• Title/Summary/Keyword: Nylon 6.6

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Effects of Blend Composition and Compatibilizer on the Mechanical Properties of Polypropylene/Acrylonitrile-Butadiene-Styrene Blends (블렌드 조성과 상용화제가 폴리프로필렌/ABS 블렌드의 기계적 물성에 미치는 영향)

  • Park, Jung-Hoon;Sung, Yu-Taek;Kim, Woo-Nyon;Hong, John-Hee;Hong, Byeong-Kwon;Yoo, Tae-Wook;Yoon, Ho-Gyu
    • Polymer(Korea)
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    • v.29 no.1
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    • pp.19-24
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    • 2005
  • Polymer blends containing polypropylene (PP) with compatibilizers were prepared using twin screw extruder. Physical properties were investigated using universal test machine (UTM) and Izod impact tester. In the PP/acrylonitrilebutadiene-styrene (ABS) blends, mechanical strength was increased with the addition of PP-g-styrene acryloritrile (PP-g-SAN) compatibilizer, and the ductility was increased with the addition of ethylene-ethyl acrylate-maleic anhydride (E-EAMAH-g-SAN) compatibilizer. For the PP/ABS/ polycarbonate (PC)/Nylon-6,6 blends, impact strength was increased with the addition of ethylene glycidylmethacrylate (E-GMA compatibilizer) up to 0.5 phr. In the case of the PP/ABS/PC/Nylon-6,6/poly(methyl methacrylate) (PMMA)/poly(oxymethylene) (POM)/poly(vinyl acetate) (PVC)/poly(butylene terephthalate) (PBT) blends, mechanical properties were increased by the complex compatibilizing effects of PP-g-SAN, E-EA-MAH-g-SAN and E-GMA, respectively.

Preparation and Characterization of Nylon 6,5 Copolymers from ε-Caprolactam and 2-Piperidone (ε-Caprolactam과 2-Piperidone으로부터 나일론 6,5 공중합체 제조 및 특성평가)

  • Kim, Hye Young;Goh, Jin-Seon;Ryu, Mi Hee;Kim, Dae Su;Song, Bong-Keun;Lee, Seung Hwan;Park, Si-Jae;Jegal, Jonggeon
    • Polymer(Korea)
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    • v.38 no.1
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    • pp.31-37
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    • 2014
  • To prepare biomass based nylon 6,5 copolymers, ${\varepsilon}$-caprolactam and 2-piperidone, the monomers of nylon 6,5 copolymers, were synthesized respectively from lysine and 5-aminovaleric acid which were produced from glucose by the fermentation process. The copolymers were then polymerized by the anionic ring opening polymerization of them at $40^{\circ}C$, using potassium tert-butoxide as a catalyst and acetyl-2-caprolactam and carbon dioxide as initiators. The prepared copolymers were characterized with various analytical methods: their viscosity molecular weight ($M_{\eta}$) was as high as 30000 g/mol and polymerization yield was over 50%, and it was found that they were semi-crystalline polymers having melting point at $165^{\circ}C$ which was much lower than its thermal degradation point, $250^{\circ}C$. These polymers were expected to have good thermal processability and application fields.

Synthesis and Properties of Nylon 6/PEG Random Block Copolymer/Clay Nanocomposite via in situ Polymerization (in situ중합을 통한 나일론 6-PEG 랜덤공중합체/점토 나노복합체의 합성 및 물성)

  • Angelica S. Lopez;Pio Sifuentes;Kim, Kap-Jin
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.72-74
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    • 2003
  • There has been extensive interest in the development of new nanocomposites. One kind of these systems is the hybrid based on organic polymers and inorganic minerals consisting of layered silicates. Some properties like stiffness, strength, barrier properties, thermal, and oxidative stability can be improved by the presence of the filler in the polymeric matrix[1]. It is reported that, in the nylon 6/clay nanocomposites, the modulus is increased, but impact strength and elongation at break are drastically decreased. (omitted)

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Effect of Fabric Design Condition on the Mechanical Properties and Handle of Nylon/Cotton Union Fabrics for Sport Jacket (스포츠쟈켓용 나일론/면 교직물의 설계조건에 따른 역학적 특성과 태)

