• Title/Summary/Keyword: Orbital Information

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일치환된 방향족 고리의 NO2+ 치환반응에서의 반응성과 지향성에 관한 연구

  • Nam, Yeon-Sik;Kim, Seon-Gyeong;Jo, Dae-Heum
    • Proceeding of EDISON Challenge
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    • 2015.03a
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    • pp.40-47
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    • 2015
  • 본 연구에서는 일치환된 방향족 화합물의 $NO_2{^+}$ 치환반응에서의 반응성 (reactivity)과 지향성 (regioselectivity)에 대해 분석하였다. 기존의 연구에 따르면, 방향족 고리와 치환체 사이의 ${\sigma}$ 결합을 통한 유발효과와 ${\pi}$ 결합을 통한 공명효과로 인해 벤젠 고리의 전자 분포가 증가하게 되면 반응성이 증가하는 것으로 알려져 있다. 또한 반응중간생성물인 탄소양이온의 안정성을 통해 지향성을 확인할 수 있는 것으로 알려진 바가 있다. 이에 따라, 본 연구에서는 반응성과 지향성이 실험적으로 잘 알려진 7가지의 치환기 (OH, $OCH_3$, $CH_3$, Cl, COOH, CN, $NO_2$)를 선정하여 DFT functional인 B3LYP를 사용하여 natural bond orbital (NBO) 계산을 하였고, 각각의 일치환된 벤젠 고리가 갖는 전자 분포를 ${\sigma}$${\pi}$ 전자로 나누어서 보기로 했다. 그 결과, 일치환된 방향족 고리 치환반응의 반응성과 지향성은 ${\sigma}$ 결합을 통한 유발효과에 의해서는 영향을 받지 않고, 공명 효과로 인한 반응물의 ${\pi}$ 전자 분포에 의해 결정되는 것을 확인할 수 있었다. 이외에도 반응성을 비교 하기 위해 친핵체로 작용하는 일치환된 방향족 고리의 highest occupied molecular orbital(HOMO) 에너지와 친전자체인 $NO_2{^+}$의 lowest unoccupied molecular orbital (LUMO) 에너지의 차이를 비교하였으며, 친핵체의 HOMO 에너지가 높을수록 반응성이 커짐을 알 수 있었다.

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A Three-layered Optical Waveguide of Second-order Orbital Angular Momentum Mode Guiding for Photonic Integrated Circuit (3층 구조를 가지는 광 집적회로용 2차 궤도 각운동량 광 도파로)

  • Lee, In-Joon;Kim, Sang-In
    • The Journal of the Korea institute of electronic communication sciences
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    • v.14 no.4
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    • pp.645-650
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    • 2019
  • In this paper, a specifically designed waveguide structure that can carry first, and second-order orbital angular momentum(: OAM) mode is proposed. The proposed optical waveguide consists of three Si stripes embedded in $SiO_2$, which is suitable for implementing on-chip integration and fabrication by standard thin film deposition and etching processes. The second-order OAM mode was generated by combining two eigenmodes, which are calculated by finite difference method(: FDM). The topological charge number of the first, and second-order OAM mode was calculated as l=0.9642 and 1.8766 respectively, which is close to the theoretical value.

Feasibility of Using Norad Orbital Elements for Pass Programming and Catalog Generation for High Resolution Satellite Images (고해상도 위성영상 촬영계획 수립 및 카탈로그 생성을 위한 NORAD 궤도 데이터의 이용 가능성 연구)

