• Title/Summary/Keyword: Optical concentration

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Optical Absorption and Fluorescence of NADH Encapsulated Sol-Gel Silicate Gels

  • Hong, Hye-Jeong;Jiin Jung;Jeong, Ae-Young;Kim, Dong-Pyo;Bae, Byeong-Soo
    • The Korean Journal of Ceramics
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    • v.6 no.4
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    • pp.359-363
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    • 2000
  • Reduced nicotinamide adenine dinucleotide (NADH) was encapsulated in transparent porous sol-gel silicate gels using by different organoalkoxysilane precursor. Characteristics optical absorption and fluorescence of NADH in the gels were examined with depending on NADH concentration and compared. Optical absorption in the aminopropyltrimethoxysilane (APTMS) gel is highest and remains constant during aging the gel. Thus, it is found that NADH in the APTMS gel is most stable and activated. On the other hand, methyltriethoxysilane (MTES) gel presents the lowest optical absorption diminishing with aging the gel. Measurable increase of fluorescence with raising the NADH concentration is observed except for the APTMS gel due to its solubility in the buffer during fluorescence measurement.

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Change of the Size-Resolved Aerosol Concentration Due to Relative Humidity (습도 변화에 따른 에어로졸의 농도 및 크기의 변화경향 파악)

  • Jung, Chang Hoon;Park, Jin Hee;Kim, Yong Pyo
    • Particle and aerosol research
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    • v.9 no.2
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    • pp.69-78
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    • 2013
  • In this study, the atmospheric aerosol concentration measured at different relative humidity levels was analyzed. Using an optical particle counter, PM10 and PM2.5 concentration as well as particle size distribution were measured and the relation between these size resolved data and relative humidity was studied. The results showed that mass concentration increases as relative humidity increases. The comparison between PM1, PM2.5 and PM10 showed that the fine particles grow more than coarse particles as relative humidity increases. The results also showed that PM10-2.5 and relative humidity do not show close correlation, which means that the mass increase of PM10 at high relative humidity is mainly due to the growth of PM2.5.

Remote Estimation Models for Deriving Chlorophyll-a Concentration using Optical Properties in Turbid Inland Waters : Application and Valuation (분광특성을 이용한 담수역 클로로필-a 원격 추정 모형의 적용과 평가)

  • Lee, Hyuk;Kang, Taegu;Nam, Gibeom;Ha, Rim;Cho, Kyunghwa
    • Journal of Korean Society on Water Environment
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    • v.31 no.3
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    • pp.272-285
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    • 2015
  • Accurate assessment of chlorophyll-a (Chl-a) concentrations in inland waters using remote sensing is challenging due to the optical complexity of case 2 waters. and the inherent optical properties (IOPs) of natural waters are the most significant factors affecting light propagation within water columns, and thus play indispensable roles on estimation of Chl-a concentrations. Despite its importance, no IOPs retrieval model was specifically developed for inland water bodies, although significant efforts were made on oceanic inversion models. So we have applied and validated a recently developed Red-NIR three-band model and an IOPs Inversion Model for estimating Chl-a concentration and deriving inland water IOPs in Lake Uiam. Three band and IOPs based Chl-a estimation model accuracy was assessed with samples collected in different seasons. The results indicate that this models can be used to accurately retrieve Chl-a concentration and absorption coefficients. For all datasets the determination coefficients of the 3-band models versus Chl-a concentration ranged 0.65 and 0.88 and IOPs based model versus Chl-a concentration varied from 0.73 to 0.83 respectively. and Comparison between 3-band and IOPs based models showed significant performance with decrease of root mean square error from 18% to 33.6%. The results of this study provides the potential of effective methods for remote monitoring and water quality management in turbid inland water bodies using hyper-spectral remote sensing.

