• 제목/요약/키워드: Nylon 6.6

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나일론6/MMT 나노복합체 섬유의 제조 및 특성 (Preparation and Characterization of Nylon 6/MMT Nanocomposite Fiber)

  • 김갑진;최은화;;박정일;이종순
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2003년도 가을 학술발표회 논문집
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    • pp.219-220
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    • 2003
  • 나일론 6의 열변형온도와 탄성률을 증가시키는 동시에 높은 기체 차단성을 얻기 위하여 Na-montmorillonite (Na-MMT) 또는 유기화제로 개질된 MMT (organo-MMT)를 나일론 6과 melt-compounding함으로써 나일론 6 분자쇄가 MMT 층 내로 intercalation하거나 MMT의 각 층을 완전히 exfoliation시켜 나일론 6/MMT 나노복합체를 제조하는 방법과 Na-MMT 또는 organo-MMT의 존재하에서 $\varepsilon$-caprolactam (CL)을 in situ 중합함으로써 대부분의 MMT가 각각의 층으로 exfoliation 되도록하여 나일론 6/MMT 나노복합체를 제조하는 방법이 널리 쓰이고 있다 [1-2]. (중략)

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양송이 색소의 특성과 염색성에 관한 연구(III) -염색 조건에 따른 색차 분석을 중심으로- (A Study on the Characterization and Dyeability of Mushroom Colorant(III) -Analysis of Color Difference Value Depending on Dyeing Condition)

  • 서영숙;정지윤
    • 복식문화연구
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    • 제6권1호
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    • pp.58-70
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    • 1998
  • The color difference value of fabrics dyed with browning extracts from mushroom were as follows. 1. Two hours of dyeing depending on pH at 95℃ exhibited colors of YR and Y. The color of wool and nylon was darkest brown at pH 4, but light brown or yellow as pH increased. The color of silk was darkest brown at pH 5 and pH changes resulted in the same tendency as in wool. 2. In wool the color was changed to darker brown as time prolonged, however, there was no further color change after 9hr and value and chroma of wool declined. 3. At pH 4, the increase in temperature turned colors of sil, wool and nylon into dark brown from light yellow. 4. As the result of repetitive dyeing, colors of silk, wool and nylon gradually turned into darker brown. The repetitive dyeing was more effective in dark color and high colorfastness compared to a prolonged dyeing. 5. The amount of mordant resulted in color changes between light yellow and dark brown without various color changed. 6. In color change according to methods of mordant, post-mordant with CuSO₄·5H₂O and with SnCl·2H₂O showed colors of green and light yellow, respectively.

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나일론 시트와 염료를 이용한 고감도 색변환 포름알데히드 가스 센서 (Highly Sensitive Colorimetric Formaldehyde Gas Sensors using Nylon Sheet and Dye)

  • 정승화;조영범;김용신
    • 센서학회지
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    • 제26권6호
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    • pp.420-426
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    • 2017
  • A colorimetric sensor was investigated to achieve a low-cost warning device for harmful gaseous formaldehyde (HCHO). The sensor is based on selective reactions between hydroxylamine sulfate and HCHO, leading to the production of sulfuric acid. The produced acid results in color-changing response through the acid-base reaction with dye molecules impregnated on a solid membrane substrate. For attaining this purpose, sensors were fabricated by drop-casting a dye solution prepared using different pH indicators on various commercially available polymer sheets, and their colorimetric responses were evaluated in terms of sensitivity and reliability. The colorimetric sensor using bromophenol blue (BPB) and nylon sheet was found to exhibit the best performance in HCHO detection. An initial bluish green of a sensor was changed to yellow when exposed to gaseous formaldehyde. The color change was recorded using an office scanner and further analyzed in term of RGB distance for quantifying sensor's response at different HCHO(g) concentrations. It exhibited a recognizable colorimetric response even at 50 ppb, being lower than WHO's standard of 80 ppb. In addition, the sensor was found to have quite good selectivity in HCHO detection under the presence of common volatile organic compounds such as ethanol, toluene, and hexane.

나일론 및 셀룰로스 섬유 혼입률 변화가 콘크리트의 공학적 특성에 미치는 영향 (Effect of the Nylon and Cellulose Fiber Contents on the Mechanical Properties of the Concrete)

  • 한천구;한민철;신현섭
    • 한국건축시공학회지
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    • 제7권3호
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    • pp.83-90
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    • 2007
  • This study is to investigate the effects of nylon(NY) and cellulose(CEL) fiber contents on the mechanical properties of the concrete. The results were summarized as following. Test showed that increase of NY and CEL fiber contents decreased fluidity of fresh concrete, so the loss of the fluidity would be considered when they were over added. Air contents were slight increased, but they satisfied the target air content. Bleeding capacity of concrete containing fiber significantly was declined. In addition, concrete containing higher amounts of fiber retarded setting time remarkably. Plastic shrinkage crack was reduced with the use of fiber due to increasing fiber contents and changing fiber classes, and NY fibers to prevent the plastic shrinkage crack effectively. Compressive and tensile strength of almost specimens were increased when air contents of the fresh concrete were fixed according to fiber contents, and flexural strength was increased according to fiber contents. For the impact strength of specimens, the specimen containing $0.6kg/m^3$ of NY fibers, showed the most favorable impact strength, The fiber reinforced concrete using NY fibers exhibited superior mechanical performance, and it was considered that $0.6kg/m^3$ of was desirable as the most favorable adding amount.

