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Silver nanowires and nanodendrites synthesized by plasma discharge in solution for the catalytic oxygen reduction in alkaline media

  • Kim, Hoe-Geun;Song, Myeon-Gyu;Kim, Dong-U;Lee, Sang-Yul
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.62-62
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    • 2018
  • Pt is still considered as one of the most active electrocatalysts for ORR in alkaline fuel cells. However, the high cost and scarcity of Pt hamper the widespread commercialization of fuel cells. As a strong candidate for the replacement of Pt catalyst, silver (Ag) has been extensively studied due to its high activity, abundance, and low cost. Ag is more stable than Pt in the pH range of 8~14 as the equilibrium potential of Ag/Ag+ being ${\approx}200mV$ higher than that of Pt/PtO. However, Ag is the overall catalytic activity of Ag for oxygen reduction reaction(ORR) is still not comparable to Pt catalyst since the surface Ag atoms are approximately 10 times less active than Pt atoms. Therefore, further enhancement in the ORR activity of Ag catalysts is necessary to be competitive with current cutting-edge Pt-based catalysts. We demonstrate the architectural design of Ag catalysts, synthesized using plasma discharge in liquid phase, for enhanced ORR kinetics in alkaline media. An attractive feature of this work is that the plasma status controlled via electric-field could form the Ag nanowires or dendrites without any chemical agents. The plasma reactor was made of a Teflon vessel with an inner diameter of 80 mm and a height of 80 mm, where a pair of tungsten(W) electrodes with a diameter of 2 mm was placed horizontally. The stock solutions were made by dissolving the 5-mM AgNO3 in DI water. For the synthesis of Agnanowires, the electricfield of 3.6kVcm-1 in a 200-ml AgNO3 aqueous solution was applied across the electrodes using a bipolar pulsed power supply(Kurita, Seisakusyo Co. Ltd). The repetition rate and pulse width were fixed at 30kHz and 2.0 us, respectively. The plasma discharge was carried out for a fixed reaction time of 60 min. In case of Ag nanodendrites, the electric field of 32kVcm-1 in a 200-ml AgNO3 aqueous solution was applied and other conditions were identical to the plasma discharge in water in terms of electrode configuration, repetition rate and discharge time. Using SEM and STEM, morphology of Ag nanowires and dendrites were investigated. With 3.6 kV/cm, Ag nanowire was obtained, while Ag dendrite was constructed with 32 kV/cm. The average diameter and legth of Ag nanowireses were 50 nm and 3.5 um, and thoes values of Ag dendrites were 40 nm and 3.0 um. As a results of XPS analysis, the surface defects in the Ag nanowires facilitated O2 incorporation into the surface region via the interaction between the oxygen and the electron cloud of the adjacent Ag atoms. The catalytic activity of Ag for oxygen reduction reaction(ORR) showed that the catalytic ORR activity of Ag nanowires are much better than Ag nanodendrites, and electron transfer number of Ag nanowires is similar to that of Pt (${\approx}4$).

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Anti-collision algorithm using Bin slot information for UHF (Bin 슬롯 정보를 이용한 UHF 대역 Anti-collision 알고리즘)

  • Choi Ho-Seung;Kim Jae-Hyun
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.43 no.1 s.343
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    • pp.41-48
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    • 2006
  • An anti-collision algorithm is very important in the RFID system because it decides tag identification time and tag identification accuracy. We propose improved anti-collision algorithms using Bin slot in RFID system. In the proposed algorithms, if the reader memorizes the Bin slot information, it can reduce the repetition of unnecessary PingID command and the time to identify tags. If we also use ScrollA11ID command in the proposed algorithm, the reader knows the sequence of collided E bits. Using this sequence, the reader can reduce the repetition of PingID command and tag identification time. We analyze the performance of the proposed anti-collision algorithms and compare the performance of the proposed algorithms with that of the conventional algorithm. We also validate analytic results using simulation. According to the analysis, for the random tag n, comparing the proposed algorithms with the conventional algorithm, the performance of the proposed algorithms is about $130\%$ higher when the number of the tags is 200. And for the sequential tag ID, the performance of the conventional algorithm decreases. On the contrary, the performance of the proposed algerian using ScrollA11ID command is about $16\%$ higher than the case of using random tag ID.

