• Title/Summary/Keyword: Optical Gap Sensor

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Effect of Surfactants on ZnO Synthesis by Hydrothermal Method and Photocatalytic Properties (계면활성제 첨가에 의한 산화아연의 수열합성과 광촉매 특성)

  • Hyeon, Hye-Hyeon;Lee, Dong-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.1
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    • pp.50-57
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    • 2017
  • Zinc oxide is, one of metal oxide semiconductor, harmless to human and environment-friendly. It has excellent chemical and thermal stability properties. Wurtzite-zinc oxide is a large band gap energy of 3.37 eV and high exciton binding energy of 60 meV. It can be applied to various fields, such as solar cells, degradation of the dye waste, the gas sensor. The photocatalytic activity of zinc oxide is varied according to the particle shape and change of crystallinity. Therefore, It is very important to specify the additives and the experimental variables. In this study, the zinc oxide were synthesized by using a microwave assisted hydrothermal synthesis. The precursor was used as the zinc nitrate, the pH value was controlled as 11 by NaOH. Surfactants are the ethanolamine, cetyltrimethylammonium bromide, sodium dodecyl sulfate, sorbitan monooleate was added by changing the concentration. The composite particles had the shape of a star-like, curcular cone, seed shape, flake-sphere. Physical and chemical properties of the obtained zinc oxide was characterized using x-ray diffractometer, field emission scanning electron microscopy, thermogravimetric analysis and optical properties was characterized using UV-visible spectroscopy, photoluminescence and raman spectroscopy.

The Analysis of 2001 Land Use Distribution of Daejeon Metropolitan City based on KOMPSAT-1 EOC Imagery (KOMPSAT-1 EOC 자료를 활용한 2001년도 대전시 토지이용 현황의 공간적 분포 분석)

  • Kim, Youn-Soo;Jeon, Gap-Ho;Lee, Kwang-Jae
    • Journal of the Korean Association of Geographic Information Studies
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    • v.7 no.3
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    • pp.13-21
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    • 2004
  • The dissemination of commercial satellite images. which have the high spatial resolution such as aerial photos, are the active trend in remote sensing community because of the recent development in satellite and sensor technology. Such high resolution satellite images provide a unique tool for the monitoring of ongoing urban land use change. Especially KOMPSAT-1, which was launched at December 1999 and successfully operated up to now, provides repeatedly panchromatic images over Korean peninsula, which has the spatial resolution of 6.6m. Based upon this KOMPSAT-1 EOC image data we can try to analyze and assess the temporal urban land use change, which could not be done because lack of such data. The aim of this paper is to analyze and assess the spatial land use characteristics of Daejeon Metropolitan City based on KOMPSAT-1 EOC data. The land use map of year 2001 is generated through the modification of the year 2000 land use map, which is published by National Geographic Information Institute, using visual interpretation of KOMPSAT-1 EOC image which is acquired in year 2001. This study can be the start point of the time series analysis of the long term land use change monitoring mit KOMPSAT-1 EOC data.

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Photocurrent Study on the Splitting of the Valence Band and Growth of CuAlSe2 Single Crystal Thin Film by Hot Wall Epitaxy (Hot Wall Epitaxy(HWE)법에 의한 CuAlSe2 단결정 박막의 성장과 가전자대 갈라짐에 대한 광전류 연구)

