• Journal of Soil and Groundwater Environment
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• v.27 no.4
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• pp.49-62
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• 2022

The magnesium and iron-based layered double hydroxide (Mg-Fe LDH) was synthesized by the co-precipitation process and the bead type LDH (BLDH, 5~6 mm in diameter) was manufactured by using the Mg-Fe LDH and the starch as a binder. To evaluate the feasibility of the BLDH as the As stabilizer in the soil, various experiments were performed and the As stabilization efficiency of the BLDH was compared to that of powdered type LDH (PLDH, <149 ㎛ in diameter). For the As sorption batch experiment, the As sorption efficiency of both of the PLDH and the BLDH showed higher than 99%. For the stabilization experiment with soil, the As extraction reducing efficiency of the PLDH was higher than 87%, and for the BLDH, it was higher than 80%, suggesting that the BLDH has similar the feasibility of As stabilization for the contaminated soil, compared to the PLDH. From the continuous column experiments, when more than 7% BLDH was added into the soil, the As stabilization efficiency of the column maintained at over 91% for 7 pore volume flushing (simulating about 21 months of rainfall) and slowly decreased down to 64% after that time (to 36 months) under the non-equilibrium conditions. Results suggested that more than 7% of BLDH added in As-contaminated soil could be enough to stabilize As in soil for a long time. The main As fixation mechanisms on the LDH were also identified through the X-ray fluorescence (XRF), the X-ray diffraction (XRD), and the Fourier transform infrared (FT-IR) analyses. Results showed that the LDH has enough of an external surface adsorption capacity and an anion exchange capability at the interlayer spaces. Results of SEM/EDS and BET analyses also supported that the Mg-Fe LDH used in this study has sufficient porous structures and outer surfaces to fix the As. The reduction of carbonate (CO₃^2-) and sulfate (SO₄^2-) anions in the LDH after the reaction between As and the LDH was observed through the FT-IR, the XRF, and the XRD analyses, suggesting that the exchange of some of these anions with the arsenate (H₂AsO₄^- or HAsO₄^2-) occurs at the LDH interlayers during the stabilization process in soil.

• Korean Journal of Ecology and Environment
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• v.55 no.4
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• pp.376-389
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• 2022

Despite the consumption of disinfectants have been increased by COVID-19 pandemic, the fate of the chemicals in aquatic food webs are still unclear. In order to understand the trophic transfer of the chemicals, the concentration of disinfectants including six benzalkonium chloride (BACs) and five didecyldimethylammonium chlorides(DDACs) were measured at the Geum (2020), Han (2021), and Yeongsan River (2021), before and after rainfall. The highest concentration of ∑BACs (mainly C12 and C14) and ∑DDACs (mainly C10 and C14) were observed in the Han River, followed by Yeongsan River, Geum River Estuary, and Gapcheon. After rainfalls, both concentration and detection frequency were decreased in all sites. Although the BAC and DDAC seems to be accumulated in organisms, they were bio-diluted rather than magnified in the aquatic food web with the biomagnification factor(BMF) of less than 1, trophic magnification slope (TMS) from -0.236 to 0.001, and trophic magnification factor(TMF) from 0.85 to 1.01.

• Journal of the Korean GEO-environmental Society
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• v.24 no.8
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• pp.5-11
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• 2023

Due to frequent occurrences of concentrated heavy rainfall caused by abnormal climate conditions in recent years, collapses of steep slopes have been occurring frequently due to surface erosion and increased pore water pressure. Various methods are being applied to prevent slope collapses, such as increasing the resistance to movement and reducing pore water pressure. Research on these methods has been consistently conducted as they provide an efficient response to slope collapses by satisfying both the conditions of resistance to movement and pore water pressure simultaneously. Therefore, in this study, we propose an upward slope reinforcement method by burying drainage materials with an upward slope inclination, instead of the conventional horizontal application. This approach aims to satisfy both slope reinforcement and drainage functions effectively, offering a comprehensive solution for slope stabilization. Furthermore, to determine the optimal burial angle that exhibits the most effective reinforcement and drainage effects of the proposed method, we investigated the reinforcement and drainage effects under conditions where the horizontal drainage materials were set at angles ranging from 0° to 60° in increments of 10° on a representative cross-section. Additionally, indoor model experiments were conducted under the conditions of 40°, which showed the most outstanding drainage effect, and 20°, which exhibited the highest safety factor, to validate the numerical analysis results. The results showed that the burial angle of 40° exhibits a relatively higher drainage effect as with the numerical analysis results, while the angle of 20° results in inadequate drainage and observed slope collapse.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.28 no.6B
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• pp.709-721
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• 2008

