• Journal of the Korean Chemical Society
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• v.40 no.5
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• pp.357-364
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• 1996

Stereochemistries of acetoxy 1,3-oxathiolane 1 were determined by two methods. First, the structures of $\alpha$ isomer 7 and $\beta$ isomer 9 were confirmed by the difference of their conversion rates to dihydrooxathiin 2 under acid catalysis. When the acetoxy leaving group is located in trans relationship to sulfur, a isomer in which carboxanilide is less hindered sterically against the 1,3-oxathiolane ring is $\beta$ isomer 7, and the other isomer of which the reaction rate is slower than 7 is $\beta$ isomer 9. Second, in the deuterium reactions of diastereomeric sulfoxides, the isomers of which methine hydrogen is substituted to deuterium were cis isomers 15 and 17, and another isomers of which methyl hydrogen is substituted to deuterium were trans isomers 16 and 18. Substitution of either methine or methyl hydrogen to deuterium resulted from stereospecific ring opening followed by recyclization by [2,3] sigmatropic rearrangement.

• The korean journal of orthodontics
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• v.50 no.3
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• pp.206-215
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• 2020

Osteochondroma is a common benign tumor of bones, but it is rare in the mandibular condyle. With its outgrowth it manifests clinically as deviation of the mandible limitation of mouth opening, and facial asymmetry. After the tumor is diagnosed on the basis of clinical symptoms and radiographic examination including cone-beam computed tomography (CBCT) analysis, an appropriate surgery and treatment plan should be formulated. Herein, we present the case of a 44-year-old female patient who visited our dental hospital because her chin point had been deviating to the left side slowly but progressively over the last 3 years and she had difficulty masticating. Based on CBCT, she was diagnosed with skeletal Class III malocclusion accompanied by osteochondroma of the right mandibular condyle. Maxillary occlusal cant with the right side down was observed, but it was confirmed to be an extrusion of the molars associated with dental compensation. Therefore, after intrusion of the right molars with the use of temporary anchorage devices, sagittal split ramus osteotomy was used to remove the tumor and perform orthognathic surgery simultaneously. During 6 months after the surgery, continuous bone resorption and remodeling were observed in the condyle of the affected side, which led to a change in occlusion. During the postoperative orthodontic treatment, intrusive force and buccal torque were applied to the molars on the affected side, and a proper buccal overjet was created. After 18 months, CBCT revealed that the rate of bone absorption was continuously reduced, bone corticalization appeared, and good occlusion and a satisfying facial profile were achieved.

• Advances in pediatric surgery
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• v.16 no.2
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• pp.101-107
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• 2010

Herniorrhaphy of Indirect inguinal hernia (IIH) is one of the most frequently performed surgical procedures in children. The overall incidence of inguinal hernias in childhood ranges from 0.8 to 4.4 %. The incidence is up to 10 times higher in boys than girls, especially much higher in premature infants. IIHs in children are basically an arrest of embryologic development rather than an acquired weakness, which explains the increased incidence in premature infants. In normal development, the processus vaginalis closes, obliterating the peritoneal opening of the internal ring between 36th and 40th week of gestation. This process is often incomplete, leaving a small patent processus in many newborns. However, closure continues postnatally, and the rate of patency is inversely proportional to age of the child. The presence of a patent processus vaginalis is a necessary but not sufficient variable in developing a congenital IIH. In other words, all congenital IIHs are preceded by a patent processus vaginalis, but not all patent processus vaginalis go on to become IIHs. The overall incidence of IIH in population is approximately 1 to 2 % and the incidence of a processus vaginalis is approximately 12 to 14%, clinically appreciable IIH should develop in approximately 8 to 12 % of patients with a patent processus vaginalis. Although the classic open inguinal hernia repair remains the gold standard for most pediatric surgeons, laparoscopic repair is being performed in many centers. Like open technique, laparoscopic technique is fundamentally a high ligation of the indirect hernia sac with or without internal ring ligation. The advantages of laparoscopic approach include the ease of examining the contralateral internal ring, the avoidance of access damage to vas and vessels during mobilization of cord, decreased operative time, and an ability to identify unsuspected direct or femoral hernias. Almost all groin hernias in children are IIHs and occur as a result of incomplete closure of processus vaginalis. The treatment is repair by high ligation of hernia sac, which can be done by an open or laparoscopic technique. The contralateral side can be explored by laparoscopy or left alone, open exploration is no longer indicated due to potential risk of infertility.

• Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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• 2001.05a
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• pp.320-325
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• 2001

In this study, CT specimen were prepared from Pressure Vessel Steel which was used for pressure vessel plates for room and low temperature service. And we got the following characteristics from fatigue crack growth test carried out in the environment of room and low temperature at $25^{\circ}C$, -3$0^{\circ}C$, -6$0^{\circ}C$, -8$0^{\circ}C$, -10$0^{\circ}C$ and -12$0^{\circ}C$ and in the range of stress ratio of 0.05 and 0.3 by means of opening mode displacement. At the constant street ratio, the threshold stress intensity factor range ΔK$_{th}$ in the early stage of fatigue crack growth(Region I) and stress intensity factor range ΔK in the stable of fatigue crack growth(Region II) was increased in proportion to descend temperature. It assumed that the fatigue resistance characteristics and fracture strength at low temperature is considerable higher than that of room temperature in the early stage and stable of fatigue crack growth region. The straight line slope relation of logarithm do/dN -ΔK in RegionII, that is, the fatigue crack growth exponent m increased with descending temperature at the constant stress ratio. It was assumed that the fatigue crack growth rate do/dN is rapid in proportion to descending temperature in Region IIand the cryogenic-brittleness greatly affect a material with decreasing temperature.e.greatly affect a material with decreasing temperature.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.6
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• pp.764-772
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• 2016

This paper presents on the evaluation of numerical analysis model of a ball valve used for a gas pipeline. The ball valve has important role to control the gas flow of the pipeline as well as safety operation to prevent gas explosion at the emergency. For the validation of numerical simulation, the computational domains are introduced three different types: a hexahedron chamber connected to a pipeline outlet without considering the geometry of pressure tubes, a pipeline only considered the geometry of pressure tubes, and a pipeline connected both of the a hexahedron chamber and pressure tubes. The commercial code, SC/Tetra, is introduced to solve the three-dimensional steady-state Reynolds-averaged Navier-Stokes analysis in the present study. The valve flow coefficient and valve loss coefficient with respect to the valve opening rate of 30%, 50%, and 70% are compared with experimental results. Throughout the numerical analysis for the three analysis domains, pressure computed along the pipeline is affected by computational domains. It is noted pressure obtained by the computational model considering both of the a hexahedron chamber and pressure tubes has a relatively good agreement to the experimental data.

• KIEAE Journal
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• v.14 no.5
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• pp.117-121
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• 2014

Even though a study of airtightness performance of apartment and detached house have been done constantly, there are few of studies of multi-family housing which increasing every year. Therefore, this study analyzed airtightness performance of 20 households of one room in Daejeon to investigate airtightness performance standard. All experiments were performed under the same conditions except sealing windows to investigate airtightness performance without sealing windows (natural condition) and airtightness performance with sealing windows of studio apartment. As results, (1) average ACH50 without sealing windows was 19.2/h for pressurization, and 12.8/h for depressurization and (2) average ACH50 with sealing windows was 16.0/h for pressurization, and 10.7/h for depressurization and ACH50 in both condition, ACH50 under pressurization was about 50% higher than that under depressurization. Throughout this experiment, we can figure out that about 16% of air infiltration rate is occurred in windows, and the other 84% is occurred in rest of places such as Junction structure, socket and ventilating opening.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.29 no.4
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• pp.175-184
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• 2017

