• Journal of the Korean Society for Nondestructive Testing
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• v.32 no.4
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• pp.369-375
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• 2012

In order to overcome the detection limit by the current nondestructive evaluation technology, a nonlinear resonant ultrasound spectroscopy(NRUS) technique was applied for detection of micro-scale cracks in a material. A down-shift of the resonance frequency and a variation of normalized amplitude of the resonance pattern were suggested as the nonlinear parameter for detection of micro-scale cracks in a materials. A natural-like crack were produced in a standard compact tension(CT) specimen by a low cycle fatigue test and the resonance patterns were acquired in each fatigue step. As the exciting voltage increases, a down-shift of resonance frequency were increases as well as the normalized amplitude decrease. This nonlinear effects were significant and even greater in the cracked specimen, but not observed in a intact specimen.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.165-165
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• 2006

We prepared nonlinear optical (NLO) polymers possessing thermal and temporal stability, which were based on the polyimides appended with NLO chromophores. NLO chromophores with a terminal hydroxyl group have been synthesized by coupling between aminobenzene or julolidine donor and phenylene bridge, and then subsequent coupling between the resulting product and tricyanofuran acceptor. The chromophores were chemically bonded to the polyimides backbone through Mitsunobu reaction. The NLO polymers showed $160-170^{\circ}C$ of Tgs and were thermally stable up to $200^{\circ}C$. We obtained optical quality films by spincoating and evaluated their electro-optical properties and temporal stability.

• Proceedings of the Materials Research Society of Korea Conference
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• 1998.08a
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• pp.55.4-55
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• 1998

• Proceedings of the Korean Society of Potoscience Conference
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• spring
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• pp.18-18
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• 1998

• Proceedings of the Materials Research Society of Korea Conference
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• 1998.08a
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• pp.149.1-149
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• 1998

• Bulletin of the Korean Chemical Society
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• v.32 no.5
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• pp.1443-1454
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• 2011

Methods to prepare novel second-order nonlinear optical (2O-NLO) materials composed of all-silica zeolite (silicalite-1) and a series of 2O-NLO molecules having high second order hyperpolarizability constants (${\beta}$ values) are reviewed. These methods include the development of novel methods to incorporate a series of hemicyanine (HC) molecules into the channels of silicaite-1 films in uniform orientations. The first method is to incorporate HC molecules tethered with long alkyl chains (octadecyl or longer) into the silicalite-1 channels with the long alkyl chain side first through the hydrophobic-hydrophobic interaction between the long alky chains and the silicalite-1 channels. The second method is to incorporate the HC molecule tethered with a medium length alkyl chain (nonyl) into the silicalite-1 channels with the medium length alkyl chain side first through hydrophobic-hydrophobic interaction between the medium length alky chain in the photoexcited state and the silicalite-1 channels. The third method is to incorporate the HC molecule tethered with propionic acid into the silicalite-1 channels with the propionic acid side last mediated by a tetrabultylammonium cation ion-paired to the propionate unit. A method to prepare a novel third-order nonlinear optical (3O-NLO) material composed of zeolite-Y and PbS or PbSe quantum dots is also reviewed. This Account thus describes a promising new direction to which the search for highly sensitive 2O-NLO and 3O-NLO materials has to be conducted and a new direction to which zeolite research and applications have to be expanded.

• Proceedings of the KSME Conference
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• 2001.11a
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• pp.222-227
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• 2001

Nonlinear acoustic effect has been considered as an effective tool for the evaluation of material degradation. In this paper, the applicability of nonlinear acoustic effect to the evaluation of degradation of 2.25Cr-1Mo steel is investigated. Firstly, a number of 2.25Cr-1Mo steel samples were heat-treated, and their damage mechanism was examined. Secondly, Ultrasonic nonlinear parameter was measured. Nonlinear acoustic parameter was found to be clearly sensitive to the material degradation.

• International Journal of Highway Engineering
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• v.10 no.1
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• pp.63-74
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• 2008

Resilient deformation characteristics on unbound pavement materials have been adopted for design and nonlinear analysis of pavement structure under traffic loadings. However, relatively few studies have been done on the nonlinear resilient behavior of unbound pavement materials in Korea. In addition, only the limited information is available for estimating the resilient modulus values on unbound materials. In this study, a laboratory resilient-deformation test under repeated loadings is performed in order to fud a proper constitutive model that correlates the resilient modulus with stress state from field condition. Finally, a finite element analysis is conducted for evaluating the nonlinear characteristics of unbound materials. and the pavement performance respectively.

• Composites Research
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• v.12 no.1
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• pp.59-67
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• 1999

The effects of fiber waviness on tensile/compressive nonlinear elastic behaviors of graphite/epoxy unidirectional composite materials are studied theoretically and experimentally. New constitutive models are proposed to predict elastic properties and tensile/compressive nonlinear behaviors of composite materials. Three types of wavy pattern are considered: uniform, graded and localized fiber waviness. Complementary energy density and incremental method are used to incorporate the material and geometrical nonlinearities due to fiber waviness. Tensile/compressive tests are conducted on the specimens with fiber waviness. It is found that the predictions are in good agreement with the experimental results.

• Journal of the Korean Ceramic Society
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• v.43 no.9 s.292
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• pp.569-574
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• 2006

Transparent glass-ceramics containing fresnoite crystals have been prepared by controlled heat treatment in $K_2O-BaO-TiO_2-SiO_2$ and their nonlinear optical and luminescent properties were investigated using Maker fringe method and Spectrofluorometer. The second harmonic generation was observed in all samples and the values decreased with increasing $K_2O$ content. The luminescence of blue light at ${\sim}482nm$ could be observed and it was shown that the luminescent property was controlled by the $K_2O$ content.