• Near Infrared Analysis
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• 제1권1호
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• pp.1-7
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• 2000

A convenient algorithm for optimizing wavelength selection in multiple linear regression (MLR) has been developed. MOP (MLP Optimization Program) has been developed to test all possible MLR calibration models in a given spectral range and finally find an optimal MLR model with external validation capability. MOP generates all calibration models from all possible combinations of wavelength, and simultaneously calculates SEC (Standard Error of Calibration) and SEV (Standard Error of Validation) by predicting samples in a validation data set. Finally, with determined SEC and SEV, it calculates another parameter called SAD (Sum of SEC, SEV, and Absolute Difference between SEC and SEV: sum(SEC+SEV+Abs(SEC-SEV)). SAD is an useful parameter to find an optimal calibration model without over-fitting by simultaneously evaluating SEC, SEV, and difference of error between calibration and validation. The calibration model corresponding to the smallest SAD value is chosen as an optimum because the errors in both calibration and validation are minimal as well as similar in scale. To evaluate the capability of MOP, the determination of benzene content in unleaded gasoline has been examined. MOP successfully found the optimal calibration model and showed the better calibration and independent prediction performance compared to conventional MLR calibration.

• 한국근적외분광분석학회:학술대회논문집
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• 한국근적외분광분석학회 2001년도 NIR-2001
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• pp.4102-4102
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• 2001

In multivariate analysis, absorbance spectrum is measured over a band of wavelengths. One does not often pay attention to the size of this wavelength band. However, it is desirable that spectrum is measured at only necessary wavelengths as long as the acceptable accuracy of prediction can be met. In this paper, the method of selecting an optimal band of wavelengths based on the loading vector analysis was proposed and applied for determining total protein in human serum using near-infrared transmission spectroscopy and PLSR. Loading vectors in the full spectrum PLSR were used as reference in selecting wavelengths, but only the first loading vector was used since it explains the spectrum best. Absorbance spectra of sera from 97 outpatients were measured at 1530∼1850 nm with an interval of 2 nm. Total protein concentrations of sera were ranged from 5.1 to 7.7 g/㎗. Spectra were measured by Cary 5E spectrophotometer (Varian, Australia). Serum in the 5 mm-pathlength cuvette was put in the sample beam and air in the reference beam. Full spectrum PLSR was applied to determine total protein from sera. Next, the wavelength region of 1672∼1754 nm was selected based on the first loading vector analysis. Standard Error of Cross Validation (SECV) of full spectrum (1530∼l850 nm) PLSR and selected wavelength PLSR (1672∼1754 nm) was respectively 0.28 and 0.27 g/㎗. The prediction accuracy between the two bands was equal. Wavelength selection based on loading vector in PLSR seemed to be simple and robust in comparison to other methods based on correlation plot, regression vector and genetic algorithm. As a reference of wavelength selection for PLSR, the loading vector has the advantage over the correlation plot since the former is based on multivariate model whereas the latter, on univariate model. Wavelength selection by the first loading vector analysis requires shorter computation time than that by genetic algorithm and needs not smoothing.

• 한국기계가공학회지
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• 제13권5호
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• pp.98-106
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• 2014

This study was carried out to evaluate the plant growth rate according to the wavelength characteristics of LED light sources. In order to achieve this, red, green, blue and white LEDs were arrayed in a rectangle array consisting of LED modules which can be combined with each other.. This can facilitate the selection of the optimal characteristics of the light from monochromatic red, green, blue and white LEDs or mixed LEDs for plant growth. Experiments to evaluate the growth rate according to the wavelength characteristics of the LEDs with several plants, in this case ice plants, lettuce, barley, broccoli and chives, were performed.

• 한국통신학회논문지
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• 제23권4호
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• pp.1051-1058
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• 1998

광굴절결정에서 두 기록빔의 입사각에 따른 파장선택성을 이용해 원하는 통과대역과 중심파장을 갖는 대역통과필터로의 응용을 제안하였다. 2광파결합을 통해 Fe가 0.02Wt.% 도핑된 $LiNbO_3$ 결정의 회절특성을 실험함으로써, 가장 우수한 회절효율을 갖는 조건을 도출하고, 이러한 조건에서 원하는 대역 및 파장을 선택해 낼 수 있는 대역통과필터를 전광학적으로 구현하였다. 또한, 기록빔의 입사각을 변화시킴으로써, 임의의 원하는 필터 특성을 얻을 수 있음을 실험적으로 증명하였다.

• Journal of Biosystems Engineering
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• 제43권3호
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• pp.219-228
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• 2018

Purpose: This study evaluated the feasibility of a near-infrared spectroscopy technique for the rancidity prediction of soybean oil. Methods: A near-infrared spectroscopy technique was used to evaluate the rancidity of soybean oils which were artificially deteriorated. A soybean oil sample was collected, and the acid values were measured using titrimetric analysis. In addition, the transmission spectra of the samples were obtained for whole test periods. The prediction model for the acid value was constructed by using a partial least-squares regression (PLSR) technique and the appropriate spectrum preprocessing methods. Furthermore, optimal wavelength selection methods such as variable importance in projection (VIP) and bootstrap of beta coefficients were applied to select the most appropriate variables from the preprocessed spectra. Results: There were significantly different increases in the acid values from the sixth days onwards during the 14-day test period. In addition, it was observed that the NIR spectra that exhibited intense absorption at 1,195 nm and 1,410 nm could indicate the degradation of soybean oil. The PLSR model developed using the Savitzky-Golay $2^{nd}$ order derivative method for preprocessing exhibited the highest performance in predicting the acid value of soybean oil samples. onclusions: The study helped establish the feasibility of predicting the rancidity of the soybean oil (using its acid value) by means of a NIR spectroscopy together with optimal variable selection methods successfully. The experimental results suggested that the wavelengths of 1,150 nm and 1,450 nm, which were highly correlated with the largest absorption by the second and first overtone of the C-H, O-H stretch vibrational transition, were caused by the deterioration of soybean oil.

