• Title/Summary/Keyword: Open complex

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Synthesis of Complex Compounds Ni(II)-Chlorophyll as Dye Sensitizer in Dye Sensitizer Solar Cell (DSSC)

  • Darmokoesoemo, Handoko;Fidyayanti, Arista Rahma;Setyawati, Harsasi;Kusuma, Heri Septya
    • Korean Chemical Engineering Research
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    • v.55 no.1
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    • pp.19-26
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    • 2017
  • Increasing global energy demand has resulted in an energy crisis. The dye sensitizer solar cell (DSSC) is an alternative source because of its ability to convert the sun's energy into electrical energy. Our aim was to determine the effect of synthesized Ni(II)-Chlorophyll for enhancing the efficiency of solar cells based DSSC. Complex compound Ni(II)-Chlorophyll was successfully synthesized as a dye sensitizer of $Ni(NO_3)_2.6H_2O$ and chlorophyll ligand with saponification method. Characterization results with spectrophotometer UV-Vis showed that the complex compounds of Ni(II)-Chlorophyll have a maximum wavelength of 295.00 nm, 451.00 and 665.00 nm. The bond between the ligand and metal appears in the vibration Ni-O at wave number $455.2cm^{-1}$. Complex compoun Ni(II)-Chlorophyll has a magnetic moment 7.10 Bohr Magneton (BM). The performance of complex compound Ni(II)-Chlorophyll as a dye sensitizer shows the value of short-circuit current (Jsc) at $3.00mA/cm^2$, open circuit voltage (Voc) at 0.15 V and the efficiency (${\eta}$) 0.20%.

A Simple Java Sequence Alignment Editing Tool for Resolving Complex Repeat Regions

  • Ham, Seong-Il;Lee, Kyung-Eun;Park, Hyun-Seok
    • Genomics & Informatics
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    • v.7 no.1
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    • pp.46-48
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    • 2009
  • Finishing is the most time-consuming step in sequencing, and many genome projects are left unfinished due to complex repeat regions. Here, we have developed BACContigEditor, a prototype shotgun sequence finishing tool. It is essentially an editor that visualizes assemblies of shotgun sequence fragment reads as gapped multiple alignments. The program offers some flexibility that is needed to rapidly resolve complex regions within a working session. The sole purpose of the release is to promote collaborative creation of extensible software for fragment assembly editors, foster collaborative development, and reduce barriers to initial tool development effort. We describe our software architecture and identify current challenges. The program is available under an Open Source license.

A Study on the Characteristics of the Super High-Rise Housing Complex in Hong Kong (홍콩 초고층 주거단지의 특징에 관한 연구)

  • Kim Sung-Hwa;Lee Jae-Hoon
    • Journal of the Korean housing association
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    • v.16 no.4
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    • pp.37-44
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    • 2005
  • The purpose of this study is to analyze the typological characteristics of super high-rise housings in Hong Kong. The results are as follows; 1) Most of the plan types of the residential building in Hong Kong are tower types and they show lots of curves on the external resident blocks so that each resident families can face maximum open air. 2) Each residential unit is arranged symmetrically and systematically around the central core. 3) The most of core types are central core types which are usually planned to place void light well to improve lighting and ventilation. 4) Rooms are arranged in line from entrance to kitchen, to living & dinning room, and finally bedroom and bathroom. Dinning area is arranged together with living area. 5) At least, more than two sides of the each unit were facing the open air; one side is for the view from a bedroom or a livingroom, the other side is for the ventilation of a kitchen or a bathroom.

A Proteomic Screen for Presynaptic Terminal N-type Calcium Channel (CaV2.2) Binding Partners

  • Khanna, Rajesh;Zougman, Alexandre;Stanley, Elise F.
    • BMB Reports
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    • v.40 no.3
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    • pp.302-314
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    • 2007
  • N type calcium channels (CaV2.2) play a key role in the gating of transmitter release at presynaptic nerve terminals. These channels are generally regarded as parts of a multimolecular complex that can modulate their open probability and ensure their location near the vesicle docking and fusion sites. However, the proteins that comprise this component remain poorly characterized. We have carried out the first open screen of presynaptic CaV2.2 complex members by an antibody-mediated capture of the channel from purified rat brain synaptosome lysate followed by mass spectroscopy. 589 unique peptides resulted in a high confidence match of 104 total proteins and 40 synaptosome proteome proteins. This screen identified several known CaV2.2 interacting proteins including syntaxin 1, VAMP, protein phosphatase 2A, $G_{o\alpha}$, G$\beta$ and spectrin and also a number of novel proteins, including clathrin, adaptin, dynamin, dynein, NSF and actin. The unexpected proteins were classified within a number of functional classes that include exocytosis, endocytosis, cytoplasmic matrix, modulators, chaperones, and cell-signaling molecules and this list was contrasted to previous reports that catalogue the synaptosome proteome. The failure to detect any postsynaptic density proteins suggests that the channel itself does not exhibit stable trans-synaptic attachments. Our results suggest that the channel is anchored to a cytoplasmic matrix related to the previously described particle web.