Structural, Optical and Electrical Properties of ZnO Thin Films with Zn Concentration (Zn 농도변화에 따른 ZnO 박막의 구조, 광학 및 전기적 특성 연구)

  • 한호철;김익주;태원필;김진규;심문식;서수정;김용성
    • Journal of the Korean Ceramic Society
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    • v.40 no.11
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    • pp.1113-1119
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    • 2003
  • We used isopropanol which has low boiling point to prepare thin films at low temperature and changed mole concentration of zinc acetate from 0.3 to 1.3 mol/l. The structural, optical and electrical properties of ZnO thin films with Zn content were investigated. ZnO thin films highly oriented along the c-axis were obtained at Zn concentration of 0.7 mol/l. ZnO thin films with Zn concentration of 0.7 mol/l showed a homogeneous surface layer of nano structure. The transmittance of ZnO thin films by UV-vis. measurement was about 87% under the Zn concentration of 0.7 mol/l, but rapidly decreased over the 1.0 mol/l. The optical band gap energy was obtained from 3.07 to 3.22 eV which is very close to the band gap of bulk ZnO (3.2 eV). The electrical resistivity of ZnO thin films was about 150 $\Omega$-cm that shows little difference with Zn concentration. I-V curves of ZnO thin films exhibited typical ohmic contact properties.

Relationship of Optical Density and Wavelength on Light Source for Activated Sludge Concentration (활성슬러지 농도에 따른 광학밀도와 광원파장의 상관관계)

  • Kim, Do-Han;Lee, Chang-Han;Wang, Bo-Kwon;Suh, Jung-Ho;Song, Seung-Koo
    • KSBB Journal
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    • v.25 no.1
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    • pp.67-72
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    • 2010
  • In this study, we developed a comprehensive correlation for better prediction of the activated sludge concentration in the relationship between measurement of optical density by the Beer's law and sludge properties. Effects of activated sludge properties, which are sludge types and anaerobic storage time, show that absorbance deviation for sludge properties decreased on wavelength of light source near to 950 nm. We also developed a method to measure limitation with non-linear correlation on the measurement of high concentration by the Beer's law using a double layer probe cell and empirical equations.

Fabrication and Optical Characterization of Highly Dy3+-ion-incorporated Alumino-borosilicate Glasses for Magneto-optical Applications at 1550 nm (1550 nm 자기광학 응용을 위한 고농도 Dy3+ 이온이 함유된 알루미노보로실리케이트 유리의 제조 및 자기광학 특성 분석)

  • Kadathala Linganna;Yong-Tak Ryu;Young-Ouk Park;Bong-Ahn Yu;Bok Hyeon Kim
    • Korean Journal of Optics and Photonics
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    • v.35 no.3
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    • pp.115-120
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    • 2024
  • Magneto-optical (MO) materials have attracted much attention, since they can be utilized for various optical applications, such as magnetic field sensors, optical current sensors, optical isolators, and optical circulators. In this study, alumino-borosilicate (ABS) glasses with high concentrations of Dy3+ ions were fabricated by a conventional melt-quenching technique, and the dependence of their thermal, optical, and magneto-optical properties on Dy3+ ion concentration was investigated. The MO property of the glasses was investigated by measurement of Faraday rotation at 1550 nm. The Faraday rotation angle increased linearly with the increase of Dy3+ ion concentration in the glasses. A very high Verdet constant of -6.86 rad/(T·m) was obtained for glass with a Dy3+ ion concentration of 30 mol%. In addition, the ABS-Dy glasses showed good thermal stability of greater than 128 ℃ against crystallization, and high optical transmission of 70% in the visible to near-infrared windows of 480-720, 1390-1560, and 1800-2400 nm. Due to the high Verdet constant and good thermal stability, the ABS-Dy glasses in this study could be candidate optical materials for MO device applications at 1550 nm.

