• Title/Summary/Keyword: Organic Cation

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Vegetation Structure of Hongdo Island (홍도의 식생구조)

  • Lee, Ji-Hye;Do, Mi-Sol;Song, Ho-Kyung
    • Korean Journal of Environment and Ecology
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    • v.27 no.5
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    • pp.592-613
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    • 2013
  • This study was carried out to analyze the vegetation properties, soil characteristic, and ordination of forest in Hongdo island and the results are as follows: Castanopsis cuspidata var. sieboldii community, Quercus acuta community, Machilus thunbergii community, Pinus densiflora community and Carpinus coreana community. The results of importance value on the vegetation of Hongdo island consisted of the following in order: 75.56% of Castanopsis cuspidata var. sieboldii, the highest, 34.84% of Pinus densiflora, 29.11% of Machilus thunbergii, 26.88% of Camellia japonica, 17.79% of Quercus acuta, 15.23% of Dendropanax morbifera, 13.41% of Ligustrum japonicum, 12.67% of Carpinus coreana. Due to the high organic matter, total nitrogen and low pH, the soil properties of Hongdo island are different from those of other forest in Korea. The composition of soil properties in the same areas are as follows: organic matter, total nitrogen, available phosphorous, exchangeable $K^+$, exchangeable $Ca^{2+}$, exchangeable $Mg^{2+}$ contained, and soil pH. The capacities of these chemical properties of the soil ranged from 14.48~25.45%, 0.49~0.90%, 26.00~58.68 mg/kg, $0.64{\sim}1.64cmol^+/kg$, $6.22{\sim}21.5cmol^+/kg$, $2.92{\sim}6.95cmol^+/kg$, and 4.42~5.44 respectively. The results of the correlation between communities and soil conditions of vegetation of Hongdo island by DCCA ordination method are as follows: Castanopsis cuspidata var. sieboldii community was found in the highest soil moisture and followed in order Machilus thunbergii community, Quercus acuta community. The Machilus thunbergii community was found in the highest pH, exchangeable $Ca^{2+}$, exchangeable $Mg^{2+}$, exchangeable $K^+$ and cation exchange capacity. The Carpinus coreana community was found in the highest elevation, total nitrogen, cation exchange capacity, exchangeable $Mg^{2+}$ and followed in order Pinus densiflora community.

Effect of Application Time and Rate of Mixed Expeller Cake on Soil Environment and Rice Quality (혼합유박 시용량 및 시용시기가 토양환경과 미질에 미치는 영향)

  • Yang, Chang-Hyu;Yoo, Chul-Hyun;Kim, Byeong-Su;Park, Woo-Kyun;Kim, Jae-Duk;Jung, Kwang-Yong
    • Korean Journal of Soil Science and Fertilizer
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    • v.41 no.2
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    • pp.103-111
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    • 2008
  • This study was carried out to investigate the optimal application rate and time of mixed expeller cake (MEC) for the replacement of chemical fertilizer. Dongjin-1, as cultivated rice was used at Fluvio-marine deposit in Honam plain paddy field. Soil chemical properties were improved by the application of MEC. Contents of total nitrogen and organic matter were higher in 70%, 100% plots of basal dressing than standard fertilizer application (SFA) plot. Cation exchangeable capacity was highly increased in 70% plot of basal dressing. Also, the content of organic matter in soil was increased with MEC application. Cation exchangeable capacity, total nitrogen and available phosphate were decreased according to late application time. The content of inorganic nitrogen in soil showed high tendency at more application rate of MEC, and nitrogen mineralization at harvest season have finished in 50%, 70% plots of basal dressing. The content of inorganic nitrogen in soil was increased according to late application time, however it was decreased in the late period of growth. Leaf color value became darker with increased application rate of MEC. Leaf color was dark green in MEC application plots at panicle formation stage, on the other hand, it was light green in 50%, 70% plots of basal dressing at heading stage. SPAD reading value of leaf-color was high during the whole growth stage in MEC application plots. More application rate of MEC showed higher tendency of fertilizer nitrogen absorption. Nitrogen use efficiency was the highest in 70% plot of basal dressing. Absorbed amount of fertilized nitrogen was increased in 10~15days before transplanting and nitrogen use efficiency was high according to the late application time. The ratio of perfect kernel and the content of protein on hulled rice showed high tendency at the less application rate of MEC. The ratio of head rice on milled rice showed high tendency at the less application rate of MEC. Rice yield increased 4% in 100% and 70% plots of basal dressing compare with SFA ($5.18Mg\;ha^{-1}$) plot respectively. Ear and culm length of rice were long according to the late application time, while the numbers of spikelet and ear were increased and the percentage of ripened grain was decreased. Rice yield was increased 2~5% in all MEC application plots compared to SFA plot and especially, increased 10~15days before transplanting in application plots. The optimal application rate and time of MEC on normal paddy field in plain were concluded that 70% basal dressing and 10~15days before transplanting