A Study on the Service Facilities Plan for APT Community Culture Activation (공동체 문화 활성화를 위한 APT단지 부대복리시설 계획에 관한 연구)

  • Lee, Gwang-Young;Cho, Jin-Man
    • Journal of the Korean housing association
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    • v.19 no.2
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    • pp.55-62
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    • 2008
  • This study is researched to provide design guidelines of service facilities and programs that apartment residents want along with the increased quality of life. This study is signifiant because it sought effective methods to activate the com-munity culture through service facilities in apartment complexes and the design standard and planning direction for residents. The study results are as follows. In the result of the correlations analysis and multiple regression analysis for the importancy of service facilities in apartment complexes, the following orders were considered as important factor; man-ager office, open space, resident community facility, elderly people meeting and activity facility, walking paths, resident athletic facility, a children's playground, library, and rest areas in the complex. and result of the correlations analysis and multiple regression analysis is the following: service facilities whole importance (y) = 1.413$+0.262^*{\times}1$ (manager office importance)$+0.271^*{\times}2$ (open space importance) $+0.185^*{\times}3$ (resident community facility importance) $+0.136{\times}4$ (elderly people meeting and activity facility importance)$+0.036^*{\times}5$ (walking paths importance) $+0.031^*{\times}6$ (resident athletic facility importance) + $(-0.042)^*{\times}7$ (a children's playground importance) + $(-0.045)^*{\times}8$ (library importance) + $(-0.0097)^*{\times}9$ (rest areas importance).

The prognostic implication of postoperative ECG changes in congenital heart surgery (술후 심전도 변화가 예후에 미치는 영향에 관한 고찰 -선천성 심질환을 중심으로-)

  • 정황규
    • Journal of Chest Surgery
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    • v.19 no.3
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    • pp.363-373
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    • 1986
  • Even though the pathogenesis is still controversial, electrocardiographic changes after congenital open heart surgery depend on various etiologic factors. Author reviewed 261 cases of congenital open heart surgery patient experienced in the Dept. of Thoracic & Cardiovascular Surgery, Pusan National University Hospital, since July, 1981 to Sept., 1985. The results were summarized as followed: 1. The age distribution was from 3 to 29 years old with mean age 10.8 years. And the most frequent congenital heart defect we had done operation was VSD. 2. Preoperatively, the most frequent ECG finding was abnormal QRS complex and postoperatively the most frequent ECG change was arrhythmia. 3. The most frequent arrhythmia before operation was intraventricular conduction disturbance. 4. Right ventriculotomy incision produced the more frequent abnormal ECG changes postoperatively than right atriotomy or pulmonary arteriotomy. 5. According to the operative technique, outflow patch graft of TOF repair produced the highest frequency of ECG changes after operation, and in comparing simple and patch closure of VSD, the latter was higher frequency of ECG changes, in valvotomy and infundibulectomy of PS, the latter was higher too. 6. The common symptom and signs in abnormally ECG changed patients after operation were palpitation, dyspnea, congestive heart failure and murmur in this order., 7. The longer the time of CPB, the more number of abnormally ECG changed patients had been developed after operation. 8. The most of postoperative ECG changed patients recovered spontaneously or with only medication and were clinically insignificant. And the rest other minor group recovered with temporary pacing. Eight cases out of 261 [3.1%], these with abnormal QRS complex and arrhythmia couldn`t recover in spite of every effort and eventually succumbed.

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Experimental and Computational Investigation of Wind Flow Field on a Span Roof Structure

  • K B Rajasekarababu;G Vinayagamurthy;Ajay Kumar T M;Selvirajan S
    • International Journal of High-Rise Buildings
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    • v.11 no.4
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    • pp.287-300
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    • 2022
  • Unconventional structures are getting more popular in recent days. Large-span roofs are used for many structures, such as airports, stadiums, and conventional halls. Identifying the pressure distribution and wind load acting on those structures is essential. This paper offers a collaborative study of computational fluid dynamics (CFD) simulations and wind tunnel tests for assessing wind pressure distribution for a building with a combined slender curved roof. The hybrid turbulence model, Improved Delayed Detached Eddy Simulation (IDDES), simulates the open terrain turbulent flow field. The wind-induced local pressure coefficients on complex roof structures and the turbulent flow field around the structure were thus calculated based upon open terrain wind flow simulated with the FLUENT software. Local pressure measurements were investigated in a boundary layer wind tunnel simultaneous to the simulation to determine the pressure coefficient distributions. The results predicted by CFD were found to be consistent with the wind tunnel test results. The comparative study validated that the recommended IDDES model and the vortex method associated with CFD simulation are suitable tools for structural engineers to evaluate wind effects on long-span complex roofs and plan irregular buildings during the design stage.

