• Bulletin of the Korean Chemical Society
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• v.34 no.2
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• pp.415-420
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• 2013

Effect of chemical substitution at the para-position of the thiophenoxyl radical has been theoretically investigated in terms of energetics, structures, charge densities and orbital shapes for the ground and first electronically excited states. It is found that the adiabatic energy gap increases when $CH_3$ or F is substituted at the para-position. This change is attributed to the stabilization of the ground state of thiophenoxyl radical through the electron-donating effect of F or $CH_3$ group as the charge or spin of the singly-occupied molecular orbital is delocalized over the entire molecule especially in the ground state whereas in the excited state it is rather localized on sulfur and little affected by chemical substitutions. Quantitative comparison of predictions based on four different quantum-mechanical calculation methods is presented.

• Journal of International Society for Simulation Surgery
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• v.1 no.1
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• pp.7-12
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• 2014

Purpose Surgical correction of various occular problems which do not have visual problem in plastic surgical area is to normalize the appearance of the face by restoring the normal position of orbit and eyeball. With development of surgical technique, the orbit can be restored exactly in trauma patient and can be moved totally in hypertelorism, as an example of congenital disease. All these surgeries are based on the hypothesis that the position of oclular glove moves in the plane in a quantitatively predictable reationship to osseous orbit movement. However, no studies have critically evaluated between the change of periorbital soft tissue and the outcome of the surgical correction, because there is no method of objective, quantitave evaluation of the periorbital soft tissue. Method Author suggest the methodology for quantitative assessment of ocular and periocular fat changes using the manipulation of digital images of computed tomographic scan. Results The method was allowed to evaluate inter-dacryon distance, inter-centroid distance, movement of the medial orbital wall, movement of the lateral orbital wall, alteration of thickness of the lateral periorbital fat as indicator of movement of the orbital wall and orbit in the patient with congenital periorbital anomaly and postoperative periorbital surgery. The goal of surgical correction of various occular problems which do not have visual problem in plastic surgical area is to normalize the appearance of the face by restoring the normal position of orbit and eyeball. With development of surgical technique, the orbit can be restored exactly in trauma patient and can be moved totally in hypertelorism, as an example of congenital disease. All these sugeries are based on the hypothesis that the position of oclular glove moves in the plane in a quantitatively predictable relationship to osseous orbit movement. However, no studies have critically evaluated between the change of periorbital soft tissue and the outcome of the surgical correction, because there is no method of objective, quantitave evaluation of the periorbital soft tissue. In this report, author suggest the methodology for quantitative assessment of ocular and periocular fat changes using the manipulation of digital images of computed tomographic scan. Conclusion The method suggested is objective and accurate method in measurement of the orbital contents. It takes time and is not easy to do, however, this kind of measurement for fine structures will be more easily available in near future.

• Archives of Craniofacial Surgery
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• v.18 no.4
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• pp.249-254
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• 2017

Background: Lower eyelid incisions are widely used for the orbital approach in periorbital trauma and aesthetic surgery. In general, the subciliary approach is known to cause disposition of the lower eyelid by scarring the anterior lamella in some cases. On the other hand, many surgeons believe that a transconjunctival approach usually does not result in such complications and is a reliable method. We measured positional changes in the lower eyelid in blowout fracture repair since entropion is one of the most serious complications of the transconjunctival orbital approach. Methods: To measure the positional changes in the lower eyelids, we analyzed preoperative and postoperative photographs over various time intervals. In the analysis of the photographs, marginal reflex distance 2 ($MRD_2$) and eyelash angle were used as an index of eyelid position. Statistical analyses were performed to identify the significance in the positional changes. All patients underwent orbital reconstruction through a transconjunctival incision by a single plastic surgeon. Results: In 42 blowout fracture patients, there was no statistical significant difference in the MRD2 and eyelash angle. Furthermore, there were no clinical complications, such as infection, hematoma, bleeding, or implant protrusion, during the follow-up periods. Conclusion: The advantages of the transconjunctival approach for orbital access include minimal scarring and a lower risk of eyelid displacement compared with other approaches. Based on these results, we recommend the transconjunctival approach for orbital exposure as a safe and reliable method.

