• Title/Summary/Keyword: Nonthermal

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Effect of Hydrocarbons on the Promotion of NO-$NO_2$ Conversion in NonThermal Plasma DeNOx Treatment (비열 플라즈마에 의한 NO의 산화에 탄화수소 첨가제가 미치는 영향)

  • Shin, Hyun-Ho;Yoon, Woong-Sup
    • 한국연소학회:학술대회논문집
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    • 2000.12a
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    • pp.33-46
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    • 2000
  • In the present study, a systematic chemical kinetic calculations were made to investigate the augmentation of NO-$NO_2$ conversion due to the addition of various hydrocarbons (methane, ethylene, ethane, propene, propane) in the nonthermal plasma treatment. It is included in the present conclusion that the reaction between hydrocarbon and oxygen radicals induced by electron collision, is believed to be a primarily process for triggering the overall NO oxidation and the eventual NOx reduction. Upon the completion of the initiating step, various radicals (OH, $NO_2$ etc.) successively produced by hydrocarbon decomposition form the primary path of NO-$NO_2$ conversion. When the initiating step is not activated, hydrocarbon consumption rate appeared to be very low, thereby the targeted level of NO conversion can only be achieved by the addition of more input energy. Present study showed ethylene and propene to have higher affinity with 0 radical under all conditions, thereby both of these hydrocarbons show very fast and efficient NO-$NO_2$ oxidation. It was also shown that propene is superior to ethylene in the aspect of NOx removal.

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Effect of Hydrocarbons on the Promotion of $NO-NO_{2}$ Conversion in NonThermal Plasma DeNOx Treatment (비열 플라즈마에 의한 NO의 산화에 탄화수소 첨가제가 미치는 영향)

  • Shin, Hyun-Ho;Yoon, Woong-Sup
    • 한국연소학회:학술대회논문집
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    • 2000.05a
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    • pp.178-188
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    • 2000
  • In the present study, a systematic chemical kinetic calculations were made to investigate the augmentation of $NO-NO_{2}$ conversion due to the addition of various hydrocarbons (methane, ethylene, ethane, propene, propane) in the nonthermal plasma treatment. It is included in the present conclusion that the reaction between hydrocarbon and oxygen radicals induced by electron collision, is believed to be a primarily process for triggering the overall NO oxidation and the eventual NOx reduction. Upon the completion of the initiating step, various radicals (OH, $HO_{2}$ etc.) successively produced by hydrocarbon decomposition form the primary path of $NO-NO_{2}$ conversion. When the initiating step is not activated, hydrocarbon consumption rate appeared to be very low, thereby the targeted level of NO conversion can only be achieved by the addition of more input energy. Present study showed ethylene and propene to have higher affinity with 0 radical under all conditions, thereby both of these hydrocarbons show very fast and efficient $NO-NO_{2}$ oxidation. It was also shown that propene is superior to ethylene in the aspect of NOx removal.

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Removal Characteristics of Soot and NO by Nonthermal Plasma and Radical in a Diesel Engine (비열플라즈마와 라디칼을 이용한 디젤엔진의 매연 및 NO 제거 특성)

  • Jang, Yeong-Jun;Choe, Seung-Hwan;Kim, Gyu-Bo;Jeon, Chung-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.4
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    • pp.547-554
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    • 2002
  • We are facing the serious environmental pollution difficulties such as acid rain, green house effects, etc. The gaseous matter NOx, SOx, VOCs which are regarded as main factors for these current pollutions are mainly emitted from power plants and vehicles. Therefore several leading countries are regulating the emissions strictly, especially the exhaust emissions from a Diesel engine without an aftertreatment device. The objective of this study is to find out soot and NO removal characteristics focused on the emissions of a Diesel engine by using nonthermal plasma for each engine speeds and loads. Electrostatic precipitator(wire-to-plate type reactor) is used for soot removal. Radicals generated from outer air and put into a mixing chamber in the end of exhaust line are used for NO removal. Concentration of exhaust emissions is analyzed from the gas analyzer(KaneMay) and FTIR to estimate by-products.

Study of toluene decomposition using nonthermal plasma and catalyst (저온플라즈마와 촉매를 이용한 톨루엔 분해 연구)

  • Lim, Yun Hui;Lee, Ju-Yeol;Shin, Jae-Ran;Choi, Jin-Sik;Park, Byung Hyun
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.4
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    • pp.541-548
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    • 2014
  • This study was performed to obtain high conversion efficiency of $C_7H_8$ using non-thermal plasma and metal-supported catalyst. Adsorption-desorption characteristics of toluene was performed using 4A type (Zeolite) filled in a concentration reactor. Through this test, it was found that the concentration reactor has 0.020 g/g of adsorption capacity (at ambient temperature and pressure) and 3,600 ppm of desorption property at $150^{\circ}C$ (with in 20 min). In case of developed catalyst, toluene decomposition rate of Pd-AO (Pd coated catalyst) was better than Pd/Cu-AO and Pd/Ag-AO (Pd/Ag composite metal catalyst). Developed non-thermal plasma system was obtained flame amplification effect using injection process of desorbed tolune, and 98% of removal efficiency.

