• Title/Summary/Keyword: Nonlinear crystal

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Structural Characteristics of 3- and 4-Coordinate Borons from 11B MAS NMR and Single-Crystal NMR in the Nonlinear Optical Material BiB3O6

  • Kim, Woo Young;Lim, Ae Ran
    • Journal of the Korean Magnetic Resonance Society
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    • v.17 no.1
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    • pp.24-29
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    • 2013
  • The structural characteristics of 4-coordinate $BO_4$ [B(1)] and 3-coordinate $BO_3$ [B(2)] groups in $BiB_3O_6$ were studied by $^{11}B$ magic angle spinning (MAS) and single-crystal nuclear magnetic resonance (NMR) spectroscopy. The spin-lattice relaxation time in the laboratory frame, $T_1$, for $^{11}B$ decreased slowly with increasing temperature, whereas the spin-lattice relaxation times in the rotating frame, $T_{1{\rho}}$, for B(1) and B(2), which differed from $T_1$, were nearly constant. Further, $T_{1{\rho}}$ for B(1) and B(2) showed very similar trends, although the $T_{1{\rho}}$ value of B(2) was shorter than that of B(1). The 3-coordinate $BO_3$ and 4-coordinate $BO_4$ were distinguished by $^{11}B$ MAS NMR spectrum and $T_{1{\rho}}$.

Characteristics of Sŏlc Filters in X(2) Nonlinear Photonic Crystal

  • Kee, Chul-Sik;Lee, Jong-Min;Lee, Yeung-Lak
    • Journal of the Optical Society of Korea
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    • v.11 no.3
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    • pp.130-132
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    • 2007
  • The characteristics of $S\breve{o}lc$ filters in $X^{(2)}$ nonlinear photonic crystals, periodically poled lithium niobate ($LiNbO_3$), were investigated by the Jones matrix method. The transmittance increases and the full width half maximum of the filter becomes narrow as the duty ratio increases. However, the filtering wavelength does not change. The transmittance at the filtering wavelength is over 95% when the duty ratio is larger than 0.35.

Measurement of the nonlinear optical susceptibilies of porous silicon (다공질 규소의 비선형 광학감수율 측정)

  • 조창호;서영석;김영유
    • Korean Journal of Optics and Photonics
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    • v.10 no.4
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    • pp.289-293
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    • 1999
  • The nonlinear susceptibilities of the porous silicon surface were determined from the second harmonic generation. The value of nonlinear susceptibility, ${\chi}^{(2)}_{zzz}$ was $1.04{\times}10_{-7}$ esu which had an intensity of two orders of magnitude greater than that of silicon crystal wafers. The orientation angle of absorbed molecules on the porous silicon surface was ${16.8}^{\circ}$.

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Nonlinear Optical Properties and Photoluminescence of CuCl Nanocrystals Embedded in Silica Glass

  • 이민영
    • Bulletin of the Korean Chemical Society
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    • v.16 no.2
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    • pp.126-129
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    • 1995
  • Linear and nonlinear optical properties of CuCl nanocrystals in silica glass have been studied using low temperature absorption, degenerate four wave mixing (DFWM), and time-resolved photoluminescence spectroscopy. Assuming a spherical shape, effective radius of the CuCl quantum dots was estimated to be 2.5 nm, which is obtained from low temperature absorption data. The DFWM experiment was performed in 380-386 nm wavelength region, and the diffracted signal was measured as a function of wavelength with 1.0 nm interval. Time-resolved photoluminescence measurement was also carried out at 77 K to obtain the time response of CuCl nanocrystals. The experimental results on the large third order nonlinear optical of CuCl quantum dots are explained in terms of crystal size and oscillator strength of quantum spheres.

$KTiOPO_4 (KTP)$ Single Crystal Growth by TSSG Technique (TSSG법에 의한 $KTiOPO_4 (KTP)$ 단결정 육성)

  • 김정환;강진기
    • Korean Journal of Crystallography
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    • v.3 no.1
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    • pp.37-43
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    • 1992
  • KTiOP04 is a nonlinear optical crystal which is most widely used for frequency doubling of the radiation of Nd : YAG laser. In the experiment, sin ale crystals of KTiOP04 were grown by TSSG technique using 3K2W04·P2O5 flux. Low temperature gradient furnace suitable for KTP single crystal growth was used. Seed crystal was placed at the surface of the solution for the purpose of better observation of the growing crystals and the possibility of diameter control. Solution included 66.7mol% KTiOP04 for all experiments and its saturation temperature was 1020℃. The conditions of single crystal growth were as follows: cooling rate 0.2℃/h, crystal rotation rate 50rpm, c -axis seed. Using these conditions, single crystals up to 23 ×25×25mm3 have been groan from about 100cc solution. We have also observed a change in the crystal growth habit which resulted in the formation of large (201) faces and small (100) faces. And some crystals have (101) faces.

