• Nuclear Engineering and Technology
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• v.55 no.8
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• pp.2889-2896
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• 2023

The waste acceptance criteria for heavy metals in mixed waste should be developed by reflecting the leaching behaviors that could highly depend on the repository design and environment surrounding the waste. The current standards widely used to evaluate the leaching characteristics of heavy metals would not be appropriate for the silo-type repository since they are developed for landfills, which are more common than a silo-type repository. This research aimed to explore the leaching behaviors of cementitious waste with Pb, Cd, and Sb metallic and oxide powders in an environment simulating a silo-type radioactive waste repository. The Toxicity Characteristic Leaching Procedure (TCLP) and the ANS 16.1 standard were employed with standard and two modified solutions: concrete-saturated deionized and underground water. The compositions and elemental distribution of leachates and specimens were analyzed using an inductively coupled plasma optical emission spectrometer (ICP-OES) and energy-dispersive X-ray spectroscopy combined with scanning electron microscopy (SEM-EDS). Lead and antimony demonstrated high leaching levels in the modified leaching solutions, while cadmium exhibited minimal leaching behavior and remained mainly within the cement matrix. The results emphasize the significance of understanding heavy metals' leaching behavior in the repository's geochemical environment, which could accelerate or mitigate the reaction.

• Journal of Advanced Engineering and Technology
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• v.6 no.2
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• pp.125-129
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• 2013

In the pyrochemcial process of spent nuclear fuel, it is necessary to separate rare earth nuclides from LiCl-KCl eutectic waste salt for radioactive waste reduction. This paper presents the phosphorylation of neodymium chloride in LiCl-KCl-NdCl₃ system using Li₃PO₄-K₃PO₄ as a phosphorylation agent in a chemical reactor with pitched blade impellers. The phosphorylation test was performed changing operation temperature, stirring rate, and amount of phosphorylation agent. Neodymium chloride was effectively converted into neodymium phosphate (NdPO₄). It was confirmed that more than 99 wt% of neodymium can be separated from LiCl-KCl-NdCl₃ system using a phosphorylation method l

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.19 no.4
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• pp.435-446
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• 2021

This article examines the consequences of a significant spent fuel management decision or event in the United States, South Korea and Taiwan. For the United States, it is the financial impact of the Department of Energy's inability to take possession of spent fuel from commercial nuclear power companies beginning in 1998 as directed by Congress. For South Korea, it is the potential financial and socioeconomic impact of the successful construction, licensing and operation of a low and intermediate level waste disposal facility on the siting of a spent fuel/high level waste repository. For Taiwan, it is the operational impact of the Kuosheng 1 reactor running out of space in its spent fuel pool. From these, it draws six broad lessons other countries new to, or preparing for, nuclear energy production might take from these experiences. These include conservative planning, treating the back-end of the fuel cycle holistically and building trust through a step-by-step approach to waste disposal.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2012.10a
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• pp.325-326
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• 2012

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.17 no.4
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• pp.389-403
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• 2019

Large amounts of concrete waste are likely to arise from the decommissioning of a Kori-1 nuclear power plant. Several studies have been conducted on decommissioning concrete waste in recent decades, however, they have been limited to contaminated concrete issues or were small pilot-scale experiments. This study constructed two industrial-scale models of on-site concrete waste management for clean as well as contaminated concrete. To evaluate the performance of both the models, simulations were conducted using the Flexsim software. The concrete particle size distribution of Kori-1 and concrete processor properties based on widely used construction equipment were used as sources of input data for the simulations. It was observed that it may take over two years to complete the on-site concrete management processes owing to the performance of existing processors. In addition, it was demonstrated that it is essential to identify bottlenecks in the system and enhance the performance of the relevant processors to avoid delays of the decommissioning schedule. Our results suggest that this novel approach can contribute to developing schedules or expediting delayed activities in the Kori-1 decommissioning project.

