• 해양환경안전학회지
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• 제2권1호
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• pp.67-75
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• 1996

An innovative batch electrolytic system consisted of electrolytic basin, which was equipped with DSA(Dimensionally Stable Anode) type insoluble electrode, Ti/IrO2 anode and H-C metal cathode, and flotation separator was developed for the efficient treatment of shipboard emulsified oily wastewater. The electorod cleance and current density of elecrolytic basin to ensure maximum treatment efficiency of oily wastewater was evaluated as 6 mm, 3 A/dm3, respectively. The electrolytic efficiency of oily wastewater was affected by the operationtemperature, and it means that the temperature controller to ensure the stabiity of the process is required. The conductivity in the electrolytic basin was increased with the percentage of sea water in the oily wastewater, and over 90% of treatment efficiency of oily wastewater could be obtained at 7% of sea water. The oil removal rate was increased according to the increase of the quantity of electricity, and the maximum value of electrilyic rate constant was 288 mgoil/A.min. The information obtained from this study might be used for development of an efficient continuous electrolytic system treating the emulsified oily wastewater.

• Journal of Advanced Marine Engineering and Technology
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• 제17권4호
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• pp.20-27
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• 1993

Emulsified oily wastewater is generally hard to treat in separating oil and water by conventional separators. In this paper the magnetohydrodynamic water treatment device was used to separate oil from emulsified oily wastewater which contained high conductivity. The emulsified oil removal rates and economic ranges of oil separation at various factors were investigated to confirm the influence of the magnetic field in MHD water treatment device according to the characteristics of emulsion brake. Experimental results proved that the oil removal rates were proportional to Lorentz force which depends on the intensity of magnetic field, conductivity and velocity of wastewater.

• 해양환경안전학회지
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• 제6권1호
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• pp.57-67
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• 2000

All crude oil carries a little of water, sand, and mineral sediment molecules tightly bounded with hydrocarbons. The result is the gradual precipitation of these heavier elements into thick, granular petroleum by products known as crude oil sludge. The oily sludges in ship tanks and in storage facilities have to be treated efficiently in order to keep the security and the capacity of storage facilities, to protect a serious environmental pollution, and to retrieve lost resource. The oily sludge treatment system should be designed to satisfy requirements mentioned in safe work condition. As a basic study, in this paper, an oily sludge treatment system by ultrasonic waves was proposed. Then, the features of ultrasonic energy and recovery of sludge with ultrasonic waves are investigated by experiments. As results, we found that ultrasonic waves are a new energy to flow oil sludge environment-friendly in safe work condition. In addition, it was shown that ultrasonic energy is more efficient than thermal energy in treating oil sludge, and that the volume of wastes for disposal is reduced remarkably.

• 한국염색가공학회지
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• 제11권6호
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• pp.24-35
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• 1999

This study was carried out to investigate the changes of surface characteristics of polyester fabrics on the deposition and the removal of oily soils from polyester fabrics in detergency, The relations between the removal of soil and the changes of surface properties of polyester fabrics treated with water- and oil-repellent agents were discussed before and after various wash cycles. Two kinds of fluoropolymers were selected as water-and oil-repellent finishing agents. The effects of water- and oil-repellent finishes were determined by the water repellency and oil repellency. The surface properties of untreated and treated polyester fabrics were evaluated with respect to contact angle and wicking time. The treatment of polyester fabrics with fluoropolymers improved efficiently water repellency, oil repellency, contact angle and wicking time. But those properties were greatly decreased after 3 times of wash cycles in detergency The deposition of oily soils on the untreated fabrics was drastically increased with increasing of wash cycles. The deposition and the removal of oily soils from fabrics treated with fluoropolymer having hydrophobic components were very low after various wash cycles. The deposition and the removal of oily soils on the fabrics treated with fluoropolymer having hydrophilic components were high comparatively after various wash cycles. Even though the surface properties of treated fabrics were greatly decreased with the increasing of wash cycles, the remains of oily soils on the fabrics were lower than those of untreated fabrics in various wash cycles. But the remains of soils were drastically increased after 10 times of wash cycles in any cases.

