• Title/Summary/Keyword: Optical and chemical properties

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A Study of Physical and Optical Properties of GaN grown using In-situ SiN Mask by MOCVD (In-situ SiN Mask를 이용하여 성장한 GaN 박막의 물성적, 광학적 특성 연구)

  • Kim, Deok-Kyu;Jeong, Jong-Yub;Park, Choon-Bae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07a
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    • pp.121-124
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    • 2004
  • We have grown GaN layers with in-situ SiN mask by metal organic chemical vapor deposition(MOCVD) and study the physical properties of the GaN layer. We have also investigate the effect of the SiN mask on its optical property. By inserting a SiN mask, (102) the full width at half maximum(FWHM) decreased from 480 arcsec to 409 arcsec. The PL intensity of GaN with SiN mask improved 2 times to that without SiN mask. We have thus shown that the SiN mask improved significantly the physical and optical properties of the GgN layer.

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Electrical and Optical Properties of Sb-doped SnO2 Films Prepared by Chemical Vapor Deposition (화학증착법에 의해 제조된 Sb-doped $SnO_2$ 박막의 전기적 및 광학적 특성)

  • 이수원;김광호
    • Journal of the Korean Ceramic Society
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    • v.29 no.4
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    • pp.319-327
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    • 1992
  • Sb-doped SnO2 films were formed on Corning glass 7059 substrate by chemical vapor deposition using simulataneous hydrolysis of SnCl4 and SbCl5. Fairly good transparent conducting film with a low resistivity of ~6$\times$10-4{{{{ OMEGA }}cm and high average optical transparency above ~85% in the range of visible light was obtained at the deposition condition of 50$0^{\circ}C$ and input-gas ratio, [Psbcl5/Psncl4] of 0.05. Film conductivity was improved without loosing optical transparency at light doping of Sb and found to be due to the increase of electron concentration. However, high doping of Sb into SnO2 film largely deteriorated conductivity, optical transparency and crystallinity of the film.

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Synthesis and Characterization of Nonlinear Optical Polymers Having Quinoline-based Chromophores

  • Kim, Min-Ho;Jin, Jung-Il;Lee, Chul-Joo;Kim, Nak-Joong;Park, Ki-Hong
    • Bulletin of the Korean Chemical Society
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    • v.23 no.7
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    • pp.964-970
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    • 2002
  • We synthesized three kinds of chromophores incorporating aromatic quinoline unit as a $\pi-conjugated$ bridge in order to prepare more thermally stable nonlinear optical (NLO) chromophores than general stilbene unit. The NLO poly(methylmethacrylate) copolymer, polyimides, and polyester were successfully synthesized by these corresponding quinoline-based monomers. Their physical and optical properties were investigated by thermogravimetry, gel permeation chromatography, ultraviolet-visible spectroscopy, second harmonic generation (SHG) and electro-optic (EO) measurement. All the polymers exhibited better thermal stability,however their NLO activity was a little lower than that of general stilbene-based NLO polymers. Among three kinds of polymers, the PMMA copolymer with quinoline chromophores had the largest SHG coefficient d33 value of 27 pm/V (at 1.064 $\mu\textrm{m})$ and EO coefficient r33 value of 6.8 pm/V (at 1.3 $\mu\textrm{m}$).

Change of Anti-reflective Optical Property by Nano-structural Control of Alumina Layer through Hydro-thermal Process (수열합성 공정을 통한 알루미나 코팅층의 나노구조 조절에 의한 반사방지 특성의 변화)

  • Lee, Yun-Yi;Son, Dae-Hee;Lee, Seung-Ho;Lee, Gun-Dae;Hong, Seong-Soo;Park, Seong-Soo
    • Applied Chemistry for Engineering
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    • v.21 no.5
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    • pp.564-569
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    • 2010
  • Highly anti-reflective optical property has been focussed in the field of thin film and display because of increasing demands to the high transparency and clearness of optical component. In this study, to obtain anti-reflective property, the formation of aluminium oxide with nanoscaled flowerlike frame structure was introduced as oxide material monolayer on the substrate by hydrothermal synthesis through sol-gel method. The properties of coating layer were measured by the means of UV-Vis spectroscopy, FT-IR spectroscopy, XRD, and FE-SEM. The morphology of coating layer in alumina-sol coated samples was controlled by hydrothermal temperature and time with aid of ultrasound. It was found that high transparency and anti-reflective optical properties were obtained the formation of flowerlike nanoframe structure.

A Study on the Optical Properties of Diamod-Like Carbon Film (Diamond-Like Carbon 박막의 광학적 특성에 관한 연구)

  • 권도현;박성계;남승의;김형준
    • Journal of the Korean Vacuum Society
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    • v.10 no.2
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    • pp.194-200
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    • 2001
  • In this study, the optical properties of diamond-like carbon(DLC) films, which was synthesized by 13.56 MHz rf plasma enhanced chemical vapor deposition system(PECVD), were investigated. We observed the variation of the transmittance and optical band gap with respect to deposition condition. The change of the transmittance and optical band gap of the DLC films were investigated as a function of RF power, working pressure, and additional gas. The optical band gap decreased with the increase of RF power and working pressure. We could verify the bond structures change of DLC films by observing the content of hydrogen using FT-IR spectroscopy. And the addition of hydrogen and nitrogen decreased the optical band gap by the breakage of C-H bond of DLC films during the deposition.

