• Title/Summary/Keyword: O/F Ratio Variation

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Study on the Structural and Transporting Property of Sr2Ru1-xCuxO4-y(0.0≤x≤0.5) (Sr2Ru1-xCuxO4-y(0.0≤x≤0.5) 화합물의 구조 및 전달 특성에 대한 연구)

  • Park, Jung-Chul
    • Journal of the Korean Chemical Society
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    • v.47 no.6
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    • pp.614-618
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    • 2003
  • $Sr_2Ru_{1-x}Cu_xO_{4-y}(0.0{\le}x{\le}0.5)$ compounds were prepared using a conventional solid state reaction. Based on the Rietveld refinements of X-ray diffraction results, it is revealed that $Sr_2Ru_{1-x}Cu_xO_{4-y}$ compounds are the single phases with K2NiF4 type tetragonal system in the range of 0=x=0.3, while the mixed phases of$Sr_2RuO_4$ and $Sr_2CuO_3$ in the range of $0.4{\le}x{\le}0.5$. By means of X-ray photoelectron spectroscopy, the valence states of Ru and Cu in $Sr_2Ru_{1-x}Cu_xO_{4-y}$, have been confirmed to 4+ and 2+, respectively. The bond length difference between $Ru-O_1 ({\times}4)\;and\;Ru-O_2 ({\times}2)\;in\;RuO_6$ octahedron is gradually decreased with increasing Cu content in $Sr_2Ru_{1-x}Cu_xO_{4-y}$, which results in the lower c/a ratio. So, it might be assured that the variation of local symmetry of $RuO_6$ octahedron is very closely related to the transporting property of $Sr_2Ru_{1-x}Cu_xO_{4-y}$ compounds. The behavior of resistivity discloses that the metallic property in $Sr_2RuO_4$ changes into the semiconducting one in proportion to the Cu content in $Sr_2Ru_{1-x}Cu_xO_{4-y}$.

A Clothing-Ergonomics Study on the Variation of Upper Arm Skin Surface According to Arm Movements - on the arm movements to the vertical direction in front and in side - (신체동작에 따른 상지형태변화에 관한 피복인간공학적 연구 - 전방수직동작과 측방수직동작을 중심으로 -)

  • Kim Hae-Kyung;Park Eun-Joo;Jeon Eun-Kyung
    • Journal of the Korean Society of Clothing and Textiles
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    • v.13 no.1 s.29
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    • pp.49-58
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    • 1989
  • A clothing-erogonomics study was performed to investigate the difference of the upper arm skin skin surface and the relationship among the three aspects of upper arm (height of sleeve rap, sleeve width and armhole girth) by changing arm movements. Plaster cast was used for this experimental research. Arm movements consist of 9 types; just carmly standing on ($0^{\circ}$), and each 4 types ($45^{\circ},\;90^{\circ},\;135^{\circ},\;180^{\circ}$) to the vertical direction in front and in side. The results were as follows; 1) As the arm-movement angle increased, the height of sleeve cap decreased and that ratio was largest in the portion A-B3. 2) The steeve width was enlarged with the increment of movement angle in all portions of upper arm except B1-B5. 3) As increasing the movement angle, the whole armhole girth decreased and the ratio o(front armhole girth (F-A) was larger than that of back. 4) In the vertical direction in front, the height o( the sleeve caps was larger, the sleeve widths were smaller than in the vertical direction in side in all movement types, but there was no significant difference in arm-hole girth between the two cases. 5) There were significantly negative relationships between measurements in height of sleeve cap and those in sleeve width, and also between those in height of sleeve cap and in arm-hole girth. And significantly positive relationships were found between neasurements in height of sleeve cap and those in arm-hole girth.

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Life Table Descriptions of Tetrastichus sp. (Hymenoptera: Eulophidae) on Hyphatria cunea Drury

  • Lee, Jang-Hoon;Lee, Ki-Sang;Lee, Hai-Poong
    • Animal cells and systems
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    • v.6 no.1
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    • pp.19-22
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    • 2002
  • Life table studies were conducted in the laboratory for the eulophid gregarious pupal parasitoid, Tetrastichus sp., on Hyphantria cunea Drury at a constant temperature of 28.2$\pm$2$^{\circ}C$, 50-60% RH to evaluate their impact on the host and their potential biological control. Development of immature stage took 20.1$\pm$2.7 d: adult females lived for 23.2$\pm$2.2 (range, 16-27)d and produced a mean of 53.6$\pm$26.6 adult progeny per female, with a sex ratio of 1: 9.5 (M:F). The intrinsic rate of natural increase (r$_{m}$) was 0.178/ female/day; the net reproductive rate (R$_{o}$), 46.74; the capacity for increase (r$_{c}$) 0.177; the finite rate of increase (λ) 1.19/female/day; thus each female contributed 46.74 individuals to the population in a mean generation time of 21.6 d. Biological factors in determining the life history trait variation of the parasitoid were discussed.d.d.d.