Data Allocation for Multiple Broadcast Channels (다중 방송채널을 위한 데이타 할당)

  • Jung Sungwon;Nam Seunghoon;Jeong Horyun;Lee Wontaek
    • Journal of KIISE:Databases
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    • v.33 no.1
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    • pp.86-101
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    • 2006
  • The bandwidth of channel and the power of the mobile devices are limited on a wireless environment. In this case, data broadcast has become an excellent technique for efficient data dissemination. A significant amount of researches have been done on generating an efficient broadcast program of a set of data items with different access frequencies over multiple wireless broadcast channels as well as single wireless broadcast channel. In this paper, an efficient data allocation method over multiple wireless broadcasting channels is explored. In the traditional approaches, a set of data items are partitioned into a number of channel based on their access probabilities. However, these approaches ignore a variation of access probabilities of data items allocated in each channel. In practice, it is difficult to have many broadcast channels and thus each channel need to broadcast many data items. Therefore, if a set of data items broadcast in each channel have different repetition frequencies based on their access frequencies, it will give much better performance than the traditional approaches. In this paper, we propose an adaptive data allocation technique based on data access probabilities over multiple broadcast channels. Our proposed technique allows the adaptation of repetition frequency of each data item within each channel by taking its access probabilities into at count.

Effect of repeated learning for two dental CAD software programs (두 종의 치과용 캐드 소프트웨어에 대한 반복학습의 효과)

  • Son, KeunBaDa;Lee, Wan-Sun;Lee, Kyu-Bok
    • Journal of Dental Rehabilitation and Applied Science
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    • v.33 no.2
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    • pp.88-96
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    • 2017
  • Purpose: The purpose of this study is to assess the relationship between the time spent designing custom abutments and repeated learning using dental implant computer aided design (CAD) software. Materials and Methods: The design of customized abutments was performed four stages using the 3DS CAD software and the EXO CAD software, and measured repeatedly three times by each stage. Learning effect by repetition was presented with the learning curve, and the significance of the reduction in the total time and the time at each stage spent on designing was evaluated using the Friedman test and the Wilcoxon signed rank test. The difference in the design time between groups was analyzed using the repeated measure two-way ANOVA. Statistical analysis was performed using the SPSS statistics software (P < 0.05). Results: Repeated learning of the customized abutment design displayed a significant difference according to the number of repetition and the stage (P < 0.001). The difference in the time spent designing was found to be significant (P < 0.001), and that between the CAD software programs was also significant (P = 0.006). Conclusion: Repeated learning of CAD software shortened the time spent designing. While less design time on average was spent with the 3DS CAD than with the EXO CAD, the EXO CAD showed better results in terms of learning rate according to learning effect.

K-th Path Search Algorithms with the Link Label Correcting (링크표지갱신 다수경로탐색 알고리즘)

  • Lee, Mee-Young;Baik, Nam-Cheol;Choi, Dae-Soon;Shin, Seong-Il
    • Journal of Korean Society of Transportation
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    • v.22 no.2 s.73
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    • pp.131-143
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    • 2004
  • Given a path represented by a sequence of link numbers in a graph, the vine is differentiated from the loop in a sense that any link number can be visited in the path no more than once, while more than once in the loop. The vine provides a proper idea on complicated travel patterns such as U-turn and P-turn witnessed near intersections in urban transportation networks. Application of the link label method(LLM) to the shortest Path algorithms(SPA) enables to take into account these vine travel features. This study aims at expanding the LLM to a K-th path search algorithm (KPSA), which adopts the node-based-label correcting method to find a group of K number of paths. The paths including the vine type of travels are conceptualized as drivers reasonable route choice behaviors(RRCB) based on non-repetition of the same link in the paths, and the link-label-based MPSA is proposed on the basis of the RRCB. The small-scaled network test shows that the algorithm sequence works correctly producing multiple paths satisfying the RRCB. The large-scaled network study detects the solution degeneration (SD) problem in case the number of paths (K) is not sufficient enough, and the (K-1) dimension algorithm is developed to prevent the SD from the 1st path of each link, so that it may be applied as reasonable alternative route information tool, an important requirement of which is if it can generate small number of distinct alternative paths.

