• Bulletin of the Korean Chemical Society
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• v.31 no.7
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• pp.1941-1944
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• 2010

The heterojunction structures of BiOCl/$Bi_3O_4Cl$, exhibiting considerable visible-light photocatalytic efficiency, were prepared by a simple wet-chemical process at ambient condition. The prepared nanocomposites were characterized by XRD, TEM, and UV-visible diffuse reflectance spectra. Under visible light (${\lambda}\geq$420 nm) irradiation, BiOCl/$Bi_3O_4Cl$ exhibited an enhanced photocatalytic activity in decomposing 2-propanol (IP) in gas phase and salicylic acid (SA) in aqueous solution, whereas the bare BiOCl and $Bi_3O_4Cl$ showed negligible activities. It is deduced that the remarkable visible-light photocatalytic activity of the BiOCl/$Bi_3O_4Cl$ originates from the hole $(h^+)$ transfer between VB of the $Bi_3O_4Cl$ and BiOCl semiconductors.

• Journal of the Korean Ceramic Society
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• v.24 no.4
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• pp.397-403
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• 1987

Pb(Zr0.52Ti0.48)O3 powders were prepared by hydrothermal synthesis. Using soluble salts such as Pb(NO3)2, TiCl4 and ZrOCl2$.$8H2O and oxide such as PbO and TiO2 as starting materials, PZT powder was hydrothermally synthesized at the temperature range between 150$^{\circ}C$ and 200$^{\circ}C$. The result showed that reactivity by alkali was decreased in the sequence of Pb(NO3)2, TiCl4, ZrOCl2, PbO, TiO2 and ZrO2. Using the first three soluble salts, PZT powder was synthesiged at 150$^{\circ}C$ for 1hr. In PbO-TiCl4-ZrOCl2 system, PZT powder was synthesized at 150$^{\circ}C$ for 8rs. In Pb(NO3)2-TiO2-ZrOCl2 system, PZT powder was synthesized at 150$^{\circ}C$ for 16hrs, in PbO-TiO2-ZrOCl2 system, the powder was synthesized at 200$^{\circ}C$ for 8hrs.

• Journal of the Korean Chemical Society
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• v.26 no.3
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• pp.155-159
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• 1982

The new molybdenum(Ⅴ)-triethylenetetraamine complexes such as Trien$H_4(MoOCl_5)_2,\;(MoOCl_3)_2$(trien), and$Mo_2O_4Cl_2$ (trien) have been prepared, and the chemical, magnetic and spectroscopic properties of the complexes have been investigated. Trien$H_4(MoOCl_5)_2has been isolated as green crystal and from this salt the nonelectrolytic and paramagnetic complexes,$(MoOCl_3)_2$ (trien) have been prepared by evolution of hydrogen chloride in anhydrous ethanol. Hydrolysis of triethylenetetraammonium oxopentachloromolybdate(V) yielded the nonelectrolytic and dismagnetic complex, $Mo_2O_4Cl_2$(trien) as brown solid.

• Journal of the Korean Chemical Society
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• v.26 no.6
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• pp.378-382
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• 1982

Green crystalline salts of substituted pyridinium oxopentachloromolybdates(V) were obtained from concentrated hydrochloric acid solution of molybdenum(V)-thiocyanate extract. $MoOCl_3(X-py)_2$ (X-py were 4-and 3-cyanopyridine, 2-amino-4-picoline and 4-acetylpyridine) were obtained by reflux of the corresponding substituted pyridinium salts of oxopentachloromolybdates(Ⅴ) in absolute ethanol. ($X-pyH_2$)[$MoOCl_5$]$H_2$O containing the $MoO^{3+}$ group are dissolved and hydrolysed in water but $MoOCl_3(X-py)_2$ are insoluble in water, alcohol and acetone. The complexes are paramagnetic compounds.

