• 대한토목학회논문집
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• 제30권6D호
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• pp.569-575
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• 2010

재차인원의 파악은 HOV 차로 및 HOT 차로 정책의 효과 분석뿐만 아니라, 램프미터링, 공공주차장 운영 등 다양한 부분에 대한 핵심적 입력변수이다. 재차인원에 대한 조사 방법과 TCS (Toll Collection System) 자료를 이용한 O/D 구축방법은 개별적으로 기존 연구에서 많이 수행되어 왔지만, TCS 자료를 이용한 재차인원별 O/D 구축에 대한 연구는 전무한 실정이다. 본 연구는 재차인원 정보가 추가된 TCS 자료를 조사하여 수단별 O/D를 산출하는 과정을 자료조사부터 구축과정에 대한 제반 방법론으로 제시하였다. 특정 영업소(서울 영업소) 진출 방향에 대하여 특정일에 오전 첨두, 오후 비첨두, 오후 첨두, 심야 각 2시간씩 승용차, 버스, 트럭으로 구분된 차량에 대하여 재차인원 조사(노측 조사)를 실시한 후 톨부스, 차종, 도착시간을 기준으로 매칭과정을 거쳐 해당 날짜의 TCS 자료에 재차인원 정보를 추가하여 재차인원별 O/D를 구축하였다. 한 예로써 구축 결과 오전 첨두시 서울로 향하는 나홀로 차량이 약 60%에 이르는 것으로 나타났다. 이러한 방법론은 TCS 자료를 이용한 특정 O/D 구축 방법론과 연계할 경우, 전국 센트로이드간 재차인원별 O/D 산출도 가능할 것으로 판단되며 재차인원 정보를 요구하는 교통정책의 수립에 활용되어 질 수 있을 것으로 판단된다.

• 한국항만학회지
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• 제14권2호
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• pp.175-185
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• 2000

Today freeway is experiencing a severe congestion with incoming or outgoing traffic through freeway ramps during the peak periods. Thus, the purpose of this study is to identify the traffic characteristics, analyze the relationships between the traffic characteristics and finally construct the delay predictive models on the rap junctions of freeway with 70mph speed limit. From the traffic analyses, and model construction and verification for delay prediction on the ramp junctions of freeway, the following results were obtained : ⅰ) Traffic flow showed a big difference depending on the time periods. Especially, more traffic flows were concentrated on the freeway junctions in the morning peak period. ⅱ) The occupancy also showed a big difference depending on the time periods, and the downstream occupancy(Od) was especially shown to have a higher explanatory power for the delay predictive model construction on the ramp junctions of freeway. ⅲ) The delay-occupancy curve showed a remarkable shift based on the occupancies observed : O$\_$d/〈9% and O$\_$d/$\geq$9%. Especially, volume and occupancy were shown to be highly explanatory for delay prediction on the ramp junctions of freeway under O$\_$d/$\geq$9%, but lowly for delay prediction on the ramp junctions of freeway under O$\_$d/〈9%. Rather, the driver characteristics or transportation conditions around the freeway were thought to be a little higher explanatory for the delay prediction under O$\_$d/〈9%. ⅳ) Integrated delay predictive models showed a higher explanatory power in the morning peak period, but a lower explanatory power in the non-peak periods.

• Bulletin of the Korean Chemical Society
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• 제33권12호
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• pp.4059-4062
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• 2012

The effect of a conductive agent on the structural and electrochemical properties of $Li_4Ti_5O_{12}$(LTO) spinel was investigated through neutron diffraction during Li intercalation and electrochemical measurements. The charging process of LTO is known as transformation of the white $(Li_3)_{8a}[LiTi_5]_{16d}O_{12}$ into a dark-colored $(Li_{3-X})_{8a}[Li_{X+Y}]_{16c}[LiTi_5]_{16d}O_{12}$ by incorporating the inserted Li into octahedral 16c sites, and the Li in tetrahedral 8a sites shifted to 16c sites. The occupancy of the tetrahedral 8a site varied with the existence of carbon in the electrode. Without carbon, the lattice parameter and cell volume of LTO decreased more notably than in the carbon-containing LTO electrode during Li insertion process. These phenomena might be attributed that the Li occupancy of the tetrahedral 8a of the LTO electrode without carbon was less than that of the carbon-containing LTO electrode.

• 대한토목학회논문집
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• 제32권6D호
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• pp.557-563
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• 2012

본 연구에서는 광역경제권, 특히 대구광역권 내의 산업공간구조를 분석하기 위하여 국가교통DB센터에서 제공하는 화물O/D 자료를 이용하는 방법을 제시하고자 한다. 이를 위해 화물점유율(FOR), 화물의존도(FDR), 규모를 반영한 Scale parameter의 세 가지 지표를 이용하여 대구광역권의 공간구조 분석을 실시하였다. 그 결과, 화물의 이동패턴을 고려한 각 지표들로부터 지역간 산업구조 특성 및 산업공간구조를 알아보는 데 유의미한 결과가 도출되었다. 특히, 대구시의 경우 경산시, 구미시의 화물점유율(FOR)과 화물의존도(FDR) 비율이 매우 높은 지역 연관성을 가지는 것으로 나타났고 규모를 반영한 SP지표 결과에 따르면 대구시의 주요산업은 화학 및 금속공업이 주를 이루는 것으로 나타났다.

