• Journal of Environmental Science International
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• v.5 no.2
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• pp.153-170
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• 1996

Photosynthetic pigments and their degradation products in suspended and sinking particles collected from the Gulf of Mexico waters 1987~88, were measured using High Performance liquid Chromatography (HPIC). The short term variations in flux rates of chlorophylls and carotenoids as well as-their degradation products were compared at the mesoscale cyclonic and anticyclonic circulation features (cold joie rink and warm core ring). Chlorophyll a was the predominant porphyrin of suspended particulate matter at both CCR -and WCR. Among carotenoid pigments, 19'-hexanoyloxyfucoxanthin, which is a biomarker of prymnesiophytes, was dominant pigment at both rinds. Phaeophorbide a, which is produced through the Brazing processes of grazers, was the predominant degraded pigment in sinking particles ai the study aiea. Total pigment flux in CCR was an order of magnitude higher than that in WCR. Less than l% of the standing stock of the pigments measured sank out of the upper 200m of the WCR on any given day. Thus, suspended particulate matter in Gulf of Medico was not recycled rapidly.

• Geomechanics and Engineering
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• v.14 no.3
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• pp.283-291
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• 2018

Cracks in soil provide significant preferential pathways for contaminant transport and rainfall infiltration. Water exchange between the soil matrix and crack is crucial to characterize the preferential flow, which is often quantitatively described by a water exchange ratio. The water exchange ratio is defined as the amount of water flowing from the crack into the clay matrix per unit time. Most of the previous studies on the water exchange ratio mainly focused on cracked sandy soils. The water exchange between cracks and clay matrix were rarely studied mainly due to two reasons: (1) Cracks open upon drying and close upon wetting. The deformable cracks lead to a dynamic change in the water exchange ratio. (2) The aperture of desiccation crack in clay is narrow (generally 0.5 mm to 5 mm) which is difficult to model in experiments. This study will investigate the water exchange between a deformable crack and the clay matrix using a newly developed experimental apparatus. An artificial crack with small aperture was first fabricated in clay without disturbing the clay matrix. Water content sensors and suction sensors were instrumented at different places of the cracked clay to monitor the water content and suction changes. Results showed that the water exchange ratio was relatively large at the initial stage and decreased with the increasing water content in clay matrix. The water exchange ratio increased with increasing crack apertures and approached the largest value when the clay was compacted at the water content to the optimal water content. The effective hydraulic conductivity of the crack-clay matrix interface was about one order of magnitude larger than that of saturated soil matrix.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.12 no.2
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• pp.1-10
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• 1992

In this study, the 'Comb-structure' model which has been developed from truss analogy is modified in order to be applied to the shear analysis of partially prestressed concrete members. The proposed 'Comb-structure' model is modified so that the position, the slope of concrete compressive chord and the slope of concrete diagonal strut may change according to the magnitude of loads and prestress. For the proposed mechanical model, non-linear beam and truss elements are used. By modifying the 'Compression-Field' theory, the equation to determine the slope angle of concrete diagonal strut can be induced. The anaysis results by the proposed 'Comb-structure' model are compared with the experimental results and validity of model is examined. It shows that the the result of 'Comb-structure' analysis lies between that of the modified M$\ddot{o}$rsch theory and classical M$\ddot{o}$rsch theory, and close to the measured value after cracking. The deflection of the beam and the stress of stirrup show good agreement, so it can be concluded that the proposed 'Comb-structure' analysis model explains the shear behavior of partially prestressed concrte beams after crack initiation.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.3
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• pp.1749-1755
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• 2014

Technique for analyzing a pile installed by vibrohammer was developed and parametric studies were executed in order to evaluate reliability of the developed technique. Comparing the accelerations obtained from parametric studies of varying eccentric moment and frequency, it can be seen that magnitude of maximum acceleration was proportional to the eccentric moment and square of frequency. It can also be seen that amplitude of displacement was roughly proportional to the eccentric moment but has nothing to do with the frequency. It can be said that all of the analysis results reflect characteristics of behavior of a pile in case of free vibration. Comparing the dynamic load transfer curves, maximum dynamic unit toe resistance was constant regardless of the eccentric moment and the frequency and it can be seen that dynamic unit skin friction was affected by the eccentric moment not by frequency. Comparing all of the analysis results, it can be said that the developed technique is reliable.

