• Title/Summary/Keyword: Nucleation-model

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Bubble Nucleation in Polymer Solutions (고분자 용액에서의 기포 형성)

  • 강성린;김기영;곽호영
    • Polymer(Korea)
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    • v.28 no.1
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    • pp.51-58
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    • 2004
  • The molecular cluster model for the homogeneous bubble nucleation rather than the classical nucleation theory was extended to predict the bubble nucleation events in elastomers(cross-linked polymers), polymers and polymer which are dissolved in the organic solvent. The classical theory assumes the formation of the critical bubble while the molecular cluster model assumes the critical cluster as for the initiation of the bubble nucleation. For the bubble nucleation in elastomers and polymers, the strain energy overcome by a critical bubble was also considered. The calculation results for the number of bubbles nucleated in elastormers and polymer solutions, which are about 10$\^$8/∼10$\^$12/ bubbles/㎤ are in good agreement with observed ones.

Bubble Nucleation in Polymer Solutions (폴리머 용액에서의 기포 형성)

  • Kang, Sung-Lin;Kim, Ki-Young;Kwak, Ho-Young
    • Proceedings of the KSME Conference
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    • 2003.11a
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    • pp.1228-1233
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    • 2003
  • The molecular cluster model for the homogeneous bubble nucleation was extended to predict the bubble nucleation events in elastomers, polymers and polymer solutions. For the bubble nucleation in elastomers and polymers, the strain energy overcome by a critical bubble was also considered. The calculation results for the number of bubbles nucleated are in good agreement with observed ones.

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Vapor Bubble Nucleation : A Microscopic Phenomenon

  • Kwak, Ho-Young
    • Journal of Mechanical Science and Technology
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    • v.18 no.8
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    • pp.1271-1287
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    • 2004
  • In this article, vapor bubble nucleation in liquid and the evaporation process of a liquid droplet at its superheat limit were discussed from the viewpoint of molecular clustering (molecular cluster model for bubble nucleation). For the vapor bubble formation, the energy barrier against bubble nucleation was estimated by the molecular interaction due to the London dispersion force. Bubble nucleation by quantum tunneling in liquid helium under negative pressure near the absolute zero temperature and bubble nucleation on cavity free micro heaters were also presented as the homogenous nucleation processes.

A Physically Based Dynamic Recrystallization Model for Predicting High Temperature Flow Stress (열간 유동응력 예측을 위한 물리식 기반 동적 재결정 모델)

  • Lee, H.W.;Kang, S.H.;Lee, Y.S.
    • Transactions of Materials Processing
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    • v.22 no.8
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    • pp.450-455
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    • 2013
  • In the current study, a new dynamic recrystallization model for predicting high temperature flow stress is developed based on a physical model and the mean field theory. In the model, the grain aggregate is assumed as a representative volume element to describe dynamic recrystallization. The flow stress and microstructure during dynamic recrystallization were calculated using three sub-models for work hardening, for nucleation and for growth. In the case of work hardening, a single parameter dislocation density model was used to calculate change of dislocation density and stress in the grains. For modeling nucleation, the nucleation criterion developed was based on the grain boundary bulge mechanism and a constant nucleation rate was assumed. Conventional rate theory was used for describing growth. The flow stress behavior of pure copper was investigated using the model and compared with experimental findings. Simulated results by cellular automata were used for validating the model.

A Verification of Diamond Nucleation Model

  • Yugo, S.;Kimura, T.
    • The Korean Journal of Ceramics
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    • v.2 no.4
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    • pp.181-183
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    • 1996
  • We found that our initial model agrees with most of the recent reports; however, it does not agree with some of them with respect to the kinetics of nucleus formation. This disagreement stems from the question of whether or not a nucleus precursor should be treated as an embryonic cluster.

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Modeling Heterogeneous Wall Nucleation in Flashing Flow of Initially Subcooled Water

  • Park, Jong-Woon
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05b
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    • pp.241-246
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    • 1996
  • An analytical model to calculate rate of vapor generation due to heterogeneous wall nucleation in flashing flow is developed. In the present model, an important parameter of the vapor generation term, i.e. nucleation site density is calculated by integrating its probability distribution function with respect to active cavity radius. The limits of integration are minimum and maximum active cavity radii, and these are formulated using an active cavity model for nucleate boiling. This formulation, therefore. can statistically account for the effect of surface specific thermo-physical and geometric conditions on the vapor generation rate and flashing inception. For verifying the adequacy of the present model, steady state two-fluid and the bubble transport equations are solved with applicable constitutive equations. The applicable region of the bubble transport equation is also extended to churn-turbulent flow regime to predict interfacial area concentration at high void fraction. Predicted results in terms of axial pressure and void fraction profiles along the channels are compared with experimental data of Super Moby Dick and BNL Reasonable agreements have been achieved and this shows the applicability of the present model to flashing flow analysis.