• Nuclear Engineering and Technology
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• v.52 no.4
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• pp.797-801
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• 2020

Most of irradiated graphite that should be disposed comes from moderators and reflectors of nuclear power plants. The quantity of irradiated graphite could be higher in the future if high-temperature reactors (HTRs) will be deployed. In this case noteworthy quantities of fuel pebbles containing semi-graphitic carbonaceous material should be added to the already existing 250,000 tons of irradiated graphite. Industry graphite is largely used in industrial applications for its high thermal and electrical conductivity and thermal and chemical resistance, making it a valuable material. Irradiated graphite constitutes a waste management challenge owing to the presence of long-lived radionuclides, such as ¹⁴C and ³⁶Cl. In the ENEA Nuclear Material Characterization Laboratory it has been successfully designed a procedure based on the exfoliation process organic solvent assisted, with the purpose of investigate the possibility of achieving graphite significantly less toxic that could be recycled for other purpose [1]. The objective of this paper is to evaluate the possibility of the scalability from laboratory to industrial dimensions of the exfoliation process and provide the prototype of a chemical plant for the treatment of irradiated graphite.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.15 no.4
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• pp.301-312
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• 2017

The concept of deep borehole disposal (DBD) for high-level nuclear wastes has been around for about 40 years. Now, the Department of Energy (DOE) in the United States (U.S.) is re-examining this concept through recent studies at Sandia National Laboratory and a field test. With DBD, nuclear waste will be emplaced in boreholes at depths of 3 to 5 km in crystalline basement rocks. Thinking is that these settings will provide nearly intact rock and fluid density stratification, which together should act as a robust geologic barrier, requiring only minimal performance from the engineered components. The Nuclear Waste Technical Review Board (NWTRB) has raised concerns that the deep subsurface is more complicated, leading to science, engineering, and safety issues. However, given time and resources, DBD will evolve substantially in the ability to drill deep holes and make measurements there. A leap forward in technology for drilling could lead to other exciting geological applications. Possible innovations might include deep robotic mining, deep energy production, or crustal sequestration of $CO_2$, and new ideas for nuclear waste disposal. Novel technologies could be explored by Korean geologists through simple proof-of-concept experiments and technology demonstrations.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2019.05a
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• pp.59-60
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• 2019

• Journal of Nuclear Fuel Cycle and Waste Technology
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• v.1 no.1
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• pp.9-27
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• 2013

Nagra was established in 1972 by the Swiss nuclear power plant operators and the Federal Government to implement permanent and safe disposal of all types of radioactive waste generated in Switzerland. The Swiss Nuclear Energy Act specifies that these shall be disposed of in deep geological repositories. A number of different geological formations and sites have been investigated to date and an extended database of geological characteristics as well as data and state-of-the-art methodologies required for the evaluation of the long-term safety of repository systems have been developed. The research, development, and demonstration activities are further supported by the two underground research facilities operating in Switzerland, the Grimsel Test Site and the Mont Terri Project, along with very active collaboration of Nagra with national and international partners. A new site selection process was approved by the Federal Government in 2008 and is ongoing. This process is driven by the long-term safety and feasibility of the geological repositories and is based on a step-wise decision-making approach with a strong participatory component from the affected communities and regions. In this paper a brief history and the current status of the Swiss radioactive waste management program are presented and special characteristics that may be useful beyond the Swiss program are highlighted and discussed.

• Nuclear Engineering and Technology
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• v.53 no.5
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• pp.1524-1533
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• 2021

The structural stability of a waste package is essential for containing radioactive waste for the long term in a repository. A silo-type disposal facility would require more severe verification for the structural integrity, because of radioactive waste packages staked with several tens of meters and overburdens of crushed rocks and shotcretes. In this study, structural safety was analyzed for a silo-type repository, located approximately 100 m below sea level in Gyeongju, Korea. Finite element simulation was performed to investigate the influence of the loads from the backfilling materials and waste package stacks on the mechanical stress of the disposed of wastes and containers. It was identified that the current design of the waste package and the compressive strength criterion for the solidified waste would not be enough to maintain structural stability. Therefore, an enhanced criterion for the compressive strength of the solidified waste and several reinforced structural designs for the disposal concrete container were proposed to prevent failure of the waste package based on the results of parametric studies.