Analysis of the Theoretical Performance Characteristics for Methane-fuel Bipropellant Rocket Engine (메탄을 연료로 하는 이원추진제 로켓엔진의 이론성능특성 분석)

  • Kim, Jong Hyun;Jung, Hun;Kim, Jeong Soo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.18 no.3
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    • pp.1-7
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    • 2014
  • A set of preliminary design parameters for the bipropellant rocket engine using liquid methane-fuel as green propellant were derived through a theoretical performance analysis. Chemical equilibrium analysis utilizing CEA was conducted for the prediction of combustion performance: combustion characteristics according to the O/F ratio and chamber pressure variation were investigated. For a determination of chamber-characteristic length, the vaporization time of fuel-droplet with various performance parameters was calculated by applying Spalding's 1-D droplet vaporization model. Finally, the preliminary design specification of methane-bipropellant rocket engine, which is to be performance-tested under the ground firing condition, was proposed.

Effects of Conductive Material on $LiCoO_2$ Cathode for the Lithium ion Battery (리튬이온전지용 $LiCoO_2$ 정극의 도전재료에 따른 특성)

  • Coh Chil Hoon;Moon Seong In;Hyung Yoo Eup;Yun Mun Soo;Park Chun Jun;Yun Duk Hyun;Yun Suong Kyu
    • Journal of the Korean Electrochemical Society
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    • v.2 no.2
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    • pp.88-92
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    • 1999
  • The apparent density. self-separation of the electrode composite from current collector in the electrolyte solution and specific resistance of electronic conduction of the electrode composite were examined by the variation of content of conductive material such as graphitic and black carbons in $LiCoO_2$ composite electrode for lithium ion battery. Increasing the content of conductive material, the apparent density of Lico02 composite electrode was decreased and that of $LiCoO_2$ in composite electrode was only rapidly decreased compared to that of composite. $LiCoO_2$ composite electrodes containing more than 4.1 weight percent of super s black as a conductive material were seU-separated by the immersion into 1 mol/I $LiPF_6$ in propylene carbonate and diethyl carbonate (1:1 volume ratio). Specific resistances related to the electronic conduction of composite electrode were decreased by the increasing the content i)f conductive material. Specific resistance of the composite electrode including $2\~3\%w/w$ of super s black as conductive material was similar to that of $12\%w/w$ of Lonza KS6. In the range of this study, super s black as conductive material is better than Lonza KS6 on battery capacity because of apparent density of $LiCoO_2$ in electrode composite including super s black is higher than that of Lonza KS6.

The Treatment of Synthetic Wastewater by Biological Fluidised Bed With Air Lift Aeration (간접폭기식(間接曝氣式) 생물학적(生物學的) 유동층(流動層)을 이용한 합성하수(合成下水) 처리(處理))

  • Kim, Hwan Gi;Lee, Ki Wan
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.7 no.3
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    • pp.33-44
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    • 1987
  • To improve the ability of oxygen transfer in Biological Fluidised Bed(BFB) processes, air lift aeration system was introduced, experimental investigations were performed for the oxygen transfer in reactor, the fluidisation as to Biomass Volatile Solids variation and the relationship between substrate removal rate and oxygen utilization. The experiments for this purpose were executed for the synthetic wastewater by continuous type reactor at $20^{\circ}C$ using reticulated polypropylene sheets as media. The obtained results showed that the oxygen transfer by air lift aeration would be more effective than any other aeration systems used in BFB reactor. Also, it has observed that the critical biomass concentration in reactor took a range of 20 to 23g/l. Applying cages to BFB reactor, biomass would be maintained uniformly in the bed and the fluidisation characteristics of media could be improved. Varying F/M ratio from 0.36 to 0.73, BOD removals were 91% or more. Therefore, this process was suited to the treatment of which F/M ratios are variable and specific oxygen uptake rates ($K_r$) were 0.23 to 0.26g $O_2/g\;VSS{\cdot}day$ at range of 15 to 20g BVS/l.

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Numerical Study of Rocket Exhaust Plume with Equilibrium Chemical Reaction and Thermal Radiation (평형화학반응과 복사열전달을 고려한 로켓 플룸 유동 해석)

  • Shin J.-R.;Choi J.-Y.;Choi H.-S.
    • 한국전산유체공학회:학술대회논문집
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    • 2004.03a
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    • pp.146-153
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    • 2004
  • The Numerical study has been carried out to investigate the effects of chemical reaction and thermal radiation on the rocket plume flow-field at various altitudes. The theoretical formulation is based on the Navier-Stokes equations for compressible flows along with the infinitely fast chemistry and thermal radiation. The governing equations were solved by a finite volume fully-implicit TVD(Total Variation Diminishing) code which uses Roe's approximate Riemann solver and MUSCL(Monotone Upstream-centered Schemes for Conservation Laws) scheme. LU-SGS (Lower Upper Symmetric Gauss Seidel) method is used for the implicit solution strategy. An equilibrium chemistry module for hydrocarbon mixture with detailed thermo-chemical properties and a thermal radiation module for optically thin media were incorporated with the fluid dynamics code. In this study, kerosene-fueled rocket was assumed operating at O/F ratio of 2.34 with a nozzle expansion ratio of 6.14. Flight conditions considered were Mach number zero at ground level, Mach number 1.16 at altitude 5.06km and Mach number 2.9 at altitude 17.34km. Numerical results gave the understandings on the detailed plume structures at different altitude conditions. The diffusive effect of the thermal radiation on temperature field and the effect of chemical recombination during the expansion process could be also understood. By comparing the results from frozen flow and infinitely fast chemistry assumptions, the excess temperature of the exhaust gas resulting from the chemical recombination seems to be significant and cannot be neglected in the view point of performance, thermal protection and flow physics.