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Relationship of Optical Density and Wavelength on Light Source for Activated Sludge Concentration (활성슬러지 농도에 따른 광학밀도와 광원파장의 상관관계)

  • Kim, Do-Han;Lee, Chang-Han;Wang, Bo-Kwon;Suh, Jung-Ho;Song, Seung-Koo
    • KSBB Journal
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    • v.25 no.1
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    • pp.67-72
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    • 2010
  • In this study, we developed a comprehensive correlation for better prediction of the activated sludge concentration in the relationship between measurement of optical density by the Beer's law and sludge properties. Effects of activated sludge properties, which are sludge types and anaerobic storage time, show that absorbance deviation for sludge properties decreased on wavelength of light source near to 950 nm. We also developed a method to measure limitation with non-linear correlation on the measurement of high concentration by the Beer's law using a double layer probe cell and empirical equations.

Determination of the Optical Functions of Various Liquids by Rotating Compensator Multichannel Spectroscopic Ellipsometry

  • Bang, Kyung-Yoon;Lee, Seung-Hyun;Oh, Hye-Keun;An, Il-Sin;Lee, Hai-Won
    • Bulletin of the Korean Chemical Society
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    • v.26 no.6
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    • pp.947-951
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    • 2005
  • Rotating compensator multichannel spectroscopic ellipsometry has been employed to determine the optical functions of various liquids used in chemistry. We attempted three different measurement configurations: (1) air-liquid interface, (2) prism-liquid interface, and (3) liquid-sample interface. In prism-liquid interface, we found that the prism surface had roughness and it should be considered in analysis for accurate results. In liquidsample interface, we had much higher reflection, better sensitivity, and less limitation compared to the other two configurations when crystalline silicon was used as reference sample. We discuss the merit of each configuration and present the optical functions of various liquids. Also we demonstrate Bruggeman effective medium theory to determine the optical properties of mixed liquid.

The Effect of Hydrogen Peroxide Bleaching on the Properties of Hardwood Kraft Pulp Absorbed with Birchwood Xylan

  • Li, Lizi;Lee, Sang-Hoon;Lee, Hak-Lae
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2010.04a
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    • pp.195-206
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    • 2010
  • Xylan can be applied to improve the strength properties of paper; however the optical properties, such as brightness, are decreased significantly. To solve that problem, an applicable bleaching process is therefore desired. The aim of this research was to investigate the impact of hydrogen peroxide bleaching on hardwood kraft pulp pretreated with birchwood xylan by measuring optical properties (whiteness, brightness, opacity) as well as physical properties (tensile index, tearing index, bulk) of handsheets made from the bleached pulp. Hydrogen peroxide bleaching, as a kind of totally chlorine free (TCF) bleaching method, is quite important industrially for chemical pulp. In our work, the process variables of peroxide bleaching including bleaching temperature, time, initial pH and $MgSO_4$ dosage were studied. The results showed that both good mechanical properties and optical properties could be achieved when the operating parameters were controlled properly and therefore hydrogen peroxide bleaching was proved to be a suitable method for bleaching hardwood kraft pulp with adsorption of birchwood xylan.

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Electro-active Polymer and Dielectric Elastomer Technology for Haptic Interface, Muscular Enhancement, and Tunable Optical Components (전기가변 고분자 소재를 이용한 응용소자)

  • Yoon, J.W.;Park, S.K.;Mun, S.
    • Electronics and Telecommunications Trends
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    • v.34 no.4
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    • pp.108-116
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    • 2019
  • Electro-active polymers and dielectric elastomers have many intriguing properties that enable smart interfaces and electrically tunable optical systems, such as haptic feedback devices, artificial muscles, and expansion-tunable optical elements. These device classes are of great interest owing to their promising roles in next-generation technologies including virtual or augmented reality, human sensing and muscular enhancement, and artificial skins. In this report, we review basic principles, current state-of-the-art techniques, and future prospects of electro-active and dielectric elastomer technology. We describe chemical and physical properties of the most promising polymer substances, essential elementary architectures for artificial muscle-like functionalities, and their applications to haptic interfaces, muscular enhancement, and focus-tunable optical elements.

Electrical and Optical Properties of Sb-Doped SnO2 Transparent Conductive Films Fabricated by Using Electrospinning (전기방사법을 이용하여 제조된 Sb-Doped SnO2 투명전도막의 전기적 및 광학적 특성)

  • An, Ha-Rim;Koo, Bon-Ryul;Ahn, Hyo-Jin;Lee, Tae-Kum
    • Korean Journal of Materials Research
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    • v.25 no.4
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    • pp.177-182
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    • 2015
  • Sb-doped $SnO_2$(ATO) thin films were prepared using electrospinning. To investigate the optimum properties of the electrospun ATO thin films, the deposition numbers of the ATO nanofibers(NFs) were controlled to levels of 1, 2, 4, and 6. Together with the different levels of deposition number, the structural, chemical, morphological, electrical, and optical properties of the nanofibers were investigated. As the deposition number of the ATO NFs increased, the thickness of the ATO thin films increased and the film surfaces were gradually densified, which affected the electrical properties of the ATO thin films. 6 levels of the ATO thin film exhibited superior electrical properties due to the improved carrier concentration and Hall mobility resulting from the increased thickness and surface densification. Also, the thickness of the samples had an effect on the optical properties of the ATO thin films. The ATO thin films with 6 deposited levels displayed the lowest transmittance and highest haze. Therefore, the figure of merit(FOM) considering the electrical and optical properties showed the best value for ATO thin films with 4 deposited levels.