  • Kwon, Oh-Kyung;Song, Min-Kyu
    • Fashion & Textile Research Journal
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    • v.5 no.3
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    • pp.267-272
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    • 2003
  • Tactel(Nylon66) union fabrics were woven with the specification of 70d/34f nylon as warp for sport wear jacket. Weft yarn has three types; 100% cotton yarn, nylon core-spun yarn and nylon-polyurethane covering yarn as weft. Fabric structers were plain, twill and satin weave structure with the air jet loom. The mechanical properties of 8 fabrics were measured with KES-F and primary Hand Values and Total Hand Values were calculated. The results of the study were as follows: 1) There was little difference among LTs of N/CM fabric groups. RT of the fabrics with CM100's was bigger than that of fabrics with CM80's, resulting that the fabrics with CM100's have better formability. In terms of weaving structure, twill fabrics have shape deformation. 2) In comparison of RTs with weft yarn type, RT of N-PU covering yarn was the highest, followed by Nylon core-spun yarn and cotton yarn. Thus, the fabric with N-PU covering yarn has better stability of shape deformation. 3) Stretch yarn could express an excellent silhouette formation and twill and satin structures were better structure to make curvature on human form. 4) 2HG/G value of nylon core-spun fabrics was larger than that of N/C fabrics, but the silhouette formation of N/C fabrics was excellent. 5) The RC of N/PU was the highest, followed by N/P, and N/CM. 6) Koski of N/PU fabrics was the highest, Numeri of N/PU and N/Co-I were relatively higher than the others. THVs of N/CM-IV and N/CO-II were lower than the others, resulting that, twill structure was better than plain structure for a sport wear uses.

Computer Simulation of the Effects of Content and Dispersion of Impact Modifier on the Impact Strength of Nylon 6 Composites (충격보강제의 함유량과 분산이 나일론 6 복합체의 충격강도에 미치는 영향의 컴퓨터 해석)

  • Woo, Jeong Woo;Lyu, Min-Young
    • Elastomers and Composites
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    • v.49 no.4
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    • pp.284-292
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    • 2014
  • Polymer has low mechanical strength than metal. In particular, the impact strength is very weak. Impact modifier reinforced polymers are frequently used. Impact strength of reinforced polymer is changed according to content and distribution of impact modifier. In this study, izod impact test has been simulated to analyze the mechanism of impact modifier reinforced Nylon 6. Computational results were compared for numbers and distributions of impact modifier. As the total volume of rubber particles decreased, the stress at the notch increased for the simulation model that the volume decreases as particle number increases. As the surface area of particle sphere increased, the stress and difference of principle stress increased for the simulation model that the total surface increases as particle number increases.

Effects of Crack Resistance Properties of Ozone-treated Carbon Fibers-reinforced Nylon-6 Matrix Composites (탄소섬유의 오존처리가 나일론6 기지 복합재료의 크랙저항에 미치는 영향)

  • Han, Woong;Choi, Woong-Ki;An, Kay-Hyeok;Kim, Hong-Gun;Kang, Shin-Jae;Kim, Byung-Joo
    • Applied Chemistry for Engineering
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    • v.24 no.4
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    • pp.363-369
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    • 2013
  • In this work, the effects of ozone treatments on mechanical interfacial properties of carbon fibers-reinforced nylon-6 matrix composites were investigated. The surface properties of ozone treated carbon fibers were studied by Fourier transform infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS). Mechanical interfacial properties of the composites were investigated using critical stress intensity factor ($K_{IC}$). The cross-section morphologies of ozone-treated carbon fiber/nylon-6 composites were observed by scanning electron microscope (SEM). As a result, $K_{IC}$ of the ozone-treated carbon fibers-reinforced composites showed higher values than those of as-received carbon fibers-reinforced composites due the enhanced $O_{1s}/C_{1s}$ ratio of the carbon fiber by the ozone treatments. This result concludes that the mechanical interfacial properties of nylon-6 matrix composites can be controlled by suitable ozone treatments on the carbon fibers.