This paper is to test the applicability of ModKIMSTORM (Modified KIneMatic Wave STOrm Runoff Model) by applying it to Namgangdam watershed of $2,293km^2$. Model inputs (DEM, land use, soil related information) were prepared in 500 m spatial resolution. Using five typhoon events (Saomi in 2000, Rusa in 2002, Maemi in 2003, Megi in 2004 and Ewiniar in 2006) and two storm events (May of 2003 and July of 2004), the model was calibrated and verified by comparing the simulated streamflow with the observed one at the outlet of the watershed. The Pearson's coefficient of determination $R^2$, Nash and Sutcliffe model efficiency E, the deviation of runoff volumes $D_v$, relative error of the peak runoff rate $EQ_p$, and absolute error of the time to peak runoff $ET_p$ showed the average value of 0.984, 0.981, 3.63%, 0.003, and 0.48 hr for 4 storms calibration and 0.937, 0.895, 8.08%, 0.138, and 0.73 hr for 3 storms verification respectively. Among the model parameters, the stream Manning's roughness coefficient was the most sensitive for peak runoff and the initial soil moisture content was highly sensitive for runoff volume fitting. We could look into the behavior of hyrologic components from the spatial results during the storm periods and get some clue for the watershed management by storms.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.30 no.6B
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• pp.541-549
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• 2010

While the number of rainy days is decreasing, the mean annual precipitation is increasing due to abnormal climate changes caused by the global warming in Korea. Owing to the biased-concentration of rainfall during specific short terms, not only flood but also drought becomes more and more serious. From the literature, it is easily found that previous studies about flood have been intensively conducted. However, previous studies about drought have been performed rarely. This study conducted the comparison between two representative drought indexes calculated from soil moisture and precipitation. Study area was Haenam-gun, Jeollanam-do in Korea. Soil Moisture Index(SMI) was calculated from soil moisture data while the Standardized Precipitation Index(SPI) and the Palmer Drought Severity Index(PDSI) were calculated from meteorological data. All monthly data utilized in this study were observed at the KoFlux Tower. After the comparative analysis, three indexes showed similar tendency. Therefore, it is thought that the drought index using soil moisture measured at the KoFlux Tower is reasonable, which is because the soil moisture is immediately affected by all the meteorological factors.

• Economic and Environmental Geology
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• v.35 no.6
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• pp.491-508
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• 2002

While about 80% of Jeju soils are classified as Andisols, the soils derived from volcanic ash in Dangsanbong are not Andisols. There is a significant difference of precipitation in localities of Jeju island. The study area is characterized by the lowest amount of annual rainfall in Jeju Island, and by the layered silicates as dominant solid phase in clay fraction. The purpose of this study was to characterize the mineralogy of the non-Andie soils in detail, especially hydroxy-interlayered silicates. Two major soil horizons are recognized in the soil profile developed in the Dangsanbong area, which can be designated as A and C. The soil pH($H_{2}0$), ranges from 6.6 to 7.3 increasing with depth, is higher than that of typical Andisols(pH<6.0). While the pH(NaF), ranges from 9.49 to 9.81, indicates that significant amount of amorphous phases might be present as exchanging complexes. It is estimated to about 1.542.88 wt% by using chemical selective dissolution. The organic content of surface horizon is about 2 wt%. This soil are composed of quartz, feldspar and olivine as major constituents with minor of silicate clays. Quartz is frequently observed in A and distinctly decreases in its amount with depth, while olivine is dominant phase in C and rarely observed in A. In the <0.2$\mu\textrm{m}$ size fraction, smectite and kaolinite/smectite interstratification are dominant with minor of illite. The amounts of smectite decrease with depth, while the amounts of kaolinite/smecite interstratification increase with depth, which indicates the trend of mineral transformation with increasing the degree of weathering. The proportion of kaolinite in kaolinite/smectite interstratification is about 85%, and is not changed significantly through the profile. In the 2-0.2$\mu\textrm{m}$size fraction, vermiculite, smectite, illite and kaolinite are major components with minor of chlorite. Most of chlorite are interstratified with smectite. Chlorite which is not interstratified with smectite occurs only in surface horizon. The proportion of the chlorite in the chlorite/smectite interstratification is 59-70(%) and increases with depth. Hydroxy-interlayered vermiculite(HIV) with hydroxy-Fe/AI in their interlayers occurs in both A and C horizon. The amounts of hydroxy-Fe/AI decrease with depth. Hydroxy-interlayered smectite(HIS) of which interlayers might be composed of hydroxy-Mg/Al occurs only in C horizon. As the results of mineralogical investigation for the soil profile in the study area, clay minerals might be changed and evolved through the following weathering sequences: 1) Smectite Kaolinite, HIS, Vermiculite, 2) Vermiculite HIV Chlorite.