• Membrane and Water Treatment
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• 제9권4호
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• pp.285-292
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• 2018

In the following study, Artificial Neural Network (ANN) is used for prediction of permeate flux decline during oily wastewater treatment by hybrid powdered activated carbon-microfiltration (PAC-MF) process using mullite and mullite-alumina ceramic membranes. Permeate flux is predicted as a function of time and PAC concentration. To optimize the networks performance, different transfer functions and different initial weights and biases have been tested. Totally, more than 850,000 different networks are tested for both membranes. The results showed that 10:6 and 9:20 neural networks work best for mullite and mullite-alumina ceramic membranes in PAC-MF process, respectively. These networks provide low mean squared error and high linearity between target and predicted data (high $R^2$ value). Finally, the results present that ANN provide best results ($R^2$ value equal to 0.99999) for prediction of permeation flux decline during oily wastewater treatment in PAC-MF process by ceramic membranes.

• 상하수도학회지
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• 제32권6호
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• pp.479-485
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• 2018

Large amounts of oily wastewater discharged from various industrial operations (petroleum refining, machinery industries and chemical industries) cause serious pollution in the aquatic environment. Although dissolved air flotation (DAF) separating oil pollutants using microbubbles represents current practice, bubble size cannot be selectively controlled, and lots of power is required to generate microbubbles. Therefore, to investigate performance of the DAF process, this study examined the distribution of different sizes of microbubbles resulting from changes in physical shear force via modifying shapes of a slit-nozzle without an additional power supply. Three types of slit-nozzles (different angle, shape and length of the slit-nozzle) were used to analyze the distribution of bubble size. At a slit angle of $60^{\circ}$, shear force was 4.29 times higher than a conventional slit, and particle size distribution (PSD) in the range between 2 and $20{\mu}m$ more than doubled. Treatment efficiency of synthetic oily wastewater through the coagulation-DAF process achieved 90% removal of COD by injecting $FeCl_3$ and PACl of 250 mg/L and 100 mg/L, respectively, and the same performance resulted using $FeCl_3$ of 200 mg/L and PACl of 80 mg/L employing a slit-nozzle angle of $60^{\circ}$. This study shows that a coagulation-DAF process using a modified slit-nozzle can improve the pre-treatment of oily wastewater.

• 한국해양환경ㆍ에너지학회지
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• 제4권2호
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• pp.52-60
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• 2001

갈수록 강화되고 있는 해양오염 기준에 맞추어 유성 빌지 배출시 포함된 기름의 함유량을 제어하기 위한 방법 중의 하나로 중력 분리 방식의 유수분리기가 개발되어왔다. 중력분리 방식 중 분리판식 유수관리기는 고비중을 가진 다량의 농후유를 처리하는데 있어서 효과적이기 때문에, 현재 IMO 기준인 15ppm에 부합하는 필터여과방식의 보완장치로서 사용이 가능하다. 이 논고의 목적은 분리판의 배열에 따른 유수분리 효율에 대해 검토하는 것이다. 유량, 유입유분농도 그리고 분리판 사이의 간격 등을 포함한 여러 가지 운용상의 변수가 있는 유성혼합물에 대한 효율적인 처리를 알아보기 위해 실험적 연구를 수행하였다. 실험결과 얻은 결론에서 격리판 사이의 간격이 분리효율에 지대한 영향을 미치고 있음을 알 수 있었고, 가장 좋은 분리 효율은 분리판과 내통 사이 간격과의 비율(H/Ci)이 2일 때 유입유분농도가 낮고 유량이 작은 경우에 얻어졌다.