• Journal of the Korean Ceramic Society
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• v.35 no.11
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• pp.1212-1221
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• 1998

• Elastomers and Composites
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• v.52 no.1
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• pp.9-16
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• 2017

Graphene-$BiOCl/Fe_3O_4$ nanocomposites were synthesized from $BiOCl/Fe_3O_4$ and graphene in an electric furnace operating at $700^{\circ}C$ for 12 h. The nanocomposite surface morphology and crystal structure were characterized by scanning electron microscopy and X-ray diffraction. The produced graphene-$BiOCl/Fe_3O_4$ nanocomposites acted as efficient heterogeneous photocatalysts for the degradation of organic dyes, as confirmed by UV-vis spectrophotometry.

• Restorative Dentistry and Endodontics
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• v.15 no.1
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• pp.187-200
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• 1990

The purpose of this study was to investigate antimicrobial effect of several irrigation solutions on 7 anaerobes and 2 aerobes, which are found frequently in infected root canals. The antimicrobial effects of normal saline, 3% $H_2O_2$, 0.5% & 3.5% NaOCl, 10% & 50% citric acid and mixed solutions of 3% $H_2O_2$ plus 3.5% NaOCl were compared. No. 80 paper points dipped in bacterial broth were soaked in each irrigation solutions and moved into thioglycolate broth, subcultured in agar plate for bacterial growth. The results were as follows: 1. Normal saline had no antimicrobial effect. 2. Mixed solutions of 3% $H_2O_2$ plus 3.5% NaOCl, 10% citric acid had relatively weak antimicrobial effect. 3.3% $H_2O_2$, 50% citric acid, 0.5% NaOCl showed relatively strong antimicrobial effect. 4. 3.5% NaOCl had the strongest antimicrobial effect among used 7 irrigation solutions.

• Journal of Magnetics
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• v.21 no.2
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• pp.179-182
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• 2016

In this paper, 10 nm $Fe_3O_4$ nanoparticles were modified on the surface of $2{\mu}m$ flower-like bismuth oxychloride (BiOCl) spheres by a facile co-precipitation method. The results showed that the $Fe_3O_4/BiOCl$ nanocomposites exhibited excellent photocatalytic activity and superparamagnetic property ($M_s=3.22emu/g$) under visible light for Rhodamine B (RhB) degradation. Moreover, the $Fe_3O_4-BiOCl$ photocatalyst possessed magnetic recyclable property, which could maintain high photocatalytic effective even after 20 cycle times. These characteristic indicates a promising application for wastewater treatment.

• Journal of the Korean Ceramic Society
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• v.32 no.7
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• pp.853-857
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• 1995

ZrSiO4 powders were prepared from partially hydrolyzed solution of Si(OC2H5)4 and ZrOCl2.8H2O solution by the sol-gel method and formation rate of ZrSiO4 on the reaction parameter was investigated. In order to prepare homogeneous ZrSiO4 precursor gels, the H2O/Si(OC2H5)4 molar ratio of about 2, the pH of the ZrOCl2.8H2O solution fo about 4 and stirring time of the mixed solutions of about 2 hrs were appropriate. Formation of temperature of ZrSiO4 reduced about 15$0^{\circ}C$ by milling and formation of ZrSiO4 at 1300~135$0^{\circ}C$ showed an accelerative increase through the hedvall effect by silica.

• Horticultural Science & Technology
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• v.33 no.5
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• pp.697-704
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• 2015

This study was carried out to investigate conveyance environment during shipping export to Japan and the optimum pre-treatment of cut Dendranthema grandiflorum 'Baekma'. Shipping from Korea to Japan, which usually takes three to five days, requires keeping the flower at the ideal temperature. When inspection took place in Japan, the ideal temperature was lost and deterioration began. Once the ideal temperature is lost, deterioration takes place. The results of this work showed that vase life was extended by treatment Chrysal RVB and NaOCl compared to the control (distilled water), and Chrysal RVB was used to maintain the flower from bud to full bloom. Bacterial growth was not observed after pretreatment with NaOCl or $ClO_2$. However, $ClO_2$ pre-treatment was observed to affect the early growth period of the bacteria. The chlorophyll content was the highest after Chrysal RVB or NaOCl pretreatment compared to the other treatments. Therefore, these results support pretreatment with NaOCl and Chrysal RVB of Dendranthema grandiflorum 'Baekma' for export to Japan.