• Journal of the Korea Institute of Building Construction
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• v.8 no.4
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• pp.79-85
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• 2008

The purpose of this study is to evaluate the mix design of pH reducing cement concrete which can be used for environment-friendly concrete. Cement pastes and concretes are prepared with water-binder ratios and various admixtures such as blast-furnace slag, fly ash and recycled cement, and tested for compressive strength and pH. pH is measured through pore solution expressed from hydrated cement paste by special apparatus. From the test results, regardless of water-binder ratio, The pH of expressed pore solution from hydrated cement paste which is made of ordinary portland cement with blast-furnace slag, fly ash is decreased with increasing of admixtures content, and compressive strength is also slightly improved. The compressive strength of cement paste made of recycled cement which is burnt at $1000^{\circ}C$, for 2 hours is considerably increased compared with that of none-burnt recycled cement due to restoration of hydraulic property, but pH is a little higher. Porous concrete with ordinary portland cement has high pH in the range of 12.22 to 12.59, however, that is reduced to the range of 8.95 to 10.39 by carbonation at the surface of porous concrete. The pH reduction of porous concrete is possible by various admixture addition, however their degrees are very slight. Therefore, to reduce the pH considerably, carbonation method of porous concrete is better in pH reduction methods for plant survival condition of pH of 9.0 or less. In this study, it is apparent that pH for the environment-friendly porous concrete products used in the construction field can be suppressed by this carbonation method and various admixtures addition.

• Proceedings of the Korea Concrete Institute Conference
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• 1989.10a
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• pp.25-30
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• 1989

In this paper, morter and concrete specimens made with four cements were immersed in Mgcl2, MgSO4 Solution and artifical Seawater which was corresponded with Seawater. The hydration products of immersed cement pastes were looked over by using SEM, EDS and X-ray diffraction method. The results show that the concrete made with domestic flyash cement and blast-frrnace slag cement is superior to that of ordinary portland cement in resistance to chloride and sulphate solution. Especially, it is found that the attack of Cl-ion on the concrete plays an important role of the deterioration of concrete.

• The Korean Journal of Ceramics
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• v.5 no.1
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• pp.35-39
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• 1999

For many years, alkali activated blast furnace slag cement containing no ordinary portland cement has received much attention in the view of energy saving and its many excellent properties. We examined the structural change of slag glass which was activated by alkali metal compounds using IR spectroscopy. The properties of hydrated products and unhydrated slag grains was characterized by XRD and micro-conduction calorimeter. Ion concentration change in the liquid during the hydration of blast furnace slag was also studied to investigated the hydration mechanism.

• Journal of the Korea Concrete Institute
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• v.27 no.1
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• pp.3-9
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• 2015

In this study, hydration properties of ordinary Portland cement were examined, shown from a limestone and blast furnace slag alone or their mixture up to 10% as a minor mineral additives. As of setting time, it was identified that final setting became faster as the amount of limestone mixture increased, which showed limestone accelerated early hydration faster than blast furnace slag. This is because limestone did accelerate the hydration of alite. At the age of 3 days, limestone 5%-blast furnace slag 5% mixture had the highest compressive strength of mortar. It is because hydration acceleration of alite by limestone, and $Ca(OH)_2$ that was additionally formed by hydration acceleration of alite reacted with blast furnace slag, and as a result, additionally created C-S-H hydrate. Regarding the hydration properties by the age of 7 and 28 days, limestone 3%-blast furnace slag 7% of composited mixture showed the largest compressive strength, and in comparison with the 3 days in curing age. This period is when hydration reaction of blast furnace slag is active and the amount of hydrate depends on the amount of blast furnace slag mixture more than that of the limestone mixture. And in order to vitalize hydration reaction of blast furnace slag the amount of $Ca(OH)_2$ created has to increase, and thus, a small amount of limestone is necessary that can accelerate the hydration of alite. Therefore, after the age of 7 days, the fact that there were a large amount of blast furnace slag mixture and small amount of limestone mixture was effective to the strength development of ordinary Portland cement.

• Journal of the Korea Concrete Institute
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• v.13 no.2
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• pp.175-183
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• 2001

Immersion tests with artificial seawater were carried out to investigate the resistance to seawater attack of 5 types of cement matrices. From the results of compressive strength and length change, it was found that blended cement mortars due to mineral admixtures, were superior to portland cement mortars with respect to the resistance to seawater attack. Moreover, XRD analysis indicated that the peak intensity ratio of low heat portland cement(LHC) paste, in portland cement pastes, had better results, and so did that of blended cement Paste. Pore volume of pastes by mercury intrusion porosimetry method demonstrated that total pore volume of ordinary portland cement(OPC) paste had a remarkable increase comparing with that of other pastes. In case of immersion of artificial seawater, the use of ground granulated blast-furnace slag and fly ash, however, showed the beneficial effects of 56% and 32% in reduction of total pore volume, respectively.