  • 신동석;김탁곤;곽성희;이영란
    • Korean Journal of Remote Sensing
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    • v.15 no.2
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    • pp.119-130
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    • 1999
  • At present, many ground stations all over the world are using NORAD orbit element data in order to track and communicate with Earth orbiting satellites. The North American Aerospace Defense Command (NORAD) observes thousands of Earth orbiting objects on daily basis and provides their orbital information via internet. The orbital data provided by NORAD, which is also called two line element (TLE) sets, allows ground stations to predict the time-varying positions of satellites accurately enough to communicate with the satellites. In order to complete the mission of a high resolution remote sensing satellite which requires very high positional determination and control accuracy, however, a mission control and tracking ground station is dedicated for the observation and positional determination of the satellite rather than using NORAD orbital sets. In the case of KITSAT-3, NORAD orbital elements are currently used for image acquisition planning and for the processing of acquired images due to the absence of a dedicated KITSAT-3 tracking ground system. In this paper, we tested and analyzed the accuracy of NORAD orbital elements and the appropriate prediction model to determine how accurately a satellite acquisites an image of the location of interest and how accurately a ground processing system can generate the catalog of the images.

Organic Thin-Film Transistors with Polymer Buffer Layer (고분자 완충층을 이용한 유기박막트랜지스터)

  • Choi, Hak-Bum;Hyung, Gun-Woo;Park, Il-Houng;Hwang, Seon-Wook;Kim, Young-Kwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.182-183
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    • 2008
  • We fabricated a pentacene thin film transistor with Poly-vinylalcohol (PVA) as a dielectric. And we used Poly(9-vinylcarbazole) (PVK) as a buffer layer to improve the electrical characteristics. PVK is a material used often host material for OLED device, as it has good film forming properties, large HOMO-LUMO(highest occupied molecular orbital-lowest unoccupied molecular orbital) bandgap. The performance of a OTFT device with PVA gate dielectric was improved by using the PVK. Field effect mobility, threshold voltage, and on-off current ratio of device with PVK layer were about 0.6 $cm^2$/Vs, -17V, and $5\times10^5$, respectively.

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Implementing Solar System Simulator using Python Script (파이선 스크립트를 이용한 태양계 행성 시뮬레이터 구현)

  • Choi, Eun-Young;Lee, Imgeun
    • Journal of the Korea Society of Computer and Information
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    • v.20 no.4
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    • pp.49-56
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    • 2015
  • In this paper, we introduce a simulation tool for solar system using 3D animation tool MAYA. It accurately models solar system's astronomical features, such as each planet's orbital period, orbital speed, relative size, and texture, etc. This simulator visualize the solar system in 3D, which can be used to easily understands the system's positioning and astronomical movements. With a conventional Maya modeling process using menus and UI windows, it is difficult to assign correct physical attributes of planets. We use Python script to set up each planet's astronomical parameters. The proposed simulator is rendered as real as possible to be used for virtual reality and educational purpose.

Accuracy analysis of SPOT Orbit Modeling Using Orbit-Attitude Models (궤도기반 센서모델을 이용한 SPOT 위성 궤도모델링 정확도 분석)

  • Kim, Hyun-Suk;Kim, Tae-Jung
    • Journal of Korean Society for Geospatial Information Science
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    • v.14 no.4 s.38
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    • pp.27-36
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    • 2006
  • Conventionally, in order to get accurate geolocation of satellite images we need a set of ground control points with respect to individual scenes. In this paper, we tested the possibilities of modeling satellite orbits from individual scenes by establishing a sensor model for one scene and by applying the model, which was derived from the same orbital segment, to other scenes that has been acquired from the same orbital segment. We investigated orbit-attitude models with several interpolation methods and with various parameter sets to be adjusted. We used 7 satellite images of SPOT-3 with a length of 420km and ground control points acquired from GPS surveying. Results of the conventional individual scene modeling hardly introduced differences among different interpolation methods and different adjustment parameter sets. As the results of orbit modeling, the best model was the one with Lagrange interpolation for position/velocity and linear interpolation for attitude and with position/angle bias as parameter sets. The best model showed that it is possible to model orbital segments of 420km with ground control points measured within one scene (60km).

