• Journal of the Korean Vacuum Society
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• v.12 no.S1
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• pp.95-99
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• 2003

We successfully grew InN/GaN single quantum well structures by metal-organic chemical vapor deposition and confirmed their formation by optical and structural measurements. We speculate that relatively high growth temperature ($730^{\circ}C$) of InN layer enhanced the formation of 2-dimensional quantum well structures, presumably due to high adatom mobility. As the growth interruption time increased, the PL emission efficiency from InN layer improved with peak position blue-shifted and the dislocation density decreased by one order of magnitude. The high resolution cross-sectional TEM images clearly showed that the InN layer thickness reduced from 2.5 nm (without GI) to about I urn (with 10 sec GI) and the InN/GaN interface became very flat with 10 sec GI. We suggest that decomposition and mass transport processes on InN during GI is responsible for these phenomena.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.17 no.2
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• pp.95-101
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• 2003

In this paper, partial discharges(PDs), lift off and breakdown voltage were measured when metal particles existed in a model GIS coated with epoxy resin on its bottom electrode, and the measured results were analyzed after comparing with the model DIS not coated. In order to presume the various fault case in GIS, we measured the experimental values with changing some experimental factors, such as the mixture ratio of SF$\_$6//N$_2$, the pressure of the gases, the kinds and diameter of the metal particles, and the coating thickness of the epoxy resin. As a result, the PDIV increased with the thickness of the epoxy resin, while the magnitude of PDs decreased at the same condition. The lift off voltages of steel alloy particles were higher than that of copper particles, and increased wit diameter of particles. Futhermore, the lift off voltages in the case of the electrode coated with epoxy resin were higher than that in the case of the uncoated one. In addition, the thicker the thickness of the epoxy resin was, the higher the breakdown voltage were. Thus, it was confirmed that the GIS coated with epoxy resin on its inner surface could be improved in insulation performance.

• Journal of Welding and Joining
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• v.28 no.2
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• pp.84-90
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• 2010

Fillet welding accounts for about 80% of all constructing process of ship and ocean structure. T-joint is one of the typical shapes which are frequently reported to experience the fatigue damage when the marine structure meets the storm loads. The fatigue damage is affected by the magnitude of residual stresses on the weld. Recently, many shipping registers and design guidances have required that the fatigue strength assessment method should be compensated by the effect of the residual stress in case that the random loading or storm loading is applied to the marine vessels. This study suggests the computational procedure to analyze the residual stresses of T-joint specimen that is frequently reported to get damaged by the storm loading. Experiment by XRD as well as the 3-D computational welding model is presented in order to get the profile of residual stress. Throughout the comparison of experimental result with the computational result, the computational model was validated. Thereafter, characteristics of he residual stresses in the joint are discussed.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.34 no.3
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• pp.17-24
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• 2002

An unsteady-state moisture diffusion through cellulosic fibers in paper was characterized from the moisture sorption experiment and the mathematical modeling. The sorption experiment was conducted by exposing thin dry paper specimens to a constant temperature-humidity environment. Oven dried blotting papers and filter papers were used as test samples and the gains of their weights were constantly monitored and recorded as a function of sorption time. For a mathematical approach, the moisture transport was assumed to be an one-dimensional diffusion in thickness direction through the geometrically symmetric structure of paper. The model was asymptotically simplified with a short-term approximation. It gave us a new insight into the moisture uptake phenomena as a function of square root of sorption time. The fiber-phase moisture diffusivities(FPMD) of paper samples were then determined by correlating the experimental data with the unsteady-state diffusion model obtained. Their values were found to be on the order of magnitude of $10^{-6}-10^{-7}cm^2$/min., which were equivalent to the hypothetical effective diffusion coefficients at the limit of zero porosity. The moisture sorption curve predicted from the model fairly agreed with that obtained from the experiment at some limited initial stages of the moisture uptake process. The FPMD value of paper significantly varied depending upon the current moisture content of paper. The mean FPMD was about 0.7-0.8 times as large as the short-term approximated FPMD.

