• Title/Summary/Keyword: Oil and Chemical Industry

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Controlled Hydrodynamic Cavitation-assisted Nanoreactor for Less Chemical-Higher Yield in Neutralization of Vegetable Oil Refining Process (Less Chemical-Higher Yield 탈산공정을 위한 수력 공동현상 유도 나노리엑터)

  • Kim, Ji-In
    • Food Science and Industry
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    • v.51 no.2
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    • pp.114-126
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    • 2018
  • The production of high quality oil to meet new standard needs a 'next generation' innovative oil refining tool in paradigm shift. 'Nanoneutralization' using controlled hydrodynamic cavitation-assisted Nanoreactor is successfully being introduced and commercialized into edible oil industry and it plays a key driver for sustainable development of food processing. This emerging technology using bubble dynamics as a consequence of Bernoulli's principle by hydrodynamic cavitation in Venturi-designed multi-flow through cell is radically changing the conventionally chemical-oriented neutralization. Nanoneutralization derived by the creation of nanometer-sized bubbles formed through scientifically structured geometric channels under high pressure has been proven to improve mass transfer and reaction rate so substantially reduce the chemicals required for refined vegetable oil and to increase oil yield while even improving oil quality. More researches on science behind this revolutionary technology will help usto better understand the principle and process hence makes its potential applications expandable in extraction, refining and modification of fats and oils processing.

Blending effect of pyrolyzed fuel oil and coal tar in pitch production for artificial graphite

  • Bai, Byong Chol;Kim, Jong Gu;Kim, Ji Hong;Lee, Chul Wee;Lee, Young-Seak;Im, Ji Sun
    • Carbon letters
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    • v.25
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    • pp.78-83
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    • 2018
  • Pyrolyzed fuel oil (PFO) and coal tar was blended in the feedstock to produce pitch via thermal reaction. The blended feedstock and produced pitch were characterized to investigate the effect of the blending ratio. In the feedstock analysis, coal tar exhibited a distinct distribution in its boiling point related to the number of aromatic rings and showed higher Conradson carbon residue and aromaticity values of 26.6% and 0.67%, respectively, compared with PFO. The pitch yield changed with the blending ratio, while the softening point of the produced pitch was determined by the PFO ratio in the blends. On the other hand, the carbon yield increased with increasing coal tar ratio in the blends. This phenomenon indicated that the formation of aliphatic bridges in PFO may occur during the thermal reaction, resulting in an increased softening point. In addition, it was confirmed that the molecular weight distribution of the produced pitch was associated with the predominant feedstock in the blend.

Effect of added mesophase pitch during the pitch synthesis reaction of PFO

  • Kim, Ji Hong;Kim, Jong Gu;Lee, Chul Wee;Lee, Ki Bong;Im, Ji Sun
    • Carbon letters
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    • v.23
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    • pp.48-54
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    • 2017
  • This research considers the effect of added mesophase pitch (MP) as an additive during the pitch synthesis reaction of pyrolyzed fuel oil (PFO). Two effects are generated by adding MP. One is an enhancement of thermal stability due to the high thermal property of the additive; the other is that the volatile compounds that were removed by vaporization of PFO during the thermal reaction can participate in the pitch synthesis reaction ($PFO{\rightarrow}pitch$) more efficiently. The effect differs according to the amount of the additive. When the amount of the additive is less than 7 wt%, the first effect is dominant, whereas the second effect is dominant when the additive amount exceeds 10 wt%.

CO2 Capture from the Petroleum Refining Industry (정유 산업에서의 온실가스 포집)

  • Hong, Yeon Ki
    • Journal of Institute of Convergence Technology
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    • v.11 no.1
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    • pp.13-18
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    • 2021
  • It is widely accepted that the prevention of global warming requires significant reductions in greenhouse gases, particularly CO2 emissions. Although fossil fuel-based power plants account for the majority of CO2 emissions, it is urgent to reduce CO2 emissions in industries that emit large amounts of CO2 such as steel, petrochemical, and oil refining. This paper examines the current status of CO2 emission in the domestic oil refining industry and CO2 emission sources in each unit process in the oil refining industry. Focusing on the previously developed CO2 capture process, cases and applicability of greenhouse gas reduction in FCC and hydrogen manufacturing processes, which are major processes constituting the oil refining industry, are reviewed.

