• Bulletin of the Korean Chemical Society
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• 제16권3호
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• pp.211-214
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• 1995

The catalytic activities of palladium(0,Ⅰ,Ⅱ)-diphosphine complexes were investigated in styrene oxidation using H2O2 as terminal oxidant. The rates showed a dependence on the chelate ring patterns of complexes (PdCl2L); 5-membered ring (L=dppe: 1,2-bis(diphenylphosphino)ethane) < 6-membered ring (L=dppp: 1,3-bis(diphenylphosphino)propane) < 4-membered ring (L= dppm: bis(diphenylphosphino)methane). This sequence correlates with the ligand field strength and interactions between metal and phosphine ligands. Pd(Ⅱ,Ⅰ)-diphosphine complexes which are capable of making 4-membered chelate ring showed an enhancement of catalytic activities for styrene oxidation. The catalytic activities of Pd(0,Ⅰ,Ⅱ)-diphosphine complexes are described in terms of electronic and steric factors.

• Journal of Microbiology and Biotechnology
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• 제14권4호
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• pp.766-771
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• 2004

Julong 601, a Gram-positive anaerobic bacterium strain capable of cleaving the C-ring of isoflavones daidzein and genistein, was isolated from human feces. BLAST search revealed that its complete 16S rDNA gene sequence has 99% similarity to Eubacterium ramulus. Metabolites of daidzein and genistein were determined as O-desmethylangolensin (O-Dma) and 2-(4-hydroxyphenyl) propionic acid (2-HPPA), respectively, based on UV, EI-MS, and $^1H$ and ^{13}C$ NMR spectral analyses. Enantiomers of O-Dma and 2-HPPA were isolated by chiral stationary-phase HPLC (CSP HPLC). Cleavage of the C-ring of daidzein and genistein by strain Julong 601 was highly enantioselective. Specific rotation ([$\alpha]_D$) and circular dichroism (CD) spectra of the enantiomers are reported here for the first time. Biotransformation kinetics of daidzein and genistein indicated that the C-ring of genistein has a higher susceptibility to bacterial degradation than that of daidzein.

• Bulletin of the Korean Chemical Society
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• 제10권3호
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• pp.247-250
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• 1989

The molecular structure of cyclobutylmethyl ketone (c-$C_4H_7COCH_3$) has been investigated by molecular mechanics II (MM2). For the monosubstituted cyclobutane there are two possible ring conformations, the equatorial and axial form, but for the cyclobutylmethyl ketone the equatorial form is predominant conformation. For the $COCH_3$ moiety there are two stable orientations which are the equatorial-gauche and the equatorial-trans form. The equatorial-gauche form where the C = O bond is nearly eclipsing (torsional angle ${\angle}C4-C3-C2-O10=14.5^{\circ}$) one of the ${\alpha}$C-C bonds of the four-membered ring was preferred conformer with steric energy of 13.37 kcal/mol. The equatorial-trans form where the C = O bond is nearly eclipsing (${\angle}C4-C3-C2-O10=145.0^{\circ}$) the ${\alpha}$ C-H bond of the four-membered ring was less stable conformer with steric energy of 15.40 kcal/mol.

• 대한기계학회논문집B
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• 제27권8호
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• pp.1174-1181
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• 2003

The flow around a circular cylinder was controlled by attaching O-rings to reduce drag force acting on the cylinder. Four experimental models were tested in this study; one smooth cylinder of diameter D (D=60mm) and three cylinders fitted with O-rings of diameters d=0.0167 D, 0.05D and 0.067 D with pitches of PPD=2D, 1D, 0.5D and 0.25D. The drag force, mean velocity and turbulence Intensity profiles in the near wake behind the cylinders were measured for Reynolds numbers based on the cylinder diameter in the range of Re$_{D}$=7.8$\times$10$^3$~1.2$\times$10$^{5}$ . At Re$_{D}$=1.2$\times$10$^{5}$ , the cylinder fitted with O-rings of d=0.0167D in a pitch interval of 0.25D shows the maximum drag reduction of about 5.4%, compared that with the smooth cylinder. The drag reduction effect of O-rings of d=0.067D is not so high. For O-ring circulars, as the Reynolds number increases, the peak location of turbulence intensity shifts downstream and the peak magnitude is decreased. Flow field around the cylinders was visualized using a smoke-wire technique to see the flow structure qualitatively. The size of vortices and vortex formation region formed behind the O-ring cylinders are smaller, compared with the smooth cylinder.der.