Effect of Motor Cues and Secondary Task Complexity on Driving Performance and Task Switching While Driving (운전 중 IVIS 조작 상황에서 Motor Cue와 과제의 난이도가 과제 전환과 운전 주행에 미치는 영향)

  • Ryoo, Eunhyun;Han, Kwanghee
    • Science of Emotion and Sensibility
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    • v.21 no.2
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    • pp.29-42
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    • 2018
  • As information technology is more actively incorporated into automobiles, the role of IVIS (In-Vehicle Infotainment System) is becoming increasingly important for providing convenience and entertainment for drivers. However, using the infotainment systems while driving requires task switching and attending to two visual resources simultaneously. We simulated a setting where participants have to drive while interacting with the infotainment system and examined how task difficulty and motor cues impact driver task-switching and driving performance, specifically whether the effects of motor cues differ depending on task difficulty. For the infotainment display, we used two types of number array depending on the congruency between the digit repetition and the chunking unit, while task difficulty was manipulated by the size of the touch-keys. Participants were instructed to dial two numbers on the screen while we recorded the dialing time, lateral position, inter-key press intervals, and steering wheel control. We found that dialing time and lateral position were affected by task difficulty, while the type of number array had no effect. However, the inter-key press intervals between chunked numbers and steering wheel movement both increased when participants had to use an incongruent number array, which indicates that, if number digits are repeated, chunking is ignored by the drivers. Our findings indicate that, in a dual-task condition, motor cues offset the effect of chunking and can effectively signal the timing for task switching.

Characteristics of Waste Brine from the Salting Process of Chinese Cabbage (배추의 절임공정 중 폐염수의 특성)

  • Yoon, Hye-Hyun;Jeon, Eun-Jae;Sung, Soon-Jung;Kim, Dong-Man
    • Korean Journal of Food Science and Technology
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    • v.32 no.1
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    • pp.97-101
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    • 2000
  • Major characteristics of waste brine from the repeated salting and rinsing processes of Chinese cabbage for Kimchi were investigated. Salt concentration of brine was increased with the number of successive salting steps from 12% after 1st salting step to 14% after 5th step. Total waste brine which is the representative of wastewater produced from salting process of cabbage showed 6-8% salt concentration. The pH values in all samples decreased with the number of reuse of brine and showed pH 5.9 and pH 5.2 for the mixture of brine for quarter-cut and small-cut cabbage, respectively, after 5th salting process. Soluble solid contents increased with repetition and resulted in 14-16 $^{\circ}Brix$. Total brine showed increased COD values with the number of reuse of brine and 40-50 ppm of COD values for both quarter-cut and small-cut cabbages.

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The Narrative Structure and Musical Number's Dramatic Function in Musical "Ah! My Goddess" (뮤지컬 <여신님이 보고 계셔>의 서사 구조와 뮤지컬 넘버의 극적 기능)

