• 제목/요약/키워드: Optical glass

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CuCl 미립자 분산 붕괴산염계 비선형 광학유리에서 매질유리의 상분리와 CuCl 미립자의 석출 특성 (Phase Separation of Matrix Glasses and Precipitation Characteristics of CuCl Nanocrystals in CuCl Doped Borosilicate Glasses for Nonlinear Optical Application)

  • 윤영권;한원택
    • 한국세라믹학회지
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    • 제34권8호
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    • pp.886-896
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    • 1997
  • To investigate an effect of phase separation on precipitation characteristics of CuCl nanocrystals in CuCl doped nonlinear optical glasses, borosilicate glass systems with 9 different compositions with ~2wt% of CuCl were selected and CuCl doped glasses were prepared by melting and precipitation method. Microstructural properties of the CuCl doped glasses were analyzed by optical absorption spectroscopy, acid elution test, TEM, and EDXS. While phase separation did not occur in Glass A~D, interconnected and droplet microstructures due to phase separation were found in Glass E, F and Glass G~I, respectively. In the particular composition of the matrix glasses in this study, the precipitation of the CuCl particles was observed in the phase separable glasses, not in phase non-separable glasses. The CuCl particles were precipitated in both silica-rich phase region and boronrich phase region of the glass matrix. In the case of 7.7Na2O-36.6B2O3-52.7SiO2(mole%) glass, the larger CuCl particles than those in the silica-rich phase region were observed in the boron-rich phase region.

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Structural, Optical, and Chemical Properties of Cadmium Phosphate Glasses

  • Chung, Jae-Yeop;Kim, Jong-Hwan;Choi, Su-Yeon;Park, Hyun-Joon;Hwang, Moon-Kyung;Jeong, Yoon-Ki;Ryu, Bong-Ki
    • 한국세라믹학회지
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    • 제52권2호
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    • pp.128-132
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    • 2015
  • In this study, we prepared cadmium phosphate glasses with various compositions, given by $xCdO-(100-x)P_2O_5$ (x = 10-55 mol%), and analyzed their Fourier transform infrared spectra, dissolution rate, thermal expansion coefficient, glass transition temperature, glass softening temperature, and optical band gap. We found that the thermal expansion coefficient and dissolution rate increased while the glass transition temperature and glass softening temperature decreased with increasing CdO content. These results suggest that CdO acts as a network modifier in binary phosphate glass and weakens its structure.

Feasibility of BaO-ZnO-$B_2O_3$ based Glass as a Host to Employ Various Ceramic Fillers to be applied to Barrier Ribs in Plasma Display Panels

  • Kim, Sang-Gon;Shin, Hyun-Ho;Park, Jong-Sung;Hong, Kug-Sun;Kim, Hyung-Sun
    • Journal of Information Display
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    • 제5권3호
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    • pp.25-29
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    • 2004
  • Effects of additing various types of ceramic fillers to the BZB-based glass on the thermo-chemical stability, optical reflectance, and mechanical properties were investigated. The glass system demonstrated the feasibility to host various types of ceramic fillers to form micro-composites at the processing temperature suitable for PDP systems. The optical reflectance and mechanical strength of the filler-glass composites were improved as compared to the glass itself. These results demonstrate the feasibility of applying the Pb-free BZB-based glass system as a matrix for employing various types of crystalline ceramic fillers to be used as barrier rib materials in plasma display panels.

Nano-structuring of Transparent Materials by Femtosecond Laser Pulses

  • Sohn, Ik-Bu;Lee, Man-Seop;Chung, Jung-Yong;Cho, Sung-Hak
    • Journal of the Optical Society of Korea
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    • 제9권1호
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    • pp.1-5
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    • 2005
  • Using tightly focused femtosecond laser pulses, we produce an optical waveguide and optical devices in transparent materials. This technique has the potential to generate not only channel waveguides, but also three-dimensional optical devices. In this paper, an optical splitter and U-grooves, which are used for fiber alignment, are simultaneously fabricated in a fused silica glass using near-IR femtosecond laser pulses. The fiber aligned optical splitter has a low insertion loss, less than 4㏈, including an intrinsic splitting loss of 3㏈ and excess loss due to the passive alignment of a single-mode fiber. Finally, we demonstrate the utility of the femtosecond laser writing technique by fabricating gratings at the surface and inside the silica glass.

졸-겔법에 의한 CdS 분산$SiO_2$ Glass 박막의 비선형광학특성

  • 문종수;강종봉;김경문
    • 한국세라믹학회지
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    • 제33권12호
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    • pp.1353-1364
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    • 1996
  • Recently semiconductor doped glasses have attracted attention as nonlinear optical materials because of their large third order nonlinear optical properties. The transparent and homogeneous CdS-doped SiO2 glass thin films were obtained by the dip=coating process of the sol-gel method. Thin films were consisted of glasses containing CdS microcrystallites which were formed by dissolved Cd2+ and S2- ions in a SiO2 matrix solutions. A subsequent thermal treatment of this samples led the formation of colloidal agglomerates and finally of microcrystallites. The size of CdS microcrystallites was about 4 to 15 nm after thermal treatments at various heating conditions. From the optical absorption spectra of the CdS-doped SiO2 glass films it was found that the absorption edge was blue-shifted compared with that of the bulk CdS crystal(~2, 4 eV) and that the amount of energy shift was inversely proportional to the crystal size. And the band gap energy increased with the decrease in crystallite size indicating that the quantum size effects occured.