• Membrane Journal
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• v.13 no.1
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• pp.54-63
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• 2003

The Preparation and electrochemical characterization of anion-exchange membranes containing pyridinium groups were performed. As a result, the pyridinium membranes showed good electrochemical properties, comparable to those of the commercial membranes, with electrical resistance of less than $3.0 {\Xi}cm^2$ in a 0.5 mol $dm^{-3}$ NaCl and high ionic permselectivity (the transport number of $Cl^-$ ions being 0.97). Moreover, water splitting in the membranes containing pyridinium group was about two or three order of magnitude lower than those in the commercial membranes (ｅ.ｇ. AM-1, Tokuyama Crop., Japan) at the same current density because the resonance effedt in the quaternary aromatic pyridinium group contributed to their molecular stability. In addition, the electrodialytic properties of the pyridinium membranes were evaluated in a semi-pilot scale.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.15 no.4
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• pp.675-691
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• 2002

The focus of this work is on the development of large-scale numerical optimization methods for optimal control of steady incompressible Navier-Stokes flows. The control is affected by the suction or injection of fluid on portions of the boundary, and the objective function of fluid on portions of the boundary, and the objective function represents the rate at which energy is dissipated in the fluid. We develop reduced Hessian sequential quadratic programming. Both quasi-Newton and Newton variants are developed and compared to the approach of eliminating the flow equations and variables, which is effectively the generalized reduced gradient method. Optimal control problems we solved for two-dimensional flow around a cylinder. The examples demonstrate at least an order-of-magnitude reduction in time taken, allowing the optimal solution of flow control problems in as little as half an hour on a desktop workstation.

• Journal of the Earthquake Engineering Society of Korea
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• v.20 no.7_spc
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• pp.527-536
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• 2016

This paper investigates seismic damage potential of recent September 12 M5.8 Gyeongju earthquake from diverse earthquake engineering perspectives using the accelerograms recorded at three stations near the epicenter. In time domain, strong motion durations are evaluated based on the accelerograms and compared with statistical averages of the ground motions with similar magnitude, epicentral distance and soil conditions, while Fourier analysis using FFT is performed to identify damaging frequency contents contained in the earthquake. Effective peak ground accelerations are evaluated from the calculated response spectra and compared with apparent peak ground accelerations and the design spectrum in KBC 2016. All these results are used to consistently explain the reason why most of seismic damage in the earthquake was concentrated on low-rise stiff buildings but not quite significant. In order to comparatively appraise the damage potential, the constant ductility spectrum constructed from the Gyeongju earthquake is compared with that of the well-known 1940 El Centro earthquake. Deconvolution analysis by using one accelerogram speculated to be recorded at a stiff soil site is also performed to estimate the soil profile conforming to the response spectrum characteristics. Finally, response history analysis for 39- and 61-story tall buildings is performed as a case study to explain significant building vibration felt on the upper floors of some tall buildings in Busan area during the Gyeongju earthquake. Seismic design and retrofit implications of M5.8 Gyeongju earthquake are summarized for further research efforts and improvements of relevant practice.