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A Study on Relation between the Fuel Mass Flux and the Oxidizer Mass Flux with the Initial Port Diameter in Hybrid Rocket (하이브리드 로켓에서의 초기 포트직경을 고려한 산화제 유속과 고체연료 유속과의 관계에 관한 연구)

  • Lee, Jung-Pyo;Cho, Sung-Bong;Yoon, Sang-Kyu;Park, Su-Hayng;Song, Na-Young;Kim, Gi-Hun;Cho, Jung-Tae;Sung, Hong-Gye;Moon, Hee-Jang;Kim, Jin-Kon
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2007.11a
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    • pp.243-247
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    • 2007
  • Fuel mass flux was experienced with a function of the oxidizer mass flux using initial port area of solid fuel, in stead of regression rate correlation which shows combustion characteristic in hybrid propulsion. The burning rate could be easily obtained by using the oxidizer mass flux of initial port area without iteration, and fuel configuration could be designed simply. In this experiments PE was used as fuel, COX was used as oxidizer. A variation of mass flux of solid fuel with port area is considered by changing the burning time. In the case of approximate 0.5 for an exponent of oxidizer mass flux, using the fuel mass flux correlation is more suitable than regression rate correlation in hybrid propulsion.

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Plasma Etching Characteristics of Sapphire Substrate using $BCl_3$-based Inductively Coupled Plasma ($BCl_3$ 계열 유도결합 플라즈마를 이용한 사파이어 기판의 식각 특성)

  • Kim, Dong-Pyo;Woo, Jong-Chang;Um, Doo-Seng;Yang, Xue;Kim, Chang-Il
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.363-363
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    • 2008
  • The development of dry etching process for sapphire wafer with plasma has been key issues for the opto-electric devices. The challenges are increasing control and obtaining low plasma induced-damage because an unwanted scattering of radiation is caused by the spatial disorder of pattern and variation of surface roughness. The plasma-induced damages during plasma etching process can be classified as impurity contamination of residual etch products or bonding disruption in lattice due to charged particle bombardment. Therefor, fine pattern technology with low damaged etching process and high etch rate are urgently needed. Until now, there are a lot of reports on the etching of sapphire wafer with using $Cl_2$/Ar, $BCl_3$/Ar, HBr/Ar and so on [1]. However, the etch behavior of sapphire wafer have investigated with variation of only one parameter while other parameters are fixed. In this study, we investigated the effect of pressure and other parameters on the etch rate and the selectivity. We selected $BCl_3$ as an etch ant because $BCl_3$ plasmas are widely used in etching process of oxide materials. In plasma, the $BCl_3$ molecule can be dissociated into B radical, $B^+$ ion, Cl radical and $Cl^+$ ion. However, the $BCl_3$ molecule can be dissociated into B radical or $B^+$ ion easier than Cl radical or $Cl^+$ ion. First, we evaluated the etch behaviors of sapphire wafer in $BCl_3$/additive gases (Ar, $N_2,Cl_2$) gases. The behavior of etch rate of sapphire substrate was monitored as a function of additive gas ratio to $BCl_3$ based plasma, total flow rate, r.f. power, d.c. bias under different pressures of 5 mTorr, 10 mTorr, 20 mTorr and 30 mTorr. The etch rates of sapphire wafer, $SiO_2$ and PR were measured with using alpha step surface profiler. In order to understand the changes of radicals, volume density of Cl, B radical and BCl molecule were investigated with optical emission spectroscopy (OES). The chemical states of $Al_2O_3$ thin films were studied with energy dispersive X-ray (EDX) and depth profile anlysis of auger electron spectroscopy (AES). The enhancement of sapphire substrate can be explained by the reactive ion etching mechanism with the competition of the formation of volatile $AlCl_3$, $Al_2Cl_6$ or $BOCl_3$ and the sputter effect by energetic ions.

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An Experimental study for the heat flux in liquid rocket thrust chamber (액체로켓 추력실에서 발생하는 Heat Flux에 관한 실험적 연구)

  • An, Won Geun;Park, Hui Ho;Hwang, Su Gwon;Kim, Yu
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.31 no.3
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    • pp.65-71
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    • 2003
  • In this research, we make the thin wall chamber to the measurement of heat flux of using a Kerosene/LOx liquid rocket engine's thrust chamber. The wall thickness is one millimeter. We measured outside wall temperature of thrust chamber by nine thermocouple. We suppose the system to the one-dimension unsteady state, and so the heat flux and heat transfer coefficient of thurst chamber are calculated using one-dimensional the transient energy equation by outside wall temperature. In this case, O/F ratio is 2.0, experimental variation is chamber pressure and we got the heat transfer coefficient of the proportion relation of 0.88 times for the chamber pressure.