• 한국환경과학회지
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• 제3권1호
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• pp.57-64
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• 1994

On the basis of the principle of Bratch's electronegativity equalization, we calculated group partial charges and group electronegativities for nonionic surfactants with Pauling's elecoonegativity parameters by using numerical calculation method. From calculated outputs we have investigated structural stability of micelle, characteristics of hydrophilic and hydrophobic groups, and relation between CMC(Critical Micelle Concentraion) and group partial charge and group electronegativity of hydrophilic and hydrophobic groups for nonionic surfactants. We have known that CMC by micelle formation depends upon group partial charge and group electronegativity of hydrophilic and hydrophobic groups for surfactants. Also, the structural stability of micelle in H2O solution is related to the electric double layer by the hydrophilic group of nonionic surfactants with H atoms in water CMC is diminished by the decrease of repeating units in hydrophilic group at constant hydrophobic group and is diminished by the increments of alkyl chains in hydrophobic group at constant hydrophilic group for nonionic surfactants. In conclusion, CMC is diminished because there is no electrostatic repulsion and is diminished of Debye length by the increments of partial charge of hydrophobic group.

• 대한화장품학회:학술대회논문집
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• 대한화장품학회 2003년도 IFSCC Conference Proceeding Book II
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• pp.480-507
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• 2003

A rapid and efficient method for analyzing the nonionic surfactants and silicone polymers, which control the shape and characteristics of cosmetic products and give influence on product quality, has been developed using Matrix-Assisted Laser Desorption Ionization Time of Flight Mass Spectrometry (MALDI- TOF IMS). The MALDI-TOF/MS could easily and effectively determine the molecular weight distribution and monomer units of nonionic surfactants. As a result, creating a library of mass spectrum data of surfactants used in cosmetic products using MALDI-TOF/MS and analyzing surfactants extracted from the products may become a useful method for detailed structural characterization of the surfactants. Furthermore, the MALDI-TOF/MS analysis was effective in obtaining the spectrum of silicone polymers from which the molecular weight distribution could be determined. The repetition units and structural data could also be obtained through molecular mass peaks. Additionally, the monomer ratio and terminal groups as properties of silicone copolymers could be determined

• Bulletin of the Korean Chemical Society
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• 제24권1호
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• pp.37-44
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• 2003

We examined the effect of polyether-type nonionic surfactants (Brij 35, Triton X-100, Tween 20 and Tween 80) on the potentiometric properties of sodium-, potassium- and calcium-selective membranes which are prepared with widely used ionophores and four kinds of polymer matrices [poly(vinyl chloride) (PVC), polyurethane (PU), PVC/PU blend, and silicone rubber (SR)]. It was found that the PVC-based membranes, which provide the best performance among all other matrix-based membranes in the absence of nonionic surfactants, exhibited larger change in their potentiometric properties when nonionic surfactants are added to the sample solution. On the other hand, the sodium-selective SR-based membrane with calix[4]arene, potassium-selective PVC/PU- or SR-based membrane with valinomycin, and the calcium-selective SR-based membrane with ETH 1001 provide almost identical analytical performance in the presence and absence of Tween 20 or Tween 80 surfactants. The origin of nonionic surfactants effect was also investigated by interpreting the experimental results obtained with various matrices and ionophores. The results suggest that the nonionic surfactant extracted into the membrane phase unselectively form complexes with the primary and interfering ions, resulting in increased background potential and lower binding ability for the ionophore. Such effects should result in deteriorated detection limits, reduced response slopes and lower selectivity for the primary ions.

• 한국응용과학기술학회지
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• 제33권3호
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• pp.449-458
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• 2016

Detergency and surface active properties of mixed anionic surfactants with amphoteric and nonionic were investigated. Sodium dodecyl sulfate (SDS) and ammonium dodecyl sulfate (ADS) as anionic surfactants and cocamidopropyl betaine (CAPB) as an amphoteric surfactant were used. Nonionic surfactants, which are butyl glucoside (BG), octyl glucoside (OG), decyl glucoside (DG), lauryl dimethylamine oxide (AO) and saponin were also used. To study the synergy effects of mixed SDS/ADS anionic surfactant systems, amphoteric and nonionic surfactants were added into the mixed anionic surfactants. Investigated properties of surfactant mixtures were critical micelle concentration (CMC), surface tension (${\gamma}$), wettability. In addition, based on these properties, detergency of each sample was examined. Surfactant mixtures are anionics (SDS/ADS), anionic/amphoteric/nonionic (SDS/ADS/CAPB/saponin), and anionic/nonionic (SDS/ADS/BG/saponin, SDS/ADS/OG/saponin, SDS/ADS/DG/saponin, and SDS/ADS/AO/saponin). With the addition of amphoteric and nonionic to mixed anionic surfactants, CMC and ${\gamma}$ were decreased. Addition of CAPB, which is amphoteric, showed the best property at CMC and ${\gamma}$. Furthermore, as the chain length of hydrocarbon in alkyl glucosides was increased, the CMC and ${\gamma}$ were enhanced. However, the wettability did not exactly match up with CMC and ${\gamma}$. The surfactant mixture, which contained DG, showed the best performance at wetting time. Detergency was measured at various temperatures ($15^{\circ}C$, $30^{\circ}C$, $50^{\circ}C$). The cleaning performance was enhanced by increasing washing temperature. Moreover, detergency was influenced by not only CMC and ${\gamma}$ but also wettability. Although CMC and ${\gamma}$ were not minimum at surfactant mixture that included DG, the best cleaning performance showed in that sample.