Comparison of the concentration characteristics and optical properties of aerosol chemical components in different regions (지역별 에어로졸 화학성분 농도 및 광학특성 비교)

  • So, Yun-Yeong;Song, Sang-Keun;Choi, Yu-Na
    • Journal of Environmental Science International
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    • v.28 no.1
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    • pp.107-123
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    • 2019
  • The aerosol chemical components in $PM_{2.5}$ in several regions (Seoul, Busan, Daejeon, and Jeju Island) were investigated with regard to their concentration characteristics and optical properties. The optical properties of the various aerosol components (e.g., water-soluble, insoluble, Black Carbon (BC), and sea-salt) were estimated using hourly and daily aerosol sampling data from the study area via a modeling approach. Overall, the water-soluble component was predominant over all other components in terms of concentration and impact on optical properties (except for the absorption coefficient of BC). The annual mean concentration and Aerosol Optical Ddepth (AOD) of the water-soluble component were highest in Seoul (at the Gwangjin site) ($26{\mu}g/m^3$ and 0.29 in 2013, respectively). Further, despite relatively moderate BC concentrations, the annual mean absorption coefficient of BC ($21.7Mm^{-1}$) was highest in Busan (at the Yeonsan site) in 2013, due to the strong light absorbing ability of BC. In addition, high AODs for the water-soluble component were observed most frequently in spring and/or winter at most of the study sites, while low values were noted in summer and/or early fall. The diurnal variation in the AOD of each component in Seoul (at the Gwangjin site) was slightly high in the morning and low in the afternoon during the study period; however, such distinctions were not apparent in Jeju Island (at the Aweol site), except for a slightly high AOD of the water-soluble component in the morning (08:00 LST). The monthly and diurnal differences in the AOD values for each component could be attributed to the differences in their mass concentrations and Relative Humidities (RH). In a sensitivity test, the AODs estimated under RH conditions of 80 and 90% were factors of 1.2 and 1.7 higher, respectively, than the values estimated using the observed RH.

Optical Resolution of DABS-Amino Acids with Mobile Chiral Chelate Addition (키랄킬레이트 이동상첨가법에 의한 답실아미노산의 광학이성질체 분리)

  • Lee, Seon Haeng;O, Dae Seop;Byeon, Seong Gu
    • Journal of the Korean Chemical Society
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    • v.34 no.4
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    • pp.345-351
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    • 1990
  • Optical isomers of DABS-amino acids have been separated in a reversed phae high performance liquid chromatography by adding Cu (Ⅱ)-L-Proline chelate to the mobile phase. The retention behaviors for the DABS-amino acids are discussed in terms of pH of the mobile phase and the concentrations of acetonitrile, Cu (Ⅱ) complex, and buffer. The selectivity of the optical isomers of DABS-amino acids increases with the pH of the mobile, and the concentration of the chelate, but decreases with concentration of the oganic modifier. The concentration of buffer does not affect the optical separation selectivity. A separation mechanism is illustrated by cis and trans formation based on the steric effect of the ligand exchange reaction between DABS-amino acids and the copper chelate.

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A Study on the Fracture Phenomena in Optical Disks Due to Increase of the Rotating Speed (회전속도 증가에 의한 광디스크의 파괴현상에 관한 연구)

  • 조은형;좌성훈;정진태
    • Journal of KSNVE
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    • v.11 no.3
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    • pp.437-442
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    • 2001
  • In this study, the fracture phenomena of optical disks are discussed by theoretical and experimental approaches and then some recommendations are presented to prevent the fracture. Linear equations of motion are discretized by using the Galerkin approximation. From the discretized equations, the dynamic responses are computed by the generalized- time integration method. As a fracture criterion for optical disks, the critical crack length is presented. From experimental methods, the fracture procedure is analyzed. The fracture occurs when disks have crack on the inner radius of the disks. Since the crack growth and the fracture result from the stress concentration on the tip of the crack, a measure should be taken to overcome the stress concentration. This problem can be resolved by the structural modification of a disk. This study proposes 3 types of improved optical disks.

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