• The Journal of Engineering Geology
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• v.8 no.3
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• pp.225-234
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• 1998

The behavior of the underground opening depends mainly on the magnitude of the initial stress existing before excavation and on the stress redistribution due to the excavation. In the case of elasto-plastic materials such as rock mass, as the structural behavior of surrounded opening due to excavation depends on the stress path, methods and sequence of excavation have influences on the results of numerical analysis. Therefore, in order to design underground openings with large cross-section such as underground nuclear power plants, radioactive waste disposal cavems, oil storage caverns, and so on more reasonably it is desirable to consider the effect of the excavation sequence in the analysis. In this paper, the underground structure is analyzed using the finite element method and the distinct element methods with a view to review the the effect of the excavation sequence. Based on the results of the analysis the followings are discussed : influence of excavation shape and sequence, effect of structural reinforcements, influence of multi caverns.

• Journal of Korean Society for Atmospheric Environment
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• v.22 no.6
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• pp.779-790
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• 2006

This study examines relative contributions of volatile organic compounds (VOCs) to the formation of hydroxyl (OH) and peroxy radicals such as $HO_2$ and $RO_2$ during the intensive sampling period (Jun. $1{\sim}30$, 2004) in the air of Seoul metropolitan area. As to the contribution of VOCs to $HO_x$ levels, the impact of individual VOC concentration change on $HO_2$ concentration change was more than an order of magnitude higher than that on OH concentration change during the study period. The contribution of change in isoprene concentration to $HO_2$ concentration change was 38 times higher than OH and that in the concentration of alkene compounds to $HO_2$ concentration change was 31 times higher than OH. Moreover, the concentration changes of isoprene and aromatic compounds (AROM) played significant roles in $HO_x$ concentration changes. On the other hands, aldehydes (ALD2) and alkanes (ALKA) showed anti-correlation (negative) in $HO_x$ concentration changes with low contribution ($-4{\times}10^{-3}$ pptv/ppbv (OH) and $-58{\times}10^{-3}$ ($HO_2$) for ALD2; $-1{\times}10^{-3}$ (OH) and $-15{\times}10^{-3}$ ($HO_2$) for ALKA). Unlike other VOCs, $C_2H_6$ and $C_3H_8$ showed positive or negative contribution to peroxy radicals, depending on ambient air conditions. The contribution of VOC concentration changes to changes in $CH_3O_2$ and $RO_2$ concentration showed similar pattern to $HO_x$ contribution.

• The Journal of the Korea Contents Association
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• v.12 no.9
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• pp.422-433
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• 2012

The purpose of this study was to investigate leisure constraints based on the types of leisure sports activity(individual, partner, and group activities) in order to lead people to participate in and to continue their leisure sports activities. Data were collected from leisure sports participants in Seoul and Kyungki province. A total of 286 respondents were selected using the convenience sampling method. Leisure constraint's sub-dimensions for the respondents were named as facility and environment, negative perception, lack of condition, risk of injury, and lack of time. As the results of this study, first, respondents felt facility and environmental constraint the most and negative perception constraint the lowest. Second, there were differences in negative perception and lack of condition constraints based on the magnitude of participation. Finally, there were differences in facility and environment, negative perception, lack of condition, and risk of injury constraints based on the types of leisure sports activity.

• Bulletin of the Korean Chemical Society
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• v.30 no.10
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• pp.2403-2407
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• 2009

