• Title/Summary/Keyword: Noncorrosive material

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Effect of the Coaling and Annealing on Noncorrosive of Fuel Cell Separator (코팅과 열처리가 연료전지 분리판의 내식성에 미치는 영향)

  • Kim, Gwi-Yeol
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.11
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    • pp.1000-1003
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    • 2007
  • The molten carbonate fuel cell has conspicuous feature and high potential in being used as an energy converter of various fuel to electricity and heat. However, the molten carbonate fuel cell which use strongly corrosive molten carbonate at $650^{\circ}C$ have many problem. One of the material problems is the severe corrosion of the metallic components, such as the separator. The effect of coating and annealing treatment on the corrosion for SUS 304 and SUS 430 which are the candidate materials for molten carbonate fuel cell hardware has been investigated in molten carbonate at $650^{\circ}C$ by using steady state polarization and electrochemical impedance spectroscopy method. It was found that the corrosion current of these SUS 304 and SUS 430 decreased with coating and annealing treatment.

The mobile and modular GFRP-membrane-structure with the new innovative connection system (새로운 GFRP접합 시스템을 이용한 멤브레인 파빌리옹)

  • Knippers, Jan;Park, Don-U;Hub, Alexander;Hwang, Kyung-Ju
    • Journal of Korean Association for Spatial Structures
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    • v.5 no.2 s.16
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    • pp.7-15
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    • 2005
  • Currently, the structural material, namely glass fiber reinforced polymer (GFRP) is focused on innovative structure due to lightness, excellent workability and noncorrosive characteristics, etc. However, the lack of GFRP connection technology produces only an imitation of steel and wood structures. This uses univentive design principles as well as unsuitable material applications, causes tons of surplus of materials to be wasted, and results in uneconomical structures, because the characteristics between steel and GFRP are completely different. Thus, this research develops the new, innovative GFRP connection system with considerations of the characteristics of GFRP and adopts it to a mobile und modular membrane pavilion.

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Research on the Bond Behavior of FRP Rebars subjected to Cyclic Loading (반복하중을 받는 FRP 보강근의 부착성능에 대한 연구)

  • Chang, Mun-Suk;Lee, Jung-Yoon;Park, Ji-Sun;Park, Young-Hwan
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.205-208
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    • 2006
  • The use of Fiber Reinforced Polymer (FRP) bars has been gaining popularity in the civil engineering community, as an alternative material to steel reinforcement, for their noncorrosive nature and high strength-to-weight ratio. Good performance of reinforced concrete requires adequate interfacial bond between the reinforcing material and the concrete because the load applied must be transferred from the matrix to the reinforcement. Although studies on the FRP bond behavior under monotonic loading has been reported by many, there are very little work done under cyclic loading. In this paper, we present the experimental study on the bond behavior of three different types of FRP rebars subjected to four different cyclic loading conditions.

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Optimum Design of Modular FRP Box Member to Bending Moment (휨을 받는 조립형 FRP 박스부재의 최적단면검토)

  • Kwak, Kae-Hwan;Kim, Kyung-Suk;Kim, Ho-Sun
    • Journal of The Korean Society of Agricultural Engineers
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    • v.53 no.3
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    • pp.43-51
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    • 2011
  • Fiber Reinforced Polymer (FRP)s have various advantages for construction material in that they are noncorrosive and very strong. FRPs are economical and effective for management and maintenance when applied to footbridge, beam or deck of the bridge, girder, and marine structure. For safety, optimal design for standard modulation of the cross section is necessary. Conditions of optimum are possibilities of domestic production, modular assembly, and structure materials cast in compressed area.

Etch Characteristics of CO/NH3 Plasma Gas for Magnetic Random Access Memory in Pulsed-biased Inductively Coupled Plasmas