• Korean Journal of Soil Science and Fertilizer
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• v.15 no.4
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• pp.213-220
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• 1982

Soil water changes in lysimeters with four different soils and two different available soil depths were monitored during the growing seasons of the soybean-barley cropping from 1977 to 1980 in Suweon to evaluate evapotranspiration (ET) as a function of available soil water and evaporative demand of the atmosphere. ET was calculated with soil water profile and water balance. Soil water content was measured with a neutron moisture depth gauage and The evaporative demand of the atmosphere was estimated with a class A pan evaporation. Rainfall. solar radiation, and wind speed were observed to examine heat and water balances. The average ET of soybeans ranged from 1.6 mm/day at seedling to 6.5 mm/day at flowering, and that of barley ranged from 0.5 mm/day at the regrowth stage to 4.6 mm/day at heading; however, a large variability was observed. The ratio of ET to pan evaporation ($ET/E_o$) ranged from 0.5 to 1.1 for soybeans and 0.4 to 1.2 for barley. The soil evaporation factor ($K_e$) of the $ET/E_o$ component decreased as the soil water depleted and the canopy developed. The crop transpiration factor ($K_t$), another component of $ET/E_o$, also was a function of time and the soil water. $K_t$ was constant when the available soil water fraction (f) in the root zone was greater than a threshold value, and $K_e$ was decreased linearly when f was lower than this threshold. The threshold was 0.7 for the moderate evaporative demand days, 0.4 to 0.5 for the low evaporative demand days, and 0.9 to 0.96 for the high evaporative demand days. Conclusively, the ET can be estimated from the evaporative demand of the atmosphere, $E_o$, $K_e$ and $K_t$, and the available soil water content in the root zone.

• Magazine of the Korean Society of Agricultural Engineers
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• v.13 no.1
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• pp.2177-2190
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• 1971

This experiment was made to determienthe effect of various soil moisture contents in simulated drought conditions on different stages of rice growth. The drought conditions were developed at such three rice-growing stages as transplanting, immediately after transplanting and young ear forming. Three different lengths of drought periods, which are ten days, twenty days and thirty days, were applied for each growing stage of rice. The rice variety used this experiment is Nong-rim 29. This experiment was conducted at the university farm of the Kon-Kuk University during the period of $1968{\sim}1970$. Three reprications for each of 12 treatments and split plot design were employed in this study. Bottomless wood square boxes, $1^m{\times}1^m{\times}1^m$, were burried in the test plot and box top was covered with poloyethylene sheets to avoid natural rainfall drops. Standard plots were irrigated continuously with a water depth of 40mm/day and those of drought treatments were irrigated continuously up to the beginning of the planned drought period, and they were irrigated again with a depth of 40mm/day up to the maturing stage of rice. Other methods for rice raising followed those methods developed by the Field Crops Experiment Station of the Office of Rural Development. During this experiments, climatic conditions in regard to rainfalls, sunshine hours, and temperatures were observed. According to this observation, those values measured deviate slightly from the annual means. However the growing condition of rice plants were normal. The pH value of irritation water is nearly neutral, and soils in the test plots are relatively fertile, being similar to ordinary paddy soils. Analysis of variances for number of stalks, plan-height, ear sprouting date, length of stalks, ear length, number of ears per plant, fertility, grain weitght, weight of plant, and yield were carried out. The variances for plant height, ear sprouting date, length of stalk ear length, and yield has statistical significance under drought treatments applied at three different growing stages. The variance showing the effect of lengths of drought period is highly significant for all the treatments studied except that of grain weight. The interaction between drought periods and drought treatments at different growing stages is significant for plant height, stalk length, ear length, number of ears, fertility and yield, these results indicated that droughts at different growing stages have influence on plant height, ear length, yield, and length of drought period also has strong influence on all factors studied except grain weight. The combination of drought treatments at different rice growing stages and lengths of drought periods has different effects on various agronomic characteristics, including yield. Plant height under drought treatment practiced at transplanting stage is the lowest, and drought treatment applied immediately after transplanting resulted in the least number of stalks. The effect of different lengths of drought periods on plant height and number of stalks depends signis ficantly on increasing days of drought. Ear sprouting date tends to be delayed for one or two days undedrought treatments at transplanting period and with increasing days of drought. Better yield is secured in drought treatment applied immediately after transplanting. Adverse effect war observed when drought treatment was applied at ear forming period. These effects may be attributed to the alternation of irrigation and drought causing vigorous root activity. In general, yield linearly decreases as the length of the drought period increases. The results obtained in this study demonstrate that, in order to mimimize damage due to drought, and, to save irrigation water, paddy fields, immediately after transplanting, may be not irrigated, since there is sufficient moisture in the soil, and that sufficient irrigation water should be applied again in the ear forming stage of rice plant.