• 한국식품영양과학회지
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• 제28권5호
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• pp.1099-1106
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• 1999

Effects of dietary carotenoids were investigated on metabolism of the carotenoids, and body pigmen tation in oily bittering, Acheilognathus koreensis. Two weeks later after depletion,oily bitterings were fed the diets supplemented with either lutein, cynthiaxanthin and astaxathin for 4 weeks. Carotenoids distributed to and metabolized in integument were analyed. The carotenoid isolated from the integument of wild oily bittering, composed of 47.2% zeaxanthin, 11.4% lutein epoxide, 11.0% diatoxanthin, 9.7% lutein and 8.3% zeaxanthin epoxide. Meanwhile, two weeks later after depletion, the carotenoid composed of 29.9% crytoxanthin, 19.3% zeaxanthin, 13.2% lutein epoxide, 12.0% diatoxanthin and 8.8% zeaxanthin epoxide. These indicated that zeaxanthin, diatoxanthin, lutein epoxide and zeaxanthin epoxide were actively metabolized in oily bittering, compared to that of other fresh water fish. Total carotenoid content in the integument of wild oily bittering and oily bittering depleted for two weeks was found to be 1.72mg% and 2.08mg%, respectively. Two weeks later after treatment of experimental diet, total carotenoids content was increased to 2.23mg% in lutein, 2.36mg% in cynthiaxanthin and 2.49mg% in astaxanthin supplemented group, which were relatively higher than 2.10mg% in control group. Meanwhile, 4 weeks later, total ca rotenoids content was decreased to 1.76mg% in control, 1.95mg% in lutein, 1.74mg% in cynthiaxanthin and 1.72mg% in astaxanthin supplemented groups. These result indicate that dietary carotenoids were rapidly accumulated and then metabolized to certain metabolites shortly after feeding. Body pigmentation effects of the carotenoids due to accumulation of carotenoids in the integument of oily bittering was the most effectively shown in the astaxanthin supplemented group, followed by cynthiaxanthin and lutein supplemented groups. In the integument of oily bittering, dietary carotenoids were presumably biotrans formed via either oxidative or reductive pathways as presumed the variation of total carotenoid content and carotenoid composition in all experimental groups. The lutein was oxidized either to astaxanthin via doradexanthin and doradexanthin, or to zeaxanthin epoxide via zeaxanthin by oxidative pathway. Cynthiaxanthin was converted either to diatoxanthin and zeaxanthin by reductive pathway and then to zeaxanthin epoxide by oxidative pathway, or it was converted to astaxanthin via diatoxanthin, zeaxan thin and doradexanthin by oxidative pathway. Astaxanthin was converted to doradexanthin and zeaxanthin by reductive pathway and then to zeaxanthin epoxide by oxidative pathway. These results suggest that, oxidative pathway of carotenoids was major metabolic pathway along with reductive path way in fresh water fish.

• Korean Chemical Engineering Research
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• 제49권6호
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• pp.681-687
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• 2011

오일 생산 과정에서 발생하는 부산물인 생산수(produced water)는 오일폐수(oily wastewater)의 대부분을 차지하기 때문에 환경적인 측면이나 자원적인 관점에서 볼 때, 생산수에서 오일성분을 추출 및 제거하는 기술은 매우 중요하다. 생산수 처리기술은 크게 물리적 방법과 생물학적 방법 그리고 화학적 방법으로 나눌 수 있다. 본 논문에서는 생산수의 오일제거 기술의 분류, 장단점 분석과 함께 연도별, 국가별, 출원인별, 세부기술별로 기술동향 특허분석을 하였다.

• 멤브레인
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• 제12권4호
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• pp.216-225
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• 2002

원자력 분야를 포함하는 다양한 산업에서 발생하고 있는 오일 함유 폐액의 처리에 있어서 전기여과막 공정의 적용성을 평가할 목적으로 폴리프로필렌 정밀여과막을 사용한 모의 오일 에멀젼 폐액의 막 여과 실험을 수행하였다. 이때 투과 플럭스에 대한 전기장의 효과 및 투과 플럭스에 영향을 주는 주요 인자들로써 막간 차압, 교차흐름 유속 및 오일 에멀젼 농도의 영향을 고찰하였다. 전기장을 가해주는 전기정밀여과 공정은 기존의 전기장을 사용하지 않는 막 여과 공정에 비해서 막 오염 문제를 현저히 개선함으로써 투과 플럭스가 크게 향상되었으며 장기간의 조업시에도 상당한 투과 플럭스의 유지가 가능함을 보였다.