• 한국응용과학기술학회지
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• 제25권1호
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• pp.23-31
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• 2008

In general, anionic and cationic surfactants are incompatible because their mixtures form insoluble complexes. There are, however, some complexes that are soluble and behave like regular surfactants, specifically like nonionic surfactants, thus named pseudo-nonionic surfactant complexes. Pseudo-nonionic complexes are more effective and efficient than their ionic surfactant components as shown by their equilibrium and dynamic surface tensions and interfacial tensions. They pack at the interface more than their ionic components. Since, pseudo-nonionic complexes show their own characteristics, they can be treated as separate classes of surfactants distinct from ionic and nonionic surfactants. Novel cationic surfactant was synthesized, having the polyhydroxyl group at the head group. We found that aqueous mixtures of our cationic surfactant and usual anionic surfactant(SDS) could form homogeneous solutions even at high concentration. The properties of mixed surfactant solutions were measured. Foam stability, CMC(critical micelle concentration), water hardness tolerance and thickening effect were tested. The foam stability of mixed surfactants was very good and various synergy effects were observed.

• 한국염색가공학회지
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• 제23권2호
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• pp.140-145
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• 2011

The effects of nonionic surfactant solutions of 0.1g/dL on detergency and liquid wetting/retention properties of soiled polyester/cotton(65/35) cloth were studied. Soiled polyester/cotton(65/35) cloth (EMPA 104) and 10 different nonionic surfactants (Span 20, Tween 20, 40, 60, 80, 21, 61, 81, 65, 85) were used in the study. The water retention and liquid retention capacity values of soiled cloth were decreased compared with those of unsoiled cloth. The wetting and water retention of soiled cloth improved with addition of surfactants, whereas water retention ratio(W/H) values didnot change markedly. Generally surfactants with low surface tension and high HLB (Hydrophile-lipophile balance) were more effective in improving the wetting/retention properties of soiled cloth. Nonionic surfactants having high ethylene oxide contents of 20 moles; i.e., Tween 20, 40, 60 & 80, showed better detergency than low ethylene oxide contents of 4 moles; i.e., Tween 21, 61 & 81. As HLB values of surfactants and $cos{\theta}$ of the soiled cloth increase, the detergency values of soiled cloth increased.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2004년도 총회 및 춘계학술발표회
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• pp.328-331
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• 2004

Solubilization isotherms of TCE in the nonionic surfactants were studied. In this research, the maximum solubilization of TCE in the micelle was observed at the HLB of approximately 15. Increasing carbon number, solubilization of TCE was enhanced with the same ethoxylated alcohols number in brij surfactants.

• Environmental Analysis Health and Toxicology
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• 제15권1_2호
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• pp.1-6
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• 2000

This study was designed to evaluated the ecotoxicity to Closterium ehrenbergii using Nonionic surfactants based on its chemical structure. Nonionic surfactants ecotoxicity tended to increase with decreasing the number of ethylene oxide units. The Closterium ehrenbergii test was good in sensitivity and agreement with other published results. The use of Closterium ehrenbergii test offers promising potential for ecotoxicological applications.

• 한국염색가공학회지
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• 제21권2호
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• pp.7-13
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• 2009

The effects of 0.1g/dl nonionic surfactant solutions on liquid wetting and retention properties of wool fabric are reported. The 10 different nonionic surfactants (Span 20, Tween 20, 40, 60, 80, 21, 61, 81, 65, 85), wool cloth (EMPA 217), and wool soiled cloth (EMPA 107) are used in the study. Both EMPA 217 and 107 have water contact angle($\Theta$)>$90^{\circ}$, which indicates that water spreading over a fabric surface and penetration into the fabric rarely occur. However, EMPA 217 and 107 are easily wetted with perchloroethylene(PCE) having very low values of $\Theta$'s and high values of liquid retention. Water wetting properties are greatly improved by adding nonionic surfactants into the system. Generally, hydrophilic surfactants which have low number of carbon atoms or unsaturated hydrophobic structures are effective in improving water wetting of wool fabrics. The water retention of EMPA 217 and 107 in surfactant solutions have positive relations with $cos{\Theta}$, adhesion tension, and work of adhesion. 40.3% pore volume of EMPA 217 and 26.1% pore volume of EMPA 217 can be filled with water even when we assume $cos{\Theta}=1$ (${\Theta}=0^{\circ}$).

• Korean Chemical Engineering Research
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• 제52권3호
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• pp.289-293
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• 2014

에멀션형 점착제 분야에서 노닐페닐계 비이온 계면활성제를 대체할 수 있는 친환경 비이온 계면활성제를 찾기 위해 Tween계 비이온 계면활성제를 선정하여 에멀션형 점착제를 제조한 후 이를 노닐페닐계 비이온 계면활성제인 NP-40을 사용한 점착제와 점착물성을 비교해 봄으로써 그 대체 가능성을 확인하였다. 이 결과 Tween 60과 Tween 80의 경우 NP-40의 경우보다 박리강도와 유지력 면에서 매우 우수한 점착물성을 보임을 알 수 있었다.