Development of Nonthermal Bioplasma Source Applicable to Human Liquid Fluids

  • Min, Boo-Ki;Oh, Hyun-Joo;Song, Ki-Baek;Uhm, Han-Sup;Kang, Seung-Oun;Choi, Eun-Ha
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.327-327
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    • 2011
  • A nonthermal bioplasma source was developed for application to human liquid fluids by making use of nano-size tungsten tips. Characteristics of the plasma source are investigated. Here we have used the AC voltage system. The bioplasma source generated by a tungsten tip with quartz tube and ground electrode is a low-temperature plasma without making any noticeable damage to cells at a low power operation. The breakdown voltage and current signals are measured by high voltage probe (Tektronix P6015A) and current probe (P6021). Variation of breakdown temperature near the tip electrode is larger than that in the neighborhood of ground electrode. Bubble formation during discharge has been recorded and investigated by using the high speed camera. The existence and behavior of hydroxyl and superoxide radicals are detected and measured by spectrometers. The electrical and optical properties of breakdown characteristics are also investigated.

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PARTICLE ACCELERATION IN SUPERNOVA REMNANTS

  • KANG, HYESUNG
    • Publications of The Korean Astronomical Society
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    • v.30 no.2
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    • pp.545-548
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    • 2015
  • Most high energy cosmic rays (CRs) are thought to be produced by diffusive shock acceleration (DSA) in supernova remnants (SNRs) within the Galaxy. Plasma and MHD simulations have shown that the self-excitation of MHD waves and amplification of magnetic fields via plasma instabilities are an integral part of DSA for strong collisionless shocks. In this study we explore how plasma processes such as plasma instabilities and wave-particle interactions can affect the energy spectra of CR protons and electrons, using time-dependent DSA simulations of SNR shocks. We demonstrate that the time-dependent evolution of the shock dynamics, the self-amplified magnetic fields and $Alfv{\acute{e}nic$ drift govern the highest energy end of the CR energy spectra. As a result, the spectral cutoffs in nonthermal X-ray and ${\gamma}$-ray radiation spectra are regulated by the evolution of the highest energy particles, which are injected at the early phase of SNRs. We also find that the maximum energy of CR protons can be boosted significantly only if the scale height of the magnetic field precursor is long enough to contain the diffusion lengths of the particles of interests. Thus, detailed understandings of nonlinear wave-particle interactions and time-dependent DSA simulations are crucial for understanding the nonthermal radiation from CR acceleration sources.

Image Observation of NO Particles Using ICCD Camera (ICCD Camera를 이용한 NO입자의 Image관측)

  • 전용우;하장호;박원주;이광식
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.15 no.1
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    • pp.98-103
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    • 2001
  • In this parer, the removal rate of NO in a reactor is rreasured first using nonthermal plasma generated from a wire-cylinder type reactor, then the discharge image and horizontal signal strength and vertical signal strength of NO particles is observed using ICCD(Intensified Charged Coupled Device) carrera It was fOlmd that NO rerroval rate was iflLTeased with NO concentration c1ecreasing, and that honzontal signal strength and vertical signal strength were also increased with NO concentration decreasing. Especially, this research is a1!Tffl at clarifying the discharge mechanism of NO particles by observing the images of AC discharge wnen the nonthermal plasma generated by an discharge was used.

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The Study of DNA Damage Induced by Atmospheric Pressure Plasma Jet and Their Mechanisms

  • Park, Yeunsoo;Song, Mi-Young;Yoon, Jung-Sik
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.155.1-155.1
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    • 2013
  • The goals of this study are to elucidate the plasma effects on DNA molecules to apply some plasma based applications and also to find out the mechanisms of plasma-induced DNA damage in biomolecule. Nonthermal atmospheric pressure plasma has much potential for medical, agricultural and food applications for the future. The atmospheric pressure plasma jet (APPJ) contains radicals, charged particles, low energy electrons, excited molecules and UV light. It has been started doing experiments using APPJ at the early 21th. And some recent results showed that APPJ has a possibility to apply to new fields like mentioned above. But it is kind of at the very early stages of plasma based application. It is definitely necessary much of theoretical and experimental studies to further understanding to use nonthermal atmospheric pressure plasma in biomedical, agriculture and food parts. Here we introduce a new experimental system to study plasma effects on biomolecules. And we will show some recent results of LEE-induced DNA damage using electron irradiation apparatus under ultra-high vacuum.

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Study on the Decomposition of Some Volatile Organic Compounds by Photocatalyst Plasma Reaction (광촉매 플라즈마 반응에 의한 몇가지 VOCs의 제거에 관한 연구)

  • 허경욱
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.4
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    • pp.373-380
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    • 2000
  • A new type of photocatalyst plasma air purification filter for decomposition of some VOCs has been developed. The photocatalyst plasma air purification filter employs the pulsed discharge plasma as an energy source of TiO2. photocatalyst instead of UV light. In closed room(2m3) test removal efficiency of some VOCs was 80∼100% in 15∼24 hours. In the initial step of phptocatalyst plasma reaction. Acetone and Nitromethane etc were detected. But they were completely oxidized to CO2 and H2O.

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AN ANALYSIS ON THE RARE SUBTYPES OF THE FAST SOLAR RADIO ACTIVITY

  • XIE R. X.;WANG M.
    • Journal of The Korean Astronomical Society
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    • v.29 no.spc1
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    • pp.331-332
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    • 1996
  • We present 3 rare subtypes of the FFSs observed with high temporal resolution at 4-frequency (1.42, 2.13, 2.84 and 4.2G GHz). The various FFSs occurred during the main and post-flare phase can demonstrate that coronal nonthermal electron acceleration/injection may go through the whole development process of flares, and deduce that there may exist the re-forming of loop-like structures in the post-flare phase, and the complex multi-type magnetic structures in corona.

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