Analysis of Sediment Transport in the Gaeya Open Channel by Complex Wave Field (복합 파랑장에 따른 개야수로 퇴적물이동 분석)

  • Jang, Changhwan
    • Journal of Wetlands Research
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    • v.23 no.2
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    • pp.107-115
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    • 2021
  • In order to analyze wave propagation, tidal current, and sediment transport in the vicinity of the Gaeya open channel, it was classified into before(CASE1W) and after(CASE2W) installation of various artificial structures, and the calculation results for CASE1W and CASE2W were compared. For wave propagation, the results of incident and reflected waves were derived using the SWAN numerical model, and the tidal current velocity results were derived using the FLOW2DH numerical model for tidal current. The results of the SWAN numerical model and the FLOW2DH numerical model became the input conditions for the SEDTRAN numerical model that predicts sediment transport, and the maximum bed shear stress and suspended sediment concentration distribution near the Gaeya open channel were calculated through the SEDTRAN numerical model. As a result of the calculation of the SWAN numerical model, the wave height of CASE2W was increased by 40~50 % compared to CASE1W because the incident wave was diffracted and superimposed and the reflected wave was generated by about 7 km long northen jetty. As a result of the calculation of the FLOW2DH numerical model, According to the northen breakwater, the northen jetty and Geumrando, CASE2W was calculated 10~30 % faster than CASE1W in the tidal current of the Gaeya open channel. As a result of the calculation of the SEDTRAN numerical model, the section where the maximum bed shear stress is 1.0 N/m2 or more and the suspended concentration is 80mg/L or more was widely distributed in the Gaeya open channel from the marine environment by the complex wave field(incident wave, reflected wave and tidal wave) and the installation of various artificial structures. it is believed that a sedimentation phenomenon occurred in the Gaeya open channel.

Open BIM-based quantity take-off system for schematic estimation of building frame in early design stage

  • Choi, Jungsik;Kim, Hansaem;Kim, Inhan
    • Journal of Computational Design and Engineering
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    • v.2 no.1
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    • pp.16-25
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    • 2015
  • Since construction projects are large and complex, it is especially important to provide concurrent construction process to BIM models with construction automation. In particular, the schematic Quantity Take-Off (QTO) estimation on the BIM models is a strategy, which can be used to assist decision making in just minutes, because 70-80% of construction costs are determined by designers' decisions in the early design stage. This paper suggests a QTO process and a QTO prototype system within the building frame of Open BIM to improve the low reliability of estimation in the early design stage. The research consists of the following four steps: (1) analyzing Level of Detail (LOD) at the early design stage to apply to the QTO process and system, (2) BIM modeling for Open BIM based QTO, (3) checking the quality of the BIM model based on the checklist for applying to QTO and improving constructability, and (4) developing and verifying a QTO prototype system. The proposed QTO system is useful for improving the reliability of schematic estimation through decreasing risk factors and shortening time required.

Arthroscopic and open reduction for ankle fractures (족관절 골절에 대한 관절경적 정복술과 관혈적 정복술)

  • Kim, Dong-Heon;Chang, Byeong-Chun;Lee, Jae-Sung
    • Journal of Korean Foot and Ankle Society
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    • v.2 no.2
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    • pp.82-87
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    • 1998
  • The ankle is a complex structure supporting the entire musculoskeletal system during standing and walking. And so the goals of operative treatment for ankle fractures are to obtain an anatomical reduction that is maintained by stable fixation, resulting in a healed fracture and recovery of normal function. The 64 patients who had ankle fractures were treated by arthroscopic reduction(20 cases) and open reduction (43 cases) in Konkuk university hospital from February 1991 to October 1997 and the results were analyzed in clinical and radiological aspects. The following results were obtained. According to the criteria of Meyer, arthroscopic assisted reduction group had good or excellent results in 18 cases (90%) and open reduction group good or excellent in 35 cases (83%). The difference of the results was not significant statistically, but arthroscopic assisted reduction technique has several advantages over open technique; the best assessment of articular surface, lower wound problem, postoperatively faster rate of rehabilitation and minor discomfort.

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