• 한국산업정보학회논문지
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• 제19권4호
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• pp.41-52
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• 2014

본 논문은 O링의 치수 측정에 있어 고가의 대 중형 머신비전 장비를 대체할 수 있는 소형 머신 비전 검사 장비에 기반한 O링 부품 내 외경 측정 알고리즘을 제안한다. 백라이트 조명하에 하나의 CCD 카메라를 이용하여 측정 평면으로 부터 영상을 획득하는 소형 머신 비전 검사장비에 의해 획득된 영상을 제안한 영상처리 기법 알고리즘을 이용하여 O링의 외경 및 내경치수를 측정한다. 치수 측정의 정확도를 높이기 위해 렌즈계 왜곡 보정과 원근 왜곡 보정을 소프트웨어적 기법으로 보정 하였고 O링 형상을 고려하여 타원정합 모델을 적용하였으며 보다 타원 정합의 신뢰성을 높이기 위해 RANSAC알고리즘을 적용하였다.

• 대한기계학회논문집A
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• 제37권4호
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• pp.537-545
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• 2013

금속씰의 탄성복원력은 기밀성능을 결정하는 매우 중요한 요소이다. 본 연구는 장시간 운전조건에서 기밀성능을 유지할 수 있는 금속오링씰의 구조, 즉 탄성복원력이 우수한 구조를 얻기 위하여 컴플라이언트 메커니즘 위상최적화법을 도입하였다. 진화구조최적화법의 위상최적화 알고리듬이 사용되었으며, 강성 및 유연성을 동시에 고려하는 두 가지 종류의 목적함수가 사용되었다. 금속오링씰의 외형을 고려하여 원형의 최적화 설계영역이 고려되었으며 최적화 결과로 나타난 위상의 탄성복원력은 상용품의 탄성복원력과 비교되었다.

• 한국정밀공학회지
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• 제26권2호
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• pp.86-93
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• 2009

Elastomeric O-rings have been the most common seals due to their excellent sealing capacity, and availability in costs and sizes. One of the critical applications of O-ring seals is solid rocket motor joint seal where the operating hot gas must be sealed during the combustion. This has long been a design issue to avoid the system failure. For laterally constrained, squeezed and pressurized condition, deformed shape of O-ring was measured by computed tomography method and CCD laser sensor, compared with numerical calculations. As clearance gap changes, sealing performance had been evaluated on peak contact stresses at top, bottom and side contact surfaces. As clearance gap increases, peak contact stresses and contact widths in top and side contact surfaces increase, and the asymmetry of stress distributions is promoted due to pressure increase. It is suggested that peak stress of bottom contact surface can be approximated by simple superposition of peak ones due to squeeze and pressure. Under pressurized condition, sealing performance is dependent on not peak stresses of bottom and side contact surfaces but that of top.

• 대한수학회논문집
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• 제35권2호
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• pp.447-454
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• 2020

The studies of reversible and NI rings have done important roles in noncommutative ring theory. A ring R shall be called QRUR if ab = 0 for a, b ∈ R implies that ba is contained in the upper nilradical of R, which is a generalization of the NI ring property. In this article we investigate the structure of QRUR rings and examine the QRUR property of several kinds of ring extensions including matrix rings and polynomial rings. We also show that if there exists a weakly semicommutative ring but not QRUR, then Köthe's conjecture does not hold.

• 대한수학회보
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• 제28권2호
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• pp.175-180
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• 1991

In [3], [4] and [5], Hochster and Huneke introduced the notions of the tight closure of an ideal and of the weak F-regularity of a ring. This notion enabled us to give new proofs of many results in commutative algebra. A regular ring is known to be F-regular, and a Gorenstein local ring is proved to be F-regular provided that one ideal generated by a system of parameters (briefly s.o.p.) is tightly closed. In fact, a Gorenstein local ring is weakly F-regular if and only if there exists a system of parameters ideal which is tightly closed [3]. But we do not know whether this fact is true or not if a ring is not Gorenstein, in particular, a ring is a Cohen Macaulay (briefly C-M) local ring. In this paper, we will prove this in the case of an 1-dimensional C-M local ring. For this, we study the F-rationality and the normality of the ring. And we will also prove that a C-M local ring is to be Gorenstein under some additional condition about the tight closure.

• Bulletin of the Korean Chemical Society
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• 제22권6호
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• pp.575-580
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• 2001

Intramolecular ring-ring interactions in the model compounds, $8-methoxypsoralen-CH_2O(CH_2)n-adenine(MOPCH_2OCnAd$, n=2, 3, 5, and 6) in which 5' position of 8-methoxypsoralne (8-MOP) is linked by different polymethylene bridges to N9 of adenine, have been investigated by hypochromism measurements. Efficient ring-ring stacking interactions have been observed in $MOPCH_2CO2Ad$ (7) from the percent hypochromism(%H) and fluorescence spectra of the models and a reference molecule. The 8-methoxyposralen-adenine systems have shown stronger ring-ring stacking interaction than the psoralen-adenine system.