• Journal of Fisheries and Marine Sciences Education
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• v.24 no.1
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• pp.18-24
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• 2012

This study analyses the effects of various angles in sculling on human body lift and drag by means of computational fluid dynamics, discusses the importance of sculling and provides a basis for the development of future water safety education programmes. Study subjects were based on the mean data collected from males in the age of 20s from a survey on the anthropometric dimensions of the Koreans. Moreover, lift, drag as well as coefficient values, all of which were governed by the angle of the palm, were calculated using 3-dimentional modelling produced by computational fluid dynamics programmes i.e. CFD. Interpretations were performed via general k-${\varepsilon}$ turbulence modelling in order to determine lift, drag and coefficient values. Turbulence intensity was set to one per cent as per the figures from preceding research papers and 3-dimentional simulations were performed for a total of five different angles $0^{\circ}$, $15^{\circ}$, $30^{\circ}$, $45^{\circ}$ and $60^{\circ}$. The drag and lift values for the differing angles of the hands during sculling movement are as follows. The lift and drag values gradually increased with the increasing angle of the palm, however, the magnitude of increase for drag started to predominate lift from $45^{\circ}$ and lift gradually decreased from $60^{\circ}$. Overall, it is concluded that the optimal efficiency of sculling can be achieved at the angles $15^{\circ}$ and $30^{\circ}$, and it is anticipated that greater safety and informative education can be ensured for Life saving trainees if the results were to be applied to practical settings. However, as the study was conducted using simulation programmes which performed analyses on the collected anthropometric dimension, the obtained results cannot be made universal, which warrants furthers studies involving varied study subjects with actual measurements taken in water.

• Bulletin of the Korean Chemical Society
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• v.34 no.1
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• pp.201-206
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• 2013

The second-order rate constants have been measured spectrophotometrically for the reactions of paraoxon 1 and parathion 2 with a series of alicyclic secondary amines, $OH^-$ and $HOO^-$ ions in $H_2O$ at $25.0{\pm}0.1^{\circ}C$. A linear Br${\o}$nsted-type plot with ${\beta}_{nuc}$ = 0.40 was obtained for the reactions of 1 with amines and $OH^-$. The reaction has been concluded to proceed through a concerted mechanism. $HOO^-$ deviates positively from the linear Br${\o}$nsted-type plot, implying that the ${\alpha}$-effect is operative. The magnitude of the ${\alpha}$-effect ($k_{HOO^-}/k_{OH^-}$) was found to be ca. 55 for the reaction of 1 and 290 for that of parathion 2, indicating that $HOO^-$ is highly effective in decomposition of the toxic phosphorus compounds although it is over 4 $pK_a$ units less basic than $OH^-$. Among the theories suggested as origins of the ${\alpha}$-effect (e.g., TS stabilization through an intramolecular Hbonding interaction, solvent effect, and polarizability effect), polarizability effect appears to be the most important factor for the ${\alpha}$-effect in this study, since the polarizable $HOO^-$ exhibits a larger ${\alpha}$-effect for the reaction of the more polarizable substrate 2.

• The Bulletin of The Korean Astronomical Society
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• v.43 no.2
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• pp.44.4-45
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• 2018

(4179) Toutatis (Toutatis hereafter) is one of the Near-Earth Asteroids which has been studied most rigorously not only via ground-based photometric, spectroscopic, polarimetric, and radar observations, but also via the in-situ observation by the Chinese Chang'e-2 spacecraft. However, one of the most fundamental physical properties, the geometric albedo, is less determined. In order to derive the reliable geometric albedo and further study the physical condition on the surface, we made photometric observations of Toutatis near the opposition (i.e., the opposite direction from the Sun). We thus observed it for four days on 2018 April 7-13 using three 1.6-m telescopes, which consist of the Korean Microlensing Telescope Network (KMTNet). Since the asteroid has a long rotational period (5.38 and 7.40 days from Chang'e-2, Zhao et al., 2015), the continuous observations with KMTNet matches the purpose of our photometric study of the asteroid. The observed data cover the phase angle (Sun-asteroid-observer's angle) of 0.65-2.79 degree. As a result, we found that the observed data exhibited the magnitude changes with an amplitude of ~0.8 mag. We calculated the time-variable geometrical cross-section using the radar shape model (Hudson & Ostro 1995), and corrected the effect from the observed data to derive the geometric albedo. In this presentation, we will present our photometric results. In addition, we will discuss about the regolith particles size together with the polarimetric properties based on the laboratory measurements of albedo-polarization maximum.