Second-order rate constants have been measured for two series of nucleophilic displacement reactions, i.e., reactions of 4-nitrophenyl benzoate with Z-substituted phenoxides and those of Y-substituted phenyl benzoates (1a-h) with 4-chlorophenoxide (4-ClPhO–) in 80 mol% $H_2O$/20 mol% DMSO at 25.0 ${\pm}\;0.1\;{^{\circ}C}$. The Br$\phi$nsted-type plot for reactions of 4-nitrophenyl benzoate with Z-substituted phenoxides exhibits an excellent linear correlation with ${\beta}_{nuc}$ = 0.72. Reactions of 1a-h with 4-chlorophenoxide result in also a linear Br$\phi$nsted-type plot with ${\beta}_{lg}$ = –0.62, a typical ${\beta}_{lg}$ value for a concerted mechanism. The Hammett plots correlated with ${\sigma}^o\;and\;{\sigma}^-$ constants show many scattered points for reactions of 1a-h with 4-chlorophenoxide. In contrast, the corresponding Yukawa-Tsuno plot exhibits an excellent linear correlation with $\rho_Y$ = 2.26 and r = 0.53, indicating that expulsion of the leaving group occurs at the rate-determining step (RDS) either in a concerted mechanism or in a stepwise pathway. However, a stepwise mechanism with leaving group departure being the RDS is excluded since the leaving Y-substituted phenoxide is less basic and a better nucleofuge than the incoming 4-ClPh$O^-$. Thus, the reactions have been concluded to proceed through a concerted mechanism, in which bond formation between the nucleophile and electrophilic center is more advanced than expulsion of the leaving group in the transition state on the basis of the magnitude of ${\beta}_{nuc}\;and\;{\beta}_{lg}$ values.

• Bulletin of the Korean Chemical Society
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• v.34 no.10
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• pp.2877-2882
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• 2013

Second-order rate constants ($k_{Ox^-}$) have been measured spectrophotometrically for nucleophilic substitution reactions of 4-nitrophenyl X-substituted-cinnamates (7a-7e) and Y-substituted-phenyl cinnamates (8a-8e) with butane-2,3-dione monoximate ($Ox^-$) in 80 mol % $H_2O$/20 mol % DMSO at $25.0{\pm}0.1^{\circ}C$. The Hammett plot for the reactions of 7a-7e consists of two intersecting straight lines while the Yukawa-Tsuno plot exhibits an excellent linearity with ${\rho}_X$=0.85 and r=0.58, indicating that the nonlinear Hammett plot is not due to a change in the rate-determining step but is caused by resonance stabilization of the ground state (GS) of the substrate possessing an electron-donating group (EDG). The Br${\o}$nsted-type plot for the reactions of Y-substituted-phenyl cinnamates (8a-8e) is linear with ${\beta}_{lg}$ = -0.64, which is typical of reactions reported previously to proceed through a concerted mechanism. The ${\alpha}$-nucleophile ($Ox^-$) is more reactive than the reference normal-nucleophile ($4-ClPhO^-$). The magnitude of the ${\alpha}$-effect (i.e., the $k_{Ox^-}/k_{4-ClPhO^-}$ ratio) is independent of the electronic nature of the substituent X in the nonleaving group but increases linearly as the substituent Y in the leaving group becomes a weaker electron-withdrawing group (EWG). It has been concluded that the difference in solvation energy between $Ox^-$ and $4-ClPhO^-$ (i.e., GS effect) is not solely responsible for the ${\alpha}$-effect but stabilization of transition state (TS) through a cyclic TS structure contributes also to the Y-dependent ${\alpha}$-effect trend (i.e., TS effect).

• Bulletin of the Society of Naval Architects of Korea
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• v.27 no.1
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• pp.35-44
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• 1990

Most of the medium-size ships are powered by large-bore, long-stroke, slow-speed and two-stroke diesel engines in order to improve the fuel efficiency. Such a propulsion plant develops low-frequency excitation forces/moments of significant magnitude. A RO/RO car/truck carrier is also one of the cases. In this paper, the rational methods for analysis of vertical and coupled horizontal-torsional vibrations are presented. Taking account of unusual characteristics of the hull form and structural systems, the emphasis is put on modelling methods based on beam analogy, calculation of system parameters such as added mass and its center, polar added-mass moment of inertia, shear coefficient of hull sections and coupling degree in antisymmetric modes, and modal analysis of forced vibrations.