• 한국광학회:학술대회논문집
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• 한국광학회 2002년도 하계학술발표회
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• pp.222-223
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• 2002

3차 비선형 광학현상을 이용한 레이저 분광학은 코헤런트 반스톡스 라만산란(Coherent Anti-Stokes Raman Scattering, CARS)이나 축퇴 사광자혼합(Degenerate Four-Wave Mixing, DFWM)이 기계공학의 연소진단이나 화학분야에 응용된 이래 활발히 연구되어져왔다.[1] 비선형 광학현상의 특성상, 발생한 신호는 입사 레이저광들과의 위상정합조건이 만족되는 특정한 방향으로만 진행하고 레이저광처럼 가간섭성을 갖는다. (중략)

• Macromolecular Research
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• 제15권1호
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• pp.59-64
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• 2007

Star-shaped, nonlinear optical (NLO) material was synthesized and its optical, thermal, and electro-optic properties were investigated. Three NLO-active dipolar chromophores containing a phenylene ring substituted with a bulky alkyl chain as a conjugation bridge were chemically bonded to the core of 1,1,1-tris(4-hydroxyphenyl)ethane to form a dendritic architecture. The chemical structure and purity of the chromophore were verified by NMR spectroscopy. The chromophore exhibited a broad absorption band centered at around 608 nm tailing up to 760 nm in toluene solution and also showed a discernible solvatochromic shift in more polar solvent. The chloroform solution of the dendrimer produced an absorption band with a red-shifted maximum as large as 28 nm when compared to that of the toluene solution. It was thermally stable up to $275^{\circ}C$ in a nitrogen atmosphere and had a glass transition temperature of $76^{\circ}C$. In a preliminary result, the polymer film containing the dendritic compound exhibited a shift of 19 pm/V taken at $1.55{\mu}$.

• 공업화학
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• 제9권6호
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• pp.907-913
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• 1998

전기화학적 임피던스법(electrochemical impedance spectroscopy, EIS)을 사용하여 염소이온에 의한 철근 콘크리트의 부식현상을 연구하였다. 콘크리트를 만들 때 물에 용해된 상태의 염소이온은 콘크리트 내부에 존재하게 되며, 이 염소이온의 농도를 변화시키며 실험을 수행하였다. 재령 400일 이상 EIS법으로 측정한 결과, 세밀한 전기화학적 등가회로 및 물리적 모델을 구성하였으며, 얻어진 임피던스 파라미터로부터 철근 콘크리트의부식현상을 물리적 모델로 설명할 수 있었다. 실험에서 얻은 측정값과 CNLS(complex nonlinear least squares) fitting법으로 구한 값은 잘 일치하였으며, 모델로부터 얻어진 임피던스 상수를 이용하여 부식 속도를 계산할 수 있어 이를 통한 부식 속도 예측이 가능함을 알 수 있었다.

• Journal of Power Electronics
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• 제16권5호
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• pp.1981-1989
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• 2016

Battery diagnosis is vital to battery-based applications because it ensures system reliability by avoiding battery failure. This paper presents a novel intelligent battery charger with an online diagnosis function to circumvent interruptions in system operation. The charger operates in normal charging and diagnosing modes. The diagnosis function is performed with the impedance spectroscopy technique, which is achieved by injecting a sinusoidal voltage excitation signal to the battery terminals without the need for additional hardware. The impedance spectrum of the battery is calculated based on voltage excitation and current response with the aid of an embedded digital lock in amplifier in a digital signal processor. The measured impedance data are utilized in the application of the complex nonlinear least squares method to extract the battery parameters of the equivalent circuit. These parameters are then compared with the reference values to reach a diagnosis. A prototype of the proposed charger is applied to four valve-regulated lead-acid batteries to measure AC impedance. The results are discussed.

• Journal of Power Electronics
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• 제13권3호
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• pp.429-436
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• 2013

Online simulations are utilized to reduce time and cost in the development and performance optimization of plug-in hybrid electric vehicle (PHEV) and electric vehicles (EV) systems. One of the most important factors in an online simulation is the accuracy of the model. In particular, a model of a battery should accurately reflect the properties of an actual battery. However, precise dynamic modeling of high-capacity battery systems, which significantly affects the performance of a PHEV, is difficult because of its nonlinear electrochemical characteristics. In this study, a dynamic model of a high-capacity battery cell for a PHEV is developed through the extraction of the equivalent impedance parameters using electrochemical impedance spectroscopy (EIS). Based on the extracted parameters, a battery cell model is implemented using MATLAB/Simulink, and charging/discharging profiles are executed for comparative verification. Based on the obtained results, the model is optimized for a high-capacity battery cell for a PHEV. The simulation results show good agreement with the experimental results, thereby validating the developed model and verifying its accuracy.

• Nuclear Engineering and Technology
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• 제55권7호
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• pp.2432-2437
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• 2023

Methodology for suppressing or recovering the distorted spectra, which may occur due to mutual non-uniformity and nonlinear response when a multi-detector is simultaneously operated for gamma spectroscopy, is presented with respect to its applicability to stabilization of spectra having the non-identical feature using modified full spectrum reallocation method. The modified full-spectrum reallocation method is extended to provide multiple coefficients that describe the gain drift for multi-division of the spectrum and they were incorporated into an optimization process utilizing a random sampling algorithm. Significant performance improvements were observed with the use of multiple coefficients for solving partial peak dislocation. In this study, our achievements to confirm the stabilization of spectrum having differences in moments and modify the full spectrum reallocation method provide the feasibility of the method and ways to minimize the implication of the non-linear responses normally associated with inherent characteristics of the detector system. We believe that this study will not only simplify the calibration process by using an identical response curve but will also contribute to simplifying data pre-processing for various studies as all spectra can be stabilized with identical channel widths and numbers.