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Structural and Optical Characteristics of High Quality ZnO Thin Films Grown on Glass Substrates Using an Ultrathin Graphite Layer

  • Park, Suk In;Heo, Jaehyuk;Baek, Hyeonjun;Jo, Janghyun;Chung, Kunook;Yi, Gyu-Chul
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.302.1-302.1
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    • 2014
  • We report the growth of high quality zinc oxide (ZnO) thin films on amorphous glass substrates and their structural and optical characteristics. For the growth of ZnO films, mechanically exfoliated ultrathin graphite or graphene layers were used as an intermediate layer because ZnO does not have any heteroepitaxial relationship with the amorphous substrates, which significantly improved the crystallinity of the ZnO films. Structural and optical characteristics of the films were investigated using scanning and transmission electron microscopy, x-ray diffraction, and variable temperature photoluminescence spectroscopy. High crystallinity and excellent optical characteristics such as stimulated emission were exhibited from the high quality ZnO films grown on glass substrates.

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Ga$_2$O$_3$ 첨가에 따른 SiO$_2$-PbO-K$_2$O-Al$_2$O$_3$계 적외선 센서용 Glass fiber의 광학적 특성 (Optical properties of the glass fiber by adding Ga$_2$O$_3$ in the SiO$_2$-PbO-K$_2$O-Al$_2$O$_3$ system for Infrared sensor)

  • 윤상하;강월호
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1996년도 춘계학술대회 논문집
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    • pp.68-71
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    • 1996
  • In the study, the thermal and optical properties of SiO$_2$-PbO-K$_2$O-Al$_2$O$_3$ g1asses were investigated. According to Ga$_2$O$_3$ addictions, the properties of bulk glass, transition temperature and softening temperature were increased, whereas thermal expansion coefficient was decreased; In the optical properties, refractive index was increased, and IR cut-off wavelength was enlarged from 4.64$\mu\textrm{m}$ to 5.22$\mu\textrm{m}$. But, the optical loss of fiber was decreased.

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Numerical and Experimental Investigation of the Heating Process of Glass Thermal Slumping

  • Zhao, Dachun;Liu, Peng;He, Lingping;Chen, Bo
    • Journal of the Optical Society of Korea
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    • 제20권2호
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    • pp.314-320
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    • 2016
  • The glass thermal forming process provides a high volume, low cost approach to producing aspherical reflectors for x-ray optics. Thin glass sheets are shaped into mirror segments by replicating the mold shape at high temperature. Heating parameters in the glass thermal slumping process are crucial to improve surface quality of the formed glass. In this research, the heating process of a thermal slumping glass sheet on a concave parabolic mold was simulated with the finite-element method (FEM) to investigate the effects of heating rate and soaking temperature. Based on the optimized heating conditions, glass samples 0.5 mm thick were formed in a furnace with a steel concave parabolic mold. The figure errors of the formed glass were measured and discussed in detail. It was found that the formed glass was not fully slumped at the edges, and should be trimmed to achieve better surface deviation. The root-mean-square (RMS) deviation and peak-valley (PV) deviation between formed glass and mold along the axial direction were 2.3 μm and 4.7 μm respectively.

Study of thin film transition liquid crystal display (TFT-LCD) optical waste glass applied in early-high-strength controlled low strength materials

  • Wang, Her-Yung;Chen, Jyun-Sheng
    • Computers and Concrete
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    • 제5권5호
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    • pp.491-501
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    • 2008
  • The present study verifies compressive strength, ultrasonic pulse velocity, electrical resistance,permeable ratio, and shrinkage from waste glass controlled low strength materials (WGCLSM) and early-high-strength WGCSLM specimens, by replacing the sand with waste glass percentages of 0%, 10%,20%, and 30%. This study reveals that increasing amounts of waste LCD glass incorporated into concrete increases WGCLSM fluidity and reduces the setting time, resulting in good working properties. By increasing the glass to sand replacement ratio, the compressive strength decreases to achieve low-strength effects. Furthermore, the electrical resistance also rises as a result of increasing the glass to sand replacement ratio. Early-high-strength WGCSLM aged 28 days has twice the electrical resistance compared to general WGCSLM. Early-high-strength WGCSLM aged 7 days has a higher ultrasonic pulse velocity similar to WGCSLM aged 28 days. The variation of length with age of different compositions is all within the tolerance range of 0.025%. This study demonstrates that the proper composition ratio of waste LCD glass to sand in early-high-strength WGCSLM can be determined by using different amounts of glass-sand. A mechanism for LCD optical waste glass usage can be established to achieve industrial waste minimization, resource recycling, and economic security.

HR polishing에 의한 광경화성수지 성형용 글래스 몰드의 투과율 및 표면품위 향상 (Improvement of Transmittance and Surface Integrity of Glass Mold for light-hardening polymer Using MR Polishing)

  • 이정원;김동우;조명우
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2009년도 춘계학술대회 논문집
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    • pp.78-83
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    • 2009
  • In general, Light-hardening polymer was used UV nanoimprint technology. A light-hardening polymer was had the problem of poor hardness, durability. In order to overcome the problem of polymer, inter change optical glass. However glass is very manufacture and a lowering of standars transmittance. In order to glass recover was necessary polishing process. The process is magnetorheological fluids polishing. MR polishing has been developed as a new precision finishing technique to obtain a fine surface. Hence, Magnetorheological fluids has been used for micro polishing to get micro parts. This polishing process guarantees high polishing quality by controlling the fluid density electrically. The applied material in experiments is fused silica glass. Fused silica glass is widely used in the optical field because of high degree of purity. For MR polishing experiments, MR fluid was composed with DI-water, carbonyl iron and nano slurry ceria. The wheel speed and electric current were chosen as the variables for analyzing the characteristics of MR polishing process. Outstanding surface roughness of Ra=1.58nm was obtained on the fused silica glass specimen. And originally glass transmittance was recover on the fused silica glass.

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