• 한국항만학회지
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• 제14권4호
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• pp.419-427
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• 2000

Today travel demand continues to increase with spread of economic zones. Also, urban freeway plays an important role in intra-zone transportations as a major corridor in a big city. However, most of urban freeways experience a severe congestion with the excess of inflowing or outflowing traffic through freeway ramps. The purpose of this study is to identify the traffic characteristics, analyze the relationships between the traffic characteristics and finally construct the speed predictive models on the ramp junctions of urban freeway under the intelligent transportation system(ITS) settings. From the analyses of traffic characteristics following results were obtained: ⅰ) 24 hours average traffic characteristics flow, occupancy, speed under the ITS settings showed about 40%, 38%, 8.8% increase each on urban freeway junctions period when compared with that under the non-ITS settings each other. Free flow speed and traffic flow on the mainline sections of urban freeway under the ITS settings also showed about 20% and 17% increase when compared with that under the non-ITS, respectively. ⅱ) The upstream when compared speed( $S_{u}$)and downstream occupancy( $O_{d}$) were especially shown to have higher explanatory powers on the stable flow ramp junctions, but the upstream speed( $S_{u}$) and downstream flow( $V_{d}$) were especially shown on the unstable flow ramp junctions of urban freeway under the ITS settings.ngs.ngs.

• 국제학술발표논문집
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• The 4th International Conference on Construction Engineering and Project Management Organized by the University of New South Wales
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• pp.636-646
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• 2011

Post-occupancy evaluation (POE) techniques have been developed to provide a means for evaluating occupant responses to changes in an environment and linking this response to physical measures of that environment. POE has been used to systematically evaluate the performance of buildings after they have been built and occupied for some time. This paper present findings on factors (social and physical), which influences housing residential satisfaction of a sample of occupants in four different government Housing Subsidy locations in the Gauteng Province of South Africa. Descriptive statistics were carried out on the data obtained through the use of occupant survey. Findings emanating from the survey revealed that the respondents were satisfied with their overall housing situation, but had complaints about certain aspects of the housing unit. However, the respondents felt that most of their housing needs were not being met. Also, a comparison is also made of the perceived factors of dissatisfaction amongst the housing subsidy occupants. It is recommended that a wider systematic coverage of the subject through investigation and diagnostic POE and occupants need assessment should be carried in housing subsidy schemes in South Africa.

• Bulletin of the Korean Chemical Society
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• 제10권6호
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• pp.504-509
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• 1989

The effect of oxygen-deficiency on the charge distributions and orbital energies for small copper oxide clusters representing the superconducting materials $YBa_2Cu_3O_x (6{\leq}x{\leq}7)$ were investigated by the extended Huckel molecular orbital (EHMO) method with the tight-binding model. Our calculations show +3 oxidation state of Cu(1) in the $CuO_3$ chain and +2 or +1 of Cu(2) in the $CuO_2$ layers for $YBa_2Cu_3O_7$ with the nominal charge of $Cu_3$ = +7 (or +5), while for $YBa_2Cu_3O_6$ +1 oxidation state of Cu(1) and +3 (or +2) of Cu(2) in the $CuO_2$ layers with the nominal charge of $Cu_3$ = +7 (or +5). For $Cu_3O_{12}$ cluster representing $YBa_2Cu_3O_7$ with the nominal charge of $Cu_3$ = +7 the Cu(2) $d_{{x^2}-{y^2}}$ orbitals in the $CuO_2$ layers is a typical Jahn-Teller $d^9$ system with the partial hole and the Cu(1) $d_{{_z2}-{_y2}}$ orbital in the $CuO_3$ chain contains hole occupancy. For $Cu_3O_{10}$ cluster representing $YBa_2Cu_3O_6$ with the nominal charge of Cu = +5 the orbital character of the highest partially occupied MO (HPOMO) and the lowest completely unoccupied MO (LCUMO) of $Cu_3O_{12}$ representing $YBa_2Cu_3O_7$ with the nominal charge of $Cu_3$ = +7 is reversed, and the character of Cu(1) $d{{x^2}-{y^2}}$ orbital of LCUMO of the $Cu_3O_{12} $cluster is vanished. It is suggested that the local crystal field environment of Cu(1) by the oxygens in the Cu(1) chain may play a vital role in conductivity and superconductivity, either alone or through cooperative electronic coupling with the Cu(2) layers in $YBa_2Cu_3O_7.$.