The Acquisition and dyeability of Gardenia jasminoides Colorant (치자색소의 염료화 및 염색성)

  • 서영숙;정지윤
    • The Research Journal of the Costume Culture
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    • v.7 no.2
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    • pp.315-322
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    • 1999
  • The acquistion and dyeability of the Gardenia jasminoides were examined to establish the optimum condition for extraction and storage in the process of obtaining the natural dye, Gardenia jasminoides colorant. Also the dyeability and colorfastness of Gardenia jasminoides were investigated. The results of this study are as follows. The optimum part-removed seed. In all experiments, the part of fat-removed seed and pericarp was used. The optimum condition for extraction of Gardenia jasminoides colorant was at 40℃ and for 90 min. in methanol. As storage temperature was higher, the absorbance of colorant extract decreased rapidly. The Gardenia jasminoides colorant exhibited dyeability to cotton, silk, wool, and nylon. The dyeability was the greatest in wool, and then nylon, silk, and cotton. Both wool and nylon had the greatest K/S value at pH3, however, nylon and cotton at pH 6 and pH 8 respectively. In addition, the increase in K/S value corresponded to temperature in wool and nylon, but the silk and cotton had the greatest K/S value at 60℃. Also, the K/S value increased in concomitant with the increased number of dyeing repetition. In the most cases, colorfastness of light was weak but colorfastness of laundry, sweat was relatively excellent.

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A Study on the Leakage Interception Work in the Irrigation Canal Founding on the Sandy Gravel or the Porous Soil (모래자갈과 누수성 토질을 기반으로하는 용수로의 누수방지에 대한 연구)

  • 강신업
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.12 no.2
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    • pp.1965-1970
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    • 1970
  • The experiment was carried out in order to improve the leakage stopping work in the irrigation canal founding on the porous soil. But the experiment had many problems to be studied more owing to the insufficient time and facilities. The results obtained are summarized as follows; 1. Polyethylene film is estimated not to make strength decrease owing to buring in the subsoil, but to make owing to the sunlight. 2. Coated nylon shows the tendency to deteriorate strength when it is buried in the earth or exposed to the sun for long time, but leakage is all but impermeability generally. 3. Leakage loss rates for one hour show some differences in the canal to be full with water in accordance with operating methods, that is, the clay lining section is 12.6%, the coated nylon lining section is 1.7%, the polyethylene film lining section is 1.3%, respectively. 4. Leakage quantities per wetted perimeter unit area show $3.556cc/cm^2/hr$. in the clay lining section, $1.574cc/cm^2/hr$. in the coated nylon section, $0.695cc/cm^2/hr$. in the polyethylene film lining section, respectively. 5. When the construction fund make the clay lining section as a standard, the polyethylene film section is 92.1%, the coated nylon section is 174.2%, respectively. But, the unit cost of execution may be low when the polyethylene film and the coated nylon will enable to mass-produce for the purpose of execution.

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Preparation, Physical Characteristics and Antibacterial Finishing of PCM/Nylon Fibers having Sheath/Core Structure (상전이물질(PCM)과 Nylon 6를 이용한 Sheath/Core 형태의 복합섬유 제조, 물리적 특성 및 항균가공특성 연구)

  • Kim, Hak-Soo;Hwang, Ji-Yong;Lim, Sang-Hyun;Lim, Jeong-Nam;Son, Young-A
    • Textile Coloration and Finishing
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    • v.26 no.4
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    • pp.311-321
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    • 2014
  • In this study, Aftertreatment properties of PCM/Nylon sheath/core fabrics have been determined. Especially, the relationship between finishing property and content including of PCM ratio. Samples of PCM/Nylon fabrics were monitored, separately, with 2% o.w.f solutions of each of the berberine chloride, cetylpyridinium chloride(CPC), benzyldimethylhexadecyl ammonium chloride(BDHAC) and dodecyltrimetyl ammonium bromide(DTAB). Various temperatures and liquor ratio and pH conditions were also studied to optimize aftertreatment properties. Berberine chloride finished sample showed the good color fastness. Cetylpyridinium chloride(CPC) finished sample showed very effective antibacterial properties against Staphylococcus aureus and Klebsiella pneumoniae.