• Journal of Astronomy and Space Sciences
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• v.31 no.1
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• pp.41-50
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• 2014

The Earth is not perfectly spherical and its rotational axis is not fixed in space, and these geophysical and kinematic irregularities work as dominant perturbations in satellite orbit propagation. The International Earth Rotation Service (IERS) provides the Conventions as guidelines for using the Earth's model and the reference time and coordinate systems defined by the International Astronomical Union (IAU). These guidelines are directly applied to model orbital dynamics of Earth satellites. In the present work, the effects of the latest conventions released in 2010 on orbit propagation are investigated by comparison with cases of applying the previous guidelines, IERS Conventions (2003). All seven major updates are tested, i.e., for the models of the precession/nutation, the geopotential, the ocean tides, the ocean pole tides, the free core nutation, the polar motion, and the solar system ephemeris. The resultant position differences for one week of orbit propagation range from tens of meters for the geopotential model change from EGM96 to EGM2008 to a few mm for the precession/nutation model change from IAU2000 to IAU2006. The along-track differences vary secularly while the cross-track components show periodic variation. However, the radial-track position differences are very small compared with the other components in all cases. These phenomena reflect the variation of the ascending node and the argument of latitude. The reason is that the changed models tested in the current study can be regarded as small fluctuations of the geopotential model from the point of view of orbital dynamics. The ascending node and the argument of latitude are more sensitive to the geopotential than the other elements. This study contributes to understanding of the relation between the Earth's geophysical properties and orbital motion of satellites as well as satellite-based observations.

• Journal of Korean Society for Geospatial Information Science
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• v.14 no.4 s.38
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• pp.27-36
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• 2006

Conventionally, in order to get accurate geolocation of satellite images we need a set of ground control points with respect to individual scenes. In this paper, we tested the possibilities of modeling satellite orbits from individual scenes by establishing a sensor model for one scene and by applying the model, which was derived from the same orbital segment, to other scenes that has been acquired from the same orbital segment. We investigated orbit-attitude models with several interpolation methods and with various parameter sets to be adjusted. We used 7 satellite images of SPOT-3 with a length of 420km and ground control points acquired from GPS surveying. Results of the conventional individual scene modeling hardly introduced differences among different interpolation methods and different adjustment parameter sets. As the results of orbit modeling, the best model was the one with Lagrange interpolation for position/velocity and linear interpolation for attitude and with position/angle bias as parameter sets. The best model showed that it is possible to model orbital segments of 420km with ground control points measured within one scene (60km).

• Korean Journal of Remote Sensing
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• v.19 no.3
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• pp.181-190
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• 2003

Since the operation of the first satellite-based navigation service, satellite positioning has played an increasing role in both surveying and geodesy, and has become an indispensable tool for precise relative positioning. However, in some situations, e.g. at a low angle of elevation, the use of satellites for navigation is seriously restricted because obstacles like buildings and mountains can block signals. As a mean to resolve this problem, the quasi-zenith satellite system has been proposed as a next-generation satellite navigation system. Quasi-zenith satellite is a system which simultaneously deploys several satellites in a quasi-zenith geostationary orbit so that one of the satellites always stay close to the zenith if viewed from a specific point on the ground of East Asia. Thus, if a position measurement function compatible with CPS is installed in the quasi-zenith and stationary satellites, and these satellites are utilized together with the CPS, four satellites can be accessed simultaneously nearly all day long and a substantial improvement in position measurement, especially in metropolitan areas, can be achieved. The purpose of this paper is to evaluate the effectiveness of quasi-zenith satellite system on positioning accuracy improvement through simulation by using precise orbital information of the satellites and a three-dimensional digital map. Through this developed simulation system, it is possible to calculate the number of simultaneously visible satellites and available area for positioning without the need of actual observation. Furthermore, this system can calculate the Dilution Of Precision (DOP) and the error distribution.