Preparation of isotropic pitch precursor for pitch-based carbon fiber through the co-carbonization of ethylene bottom oil and polyvinyl chloride

  • Liu, Jinchang;Shimanoe, Hiroki;Nakabayashi, Koji;Miyawaki, Jin;Ko, Seunghyun;Jeon, Young-Pyo;Yoon, Seong-Ho
    • Journal of Industrial and Engineering Chemistry
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    • v.67
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    • pp.276-283
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    • 2018
  • For the first time, polyvinyl chloride (PVC) was used as an easily-handled chlorine source for preparation of isotropic pitch-based carbon fiber (IPCF) incorporating ethylene bottom oil (EO) as a raw material. Pitch precursors were prepared by the chlorination-dehydrochlorination triggered by chlorine radicals originated from PVC; aromatization and poly-condensation reactions occurred by polyene-type radicals from PVC. Radical production and co-carbonization were facilitated by pretreatments of EO through vacuum distillation, bromination, and additional heat treatment. Pitches were prepared by the co-carbonization of pretreated EO and EO containing 20 wt% PVC, and had higher yields and better spinnability than those by simple distillation.

High Value-added Technology of Oil Sand (오일샌드 고부가화기술 동향)

  • Park, Yong-Ki;Choi, Won Choon;Jeong, Soon Yong;Lee, Chul Wee
    • Korean Chemical Engineering Research
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    • v.45 no.2
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    • pp.109-116
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    • 2007
  • As conventional light oil resources deplete, it is becoming necessary to develop unconventional resources. To meet the demand for petrochemical industry, heavier sources such as heavy oil and bitumen are being utilized. Bitumens, a complex hydrocarbon made up of a long chain of molecules, are found in oil sand. It is estimated that 830 billion barrels of oil are located in the oil sand in Alberta, Canada. This paper will review briefly (1) the basic concept of oil sand, bitumen, and heavy oil, (2) methods how to extract oil from oil sand, (3) methods how to upgrade to synthetic crude oil, and (4) economic evaluation of technology.

Case Study on Integrated In-line Oil Monitoring Sensor for Machine Condition Monitoring of Steel Making Industry (통합형 인-라인 오일 모니터링 센서의 제철설비 현장 적용사례)

  • Kong, H.;Han, H.G.;Kwak, J.S.;Chang, W.S.;Im, G.G.
    • Tribology and Lubricants
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    • v.26 no.1
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    • pp.73-77
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    • 2010
  • One of the important trends for condition monitoring in the 21st century is the development of smart sensors that will permit the cost-effective continuous monitoring of key machine equipments. In this study, an integrated in-line oil monitoring sensor assigned for continuous in situ monitoring multiple parameters of oil performance is presented. The sensor estimates oil deterioration based on the information about chemical degradation, total contamination, water content of oil and oil temperature. The oil oxidation is estimated by "chromatic ratio", total contamination is measured by the changes in optical density of oil in three optical wave-bands ('Red', 'Green' and 'Blue') and water content is evaluated as relative saturation of oil by water. In order to evaluate the sensor's effectiveness, the sensor was applied to several used oil samples in steel making industry and the results were compared with those measured by standard test methods.

Physico-chemical characterization of individual particles emitted from the air pollution point sources (대기 점오염원에서 배출되는 개별입자상물질의 물리화학적 특성)

  • Park Jeong-Ho;Suh Jeong-Min
    • Journal of Environmental Science International
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    • v.14 no.8
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    • pp.761-770
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    • 2005
  • Scanning electron microscopy / energy dispersive X-ray analyzer(SEM/EDX) has played an important role for evaluation the source of atmospheric particle because it is a powerful tool for characterizing individual particles. The SEM/EDX system provides various physical parameters like optical diameter, as well as chemical information for a particle-by-particle basis. The purpose of the study was to classify individual particle emitted from the point sources based on clustering analysis and physico-chemical analysis by SEM/EDX. The total of 490 individual particle were analyzed at 8 point sources including coal-fired power plant, incinerator, H-C oil boiler, and metal manufacturing industry. The main components were Si and AI in the coal-fired power plant, Cl and Na in the domestic waste Incinerator, S in the H-C oil boiler and S and Fe in the metal manufactory industry, respectively.