PTT BCF카펫과 나일론 BCF카펫의 압축특성(壓縮特性)에 관(關)한 연구(硏究) (Compressional Properties of PTT BCF and Nylon BCF Carpets)

  • 윤명희;김종준;전동원
    • 패션비즈니스
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    • 제8권5호
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    • pp.115-124
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    • 2004
  • PTT(polytrimethylene terephthalate) is a thermoplastic that can be melt-spun into fibers and has extensive applications in carpets, textiles and apparel, engineering thermoplastics, nonwovens, and films or sheets. This polymer combines the good properties of nylon and polyester. Compared with other synthetic fibers such as nylon and acrylic, the PTT fibers feel softer, dye easier with vibrant colors, stretch and recover better. Moreover, the PTT fibers for carpets resist most stainings, clean better, and dry faster. The PTT was first patented in 1941, but it was not until the 1990's, when Shell Chemicals developed the practical method of producing PDO, the raw material for PTT. Many studies have been done including the retention of carpet texture using an image analysis technique, or compressional resilience of the carpet for long term use. In this study, PTT and nylon BCF carpets were compared in terms of the compressional properties including the resilience, using one of the KES system for repetitive measurements. The compression resilience(RC) values of the PTT BCF carpets far exceed those of nylon 6 BCF carpets. The RC values of the PTT BCF carpet(cut) specimens are $42{\sim}45%$ for 5 successive compression deformations, while those of the nylon BCF carpet specimens(cut) are $26{\sim}28%$. There is also a similar trend in the RC values for the other type of carpet which is the loop type. This resilience is one of the important factors of carpet usage evaluation.

몬모릴로나이트로 강화된 폴리프로필렌/ 나일론 나노복합재료의 난연특성 및 기계적 특성 (Flame Retardancy and Mechanical Property of Polypropylene/ Nylon Nanocomposite Reinforced with Montmorillonite)

  • 이종훈;박호식;안인구;이윤희;김연수;이영관;남재도
    • 폴리머
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    • 제27권6호
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    • pp.576-582
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    • 2003
  • 열가소성 수지인 폴리프로필렌과 나일론 블렌드를 무기나노입자인 몬모릴로나이트와 상용화제 말레산 무수물 폴리프로필렌을 사용하여 복합화한 나노복합재료에 할로젠 계열의 난연제 데카브로모다이페닐옥사이드를 첨가하였을 때의 분산성과 난연특성 및 기계적 특성의 향상에 대해 실험하였다. 고분자 수지의 난연특성과 기계적 특성은 난연제의 첨가뿐만 아니라 나노복합화를 통해서도 향상될 수 있으며, 고분자 수지 내의 나노입자의 분산정도에 따라 매우 큰 차이가 생긴다. 고분자 수지와 무기나노입자 사이의 분산성과 그에 따른 난연특성 및 기계적 특성을 난연제와 무기나노입자의 함량에 .따라 정량적으로 측정하였다 폴리프로필렌/나일론 블렌드를 몬모릴로나이트로 복합화할 때 2회 이상 컴파운딩하면 완전히 분산되는 것을 XRD 결과로 확인하였다. 폴리프로필렌/나일론 블렌드를 복합화하면 나일론의 첨가로 인한 난연성의 저하를 극복할 수 있었으며, 무기나노입자가 완전히 분산되어 있을 때에는 추가적인 난연특성의 향상을 얻었다. 그리고 폴리프로필렌은 나일론의 첨가로 인하여 인장강도와 충격강도가 약간 증가하였으며, 무기나노입자와의 복합화를 통해서 추가적인 기계적 물성의 증가를 관찰하였다. 이로부터 폴리프로필렌의 기계적 물성의 향상을 위해 첨가한 나일론은 난연특성의 저하를 초래하지만 무기나노입자와의 복합화를 통해 난연특성의 향상과 추가적인 기계적 물성의 향상을 동시에 얻을 수 있었다.

군용 및 산자용 나일론 고강력 태섬사 및 후직물의 물성 분석 (Analysis on the Physical Property of Nylon High Tenacity Coarse Yarn and Fabric for Military and Technical Textiles)

  • 김승진;김상룡;이도현;최우혁
    • 한국염색가공학회지
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    • 제21권3호
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    • pp.43-48
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    • 2009
  • This paper surveys the mechanical properties of nylon high tenacity coarse yarn and fabric for military and technical textiles. For this purpose, 6 kinds of yarns and 2 kinds of fabrics are prepared. The yarn physical properties such as yarn count, thermal shrinkages, and tensile properties are measured and discussed with the characteristics of the domestic and imported yarns. And, the physical and mechanical properties of these fabrics are also measured and discussed with the usage of these fabrics in the military and technical textiles fields. Hereafter, the differences of physical properties between domestic and foreign yarn specimens for high functional military and technical fabrics are estimated through this study.

나일론/금속 접합을 위한 유도가열공정의 분석 (Analysis of the Induction Heating Process for the Joint of Nylon and Metal)

  • 장윤상;박정웅
    • 열처리공학회지
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    • 제15권5호
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    • pp.228-233
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    • 2002
  • The characteristics of the induction heating process are analyzed for the joint of nylon and metal. The temperature of metal surface is measured using thermocouples. The relations of temperature and induction heating parameters are analyzed. Heat equation models are constructed and the temperature distribution is predicted using Fluent. The effects of heating parameters on the joint strength are evaluated. Finally, the optimal parameters of induction heating process are proposed as 16kW and 6 seconds.