilization and Snow Cover Period on Spring Greenup of Creeping Bentgrass at Following Year (늦 가을철 시비와 적설로 인한 크리핑 벤트그래스의 이듬해 봄철 생육)

  • Lee, Duk-Ho;Jeon, Jun-Ki;Joo, Young-Kyoo
    • Asian Journal of Turfgrass Science
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    • v.23 no.1
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    • pp.123-132
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    • 2009
  • This study was designed to investigate the effect of the late fall fertilization applied with methyl urea(MU), compound chemical fertilizer(CF), humate(HM), and organic compost fertilizer(NS) on spring greenup of creeping bentgrass at following year. The plots were treated with various snow cover periods before transforming to ski slopes from golf holes during 2007 fall to 2008 spring. The highest visual quality and greenup rate were shown on MU or HM applications at 10 days before snow cover treatment. The CF treatment which had a highest phosphorus rate was most effective with a 13 cm of root length at the reconversion date to golf hole from ski slope of the following spring. However, the application of CF followed by immediate snow cover showed the worst results on visual quality and green color caused by a leaf burning damage from the residual effect of CF. At least 10 days were required to avoid phytotoxicant from undissolved granular of CF before snow cover practise. The application of NS showed the highest result on leaf dry weight at no snow cover plot in next spring, but not on green color and visual quality. Therefore, the proper interval period of snow cover after late fall fertilization should be an important management skill on the spring greenup of creeping bentgrass on following year transforming from ski slope to golf hole.

Allelopathic Effects of Crimson Clover, Hariy Vetch and Rye on Germination and Radicle Elongation of Several Crops (크림손클로버, 헤어리베치, 호밀 추출물이 몇 가지 작물의 종자 발아와 유근 생장에 미치는 allelopathy 효과)

  • Lee, Ji-Hyun;Lee, Byung-Mo;Jeon, Seung-Ho;Chung, Jong-Il;Kim, Min-Chul;Shim, Sang-In
    • Korean Journal of Weed Science
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    • v.30 no.4
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    • pp.371-379
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    • 2010
  • Crimson clover (Trifolium incarnatum), hairy vetch (Vicia villosa) and rye (Secale cereale) are common leguminous cover crops. Because they contain water-soluble allelopathic substances that show a variable level in tissue depending on growth stage of the plants, the weed inhibition effects are dependent on the growth stage of cover crops. This study investigated the allelopathic effects of crimson clover, hairy vetch and rye on soybean, radish, oilseed rape and lettuce seeds germination and seedling growth. We used extract that were prepared from the shoots of crimson clover, hairy vetch and rye at different growth stages, vegetative growth stage, flowering stage, and fruiting stage. Applications of aqueous extracts from three growth stage of cover crops strongly affected to oilseed rape and lettuce seeds germination but the treatment resulted in a slight inhibition of the germination in soybean and radish. Radical length was more sensitive to aqueous extracts than seed germination rate. Especially, three cover crops extracts at vegetative growth stage highly inhibited seedling root growth of oilseed rape and lettuce by over 80% and 90% respectively. Furthermore, the $GR_{50}$ values were lowest in the treatment of extracts from vegetative growth stage and the level of phenolics was decreased by the order of vegetative growth stage, flowering stage and fruiting stage.

Strong Carrier Localization and Diminished Quantum-confined Stark Effect in Ultra-thin High-Indium-content InGaN Quantum Wells with Violet Light Emission

  • Ko, Suk-Min;Kwack, Ho-Sang;Park, Chunghyun;Yoo, Yang-Seok;Yoon, Euijoon;Cho, Yong-Hoon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.293-293
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    • 2014
  • Over last decade InGaN alloy structures have become the one of the most promising materials among the numerous compound semiconductors for high efficiency light sources because of their direct band-gap and a wide spectral region (ultraviolet to infrared). The primary cause for the high quantum efficiency of the InGaN alloy in spite of high threading dislocation density caused by lattice misfit between GaN and sapphire substrate and severe built-in electric field of a few MV/cm due to the spontaneous and piezoelectric polarizations is generally known as the strong exciton localization trapped by lattice-parameter-scale In-N clusters in the random InGaN alloy. Nonetheless, violet-emitting (390 nm) conventional low-In-content InGaN/GaN multi-quantum wells (MQWs) show the degradation in internal quantum efficiency compared to blue-emitting (450 nm) MQWs owing higher In-content due to the less localization of carrier and the smaller band offset. We expected that an improvement of internal quantum efficiency in the violet region can be achieved by replacing the conventional low-In-content InGaN/GaN MQWs with ultra-thin, high-In-content (UTHI) InGaN/GaN MQWs because of better localization of carriers and smaller quantum-confined Stark effect (QCSE). We successfully obtain the UTHI InGaN/GaN MQWs grown via employing the GI technique by using the metal-organic chemical vapor deposition. In this work, 1 the optical and structural properties of the violet-light-emitting UTHI InGaN/GaN MQWs grown by employing the GI technique in comparison with conventional low-In-content InGaN/GaN MQWs were investigated. Stronger localization of carriers and smaller QCSE were observed in UTHI MQWs as a result of enlarged potential fluctuation and thinner QW thickness compared to those in conventional low-In-content MQWs. We hope that these strong carrier localization and reduced QCSE can turn the UTHI InGaN/GaN MQWs into an attractive candidate for high efficient violet emitter. Detailed structural and optical characteristics of UTHI InGaN/GaN MQWs compared to the conventional InGaN/GaN MQWs will be given.

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The Study on Optimum Operation Conditions of Ceramic MF Membrane Process in Y Water Treatment Plant (Y 정수장 세라믹막 여과공정 최적 운영인자 평가)

  • You, Sang-Jun;Ahn, Hyo-Won;Park, Sung-Han;Lim, Jae-Lim;Hong, Sung-Chul;Yi, Pyong-In
    • Membrane Journal
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    • v.24 no.3
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    • pp.201-212
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    • 2014
  • This study was performed to discover the optimum operation conditions for the advanced water treatment using the ceramic membrane, introduced the first in the nation at the Y water treatment plant (WTP). The result of investigation to find the optimum operation conditions which can continue preserving the filtration performance as well as satisfying both the economics and the water quality is as follows. In the ordinary water quality condition of the Y WTP, the optimum filtration time(the backwash period), which can minimize the production of backwash waste and preserve the membrane performance was examined to be 4.0 hours on basis of institution capacity ($16,000m^3/day$). Examining the recovery rate of TMP from the chemical cleaning (CIP) discovered that the inorganic contaminants, which cause membrane fouling, such as iron, manganese, aluminum, were removed through the acidic cleaning using citric acid, whereas the membrane recovery rate was found to be low. But, on the other hand, the TMP was recovered to the initial value from the alkali cleaning using the NaOCl. Therefore, the main contaminant causing the fouling was determined to be hydrophilic organic compound( biopolymer). The membrane recovery rate is highly influenced by the temperature of the cleaning chemical. That is, the rate increased with increasing temperature.