• 천문학회보
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• 제38권2호
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• pp.36-36
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• 2013

Globular clusters (GCs) are among the oldest stellar objects in the universe and provide valuable constraints on many aspects of galaxy evolution. GC systems typically exhibit bimodal color distributions the phenomenon of which has been a major topic in the area of GC research. GC color bimodality established a paradigm where scenarios to explain its origin require two GC groups with different formation origins. The GC division, asserted mainly by photometric color bimodality so far, has been viewed as the presence of two distinct metallicity subgroups within individual galaxies. In this study, we make use of spectroscopy of GC systems associated with two giant galaxies, M31 (the Andromeda) and M87 (NGC 4486), to investigate the GC bimodality and the underlying metallicity distributions. Recent spectroscopy on the globular cluster (GC) system of M31 with unprecedented precision witnessed a clear bimodality in absorption-line index distributions of old GCs. Given that spectroscopy is a more detailed probe into stellar population than photometry; the discovery of index bimodality may point to the very existence of dual GC populations. However, here we show that the observed spectroscopic dichotomy of M31 GCs emerges due to the nonlinear nature of metallicity-to-index conversion and thus one does not necessarily have to invoke two separate GC subsystems. We present spectra of 130 old globular clusters (GCs) associated with the Virgo giant elliptical galaxy M87, obtained using the Multi-Object Spectrography (MOS) mode of Faint Object Camera and Spectrograph (FOCAS) on the Subaru telescope. M87 GCs with reliable metallicity measurements exhibit significant inflection along the color-metallicity relations, through which observed color bimodality is reproduced from a broad, unimodal metallicity distribution. Our findings lend further support to this new interpretation of the GC color bimodality, which could change much of the current thought on the formation of GC systems and their host galaxies.

• 비파괴검사학회지
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• 제28권2호
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• pp.119-124
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• 2008

최근 비파괴 검사를 위한 테라헤르츠 전자기파 기술에 대한 관심이 높아지고 있으며 특히 비파괴검사에서 많은 응용이 기대된다. 테라헤르츠 시간 영역 분광법은 이러한 테라헤르츠 기술에 핵심이 되는 기술로 많은 실험이 이루어지고 있다. 본 논문에서는 테라헤르츠 시간 영역 분광에서 비선형 전광물질을 이용하는 광정류 방식을 통해 발생된 테라헤르츠 전자기파 스펙트럼이 비선형 맥스웰 방정식의 해와 실험에 의해 결정되는 흡수, 회절, 표면간섭 효과 등을 고려한 본문의 모델을 통하여 예측가능하며 실제 티타늄:사파이어 레이저 펄스를 $400{\mu}m$ CdTe에 조사하여 발생된 테라헤르츠파 주파수 스펙트럼의 측정 결과와 비교하여 매우 유사하다는 사실을 보여준다. 이를 통하여 본문에서 소개된 모델은 다른 전광물질을 통해 발생된 테라헤르츠 스펙트럼에도 확장되어 적용 될 수 있다.

• 한국군사과학기술학회지
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• 제24권3호
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• pp.264-271
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• 2021

Raman spectroscopy is an equipment that is widely used for classifying chemicals in chemical defense operations. However, the classification performance of Raman spectrum may deteriorate due to dark current noise, background noise, spectral shift by vibration of equipment, spectral shift by pressure change, etc. In this paper, we compare the classification accuracy of various machine learning algorithms including k-nearest neighbor, decision tree, linear discriminant analysis, linear support vector machine, nonlinear support vector machine, and convolutional neural network under noisy and spectral shifted conditions. Experimental results show that convolutional neural network maintains a high classification accuracy of over 95 % despite noise and spectral shift. This implies that convolutional neural network can be an ideal classification algorithm in a real combat situation where there is a lot of noise and spectral shift.

• 한국자기공명학회논문지
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• 제17권1호
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• pp.24-29
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• 2013

The structural characteristics of 4-coordinate $BO_4$ [B(1)] and 3-coordinate $BO_3$ [B(2)] groups in $BiB_3O_6$ were studied by $^{11}B$ magic angle spinning (MAS) and single-crystal nuclear magnetic resonance (NMR) spectroscopy. The spin-lattice relaxation time in the laboratory frame, $T_1$, for $^{11}B$ decreased slowly with increasing temperature, whereas the spin-lattice relaxation times in the rotating frame, $T_{1{\rho}}$, for B(1) and B(2), which differed from $T_1$, were nearly constant. Further, $T_{1{\rho}}$ for B(1) and B(2) showed very similar trends, although the $T_{1{\rho}}$ value of B(2) was shorter than that of B(1). The 3-coordinate $BO_3$ and 4-coordinate $BO_4$ were distinguished by $^{11}B$ MAS NMR spectrum and $T_{1{\rho}}$.