  • Park, Chang-Sun;Hong, Kwang-Joon;Park, Jin-Sun;Lee, Bong-Ju;Jeong, Jun-Woo;Bang, Jin-Ju;Kim, Hyun
    • Journal of Sensor Science and Technology
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    • v.13 no.2
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    • pp.157-167
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    • 2004
  • A stoichiometric mixture of evaporating materials for $CuAlSe_{2}$ single crystal thin films was prepared from horizontal electric furnace. To obtain the single crystal thin films, $CuAlSe_{2}$ mixed crystal was deposited on thoroughly etched semi-insulating GaAs(100) substrate by the hot wall epitaxy (HWE) system. The source and substrate temperatures were $680^{\circ}C$ and $410^{\circ}C$, respectively. The crystalline structure of the single crystal thin films was investigated by the photoluminescence and double crystal X-ray diffraction (DCXD). The carrier density and mobility of $CuAlSe_{2}$ single crystal thin films measured with Hall effect by van der Pauw method are $9.24{\times}10^{16}cm^{-3}$ and $295cm^{2}/V{\codt}s$ at 293 K, respectively. The temperature dependence of the energy band gap of the $CuAlSe_{2}$ obtained from the absorption spectra was well described by the Varshni's relation, $E_{g}(T)$ = 2.8382 eV - ($8.68{\circ}10^{-4}$ eV/K)$T^{2}$/(T + 155 K). The crystal field and the spin-orbit splitting energies for the valence band of the $CuAlSe_{2}$ have been estimated to be 0.2026 eV and 0.2165 eV at 10 K, respectively, by means of the photocurrent spectra and the Hopfield quasicubic model. These results indicate that the splitting of the ${\Delta}so$ definitely exists in the ${\Gamma}_{5}$ states of the valence band of the $CuAlSe_{2}$. The three photocurrent peaks observed at 10 K are ascribed to the $A_{1-}$, $B_{1-}$, and $C_{1-}$ exciton peaks for n = 1.

Status and Prospect of Unmanned, Global Ocean Observations Network (글로벌 무인해양관측 네트워크 현황과 전망)

  • Nam, Sunghyun;Kim, Yun-Bae;Park, Jong Jin;Chang, Kyung-Il
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.19 no.3
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    • pp.202-214
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    • 2014
  • We introduce status and prospect of increasingly utilizing, unmanned, global ocean observing systems, and the global network to integrate, coordinate, and manage the systems. Platforms of the ocean observing system are diversified in order to resolve/monitor the variability occurring at multiple scales in both three-dimensional space and time. Here purpose, development history, and current status of the systems in two kinds - mobile (surface drifter, subsurface float, underwater glider) and fixed platforms (surface and subsurface moorings, bottom mounts), are examined and the increased future uses to produce synergies are envisioned. Simultaneous use of various mobile and fixed platforms is suggested to more effectively design the observing system, with an example of the NSF-funded OOI (Ocean Observations Initiative) program. Efforts are suggested 1) to fill the data gap existing in the deep sea and the Southern Ocean, and toward 2) new global network for oceanic boundary currents, 3) new technologies for existing and new sensors including biogeochemical, acoustic, and optical sensors, 3) data standardization, and 4) sensor calibration and data quality control.

Properties of Photoluminescence and Growth of CdIn2Te4 Single Crystal by Bridgeman method (Bridgeman법에 의한 CdIn2Te4 단결정 성장과 광발광 특성)

  • Moon, Jong-Dae
    • Journal of Sensor Science and Technology
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    • v.12 no.6
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    • pp.273-281
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    • 2003
  • A stoichiometric mixture for $CdIn_2Te_4$ single crystal was prepared from horizontal electric furnace. The $CdIn_2Te_4$ single crystal was grown in the three-stage vertical electric furnace by using Bridgeman method. The quality of the grown crystal has been investigated by the x-ray diffraction and the photoluminescence measurements. The (001) growth plane of oriented $CdIn_2Te_4$ single crystal was confirmed from back-reflection Laue patterns. The carrier density and mobility of $CdIn_2Te_4$ single crystal measured with Hall effect by van der Pauw method are $8.61{\times}10^{16}\;cm^{-3}$ and $242\;cm^2/V{\cdot}s$ at 293 K, respectively. The temperature dependence of the energy band gap of the $CdIn_2Te_4$ single crystal obtained from the absorption spectra was well described by the Varshni's relation, $E_g(T)=1.4750\;eV-(7.69{\times}10^{-3}\;eV)T^2/(T+2147)$. After the as-grown $CdIn_2Te_4$ single crystal was annealed in Cd-, In-, and Te-atmospheres, the origin of point defects of $CdIn_2Te_4$ single crystal has been investigated by the photoluminescence(PL) at 10 K. The native defects of $V_{Te}$, $Cd_{int}$, and $V_{Cd}$, $Te_{int}$ obtained by PL measurements were classified as a donors or acceptors type. And we concluded that the heat-treatment in the Cd-atmosphere converted $CdIn_2Te_4$ single crystal to an optical n-type. Also, we confirmed that In in $CdIn_2Te_4$ did not form the native defects because In in $CdIn_2Te_4$ single crystal existed in the form of stable bonds.