• Title/Summary/Keyword: Organic Additives

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Electrokinetic Ions Injection into Kaolinite and Sand for Bioremediation (카올리나이트와 모레에서의 Bioremediation을 위한 Electrokinetic 이온 주입 특성)

  • 이호창;한상재;김수삼;오재일
    • Proceedings of the Korean Geotechical Society Conference
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    • 2001.03a
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    • pp.405-410
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    • 2001
  • Bioremediation is a degradation process of existing organic contaminants in soils and groundwater by indigenous or inoculated microorganisms. This process can provide economical solution as well as safe and effective alternative in remediation technologies. However, it has been suggested that the rate of bioremediation process of organic contaminants by microorganisms can be limited by the concentration of nutrients and TEAs(Terminal Electron Accepters). In in-situ bioremediation, conventional pumping techniques have been used for supplying these additives. However, the injection of these additives is difficult in low permeable soils, and also hindered by preferential flow paths resulting from heterogeneities in high permeable ground. Therefore, the Injection of chemical additives is the most significant concern in in-situ bioremediation. Most recently, electrokinetic technique has been applied into the bioremediation and the injection characteristics under electrokinetics have not been examined in various soil types. Therefore, in this study, electrokinetic injection method is investigated in kaolinite and sand, and the concentration of ammonium(nutrients) and sulfate(TEAs) in soil is presented.

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Effects of exogenous enzymes from invertebrate gut-associated bacteria on volatile organic compound emissions and microbiota in an in vitro pig intestine continuous fermentation model

  • Jong-Hoon Kim;Ho-Yong Park;Kwang-Hee Son
    • International Journal of Industrial Entomology and Biomaterials
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    • v.48 no.2
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    • pp.67-77
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    • 2024
  • This study aims to assess the efficacies of exogenous enzymes, derived from invertebrate gut-associated microbes, as feed additives, in reducing volatile organic compound (VOC) emissions using an in vitro pig intestine continuous fermentation system. An in vitro continuous fermentation model was used to simulate a comparable bionic digestion system by co-reacting feed, enzymatic additives (arazyme, mannanase, and xylanase, derived from the gut bacteria of Nephila clavata, Eisenia fetida, and Moechotypa diphysis, respectively), and gastrointestinal microbes, followed by an analysis of their correlations. A significant correlation was observed between exogenous enzyme supplementation and reduced VOC emissions in the fecal phase of continuous fermentation (p < 0.05). The concentration of VOCs decreased by 3.75 and 2.75 ppm in the treatment group following arazyme and multi-enzyme supplementation, respectively, compared to that in the control group (7.83 ppm). In addition, supplementation with arazyme and multiple enzymes significantly affected the microbial composition of each fermentation phase (p < 0.05). In particular, Lactiplantibacillus pentosus and Pediococcus pentosaceus, which changed in abundance according to arazyme or multi-enzyme supplementation, exhibited a positive relationship with VOC emissions. These results suggest that exogenous enzymes derived from invertebrate gut-associated bacteria can be efficiently applied as feed additives, leading to a reduction in VOC emissions.

Effect of Additives on the Hardness of Copper Electrodeposits in Acidic Sulfate Electrolyte (황산구리 전착에서의 첨가제가 구리전착층의 경도에 미치는 영향)

  • Min, Sung-Ki;Lee, Jeong-Ja;Hwang, Woon-Suk
    • Corrosion Science and Technology
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    • v.10 no.4
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    • pp.143-150
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    • 2011
  • Copper electroplating has been applied to various fields such as decorative plating and through-hole plating. Technical realization of high strength copper preplating for wear-resistant tools and molds in addition to these applications is the aim of this work. Brighters and levelers, such as MPSA, Gelatin, Thiourea, PEG and JGB, were added in copper sulfate electrolyte, and the effects of these organic additives on the hardness were evaluated. All additives in this work were effective in increasing the hardness of copper electrodeposits. Thiourea increased the hardness up to 350 VHN, and was the most effective accelarator in sulfate electrolyte. It was shown from the X-ray diffraction analysis that preferred orientation changed from (200) to (111) with increasing concentration of organic additives. Crystallite size decreased with increasing concentration of additive. Hardness was increased with decreasing crystallite size, and this result is consistent with Hall-Petch relationship, and it was apparent that the hardening of copper electrodeposits results from the grain refining effect.

In Vitro Antitumor Activity of BCNU-Loaded PLGA Wafer Containing Additives (첨가제 함유 BCNU/PLGA웨이퍼의 in vitro 항암 활성)

  • Lee, Jin-Soo;An, Tae-Kun;Shin, Phil-Kyung;Chae, Ghang-Soo;Jeong, Je-Kyo;Lee, Bong;Cho, Sun-Hang;Khang, Gil-Son;Lee, Hai-Bang
    • Polymer(Korea)
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    • v.27 no.3
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    • pp.217-225
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    • 2003
  • We fabricated the 1,3-bis(2-chloroethyl)-1-nitrosourea (BCNU, carmustine)-loaded PLGA wafers containing poly(N-vinylpyrrolidone) (PVP) or tedium chloride (NaCl) in order to control the release profile of drug in special shape (3 in diameter, 1 mm in thickness) by direct compression method. In vitro release profiles of BCNU could be controlled by additives contained in the wafers. Initial release amount, release rate and duration of BCNU could be controlled with presence of PVP or NaCl. In vitro antitumor activity accessed using 9L gliosarcoma cell line has been evaluated by assaying the viability of cells treated with BCNU released from the wafers containing additives resulting in continuous growth inhibition of 9L gliosarcoma tumor cells. Specially, the continuous growth inhibition of BCNU-loaded PLGA wafers containing additives was more effective than that of non-additive BCNU-loaded PLGA wafers. The cytotoxic effect of the drug from the wafers containing NaCl as compared to wafers containing PVP was more enhanced.