• Journal of Welding and Joining
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• v.29 no.3
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• pp.58-63
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• 2011

Bead shape control with gas force process has been developed to overcome the concave back bead in pipe orbital welding. However, It is impossible to make a convex back bead using the existing gas nozzle, because it has high gas-consuming and low gas force. The purpose of this paper, to develop optimum shape of nozzle which to reduce the consumption of gas, maximizing the shield gas force with low cost and high productivity coincide the Green welding. In this paper venturi-type nozzle was compared with existing CP-type nozzle by TIG pulse welding in overhead position. As a result, CP-type occurs the wormholes in the overhead position, but the Venturi-type without the pore and formed a good bead appearance.

• Journal of Astronomy and Space Sciences
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• v.29 no.3
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• pp.287-293
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• 2012

Satellite operating agencies are constantly monitoring conjunctions between satellites and space objects. Two line element (TLE) data, published by the Joint Space Operations Center of the United States Strategic Command, are available as raw data for a preliminary analysis of initial conjunction with a space object without any orbital information. However, there exist several sorts of uncertainties in the TLE data. In this paper, we suggest and analyze a method for estimating the uncertainties in the TLE data through mean, standard deviation of state vector residuals and covariance matrix. Also the estimation results are compared with actual results of orbit determination to validate the estimation method. Characteristics of the state vector residuals depending on the orbital elements are examined by applying the analysis to several satellites in various orbits. Main source of difference between the covariance matrices are also analyzed by comparing the matrices. Particularly, for the Korea Multi-Purpose Satellite-2, we examine the characteristics of the residual variation of state vector and covariance matrix depending on the orbital elements. It is confirmed that a realistic consideration on the space situation of space objects is possible using information from the analysis of mean, standard deviation of the state vector residuals of TLE and covariance matrix.

• Archives of Craniofacial Surgery
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• v.18 no.2
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• pp.128-131
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• 2017

With advances in diagnostic technology, radiologic diagnostic methods have been used more frequently, and physical examination may be neglected. The authors report a case of pediatric medial orbital trapdoor fracture in which the surgery was delayed because computed tomography (CT) findings did not indicate bone displacement, incarceration of rectus muscle, or soft tissue herniation. A healthy 6-year-old boy was admitted to the emergency room for right eyebrow laceration. We could not check eyeball movement or diplopia, because the patient was irritable. Thus, we performed facial CT under sedation, but there was normal CT finding. Seven days later, the patient visited our hospital due to persistent nausea and dizziness. We were able to perform a physical examination this time. Lateral gaze of right eye was limited. CT still did not show any findings suggestive of fracture, but we decided to perform exploratory surgery. We performed exploration, and found no bone displacement, but discovered entrapped soft tissue. We returned the soft tissue to its original position. The patient fully recovered six weeks later. To enable early detection and treatment, thorough physical examination and CT reading are especially needed when the patient shows poor compliance, and frequent follow-up observations are also necessary.

• Publications of The Korean Astronomical Society
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• v.22 no.4
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• pp.151-168
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• 2007

We have analyzed the comet records in the Korean history books: Samguksagi, Goryeosa, and Joseonwangjosillok. For a comparison, the Chinese and Japanese comet records collected by Kronk (1999) have also been analyzed. Power spectrum of the time series of the comet records is used to find periodic comets. Statistically significant periodicities in the power spectrum are detected at the periods of 38-40 years, about 76 years, and 300-400 years for all Korean, Chinese, and Japanese comet records. We have also calculated the past orbits of some comets that have been recently observed, to check whether or not they were recorded in the history books. We use a multistep method to numerically integrate the comet's orbital motion backward in time to 51 B.C. The gravitational force due to the Sun and the nine planets, non-gravitational force, and the relativistic effects have been considered. Comparison of comet's perihelion passage time and the position on the sky with the historical records shows that the comet Halley were recorded at every passage in both Goryeo and Joseon periods. The orbital motion of the comet Pons-Brooks has also been compared with the Korean records. For the comet Tempel-Tuttle, Swift-Tuttle, and Ikeya-Zhang, we have compared our calculation of the orbital motions with those of the previous studies.