Changes of some chemical constituents in different soil depth with textures of Fluvio-marine soil under assessment of reclamation duration (간척년수(干拓年數)에 따른 토성(土性) 및 작토층위별(作土層位別) 수종(數種) 화학성분변화(化學成分變化) 차이(差異)에 관(關)한 연구(硏究))

  • Kim, Seong Chae
    • Korean Journal of Soil Science and Fertilizer
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    • v.20 no.1
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    • pp.23-28
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    • 1987
  • A series of field and laboratory experiments were conducted to find out the changes of some soil chemical constituents in different soil depth with three different soil textures as Bongnam-clayey, Gwanghwal-silty loam and Mangyeong fine sandy soil on the assessment of reclamation duration in Fluvio-marine soil. The result obtained were summarized as follows; 1. Exchangeable potassium, calcium, magnessium, sodium with manganes, silica and cation exchange capacity were remarkably decreased with assessment of reclamation duration. Decreasing tendency was pronounced more in sandy soil than silty loam or clayly soil. 2. Soil organic matter content in top soil was increased with increasing of reclamation years. From reclamation time, about 30 years in clayly and about 80 years in silty loam and sandy soil were necessary for the maintanance of averaged organic matter content to 2.5%. 3. Potassium activity ratio ($K/{\sqrt{Ca+Mg+Na}}$) was differed with soil depth, soil texture and assessment of reclamation duration. About 50 years is may be necessary for the maintanance of potassium activities ratio in ordinary paddy soil of 0.05-0.2. 4. Percent of adsorbed sodium (PAS), ratio of adsorbed sodium (RAS) and ratio of sodium adsorbtion(RSA) were remarkably decreased with assessment of reclamation duration. Specially, decreasing tendency was pronounced more in sandy soil than silty loam and clayly soil 5. Amount of clay content in subsoil was appearently decreased during 30 years of reclamation, but clay contents in top soil was appearently decreased 50 years after reclamation.

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A Study on Acid soil amendment by Addition of Sewage Treatment Sludge mixed Oyster Shell (하수슬러지와 굴껍질의 혼합첨가에 의한 산성토양 교정효과)

  • Moon, Jong-Ik;Choi, Sung-Moon;Sung, Nak-Chang;Huh, Mock;Kim, Boo-Gil;Kim, Chul
    • Journal of the Korea Organic Resources Recycling Association
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    • v.9 no.2
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    • pp.66-70
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    • 2001
  • In this study farm soil was tested under artificial acid rain(pH = 5.34), which is average pH of Pusan metropolitan area. and to find out the soil's acid neuralization capacity, soil acidity, CEC(cation exchange capacity)and akaline meatals, such as K, Ca and Na were tested. Because oyster shells(OS) had portion of alkaline metals, OS could play a role in acid soil amendment. And soil addition of sewage treatment sludge(STS) could be a alternative for disposal method. The purpose of this study is to evlauate acid soil amendment using STS and OS. In case of soil and STS, mixing ratio was10:0, 9:1, 8:2, 7:3. And STS mixed OS was also added in acid soil as same ratio as STS. Throught the experiment, soil acidity was stationary state with slight decrease, and CEC was also stationary state but with slight increase. Allkaline metals showed differences in concentration, but all of them were tend to decrease. In conclusion, STS mixed OS could play a part in amendment of acid soil.