Effects of organic additives in cyanide zinc electroplating Bath(Part 2) (시안화아연 도금욕에 있어서 유기화합물 첨가제의 영향 (제 2 보))

  • Lee, Ju-Seong;Park, Jung-Il
    • Journal of the Korean institute of surface engineering
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    • v.12 no.3
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    • pp.174-179
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    • 1979
  • The effects of brightness, electrochemical behaviour on the organic additives, such as aldehydes, polymers, amines and condensed product obtained from epichlorohydrin and nicotinamide, in cyanide zinc electrolplating bath have been studied by controlled potential electrolyser. The results were summerized as follows: (1) It was found that the addition of only one compound of these organic compounds in the bath was unsuitable but mixture of anisaldehyde or monoethanolamine and condensed product as suitable as brightener. (2) The cathodic polarization curve of polymers or aldehydes in cyanide zinc electroplating bath was almost the same but the cathodic polarization curve of condensed product remarkable shifted to noble potential more than non-additive curve.

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Effects of Organic and Inorganic Additives on Selective Non Catalytic Reduction Reaction of NOx in a Pilot Scale Flow Reactor (파일럿 규모의 흐름반응기에서 유기 및 무기 첨가제가 질소산화물의 선택적 무촉매 환원반응에 미치는 영향)

  • Park, Soo Youp;Yoo, Kyung Seun;Lee, Joong Kee;Park, Young Kwon
    • Korean Chemical Engineering Research
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    • v.44 no.5
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    • pp.540-546
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    • 2006
  • Effects of organic and inorganic additives on the SNCR reaction of NOx were investigated in a pilot scale flow reactor with a variation of operating parameters. NOx reduction efficiency increased with the increase of a residence time and an initial NOx concentration. NOx reduction reaction by urea solution started to appear about 850 and then reached to maximum value around $970^{\circ}C$. NOx reduction efficiency also increased with the increase of NSR (Normalized Stoichiometric Ratio) up to 2.0. Addition of ethanol and phenol as an organic additives shifted the optimum temperature window to lower region with decreasing the maximum NOx reduction efficiency. This might be due to the side reaction of hydrocarbon in ethanol structure. NaOH addition widened the temperature window and enhanced the NOx reduction efficiency about 10% due to the chain reaction of NaOH and the reduction of $N_2O$.

A Study on Decreasing Metals from Hanwoo Slurry with Chemical Additives (한우액상분뇨로부터 중금속 저감을 위한 화학제재의 이용에 관한 연구)

  • Kim, Chang-Mann;Choi, Jung-Hoon;Ko, Soo-Hyun;Choi, In-Hag
    • Journal of Environmental Science International
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    • v.19 no.11
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    • pp.1385-1390
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    • 2010
  • Repeated additions of untreated slurry to soil affected ecology and caused high levels of heavy metal in soil and ground water. The objective of this study was to evaluate heavy metal from hanwoo slurry with ferrous sulfate ($FeSO_4{\cdot}7H_2O$), aluminum sulfate [$Al_2(SO_4)_3{\cdot}14H_2O$, alum] and aluminum chloride ($AlCl_3{\cdot}6H_2O$) as a way to improve environmental management in hanwoo industry. The treatment rates, which were incorporated totally within the hanwoo slurry, were 1.0 g and 1.5 g of ferrous sulfate, alum and aluminum chloride/25 g of hanwoo slurry. The various rates of chemical additives significantly increased dry matter (9.98~13.94%) and decreased pH (3.48~6.52) compared with the controls. The use of chemical additives decreased Fe (11~29%), Al (7~12%), Zn (13~36%), and Cu (4~32%) contents, except for Fe in hanwoo slurry with ferrous sulfate and Al in hanwoo slurry with alum and aluminum chloride. In addition, the reduction in heavy metal should be associated with reduction in pH. In conclusion, the results of this study suggest that alum and aluminum chloride additives at rate of 1.5 g were cost-effective management practice that significantly reduces heavy metal from hanwoo slurry, while it may be improved environmental management.

Properties Change of Electroplated Permalloy Thin Films by Organic Additives (유기첨가제에 의한 전기도금 퍼말로이 박막의 물성변화)

  • Bang, Won-Bae;Bae, Jong-Hak;Hong, Ki-Min;Chung, Jin-Seok;Ko, Young-Dong;Lee, Hee-Bok
    • Journal of the Korean Magnetics Society
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    • v.17 no.3
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    • pp.133-136
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    • 2007
  • We investigated the changes of the magnetic properties in electroplated Permalloy thin films by a few organic additives added to the plating electrolytes. Under identical electroplating conditions, the crystalline orientations and the surface roughness of the plated thin films were different from those prepared with a pure electrolyte. These property changes reduced the coercivity and increased the magnetoimpedance ratio (MIR) up to 20%.