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Crystal Plasticity Simulation of Ti-6Al-4V Under Fretting Fatigue (프레팅 피로를 받는 Ti-6Al-4V의 결정소성 시뮬레이션)

  • Goh Chung Hyun;Lee Kee Seok;Ko Jun Bin
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.29 no.4 s.235
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    • pp.511-517
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    • 2005
  • Fretting fatigue is often the root cause of the nucleation of cracks at attachments of structural components. Since fretting fatigue damage accumulation occurs over relatively small volumes, the subsurface cyclic plastic strain is expected to be rather non-uniformly distributed in polycrystalline materials. The scale of the cyclic plasticity and the damage process zones is often on the order of microstructure dimensions. Fretting damage analyses using cyclic crystal plasticity constitutive models have the potential to account for the influence of size, morphology, and crystallographic orientation of grains on fretting damage evolution. Two-dimensional plane strain simulations of fretting fatigue are performed using the cyclic properties of Ti-6Al-4V. The crystal plasticity simulations are compared to an initially isotropic $J_{2}$ theory with nonlinear kinematic hardening as well as to experiments. The influence of initially isotropic versus textured microstructure in the presence of crystallographic slip is studied.

Optimal Design of Electric Field Driven Liquid Crystal Fresnel Lens Using Taguchi's Method (다구찌 실험계획법을 이용한 액정 전계 프레넬 렌즈의 최적 설계)

  • Kim, Bong-Sik;Kim, Jong-Woon;Park, Woo-Sang
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.3
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    • pp.218-223
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    • 2012
  • A rigorous electro-optical simulation and ray tracing for an electric field driven liquid crystal Fresnel lens was proposed to obtain design parameters of the electrode pattern of the Fresnel lens. The optimal design was carried out using Taguchi's experimental method for 17.1"($368{\times}229.5$ mm) wide LCD panels with 9 views. For the calculation of the distribution of liquid crystal molecules and the optical transmission of the panel, finite difference method and extended Jones matrix method were used to deal effectively with highly nonlinear and complicated motional equations of the liquid crystal molecules and to obtain the oblique transmission characteristics of the LCD panel. As simulation results, the optimal lengths of the 3 electrodes of the Fresnel lens are 4.0 ${\mu}m$, 30 ${\mu}m$ and 83 ${\mu}m$, respectively, and the locations of the second and third electrodes are 32.9-33.0 ${\mu}m$ and 45.9-46.0 ${\mu}m$, respectively. The optimal applied voltage of the 3 electrodes are found to be 5.75 V, 7.80 V and 11.9 V, respectively.

Measurement of nonlinear optical constant of organic single crystal para-toluene sulfonate prepared by slow solution evaporation method (늦은 용액증발법으로 제작한 유기단결정 para-toluene sulfonate의 비선형 광학상수 측정)

  • 황보창권
    • Korean Journal of Optics and Photonics
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    • v.9 no.2
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    • pp.76-85
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    • 1998
  • Organic single crystal of p-toluene sulfonate(PTS) bulks and thin films were fabricated using a slow solution evaporation method. Third and fifth order nonlinear refractive indices, $n_2$and $n_3$, of PTS crystals at 1600 nm were determined by the Z-scan method and the multimode output of the PTS thin film waveguide was observed at 1350 nm. When the beam intensity is in 2-5 GW/$cm^2$, the nonlinear refractive indices are $n_{2}=6{\times}10^{-4}cm^{2}$/GW and $n_{3}=-7{\times}10^{-5}cm^{4}/GW^{2}$ and the two and three photon absorption coefficients are zero. When the beam intensity is in 5~16 GW/$cm^2$, the split-step fast Fourier transform beam propagation method simulation shows that the beam propagation in the PTS is distorted from the gaussian shape.

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