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Studies on the Relation between Acid Deposition and Soil Chemical Properties in Forest Areas - Especially in Gyeongsangnam-Do Province - (산성강하물과 산림토양 화학성의 관련성에 관한 연구 - 경상남도 지역을 중심으로 -)

  • Lee, Chong-Kyu
    • Korean Journal of Environment and Ecology
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    • v.22 no.3
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    • pp.260-267
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    • 2008
  • This study was carried out to investigated the relation between air depositions and soil properties in Gyeongsanman province. Soil pH was average 4.40 in regions, and was the highest soil pH value in Miryang-sanne(pH 5.02), the lowest pH value in Namhae-seomyeon(pH4.08). Soil pH, soil organic matter content, avail phosphorus, K, Ca and cation exchange capacity(CEC) were significantly different among regions(p<0.05). Pb in Heavy metal content was 3.86mg/kg average value, and was the highest in Keo-je region(9.87mg/kg), the lowest in Mryang-sanne (0.86mg/kg). Zn, Cd, Cr and Ni were significantly different among regions(p<0.05). Correlation between rainfall pH and soil properties were positive in soil $pH(r=0.7826^{**})$, Ca$(r=0.6278^*)$, Mg$(r=0.5841^*)$, CEC$(r=0.6341^{**})$ and Cd$(r=0.5995^*)$, and were negative in Pb$(r=-0.5283^*)$. Correlation between $SO_2$ concentration and soil properties was negative in soil pH$(r=-0.6796^{**})$, Ca$(r=-0.5810^*)$, Mg$(r=-0.5522^*)$) and CEC$(r=-0.5905^*)$. Correlation between $NO_2$ concentration and soil properties were positive in organic matter $(r=0.6208^*)$, K$(r=0.5380^*)$. It was predicted that rainfall and $SO_2$ concentration would affect soil acidification, and soil heavy metal content related Cd and Pb. Others soil heavy metal were not related.

Analysis of the Correlation between Site Environmental Factors and Tree Ring Growth in Chamaecyparis obtusa Stands in Jeonnam Province (전남 편백림에서의 입지환경요인과 연륜생장량의 상관성 분석)

  • Park, Seok-Gon;You, Han-Choon;Oh, Chan-jin;Choi, Woo-Kyong
    • Korean Journal of Environment and Ecology
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    • v.29 no.5
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    • pp.777-784
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    • 2015
  • This study verified the correlations between vegetation factors, such as the number of individual species and species diversity, and soil factors in Chamaecyparis obtusa (CO) stands in Jeollanam-do. Also, the site environmental factors that affect the annual growth of CO ring width were analyzed. Positive correlations were found between the species diversity index and Cation Exchange Capacity (CEC), available phosphate, and exchangeable $K^+$ (P<0.01). In addition, strong positive correlations were also found between the number of species that appeared in the study site and CEC, available phosphorus, exchangeable $K^+$ and exchangeable $Mg^{2+}$ (P<0.01). Tree ring growth showed strong correlations with the nutrient holding capacity and fertility of soil, including available phosphate, exchangeable $K^+$, CEC, and electrical conductivity (P<0.01). The explanatory variables of tree ring growth in CO were composed of exchangeable $K^+$, organic matter content, and soil pH. The regression model had a high level of explanatory power, 74.4%. In this model, the annual growth of CO ring width increased when exchangeable $K^+$ and organic matter content were higher but decreased when soil pH was lower. According to the analysis, it is found that the annual growth of CO ring width was significantly affected by soil fertility, including available phosphate, exchangeable $K^+$, CEC, and electrical conductivity. In addition, the soil fertility of CO stands seems to be significantly affected by the supply of fallen leaves from the understory vegetation of CO.

A study on the Graft-copolymerization of Itaconic acid onto chitosan extracted crab shells waste and its pollutants removal abilities (게 껍질 폐기물로부터 추출한 Chitosan에 Itaconic acid의 그라프트 공중합과 오염물질의 제거 능력)

  • Han, Sang-Mun;Yun, Chong-Soo;Kim, Yong-Beom
    • Journal of the Korea Organic Resources Recycling Association
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    • v.7 no.2
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    • pp.83-92
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    • 1999
  • Chitosan was prepared from chitin which was abstracted from wasted crab shells. Then itaconic acid was graft-copolymerized onto chitosan using ceric ammonium nitrate as a reaction initiator. To investigate the optimal grafting conditions, the influences of several factors on the grafting were studied, i. e., the concentrations of CAN and itaconic acid, the reaction temperature and time. And to find out its flocculation ability. the flocculation test was carried out with a metal plating factory waste water. The state of graft-copolymer was identified through IR spectra analysis. The optimal grafting conditions and flocculation results were shown to be : concentration of ceric ammonium nitrate is $3.5{\times}10^3M$, reaction temperature is $40^{\circ}C$ and reaction time is 4hrs with 0.25M of the monomer(itaconic acid). Though flocculation tests using chitosan, grafted chitosan and cation, CODcr. metal ions removal rates were measured. The order of superiority is Itaconic acid grafted chitosan>Chitosan>Cationic polymer.