  • Shin, Sa-Bin;Lee, Woo-Chang
    • The Journal of the Korea Contents Association
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    • v.14 no.3
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    • pp.113-124
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    • 2014
  • Ah! My Goddess has impressive narrative structure including a "narrative as a discourse," a "narrative as a story" and a "narrative by narrator": in a narrative as a discourse, North and South Korean soldiers make friendship; in a narrative by a narrator, main characters (including Sun-ho, Seok-gu, Ju-hwa, Chang-seop and Dong-hyeon) appear in the outer story and narrate the inner story of characters (including Dong-hyeon, Goddess and Seok-gu) within the frame of a play within a play; and in a narrative as a story, reality and fantasy intersect by the appearance of the "Goddess." This narrative structure contributes largely to 1) the character formation of space, 2) the strategic minimization of the stage, 3) the multiplicity of main characters, 4) the repetition of similar life story, and 5) the flexible change of a point of view. And the musical number serves as dramatic functions such as 1) pursuing the multiplicity of characters, 2) maximizing the effect of the expression of tragic feelings, 3) drawing audience's interest by irony and fantasy, 4) evoking the nostalgia for delicate feelings and pure wishes, and 5) ordinary female characters' playing the role of healing and salvation, thereby contributing to the reconstruction of reality and the style of fantasy.

Assessment of Public Awareness on Invasive Alien Species of Freshwater Ecosystem Using Conservation Culturomics (보전문화체학 접근방식을 통한 생태계교란 생물인 담수 외래종의 대중인식 평가)

  • Park, Woong-Bae;Do, Yuno
    • Journal of Wetlands Research
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    • v.23 no.4
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    • pp.364-371
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    • 2021
  • Public awareness of alien species can vary by generation, period, or specific events associated with these species. An understanding of public awareness is important for the management of alien species because differences in public awareness can affect the establishment and implementation of management plans. We analyzed digital texts on social media platforms, news articles, and internet search volumes used in conservation culturomics to understand public interest and sentiment regarding alien freshwater species. The number of tweets, number of news articles, and relative search volume to 11 freshwater alien species were extracted to determine public interest. Additionally, the trend over time, seasonal variability, and repetition period of these data were confirmed. We also calculated the sentiment score and analyzed public sentiment in the collected data using sentiment analysis based on text mining techniques. The American bullfrog, nutria, bluegill, and largemouth bass drew relatively more public interest than other species. Some species showed repeated patterns in the number of Twitter posts, media coverage, and internet searches found according to the specified periods. The text mining analysis results showed negative sentiments from most people regarding alien freshwater species. Particularly, negative sentiments increased over the years after alien species were designated as ecologically disturbing species.

Effect of Exposed Length of Rootstocks on the Occurrence of Bitter Pit and Tree Vigor of 'Gamhong'/M.26 Apple Cultivar

  • Kang, Seok-Beom;Moon, Young-Eel;Kweon, Hun-Joong;Park, Moo-Yong;Park, Woo-Jung;Sagong, Dong-Hoon
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.5
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    • pp.449-455
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    • 2016
  • 'Gamhong' apple cultivar which was bred by National Institute of Horticultural and Herbal Science, has high sugar contents, large types of fruit and mid-season types of cultivar. However, 'Gamhong' apple tree is very sensitive cultivar to bitter pit. Therefore, many farms have not solved the problems on bitter pit to cultivate 'Gamhong' apple tree. This study was carried out to find out the exposed length of rootstocks on the occurrence of bitter pit and fruit quality of 'Gamhong'/M.26 apple tree and seek the ideal cultivation strategy to decrease bitter pit to cultivate it. For this research, ten-years-old 'Gamhong'/M.26 apple trees were used. The difference among the treatments of the exposure of rootstock of RL (5 cm), RM (15 cm) and RH (20 cm) from the soil surface was observed with 4 repetition from 2010 to 2011. Decreased exposure of rootstocks resulted in more vigorous growth, taller height, and greater number of shoots. N and K/Ca of RH was tend to be lower than RM and RL, whereas as the exposure of rootstock decreased, fruit weight and bitter pit increased. Therefore, occurrence of bitter pit in RH was significantly lower than that of RM and RL treatment and fruit weight also decreased. There was no difference on nutrient contents of leaf and the fruit quality by the exposed of rootstock in 'Gamhong' M.26 apple tree. To reduce the occurrence of bitter pit, it may be helpful to keep the optimum exposure of rootstock within 20 cm from the soil surface.