• Bulletin of the Korean Chemical Society
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• 제19권11호
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• pp.1222-1227
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• 1998

The crystal structure of a benzene sorption complex of fully dehydrated Cd2+-exchanged zeolite X, Cd46Si100Al92O384·43C6H6 (a=24.880(6) Å), has been determined by single-crystal X-ray diffraction techniques in the cubic space group Fd3 at 21 ℃. The crystal was prepared by ion exchange in a flowing stream of 0.05 M aqueous Cd(NO3)2 for 3 d, followed by dehydration at 400 ℃ and 2 x 10-6 Torr for 2 d, followed by exposure to about 92 Torr of benzene vapor at 22 ℃. The structure was determined in this atmosphere and refined to the final error indices R1=0.054 and Rw=0.066 with 561 reflections for which I > 3σ(I). In this structure, Cd2+ ions are found at four crystallographic sites: eleven Cd2+ ions are at site 1, at the centers of the double six-oxygen rings; six Cd2+ ions lie at site I', in the sodalite cavity opposite to the double six-oxygen rings; and the remaining 29 Cd2+ ions are found at two nonequivalent threefold axes of unit cell, sites Ⅱ' (in the sodalite cavity ) and site Ⅱ (in the supercage) with occupancies of 2 and 27 ions, respectively. Each of these Cd2+ ions coordinates to three framework oxylkens, either at 2.173(13) or 2.224(10) Å, respectively, and extends 0.37 Å into the sodalite unit or 0.60 Å into the supercage from the plane of the three oxygens to which it is bound. The benzene molecules are found at two distinct sites within the supercages. Twenty-seven benzenes lie on threefold axes in the large cavities where they interact facially with the latter 27 site-Ⅱ Cd2+ ions (Cd2+-benzene center=2.72 Å; occupancy=27 molecules/32 sites). The remaining sixteen benzene molecules are found in 12ring planes; occupancy=16 molecules/16 sites. Each hydrogen of these sixteen benzenes is ca. 2.8/3.0 Å from three 12-ring oxygens where each is stabilized by multiple weak electrostatic and van der Waals interactions with framework oxygens.

• 대한화학회지
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• 제61권1호
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• pp.7-11
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• 2017

The extended $H{\ddot{u}}ckel$ method is employed to analyze the interaction of carbon monoxide with the TiC(001) surfaces, both perfect and containing carbon vacancies. CO exhibits a similar ${\sigma}$-donation interaction for both $Ti_{25}C_{25}$ and $Ti_{25}C_{23}$ clusters, as deduced from the fact that the populations of the CO $5{\sigma}$ orbital are identical upon adsorption, but it bonds more strongly with the $Ti_{25}C_{23}$ than with the $Ti_{25}C_{25}$ because the metal d electron density in $Ti_{25}C_{23}$ provides ${\pi}$ back-bonding interactions with CO that are absent in $Ti_{25}C_{25}$. This work suggests that a difference in reactivity toward CO of stoichiometric TiC and TiC with carbon defects is connected with the occupancy of $2{\pi}^*$ orbitals that leads to a significant weakening of the C-O bond.

• 한국자기학회지
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• 제18권2호
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• pp.67-70
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• 2008

$Tb_2Bi_1Ga_xFe_{5-x}O_{12}$(x=0, 1)의 조성을 가지는 분말 시료를 sol-gel 법과 진공봉합 열처리를 이용하여 합성하였다. x선 회절기, $M\ddot{o}ssbauer$ 분광기를 이용하여 시료의 결정구조 및 Ga 이온의 점유도에 관하여 연구하였다. XRD측정결과 $Tb_2Bi_1Ga_xFe_{5-x}O_{12}$ (x=0, 1)의 결정구조는 Ia3d의 공간그룹을 갖는 cubic 구조이며, $Tb_2Bi_1Fe_5O_{12}$와 $Tb_2Bi_1Ga_1Fe_4O_{12}$의 격자상수 $a_0$는 각각 $12.497\AA$, $12.465\AA$으로 분석되었다. Rietveld 분석법을 이용하여 각 이온들이 점유하는 각각의 부격자 위치를 연구하였다. $Tb_2Bi_1Ga_1Fe_4O_{12}$ 시료의 분석결과, Tb, Bi 이온은 24c 자리에, Fe 이온은 24d, 16a 자리를 점유하였으며, 비자성 이온인 Ga 이온은 모두 16a 자리를 점유하는 것으로 분석되었다. $Tb_2Bi_1Ga_xFe_{5-x}O_{12}$(x=0, 1)의 미시적인 자기구조를 분석하기 위해 시료들의 $M\ddot{o}ssbauer$스펙트럼을 측정하였다. 상온에서의 $M\ddot{o}ssbauer$스펙트럼 측정결과 철 이온들의 흡수 면적비는 $Tb_2Bi_1Fe_5O_{12}$의 경우 24d와 16a자리에서 각각 60.8%, 39.2%로, $Tb_2Bi_1Ga_1Fe_4O_{12}$의 경우 24d와 16a자리에서 각각 74.7%, 25.3%로 분석되었다. 철 이온들의 흡수 면적비 분석을 통해 비자성이온인 Ga은 모두 16a 자리를 점유하는 것을 알 수 있었다.