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Effects of Application of Liquid Pig Manure on Green Manure Crop Triticale and Subsequent Soil Quality (돈분액비 시용이 트리티케일 생육과 토양의 화학적 특성에 미치는 영향)

  • Lee, Byung-Jin;Kim, Kyeong-Mok;Chun, Hyun-Sik;Jeon, Seung-Ho;Cho, Young-Son
    • Korean Journal of Organic Agriculture
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    • v.22 no.2
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    • pp.293-302
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    • 2014
  • As part of the agricultural natural circulation, the present study was performed. Recently, there has been the movement toward reusing the Liquid Pig Manure as an alternative fertilizer sources for agricultural lands. For instance, LPM (Liquid Pig Manure) liquid fertilizer has been developed and widely used in Korea. However, the impacts of LPM on both agricultural environment and crop triticale yield have not been investigated yet. The experiments were studied on paddy field after treatment of LPM on plant height, root length, plant length, dry matter yield and soil chemical properties. The effect of LPM by application on triticale was more increased plant height, root length and plant length than the Control. Chemical soil characteristics were not significantly different between on Control and LPM. Soil pH, OM, TN, $P_2O_5$ and exchangeable cation of triticale (X Triticosecale wittmack) appeared to be lower than before the treatment. Dry matter yield were produced 834.3kg $10a^{-1}$ of in LPM plot and 684.4kg $10a^{-1}$ in Control plot. In these results show abbreviated as the application of LPM increases the yield index of triticale. However, the properties of paddy soil were not affected by the LPM application.

The Distributions of SO4-2 in the Cultivating Soils of Garlic (마늘 재배지토양중(栽培地土壤中) SO4-2의 분포(分布))

  • Chang, Gi-Chul;Chang, Sang-Moon;Choi, Jyung
    • Korean Journal of Soil Science and Fertilizer
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    • v.20 no.4
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    • pp.321-326
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    • 1987
  • This study was conducted to obtain the basic information on the application of S-fertilizer in the cultivating soil of Garlic. The distributions of cation and anion according to the soil depth in paddy field were examined. The average $SO_4{^{-2}}$ contents of surface and subsoil were 72.1 ppm and 45.1 ppm in paddy soils, and 53.1 ppm and 19.5 ppm in upland soils, respectively. In paddy soils, the contents of $SO_4{^{-2}}$ showed a positive correlation to the contents of organic matter, total nitrogen, exchangeable K, Ca, Mg and Fe. Whereas in upland soils, the contents of $SO_4{^{-2}}$ showed a positive correlation to the contents of organic matter and total nitrogen in surface soils. The exchangeable Ca and Mg contents were found to be higher with soil depth, however, the K contents was found to become very low. The $SO_4{^{-2}}$ contents was found to be higher with soil depth, indicating that $SO_4{^{-2}}$ should be leached from surface soils by percolated water.

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Physicochemical Properties of Organo­Smectites Modified by HDTMA, BDTDA, and CP (HDTMA­, BDTDA­ 및 CP­스멕타이트의 물리­화학적 특성)

  • 고상모;홍석정;송민섭
    • Journal of the Mineralogical Society of Korea
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    • v.16 no.4
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    • pp.295-305
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    • 2003
  • This study aims to provide the physicochemical properties of three kinds of organo­smectites which can be diversely used in industries. Some properties of them were compared with Na­smectite. Three kinds of organo­smectites such as Hexadecyltrimethylammonium(HDTMA), Benzyldimethyltetradecylammonium(BDTDA), and Cetylpyridinium(CP) exchanged smectites were manufactured for this study. Three types of organo­smectites showed the alkaline character(pH 9), very low swelling property and viscosity, and a fast flocculation behavior because of strong hydrophobic property in contrast to hydrophilic Na­smectite. Three organo­smectites showed the strong interlayer expansion with basal spacing from $19\AA$ to $23\AA$ compared with the Na­smectite of about 12 $\AA$. Organic cations such as HDTMA, BDTDA, and CP exchanged into smectite were completely decomposed in the temperature range from $250^{\circ}C$ to $400^{\circ}C$. Generally, three organo­smectites showed the similar mineralogical, physicochemical and thermal properties. But their properties are quite different from Na­smectite. Considering economically, CP exchanged smectite would be used for the diverse utilization field in the future time.