With the improvement of living standards, the ventilation for the mitigation of indoor or outdoor air-pollution problems has recently attracted a lot of attention. Consequently, the ventilation for the supply of outdoor fresh air into a room is treated as an important building-design factor. The ventilation is generally divided into the forced and natural types; here, the former can control the ventilation rate by using mechanical devices, but it has the disadvantages of the equipment costs, maintenance costs, and noise generation, while the latter is applied to most workshops due to the absence of noise and the low installation and maintenance costs. In this experimental study, the ventilation performance of a typical rotating-type natural ventilator, which is called a "wind turbine," was investigated with the outdoor-wind velocity and the indoor/outdoor-temperature difference. From the experiment results, it was confirmed that the temperature difference of $10^{\circ}C$ corresponds to the ventilation driving force with an outdoor-wind velocity of 1.0 m/s. Additionally, the intake-opening area of a building also exerts a great effect on the ventilation rates.

• Fire Science and Engineering
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• v.28 no.5
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• pp.23-29
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• 2014

The present study has been conducted to investigate the validity of the computational fire model and the results predicted by BRANZFIRE zone model and FDS field model are compared with a real scale fire test with spray fire in a multi-compartment. The liquid spray fires fueled with toluene and methanol are used as the fire source and the quantitative measurement of heat release rate is performed in an isolated ISO-9705 compartment with a standard door opening. The temperature field predicted by FDS model showed good agreement with the measurement in the fire room and the corridor, and BRANZFIRE model also gave acceptable result in spite of its simplicity and roughness. The mean temperature predicted by FDS model corresponds with measurement within maximum discrepancy range of 25% and the overall mean value of FDS model matched well with experimental data less than 10%. This study can contribute to establish the limitation and application scope of computational fire model and provide reference data for applying to reliable fire risk assessment.

• Clinics in Shoulder and Elbow
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• v.19 no.1
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• pp.33-38
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• 2016

Background: This study was conducted to evaluate the surgical outcomes of plate fixation using autologous iliac bone graft shaped in the form of a matchstick in clavicle nonunion resulting from prior surgical or non-surgical management. Methods: From May 2005 to February 2013, 17 patients underwent surgery for clavicle nonunion. The mean age at the time of surgery was 48.8 years. The iliac bone was harvested and shaped into slivers approximately 3 cm long, which resembled matchsticks. After opening of the medullary canal, the plate and screws were applied and cancellous bone was placed at the nonunion site. Matchstick bone grafts which were longitudinally placed and encircled on the nonunion site were tied with periosteum using 3-4 stitches. Union was determined via postoperative plane X-ray. Clinical status was evaluated using the visual analogue scale score for pain, and Constant and American Shoulder Elbow Surgeon score. Results: All patients had a stable radiological union at the follow-up. The mean duration from index operation to nonunion operation was 13.2 months (7-32 months). The mean follow-up period was 20.1 months (8-56 months), and the mean duration until union was 11.2 weeks (8-16 weeks). All clinical scores were improved at the final follow-up (p<0.001). The mean segmental defect was $3.3{\pm}2.6mm$ (1-18 mm); and the difference in clavicular length between operative and non-operative site was $5.9{\pm}6.9mm$. Conclusions: Matchstick shaped autologous iliac bone grafting technique in clavicle nonunion is acceptable with a high union rate.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.37 no.8
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• pp.812-818
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• 2009

A MOV(Main Oxidizer shutoff Valve) controls the flow rate of liquid oxygen into the rocket combustor by opening and shutting operations piloted by a pneumatic force. In order to improve the effective design for sealing parts of poppet and piston assemblies, the poppet assembly has been designed to be just contacted with the piston assembly. However, to avoid a gap at the poppet/piston contact surface and to evaluate the MOV operating performance, an analyze on the force balance during the closing motion have been performed. For the accuracy of the analysis, the friction forces and the hydraulic forces have been respectively obtained by experiments and CFD analysis. Through the analysis, some important design parameters such as the spring constant, poppet friction and orifice size in the force balance have been introduced and the required operation performance of the MOV has been proved feasible.