  • Yang, Gyeong-Chae;Jeon, Min-Hwan;Yeom, Geun-Yeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.200-200
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    • 2013
  • 기존 메모리 반도체에 비교해 빠른 재생속도와 높은 집적도, 비휘발성 등의 특성을 가지는 MRAM (Magnetic Random Access Memory)은 DRAM, flash memory 등을 대체할 수 있는 차세대 기억 소자로서 CoFeB/MgO/CoFeB로 구성된 한 개의 MTJ (Magnetic Tunnel Junction)를 단위 메모리로 사용한다. 이 MTJ 물질들은 고밀도 플라즈마를 이용한 건식 식각공정시 Cl2, BCl3 등과 같은 chlorine 을 포함한 가스를 이용하여 왔으나 식각 후 sidewall에서 발생하는 부식과 식각 선택비 확보의 어려움 등으로 마스크 물질에 제약을 받고 소자 특성이 감소하게 되는 등의 문제가 있다. 따라서 이러한 식각 문제점을 해결하기 위한 대안으로 noncorrosive 가스인 CO/NH3, CH3OH, CH4 등을 이용한 MTJ 식각 연구가 진행되어 오고 있으며 이중 CO/NH3 혼합가스는 부식성이 없고 hard mask와의 높은 선택비를 가지는 기체로 CO gas에 NH3 gas를 첨가하게 되면 etch rate이 증가하는 특성을 보인다. 또한 rf pulse-biased power를 이용하여 이온의 입사를 시간에 따라 제어함으로써 pulse off time 때 etch gas와 MTJ 물질간의 chemical reaction을 향상시킬 수 있다. 따라서 본 연구에서는 CO/NH3 혼합가스를 이용하여 다양한 rf pulse-biased power 조건에서 MTJ 물질인 CoFeB, MgO와 hard mask 물질인 W을 식각 한 뒤 식각특성을 분석하였으며 MTJ surface의 chemical binding state, surface roughness 측정을 진행하였다. 식각 샘플의 측정은 Alpha step profiler, XPS (X-ray Photoelectron Spectroscopy), AFM (Atomic Force Microscopy)를 통해 진행되었다. Time-averaged pulse bias에서는 duty ratio가 감소할수록 etch rate의 큰 감소 없이 CoFeB/W, MgO/W 물질의 etch selectivity가 향상됨을 확인할 수 있었으며 pulse off time 구간에서의 chemical reaction 향상으로 인해 식각부산물의 재증착이 감소하고 CoFeB의 surface roughness가 감소하는 것을 확인하였다.

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Concrete Shear Strength of Light Weight Concrete Beams Reinforced with GFRP bar (GFRP bar 경량콘크리트 보의 콘크리트 전단강도)

  • Jin, Min-Ho;Jang, Hee-Suk;Kim, Chung-Ho;Baek, Dong-Il
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.177-180
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    • 2008
  • Recently, the research of FRP bar as an alternative reinforcing material in reinforced concrete structures has increased to get an innovative solution to the corrosion problem. In addition to the noncorrosive nature of FRP materials, they also have a high strength-to-weight ratio. Therefore, when light weight concrete reinforced with FRP bar is used in marine environment, for instance floating structures, some advantages can be expected. But researches for the light weight concrete structure using FRP bar as a flexural reinforcement are limited to date. In this paper, the concrete shear contribution of the light weight concrete beam reinforced with GFRP bar was studied. Experiment for beams varying concrete compressive strengths and flexural reinforcement ratios was conducted and analysed. The test results showed that 75% of values obtained from proposed equation in preceding research were well agreed with the test results and were better results than the one predicted by the ACI 440.1R-06 code.

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Behaviour of One-Way Concrete Slabs Reinforced with Fiber Reinforced Polymer (FRP) Bars (FRP 보강근을 주근으로 사용한 일방향 콘크리트 슬래브의 거동)

  • Seo, Dae-Won;Han, Byum-Seok;Shin, Sung-Woo
    • Journal of the Korea Concrete Institute
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    • v.19 no.6
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    • pp.763-771
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    • 2007
  • Over the last few decades, many researches have been conducted in order to find solution to the problem of corrosion in steel reinforced concrete. As a result, methods such as the use of stainless steel bars, epoxy coatings, and concrete additives, etc., have been tried. While effective in some situations, such remedies may still be unable to completely eliminate the problems of steel corrosion. Fiber reinforced polymer (FRP) elements are appealing as reinforcement due to some material properties such as high tensile strength, low density, and noncorrosive. However, due to the generally lower modulus of elasticity of FRP in comparison with the steel and the linear behavior of FRP, certain aspects of the structural behavior of RC members reinforced with FRP may be substantially different from similar elements reinforced with steel reinforcement. This paper presents the flexural behavior of one-way concrete slabs reinforced with FRP bars. They were simply supported and tested in the laboratory under static loading conditions to investigate their crack pattern and width, deflections, strains and mode of failure. The experimental results shows that behavior of the FRP reinforced slabs was bilinearly elastic until failure. Also, the results show that the FRP overreinforced concrete beams in this study can be safe for design in terms of deformability.