• Applied Biological Chemistry
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• v.44 no.2
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• pp.97-102
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• 2001

Cheju island depends on a hydrogeologically vulnerable aquifer system as its principle source of drinking water. Most of golf courses are located in the area which is important for the ground water recharge, and pesticides are applied to golf courses often at relatively high rates. Therefore, turf pesticides in golf course should be applied without adversely impacting ground water. In this experiment, downward movement of pesticides was monitored in model greens of golf course, where different adsorbents were layered in 3-cm thickness at 35-cm depth, and effect of the adsorption layer on the leaching loss of pesticides was investigated. Major leachings were observed in the periods of heavy rain and very limited leaching was observed under artificial irrigation. Fenitrothion and triadimefon, which have relatively short persistence and high adsorption coefficient, were found in the leachate in low concentrations only at the first rainfall event, around 20 days after the pesticide application. However, diniconazole, which has a relatively long half-life (97 days), was detected in the leachate during the whole period of experiment and concentration was much higher than those of the other pesticides. Maximum leachate concentrations were 1.9, 10.3, and 84.5 ${\mu}l^{-1}$ for fenitrothion, triadimefon, and diniconazole, respectively. Therefore, in golf course green which allows rapid water percolation and has extremely low adsorption capacity, persistence in soil could be more important factor in determination of leaching potential of pesticides. Total quantity of pesticides leached from the model green was <0.2% for fenitrothion and triadimefon and 1.8% for diniconazole. Adsorption layers significantly reduced pesticide leaching, and active carbon and Orpar were more effective than zeolite. In the model green having adsorption layer of active carbon or Orpar, leaching loss of pesticides was reduced below 0.01% of the initial application.

• The Korean Journal of Mycology
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• v.45 no.4
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• pp.270-283
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• 2017

In a survey on higher fungi from 2004 to 2011, and also in 2013, in Naejangsan National Park, a total of 2 divisions, 7 classes, 21 orders, 74 families, 229 genera, and 521 species were observed. Dominant species belonged to the families Boletaceae and Russulaceae (44 species), Agaricaceae (35 species), Polyporaceae (29 species), and Amanitaceae (27 species). For the habitat environment, 21 families, 44 genera, and 192 species (36.9%) (63 species of poisonous mushroom, 79 species of edible and medicinal mushroom, and 43 species of unknown edible & poisonous mushroom) of ectomycorrhizal mushrooms were found; 41 families, 118 genera, and 199 species (38.2%) (14 species of poisonous mushroom, 85 species of edible & medicinal mushroom, and 90 species of unknown edible and poisonous mushroom) of litter decomposing and wood rotting fungi were found, and 29 families, 66 genera, and 121 species (23.2%) (8 species of poisonous mushroom, 54 species of edible and medicinal mushroom, and 47 species of unknown edible & poisonous mushroom) of grounding fungi were found, and 9 species were the other habitat. In terms of seasonality, most of the higher fungi were found in July, August, and September. In terms of altitude, the most species were observed at 200~299 m, and populations dropped by a significant level at an altitude of 700 m or higher. It seemed that the most diversified higher fungi occurred at climate conditions with a mean air temperature of $25.0{\sim}28.9^{\circ}C$, a maximum air temperature of $30.0{\sim}33.9^{\circ}C$, a minimum air temperature of $21.0{\sim}24.9^{\circ}C$, a relative humidity of 73.0~79.9%, and over 400.0 mm of rainfall.