• 한국인터넷방송통신학회논문지
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• 제21권5호
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• pp.141-147
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• 2021

본 연구를 통해 임베디드 시스템(Embedded System)에서 뉴럴 네트워크(Neural Network) 인풋의 차원 감소 방식으로 복잡한 연산량을 줄여 초분광 대용량 데이터 특징 정보의 활용률을 개선하기 위해, 전체 밴드를 밴드별 최댓값과 최솟값 차이로 부분집합으로 군집화하여, 각 부분집합에서 밴드 선택 알고리즘을 적용한다. 특징 추출과 특징 선택 기법 중에, 특징 선택 기법을 통해, 파장 범위와 관계없이 데이터세트에 맞는 최적의 밴드 수와 기존 알고리즘 적용 소요 시간과 성능을 향상하고자 한다. 이 실험을 통해 기존 밴드 선택 기법보다 1/3~ 1/9배 소요 시간을 단축했음에도 불구하고 K-최근접 이웃 분류기를 통한 성능 면에서는 약 4% 이상 향상된 의미 있는 결과를 도출하였다. 실시간 초분광 데이터 분석 활용에는 어렵지만, 개선된 가능성을 확인했다.

• Journal of Biosystems Engineering
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• 제23권6호
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• pp.571-582
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• 1998

The PLS(Partial Least Square) and ANN(Artificial Neural Network) were introduced to develop the soluble solids content prediction model of apples which is followed by making a subsequent selection of photosensor. For the optimal PLS model, number of factors needed for spectrum analysis were increased until the convergence of prediction residual error sum of squares. Analysis has shown that even part of the overall wavelength with no pretreatment may turn out better performing. The best PLS model was found in the 800 to 1,100nm wavelength region without pretreatment of second derivation, having $R^2$=0.9236, bias= -0.0198bx, SEP=0.2527bx for unknown samples. On the other hand, for the ANN model the second derivation led to higher performance. On partial range of 800 to 1,100nm wavelengh region, prediction model with second derivation for unknown samples reached $R^2$=0.9177, SEP=0.2903bx in contrast to $R^2$=0.7507, SEP =0.4622bx without pretreatment.

• Journal of Biosystems Engineering
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• 제23권6호
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• pp.561-570
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• 1998

The MLR(Multiple Linear Regression) models to estimate soluble solids content non-destructively were presented to make a selection of optimal photosensor utilized to measure the soluble solids content of apples. Visible and NIR absorbance in the 400 to 2498 nanometer(nm) wavelength region, soluble solids content(sugar content), hardness, and weight were measured for 400 apples(gala). Spectrophotometer with fiber optic probe was utilized for spectrum measurement and digital refractometer was used for soluble solids content. Correlation between absorbance spectrum and soluble solids content was analyzed to pick out the optimal wavelengths and to develop corresponding prediction model by means of MLR. For the coefficient of determination($R^2$) to be over 0.92, the MLR models out of the original absorbance were built based on 7 wavelengths of 992, 904, 1096, 1032, 880, 824, 1048nm, and the ones of the second derivative absorbance based on 5 wavelengths of 784, 1056, 992, 808, 872nm. The best model of the second derivative absorbance spectrum had $R^2$=0.91, bias= -0.02bx, SEP=0.28bx for unknown samples.

• Journal of Biosystems Engineering
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• 제39권3호
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• pp.166-173
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• 2014

Purpose: In this study, we focused on the image processing method to determine the external quality of Fuji apples by identifying surface defects such as scabs and bruises. Method: A CCD camera was used to capture filter images with 24 different wavelengths ranging between 530 nm and 1050 nm. Image subtraction and division operations were performed to distinguish the defect area from the normal areas including calyx, stem, and glaring on the apple surface image. All threshold values of the image were examined to reveal the defect area of pretreated filter images. Results: The developed operation methods were [image (720 nm) - image (900 nm)]/image (700 nm) for bruise detection and [image (740 nm) - image (900 nm)]/image (590 nm) for scab detection, which revealed 81% and 90% recognition ratios, respectively. Conclusions: Our results showed several optimal wavelengths and image processing methods to detect Fuji apple surface defects such as bruises and scabs.

• 한국세라믹학회지
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• 제56권1호
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• pp.98-103
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• 2019

Optical filters to control light wavelength of displays or cameras are fabricated by multi-layer stacking process of low and high index thin films. The process of multi-layer stacking of thin films has received much attention as an optimal process for effective manufacturing in the optical filter industry. However, multi-layer processing has disadvantages of complicated thin film process, and difficulty of precise control of film morphology and material selection, all of which are critical for transmittance and coloring effect on filters. In this study, the composite $TiO_2$, which can be used to control of UV absorption, coated on nano hollow silica sol, was synthesized as a coating material for optical filters. Furthermore, systematic analysis of the process parameters during the chemical reaction, and of the structural properties of the coating solutions was performed using SEM, TEM, XRD and photo spectrometry. From the structural analysis, we found that the 85 nm nano hollow silica with 2.5 nm $TiO_2$ shell formation was successfully synthesized at proper pH control and titanium butoxide content. Photo luminescence characteristics, excited by UV irradiation, show that stable absorption of 350 nm-light, correlated with a 3.54 eV band gap, existed for the $TiO_2$ shell-nano hollow silica reacted with 8.8 mole titanium butoxide solution. Transmittance observed on substrate of the $TiO_2$ shell-nano hollow silica showed effective absorption of 200-300 nm UV light without deterioration of visible light transparency.