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Design and manufacture of eyeball protrusion measuring device using white light scanning interferometer (백색광 간섭계를 이용한 안구 돌출 측정 장치 설계 및 제작)

  • Chang, Jung-soo;Kim, Young-kil
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.23 no.1
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    • pp.63-69
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    • 2019
  • The relative position of the orbital eye can be a criterion for evaluating several pathological conditions. It is especially useful to diagnose orbital fractures, thyroid eye disease, orbital tumors and to evaluate the outcome of medication and surgical treatment. Hertel and Naugle are representative measurement tools used to measure eyeball protrusion values, and have different measurement results, such as fixed orbits, every time they are inspected, even if the same inspector repeatedly measures them. Even with the same calibrator, it is inevitable that different manufacturers will change the design of the stationary part of the orbit, causing the surveyor to make a measurement error. In this paper, we designed and fabricated a protrusion measuring device using a white light interferometer and measured the protrusion of the human eye and found that the precision and repeatability were significantly higher than the manual measurement method.

The Influence of Injection Layers on Efficiency of Organic Light-Emitting Diodes (주입층이 OLED 소자의 효율에 미치는 영향)

  • Lee, Jeong-Gu;Lim, Kee-Joe
    • Proceedings of the KIEE Conference
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    • 2008.05a
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    • pp.181-182
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    • 2008
  • 고 효율의 유기 발광 소자 개발을 위해 무엇보다 발광 소자의 각층의 에너지 대 구조를 고려한 구조 개선과 새로운 유기물질 합성을 통해 구동전압을 낮춤으로써 전력효율을 높이고, 소모 전력을 낮추며, 수명을 증가시킬 수 있어, 많은 연구자들이 유기 발광 소자의 효율을 향상시키기 위해 다양한 노력들을 시도하고 있다. 본 연구에서는 고 효율화를 위한 방법으로 유기 발광 소자에 있어서 전자주입에 필요한 전압을 낮추고 전자 주입을 촉진시키기 위하여 발광물질의 LUMO(LOWEST UNOCCUPIED MOLECULAR ORBITAL) 준위와 음극 금속의 페르미 준위를 고려하여 전자 주입시 전위 장벽을 낮출 수 있는 에너지 대 구조를 가진 전자 주입 층을 검토하였고, 정공 주입을 촉진시키기 위하여 양극 금속의 페르미 에너지 준위와 발광 층의 HOMO(HIGHEST OCCUPIED MOLECULAR ORBITAL) 준위를 고려하여 정공 주입시 전위장벽을 낮출 수 있는 적절한 에너지 대 구조를 가진 정공 주입 층에 대하여 고찰하였다.

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Analysis and application of ocean currents information extracted from SAR satellite image (SAR 위성영상 해수유동 정보추출 및 활용)

  • Lee, Moon-Jin;Kim, Hey-Jin;Lee, Seung-Hyun;Hang, Key-Yong
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.13 no.4
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    • pp.21-26
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    • 2007
  • A study on analysis and application of ocean currents information extracted from SAR (Synthetic Aperture Radar) satellite image. The current information extracted from SAR satellite image is not real vector information but scalar information in normal direction of orbital path. To correct current information extracted from satellite image, observation of currents in the field is carried out at the same time and area as those of satellite image. In the analysis, current information extracted from satellite image is corrected by using observed ones. By this correction, the speed and the direction of current can be estimated. The extract current information seem to agree well with the observed ones.

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Ground Reflection Effect on OAM Multi-Mode Transmission System Based on Uniform Circular Arrays (UCA 기반 OAM 다중모드 전송시스템에 대한 지면 반사의 영향)

  • Yoo, Jeong-Ung;Son, Hae-Won
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.29 no.1
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    • pp.28-31
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    • 2018
  • This paper investigates the ground reflection effect on the channel capacity of an orbital angular momentum (OAM) multi-mode transmission system that uses uniform circular array (UCA) antennas. The ground-reflected signals cause inter-mode interferences between the OAM modes, and lead to system performance degradation. The OAM multi-mode channel capacity severely degrades owing to the ground reflection as the transmission distance increases. Increasing the UCA height above the ground and using highly directive array elements can mitigate the ground reflection effect and increase the channel capacity.