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Modeling of Defects Nucleation in the Inhomogeneous Liquid Crystal Director Field

  • Lee Gi-Dong;Kim Jae Chang
    • Journal of the Optical Society of Korea
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    • v.9 no.2
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    • pp.74-78
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    • 2005
  • With the fast Q-tensor method, which can model the defect dynamics in a liquid crystal director field, the nucleation and dynamical behavior of defects is modeled. In order to model the defect, hormeotropic aligned liquid crystal cell with step inhomogeneous electrode which has a height of $1\;{\mu}m$ is used. From the simulation, we can observe the nucleation and line of the defect from surface inhomogeneity and the experiment is performed for confirmation. The experimental result is compared with numerical modeling in order to verify the simulation of the defect nucleation.

Numerical modeling of defects nucleation in the liquid crystal devices with inhomogeneous surface (액정 디스플레이 소자 내에서의 불균일한 표면에 의한 결점의 발생과 모델링)

  • Lee Gi-dong;Kang Bongsoon
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.9 no.8
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    • pp.1793-1798
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    • 2005
  • We model the nucleation and motion of defects in the liquid crystal display device with inhomogeneous surface by using fast Q-tensor method, which can calculate scalar order parameter S and nucleation of the defect in the liquid crystal director field. In order to model the defect, homeotropic aligned liquid crystal cell with step inhomogeneous electrode which has a height of $1{\mu}m$ is used. From the simulation, we can observe the nucleation and line of the defect from surface inhomogeneity and the experiment is performed for confirmation.

Unequal Activation Volumes of Wall-motion and Nucleation Process in Co/Pt Multilayers

  • Cho, Yoon-Chul;Choe, Sug-Bong;Shin, Sung-Chul
    • Journal of Magnetics
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    • v.5 no.4
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    • pp.116-119
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    • 2000
  • Magnetic field dependence of magnetization reversal in Co/Pt multilayers was quantitatively investigated. Serial samples of Co/Pt multilayers were prepared by dc-magnetron sputtering under various Ar pressures. Magnetization reversal was monitored by magnetization viscosity measurement and direct domain observation using a magneto-optical microscope system, and the wall-motion speed V and the nucleation rate R were determined using a domain reversal model based on time-resolved domain reversal patterns. Both V and R were found to be exponentially dependent on the applied reversing field. From the exponential dependencies, the activation volumes for wall motion and nucleation could be determined, based on a thermally activated relaxation model, and the wall-motion activation volume was found to be slightly larger than the nucleation activation volume.

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Effect of Hexa-methylenetetramine (HMT) on Nucleation and Growth Behaviors of Ni(OH)2 Nanosheets Produced by Electrodeposition (전착법으로 제작한 Ni(OH)2 나노 시트의 핵 형성과 성장 거동에 미치는 헥사-메틸렌테트라민(HMT)의 영향)

  • Kim, Dong Yeon;Son, Injoon;Choi, Mun-Hyun
    • Journal of the Korean institute of surface engineering
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    • v.54 no.1
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    • pp.37-42
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    • 2021
  • Electrodeposition is a synthetic method that allows fine control of the nucleation and growth factors of metals and is a suitable method for studying the nucleation and growth of Ni(OH)2. Hexa-methylenetetramine (HMT) helps to form Ni(OH)2 nanosheets by increasing the OH- of the nickel precursor solution and helps to improve the electrochemical properties of the electrode. In this study, the structural properties of Ni(OH)2 nanosheets according to the HMT concentration change using electrodeposition were studied. As the concentration of HMT increased, the size and thickness of the Ni(OH)2 nanosheet adsorbed on the surface increased and porosity increased. Also, the Scharifker-Hills nucleation theory model and experimental data were compared. In conclusion, the nanosheet shape of the HMT 7.5 mM sample electrodeposited with -0.85 V vs. Ag/AgCl grew most uniformly, and the best result was obtained as an electrode material for a pseudocapacitor.