• Proceedings of the Korea Concrete Institute Conference
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• 2003.05a
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• pp.799-804
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• 2003

The purpose of this study was to investigate the effects of re-vibration and curing temperature onto the physical properties of latex-modified concrete with ordinary cement and rapid-setting cement, and thus to provide a guide line of re-vibration and curing conditions for good quality controls. The main experimental variables included two cement types(ordinary portland cement, rapid-setting cement), curing Temperature($10^{\circ}C$, $20^{\circ}C$, $30^{\circ}C$), re-vibration methods(continued, intermittent), and re-vibration times(initial setting, one day after mixing). The experimental results showed that the re-vibration affected little to the mechanical properties of LMC and RSLMC, while, the curing temperature a quite some. The early strength development was the highest at $20^{\circ}C$ curing temperature, and decreased at higher temperature. The permeability of concrete generally decreased with curing time. The rapid chloride permeability was a function of time and temperature. The chloride permeability of RSLMC was so small and negligible.

• Journal of the Korean Ceramic Society
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• v.41 no.4
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• pp.323-327
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• 2004

This study has been carried out to use the municipal solid waste sewage sludge ash generated at sewage disposal field as the raw materials of Ordinary Portland Cement (OPC). Limestone, shale, converter slag, and fly ash were used as the main raw materials. After the raw materials were mixed, these were fired at 1,300, 1,350, 1,400, 1,450, and 1,500$^{\circ}C$ for 1 h and cooled rapidly in air. The properties of clinker synthesized were examined with XRD, SEM, and burnability index by polysius method.

• Journal of the Korean Ceramic Society
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• v.41 no.5
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• pp.417-424
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• 2004

Polycarboxylate type superplasticizers (PCA) with different graft chain (Polyethylene oxide) length were synthesized by Methoxypoly (ethyleneglycol)monomethacrylate (MPEGMAA) and methacrylic acid (MAA). The effects of PCA on the hydration of Ordinary Portland Cement (OPC) were investigated by Fourier Transform Infrared Spectroscopy (FT-IR), X-Ray Diffraction (XRD) and Differential Scanning Calorimetry (DSC) techniques. The effect of graft chain length of PCA on the hydration of OPC was different at early age, but, at long age, was similar. The ratio of relative peak intensity, (I［001］/I［101］), of Ca(OH)$_2$ compared with OPC also was reduced by PCA addition.

• Geomechanics and Engineering
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• v.3 no.3
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• pp.207-218
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• 2011

This article describes laboratory research done on strength evaluations for stabilized samples made of tropical fibrous peat. The stabilizing agents used were ordinary Portland cement (OPC) as binding agent and blast furnace slag (BFS) as additive. Stabilized samples were tested for their strength through unconfined compressive strength (UCS) and California bearing ratio (CBR). Different dosage rates of OPC and BFS were used in trial and error experiments for the most effective combination for stabilized peat samples that were at their natural moisture content. Stabilized trial samples were air cured for 90 days. After detecting the most effective dosage rate in the trial samples, their values were used to prepare CBR samples at their optimum moisture content (OMC). CBR samples were then air cured from 1 to 90 days and tested under un-soaked and soaked conditions. The most effective dosage rate for the stabilized peat samples was found to be close to when 75% for OPC and 25% of BFS per total weight of OPC, and BFS. As an example, if 11.25% OPC, and 3.75% BFS are mixed with peat and compacted at their OMC and air cured for 90 days, stabilized peat will have an increase in CBR of 0.8% to 45 % for un-soaked and 20% for soaked conditions.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2017.05a
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• pp.165-166
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• 2017

Corrosion of reinforcement is the main factors affecting the durability of reinforced concrete in the world which lead to the failure of structures of reinforced concrete buildings. In this research, mixed brucite(Mg(OH)₂) into ordinary portland cement paste in ratio of 5, 10 and 15% as a kind of CO₂ fixation material. Samples were exposed to an accelerated carbonation enslavement of 20% CO₂ concentration, 60% relative humidity, and a temperature of 20℃ until tested at 3d, 7d, 14d and 28d. After 28d CO₂ accelerated curing, in the paste containing MH megnesian calcite was found by XRD and SEM-EDX. Meanwhile, paste containing Mg(OH)₂ exhibit the better pore distribution than ordinary portland cement paste and relatively good compressive strength.