• 대한화학회지
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• 제57권5호
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• pp.540-546
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• 2013

van der Waals식의 자유부피항, 강체구형입자에 대한 Carnahan-Starling식, 용액의 논랜덤 혼합을 고려한 Wilson식, NRTL식과 본 연구자의 식등을 사용하여 기체에 대한 여러 개의 새로운 상태방정식을 만들었다. 이 식들을 이용하여 순수 기체에 대한 압축인자를 계산하였고 이를 실험적인 Nelson-Obert 압축인자도표와 비교하였다. 분자의 논랜덤 분포를 고려하여 유도된 상태방정식들이 랜덤분포를 가정한 상태방정식보다 더 좋은 결과가 나왔다. 이를 통하여 분자의 논랜덤 분포가 상태방정식에 상당한 영향을 미친다는 것을 알 수 있다.

• 대한화학회지
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• 제51권4호
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• pp.312-317
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• 2007

난수 모의실험을 수행하여 격자 위에 분자를 무작위하게 배열하는 경우의 수의 분포를 다른 분자간의 최근린 상호작용수 N12에 대한 정규분포로 근사하였다. 이 분포로부터 논랜덤 혼합 격자용액의 과잉깁스 에너지 GE에 대한 근사식을 유도하였다. 이를 이용하여 여러 이성분용액의 액체-증기 상평형 계산을 하였고 기존의 식들의 계산 결과와 비교하여 보았다.

• 대한화학회지
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• 제53권6호
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• pp.663-670
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• 2009

논랜덤 혼합의 2-성분 격자용액에서 특정상호작용을 갖는 경우의 수에 대한 분포를 난수 모의실험을 통하여 구하였다. 이 분포로부터 2-성분격자용액의 과잉깁스에너지 $G^E$에 대한 근사식을 유도하였다. 이 식을 사용하여 15개의 2-성분용액에 대한 일정압력에서의 액체-증기 상평형 계산을 하였고 Wilson식, Van Laar식, Redlich-Kister식의 계산 결과와 비교하여 보았다.

• 응용통계연구
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• 제24권2호
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• pp.425-433
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• 2011

Reject inference in credit scoring is a statistical approach to adjust for nonrandom sample bias due to rejected applicants. Function estimation approaches are based on the assumption that rejected applicants are not necessary to be included in the estimation, when the missing data mechanism is missing at random. On the other hand, the density estimation approach by using mixture models indicates that reject inference should include rejected applicants in the model. When mixture models are chosen for reject inference, it is often assumed that data follow a normal distribution. If data include missing values, an application of the normal mixture model to fully observed cases may cause another sample bias due to missing values. We extend reject inference by a multivariate normal mixture model to handle incomplete characteristic variables. A simulation study shows that inclusion of incomplete characteristic variables outperforms the function estimation approaches.

• 산업기술연구
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• 제11권
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• pp.3-16
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• 1991

The lattice-fluid theory are adopted for modeling the phese equilibria in supercritical fluids, In order to investigate effects of the nonrandom distribution of holes in mixtures on the phase equilibria, the equation of state and the chemical potential of the binary miture are formulated with taking into account nonrandomness of holes distributions in the fluid mixture. The relations of phase equilibria formulated in this work are tested through predictions of solubility of heavy solids in supercritical fluids and predictions of high pressure phase equilibria of binary mixtures. Results obtained exhibit that the lattice fluid model with assumptions of nonrandomness of hole distributions is successful in quantatively mideling the phase equilibria of mixtures of molecules of dissimilar sizes, specifically solids-supercritical fluid mixtures.

• Mycobiology
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• 제46권1호
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• pp.64-71
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• 2018

The aim of this study was to investigate the pattern of distribution of mating type (MAT) genes of Tuber indicum in ectomycorhizosphere soils from natural T. indicum-producing areas and cultivated truffle orchards and ascocarp samples from different regions. Quantitative real-time PCR and multiplex PCR were used to weight the copy numbers of MAT1-1-1 and MAT1-2-1 in natural truffle soils and cultivated orchard soils. The effect of limestone on the pattern of truffle MAT genes and the correlation between soil properties and the proportion of MAT genes were also assessed. These results indicated that an uneven and nonrandom distribution of MAT genes was common in truffle-producing areas, cultivated truffle orchards, and ascocarps gleba. The competition between the two mating type genes and the expansion of unbalanced distribution was found to be closely related to truffle fructification. Limestone treatments failed to alter the proportion of the two mating type genes in the soil. The content of available phosphorus in soil was significantly correlated with the value of MAT1-1-1/MAT1-2-1 in cultivated and natural ectomycorhizosphere soils. The application of real-time quantitative PCR can provide reference for monitoring the dynamic changes of mating type genes in soil. This study investigates the distributional pattern of T. indicum MAT genes in the ectomycorhizosphere soil and ascocarp gleba from different regions, which may provide a foundation for the cultivation of T. indicum.